BRPI0416081A - processo para a operação a longo prazo de uma oxidação parcial em fase gasosa heterogeneamente catalisada de acroleìna a ácido acrìlico - Google Patents

processo para a operação a longo prazo de uma oxidação parcial em fase gasosa heterogeneamente catalisada de acroleìna a ácido acrìlico

Info

Publication number
BRPI0416081A
BRPI0416081A BRPI0416081-9A BRPI0416081A BRPI0416081A BR PI0416081 A BRPI0416081 A BR PI0416081A BR PI0416081 A BRPI0416081 A BR PI0416081A BR PI0416081 A BRPI0416081 A BR PI0416081A
Authority
BR
Brazil
Prior art keywords
long
acrylic acid
gas phase
term operation
acrolein
Prior art date
Application number
BRPI0416081-9A
Other languages
English (en)
Inventor
Martin Dieterle
Jochen Petzoldt
Klaus Joachim Mueller-Engel
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE2003150822 external-priority patent/DE10350822A1/de
Application filed by Basf Ag filed Critical Basf Ag
Publication of BRPI0416081A publication Critical patent/BRPI0416081A/pt
Publication of BRPI0416081B1 publication Critical patent/BRPI0416081B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/50—Constitutive chemical elements of heterogeneous catalysts of Group V (VA or VB) of the Periodic Table
    • B01J2523/55—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/60—Constitutive chemical elements of heterogeneous catalysts of Group VI (VIA or VIB) of the Periodic Table
    • B01J2523/68—Molybdenum

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"PROCESSO PARA A OPERAçãO A LONGO PRAZO DE UMA OXIDAçãO PARCIAL EM FASE GASOSA HETEROGENEAMENTE CATALISADA DE ACROLEìNA A áCIDO ACRìLICO". A invenção refere-se à operação a longo prazo de uma oxidação parcial em fase gasosa heterogeneamente catalisada de acroleína, de modo a formar ácido acrílico. A temperatura do catalisador de leito sólido aumenta ao longo do tempo, e a oxidação parcial é interrompida e um gás contendo oxigênio é passado através do catalisador de leito sólido, antes que a temperatura alcance a 8<198>C.
BRPI0416081-9A 2003-10-29 2004-10-08 Processo para a operação a longo prazo de uma oxidação parcial em fase gasosa heterogeneamente catalisada de acroleína a ácido acrílico BRPI0416081B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US51491803P 2003-10-29 2003-10-29
DE2003150822 DE10350822A1 (de) 2003-10-29 2003-10-29 Verfahren zum Langzeitbetrieb einer heterogen katalysierten Gasphasenpartialoxidation von Acrolein zu Acrylsäure
DE10350822.8 2003-10-29
US60/514918 2003-10-29
PCT/EP2004/011259 WO2005047226A1 (de) 2003-10-29 2004-10-08 Verfahren zum langzeitbetrieb einer heterogen katalysierten gasphasenpartialoxidation von acrolein zu acrylsäure

Publications (2)

Publication Number Publication Date
BRPI0416081A true BRPI0416081A (pt) 2007-01-02
BRPI0416081B1 BRPI0416081B1 (pt) 2014-08-19

Family

ID=34593353

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0416081-9A BRPI0416081B1 (pt) 2003-10-29 2004-10-08 Processo para a operação a longo prazo de uma oxidação parcial em fase gasosa heterogeneamente catalisada de acroleína a ácido acrílico

Country Status (11)

Country Link
US (1) US7022877B2 (pt)
EP (1) EP1682477B1 (pt)
JP (1) JP4611311B2 (pt)
KR (1) KR101096355B1 (pt)
CN (1) CN100543005C (pt)
BR (1) BRPI0416081B1 (pt)
MY (1) MY139360A (pt)
RU (1) RU2365577C2 (pt)
TW (1) TWI332496B (pt)
WO (1) WO2005047226A1 (pt)
ZA (1) ZA200604227B (pt)

Families Citing this family (47)

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US7589046B2 (en) * 2003-06-04 2009-09-15 Basf Aktiengesellschaft Thermal treatment of the precursor material of a catalytically active material
DE102004025445A1 (de) * 2004-05-19 2005-02-10 Basf Ag Verfahren zum Langzeitbetrieb einer heterogen katalysierten Gasphasenpartialoxidation wenigstens einer organischen Verbindung
US7439389B2 (en) 2005-03-01 2008-10-21 Basf Aktiengesellschaft Process for preparing at least one organic target compound by heterogeneously catalyzed gas phase partial oxidation
DE102006000996A1 (de) 2006-01-05 2007-07-12 Basf Ag Verfahren der heterogen katalysierten Gasphasen-Partialoxidation wenigstens einer organischen Ausgangsverbindung
EP1734030A1 (de) * 2006-01-18 2006-12-20 BASF Aktiengesellschaft Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation einer organischen Ausgangsverbindung
DE102007055086A1 (de) 2007-11-16 2009-05-20 Basf Se Verfahren zur Herstellung von Acrylsäure
DE102007004960A1 (de) 2007-01-26 2008-07-31 Basf Se Verfahren zur Herstellung von Acrylsäure
DE102007006647A1 (de) * 2007-02-06 2008-08-07 Basf Se Verfahren zur Regenerierung eines im Rahmen einer heterogen katalysierten partiellen Dehydrierung eines Kohlenwasserstoffs deaktivierten Katalysatorbetts
DE102007010422A1 (de) * 2007-03-01 2008-09-04 Basf Se Verfahren zur Herstellung eines Katalysators bestehend aus einem Trägerkörper und einer auf der Oberfläche des Trägerkörpers aufgebrachten katalytisch aktiven Masse
DE102007019597A1 (de) * 2007-04-24 2008-05-15 Basf Ag Verfahren der Inbetriebnahme einer heterogen katalysierten partiellen Gasphasenoxidation von Acrolein zu Acrylsäure oder von Methacrolein zu Methacrylsäure
TW200948474A (en) 2008-04-09 2009-12-01 Basf Se Coated catalysts comprising a multimetal oxide comprising molybdenum
JP5501221B2 (ja) 2008-04-09 2014-05-21 株式会社日本触媒 アクロレインおよび／またはアクリル酸の製造方法
CN102112429B (zh) 2008-07-28 2015-09-16 巴斯夫欧洲公司 从丙烯酸c3前体化合物的气态产物混合物中分离作为主成份含有的丙烯酸和作为副产物含有的乙二醛的方法
DE102008041573A1 (de) 2008-08-26 2010-03-04 Basf Se Verfahren zur Auftrennung von in einem Produktgasgemisch einer partiellen heterogen katalysierten Gasphasenoxidation einer C3-Vorläuferverbindung der Acrylsäure als Hauptbestandteil enhaltener Acrylsäure und als Nebenprodukt enthaltenem Glyoxal
DE102008040799A1 (de) 2008-07-28 2008-12-11 Basf Se Verfahren zur Auftrennung von in einem Produktgasgemisch einer partiellen heterogen katalysierten Gasphasenoxidation einer C3-Vorläuferverbindung der Acrylsäure als Hauptbestandteil enthaltener Acrylsäure und als Nebenprodukt enthaltenem Glyoxal
WO2010038677A1 (ja) * 2008-09-30 2010-04-08 株式会社日本触媒 アクロレインおよび／またはアクリル酸製造用の触媒および該触媒を用いたアクロレインおよび／またはアクリル酸の製造方法
EP2347823B1 (en) * 2008-09-30 2016-08-31 Nippon Shokubai Co., Ltd. Catalyst for producing acrylic acid and process for producing acrylic acid using the catalyst
DE102009027401A1 (de) 2009-07-01 2010-02-18 Basf Se Verfahren der Abtrennung von Acrylsäure aus dem Produktgasgemisch einer heterogen katalysierten partiellen Gasphasenoxidation wenigstens einer C3-Vorläuferverbindung
DE102010001228A1 (de) 2010-01-26 2011-02-17 Basf Se Verfahren der Abtrennung von Acrylsäure aus dem Produktgasgemisch einer heterogen katalysierten partiellen Gasphasenoxidation wenigstens einer C3-Vorläuferverbindung
WO2011000808A2 (de) 2009-07-01 2011-01-06 Basf Se Verfahren der abtrennung von acrylsäure aus dem produktgasgemisch einer heterogen katalysierten partiellen gasphasenoxidation wenigstens einer c3-vorläuferverbindung
CN102040505B (zh) * 2009-10-13 2014-04-23 中国石油化工股份有限公司 由不饱和醛氧化制不饱和酸的方法
DE102010042216A1 (de) 2010-10-08 2011-06-09 Basf Se Verfahren zur Hemmung der unerwünschten radikalischen Polymerisation von in einer flüssigen Phase P befindlicher Acrylsäure
DE102012207811A1 (de) 2012-05-10 2012-07-12 Basf Se Verfahren der heterogen katalysierten Gasphasenpartialoxidation von (Meth)acrolein zu (Meth)acrylsäure
US9399606B2 (en) 2012-12-06 2016-07-26 Basf Se Catalyst and process for the oxidative dehydrogenation of N-butenes to butadiene
EA201591040A1 (ru) 2012-12-06 2015-11-30 Басф Се Способ окислительного дегидрирования н-бутенов в бутадиен
US10144681B2 (en) 2013-01-15 2018-12-04 Basf Se Process for the oxidative dehydrogenation of N-butenes to butadiene
DE102013202048A1 (de) 2013-02-07 2013-04-18 Basf Se Verfahren zur Herstellung einer katalytisch aktiven Masse, die ein Gemisch aus einem die Elemente Mo und V enthaltenden Multielementoxid und wenigstens einem Oxid des Molybdäns ist
US20160122264A1 (en) * 2013-06-17 2016-05-05 Basf Se Method for the oxidative dehydration of n-butenes into 1,3-butadien
EP3019458B1 (de) 2013-07-10 2017-04-05 Basf Se Verfahren zur oxidativen dehydrierung von n-butenen zu butadien
WO2015007839A1 (de) * 2013-07-18 2015-01-22 Basf Se Verfahren zur oxidativen dehydrierung von n-butenen zu 1,3-butadien
JP2015120133A (ja) * 2013-12-25 2015-07-02 株式会社日本触媒 アクリル酸製造用の触媒および該触媒を用いたアクリル酸の製造方法
US9776940B2 (en) 2015-08-07 2017-10-03 Basf Se Process for production of acrylic acid
CN109305905B (zh) * 2017-07-28 2021-06-18 中国石油化工股份有限公司 丙烯酸合成的方法
KR102893876B1 (ko) 2018-07-26 2025-12-03 바스프 에스이 액상 p 중 존재하는 아크릴산의 원치않는 라디칼 중합의 억제 방법
EP3770145A1 (en) 2019-07-24 2021-01-27 Basf Se A process for the continuous production of either acrolein or acrylic acid as the target product from propene
CN115335354A (zh) 2020-03-26 2022-11-11 巴斯夫欧洲公司 抑制存在于液相p中的丙烯酸的不期望的自由基聚合的方法
KR20230002897A (ko) 2020-04-21 2023-01-05 바스프 에스이 원소 Mo, W, V 및 Cu를 함유하는 촉매 활성 다원소 산화물의 제조 방법
CN116490275A (zh) 2020-10-29 2023-07-25 巴斯夫欧洲公司 制备核壳催化剂的方法
JP2025541831A (ja) 2022-12-07 2025-12-23 ベーアーエスエフ・エスエー 元素Ｍｏ、Ｗ、Ｖ、Ｃｕ、およびＳｂを含有する触媒活性多元素酸化物を製造するための方法
WO2025125092A1 (de) 2023-12-14 2025-06-19 Basf Se Verfahren zur herstellung eines die elemente mo, w, v, cu und sb enthaltenden katalytisch aktiven multielementoxids
WO2025172146A1 (de) 2024-02-15 2025-08-21 Basf Se Verfahren zur herstellung von acrylsäure
WO2025219135A1 (en) 2024-04-17 2025-10-23 Basf Se Process for utilizing high calorific acrylic acid production waste streams
WO2025219137A1 (en) 2024-04-17 2025-10-23 Basf Se Process for utilizing acrylic acid production waste streams by gasification and fermentation
WO2025219136A1 (en) 2024-04-17 2025-10-23 Basf Se Process for utilizing acrylic acid production waste streams
WO2026017456A1 (de) 2024-07-15 2026-01-22 Basf Se Verfahren zur herstellung eines katalysators umfassend eine wasserbehandlung
WO2026032892A1 (de) 2024-08-05 2026-02-12 Basf Se Verfahren zur herstellung von (meth)acrylsäurealkylester ausgehend von (meth)acrylsäure
WO2026032891A1 (de) 2024-08-05 2026-02-12 Basf Se Verfahren zur abtrennung von (meth)acrylsäure

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JP3562983B2 (ja) * 1997-11-25 2004-09-08 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造方法
US6384274B1 (en) 1998-09-27 2002-05-07 Rohm And Haas Company Single reactor process for preparing acrylic acid from propylene having improved capacity
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JP2004228273A (ja) 2003-01-22 2004-08-12 Renesas Technology Corp 半導体装置

Also Published As

Publication number Publication date
TWI332496B (en) 2010-11-01
WO2005047226A1 (de) 2005-05-26
EP1682477B1 (de) 2016-04-13
TW200533649A (en) 2005-10-16
RU2006118149A (ru) 2007-12-10
ZA200604227B (en) 2007-09-26
EP1682477A1 (de) 2006-07-26
CN1874985A (zh) 2006-12-06
BRPI0416081B1 (pt) 2014-08-19
MY139360A (en) 2009-09-30
JP4611311B2 (ja) 2011-01-12
RU2365577C2 (ru) 2009-08-27
CN100543005C (zh) 2009-09-23
JP2007509864A (ja) 2007-04-19
KR101096355B1 (ko) 2011-12-20
KR20060109876A (ko) 2006-10-23
US7022877B2 (en) 2006-04-04
US20050096483A1 (en) 2005-05-05

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