BRPI0408650A - processo para oxidar parcialmente propeno a acroleìna em fase gasosa - Google Patents
processo para oxidar parcialmente propeno a acroleìna em fase gasosaInfo
- Publication number
- BRPI0408650A BRPI0408650A BRPI0408650-3A BRPI0408650A BRPI0408650A BR PI0408650 A BRPI0408650 A BR PI0408650A BR PI0408650 A BRPI0408650 A BR PI0408650A BR PI0408650 A BRPI0408650 A BR PI0408650A
- Authority
- BR
- Brazil
- Prior art keywords
- gas phase
- acrolein
- catalyst bed
- fixed catalyst
- partially oxidizing
- Prior art date
Links
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 3
- 230000001590 oxidative effect Effects 0.000 title abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title abstract 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 3
- 230000007704 transition Effects 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 239000012495 reaction gas Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/58—Preparation of carboxylic acid halides
- C07C51/64—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
- C07C57/04—Acrylic acid; Methacrylic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
"PROCESSO PARA OXIDAR PARCIALMENTE PROPENO A ACROLEìNA EM FASE GASOSA". é exposto um método para a oxidação em fase gasosa parcial heterogeneamente catalisada de propeno a acroleína, de acordo com a qual a mistura do gás de reação inicial é oxidada em um leito de catalisador fixo, que compreende pelo menos duas zonas de leito de catalisador fixo e é acomodado em duas zonas de temperatura sucessivas A, B, a transição da zona de temperatura A para a zona de temperatura B não coincidindo com uma transição de uma zona de leito de catalisador fixo para outra.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2003113210 DE10313210A1 (de) | 2003-03-25 | 2003-03-25 | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrolein |
| US47579503P | 2003-06-05 | 2003-06-05 | |
| PCT/EP2004/002932 WO2004085362A1 (de) | 2003-03-25 | 2004-03-20 | Verfahren der heterogen katalysierten partiellen gasphasenoxidation von propen zu acrolein |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0408650A true BRPI0408650A (pt) | 2006-03-07 |
| BRPI0408650B1 BRPI0408650B1 (pt) | 2013-07-09 |
Family
ID=33099279
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0408650-3B1A BRPI0408650B1 (pt) | 2003-03-25 | 2004-03-20 | processo para oxidar parcialmente propeno a acroleÍna em fase gasosa |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7211691B2 (pt) |
| EP (1) | EP1611073B1 (pt) |
| JP (1) | JP4504355B2 (pt) |
| KR (1) | KR101065106B1 (pt) |
| CN (1) | CN100519500C (pt) |
| BR (1) | BRPI0408650B1 (pt) |
| MY (1) | MY136659A (pt) |
| TW (1) | TWI311131B (pt) |
| WO (1) | WO2004085362A1 (pt) |
| ZA (1) | ZA200508598B (pt) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI311131B (en) | 2003-03-25 | 2009-06-21 | Basf Ag | Heterogeneously catalyzed partial gas phase oxidation of propene to acrolein |
| WO2004085365A2 (de) * | 2003-03-25 | 2004-10-07 | Basf Aktiengesellschaft | Verfahren der heterogen katalysierten partiellen gasphasenoxidation von acrolein zu acrylsäure |
| DE10313214A1 (de) * | 2003-03-25 | 2004-10-07 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Acrolein zu Acrylsäure |
| DE10313212A1 (de) * | 2003-03-25 | 2004-10-07 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrolein |
| KR101013249B1 (ko) * | 2003-03-25 | 2011-02-09 | 바스프 에스이 | 아크릴산을 형성하기 위한 프로펜의 불균질 촉매화 부분기체상 산화 방법 |
| BRPI0413297B1 (pt) | 2003-08-06 | 2014-01-21 | Processo para operar uma oxidação parcial contínua em fase gasosa catalisada de maneira heterogênea de pelo menos um composto orgânico | |
| US7592483B2 (en) * | 2004-07-01 | 2009-09-22 | Basf Aktiengesellschaft | Preparation of acrolein or acrylic acid or a mixture thereof by heterogeneously catalyzed partial gas phase oxidation of propylene |
| EP1734030A1 (de) * | 2006-01-18 | 2006-12-20 | BASF Aktiengesellschaft | Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation einer organischen Ausgangsverbindung |
| WO2008058918A1 (de) * | 2006-11-15 | 2008-05-22 | Basf Se | Verfahren zum betreiben einer exothermen heterogen katalysierten partiellen gasphasenoxidation einer organischen ausgangsverbindung zu einer organischen zielverbindung |
| DE102010048405A1 (de) | 2010-10-15 | 2011-05-19 | Basf Se | Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation von Proben zu Acrolein |
| DE102011076931A1 (de) | 2011-06-03 | 2012-12-06 | Basf Se | Wässrige Lösung, enthaltend Acrylsäure und deren konjugierte Base |
| EP3476471A1 (de) * | 2017-10-25 | 2019-05-01 | Linde Aktiengesellschaft | Verfahren und reaktor zur bildung und zur katalytischen umsetzung eines eduktgemischs |
| EP3770145A1 (en) | 2019-07-24 | 2021-01-27 | Basf Se | A process for the continuous production of either acrolein or acrylic acid as the target product from propene |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19948248A1 (de) | 1999-10-07 | 2001-04-12 | Basf Ag | Verfahren der katalytischen Gasphasenoxidation von Propen zu Acrylsäure |
| DE19910506A1 (de) | 1999-03-10 | 2000-09-14 | Basf Ag | Verfahren der katalytischen Gasphasenoxidation von Propen zu Acrolein |
| MY121878A (en) * | 1999-03-10 | 2006-02-28 | Basf Ag | Method for the catalytic gas-phase oxidation of propene into acrylic acid |
| MY119958A (en) * | 1999-03-10 | 2005-08-30 | Basf Ag | Catalytic gas-phase oxidation of propene to acrylic acid |
| DE19948523A1 (de) | 1999-10-08 | 2001-04-12 | Basf Ag | Verfahren der katalytischen Gasphasenoxidation von Propen zu Acrylsäure |
| DE19948241A1 (de) | 1999-10-07 | 2001-04-12 | Basf Ag | Verfahren der katalytischen Gasphasenoxidation von Propen zu Acrolein |
| MY121141A (en) * | 1999-03-10 | 2005-12-30 | Basf Ag | Method for the catalytic gas-phase oxidation of propene into acrolein |
| DE19927624A1 (de) | 1999-06-17 | 2000-12-21 | Basf Ag | Verfahren der katalytischen Gasphasenoxidation von Propen zu Acrylsäure |
| JP3732080B2 (ja) * | 1999-08-31 | 2006-01-05 | 株式会社日本触媒 | 接触気相酸化反応器 |
| JP2001137688A (ja) * | 1999-08-31 | 2001-05-22 | Nippon Shokubai Co Ltd | 多管式反応器 |
| DE19955168A1 (de) | 1999-11-16 | 2001-05-17 | Basf Ag | Verfahren der katalytischen Gasphasenoxidation von Propen zu Acrylsäure |
| US6620968B1 (en) | 1999-11-23 | 2003-09-16 | Rohm And Haas Company | High hydrocarbon space velocity process for preparing unsaturated aldehydes and acids |
| TWI311131B (en) | 2003-03-25 | 2009-06-21 | Basf Ag | Heterogeneously catalyzed partial gas phase oxidation of propene to acrolein |
| DE10313212A1 (de) | 2003-03-25 | 2004-10-07 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrolein |
| KR101013249B1 (ko) | 2003-03-25 | 2011-02-09 | 바스프 에스이 | 아크릴산을 형성하기 위한 프로펜의 불균질 촉매화 부분기체상 산화 방법 |
| DE10313208A1 (de) | 2003-03-25 | 2004-10-07 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrylsäure |
| WO2004085365A2 (de) | 2003-03-25 | 2004-10-07 | Basf Aktiengesellschaft | Verfahren der heterogen katalysierten partiellen gasphasenoxidation von acrolein zu acrylsäure |
-
2004
- 2004-02-19 TW TW093104128A patent/TWI311131B/zh not_active IP Right Cessation
- 2004-02-20 MY MYPI20040570A patent/MY136659A/en unknown
- 2004-02-24 US US10/784,825 patent/US7211691B2/en not_active Expired - Lifetime
- 2004-03-20 CN CNB2004800080922A patent/CN100519500C/zh not_active Expired - Lifetime
- 2004-03-20 WO PCT/EP2004/002932 patent/WO2004085362A1/de not_active Ceased
- 2004-03-20 BR BRPI0408650-3B1A patent/BRPI0408650B1/pt not_active IP Right Cessation
- 2004-03-20 JP JP2006504765A patent/JP4504355B2/ja not_active Expired - Lifetime
- 2004-03-20 KR KR1020057017976A patent/KR101065106B1/ko not_active Expired - Lifetime
- 2004-03-20 EP EP04722151A patent/EP1611073B1/de not_active Expired - Lifetime
-
2005
- 2005-10-24 ZA ZA2005/08598A patent/ZA200508598B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2006521315A (ja) | 2006-09-21 |
| TW200424163A (en) | 2004-11-16 |
| TWI311131B (en) | 2009-06-21 |
| JP4504355B2 (ja) | 2010-07-14 |
| ZA200508598B (en) | 2006-12-27 |
| KR101065106B1 (ko) | 2011-09-16 |
| US20040192964A1 (en) | 2004-09-30 |
| BRPI0408650B1 (pt) | 2013-07-09 |
| CN1764625A (zh) | 2006-04-26 |
| US7211691B2 (en) | 2007-05-01 |
| CN100519500C (zh) | 2009-07-29 |
| WO2004085362A1 (de) | 2004-10-07 |
| MY136659A (en) | 2008-11-28 |
| KR20050121216A (ko) | 2005-12-26 |
| EP1611073A1 (de) | 2006-01-04 |
| EP1611073B1 (de) | 2012-08-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 20/03/2004, OBSERVADAS AS CONDICOES LEGAIS. |
|
| B25D | Requested change of name of applicant approved | ||
| B21A | Patent or certificate of addition expired [chapter 21.1 patent gazette] |
Free format text: PATENTE EXTINTA EM 20/03/2024 |