BRPI0417912A - método para produzir um revestimento de óxido de ferro sobre um artigo de vidro em um processo on-line de "float glass" à pressão atmosférica, e artigo de vidro revestido - Google Patents
método para produzir um revestimento de óxido de ferro sobre um artigo de vidro em um processo on-line de "float glass" à pressão atmosférica, e artigo de vidro revestidoInfo
- Publication number
- BRPI0417912A BRPI0417912A BRPI0417912-9A BRPI0417912A BRPI0417912A BR PI0417912 A BRPI0417912 A BR PI0417912A BR PI0417912 A BRPI0417912 A BR PI0417912A BR PI0417912 A BRPI0417912 A BR PI0417912A
- Authority
- BR
- Brazil
- Prior art keywords
- glass article
- iron oxide
- oxide coating
- producing
- atmospheric pressure
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/366—Low-emissivity or solar control coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/245—Oxides by deposition from the vapour phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
- C03C17/3417—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials all coatings being oxide coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/217—FeOx, CoOx, NiOx
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/152—Deposition methods from the vapour phase by cvd
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
- Chemical Vapour Deposition (AREA)
- Laminated Bodies (AREA)
- Physical Vapour Deposition (AREA)
Abstract
"MéTODO PARA PRODUZIR UM REVESTIMENTO DE óXIDO DE FERRO SOBRE UM ARTIGO DE VIDRO EM UM PROCESSO ON-LINE DE 'FLOAT GLASS' A PRESSãO ATMOSFéRICA, E ARTIGO DE VIDRO REVESTIDO". é definido um método para produzir um revestimento de óxido de ferro sobre um artigo de vidro. O artigo é preferivelmente para uso como um envidraçamento para uso arquitetónico. O método inclui proporcionar um substrato de vidro aquecido possuindo uma superfície sobre a qual o revestimento é para ser depositado. Ferroceno e um oxidante são dirigidos na direção e ao longo da superfície a ser revestida, e o ferroceno e o oxidante são reagidos na ou próximo da superfície do substrato de vidro para formar um revestimento de óxido de ferro.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/765,256 US7939129B2 (en) | 2004-01-26 | 2004-01-26 | Deposition of iron oxide coatings on a glass substrate |
| PCT/US2004/041061 WO2005075370A1 (en) | 2004-01-26 | 2004-12-09 | Deposition of iron oxide coatings on a glass substrate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0417912A true BRPI0417912A (pt) | 2007-04-10 |
Family
ID=34795440
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0417912-9A BRPI0417912A (pt) | 2004-01-26 | 2004-12-09 | método para produzir um revestimento de óxido de ferro sobre um artigo de vidro em um processo on-line de "float glass" à pressão atmosférica, e artigo de vidro revestido |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US7939129B2 (pt) |
| EP (1) | EP1708972B1 (pt) |
| JP (3) | JP5188712B2 (pt) |
| KR (1) | KR20060127085A (pt) |
| CN (1) | CN1906135B (pt) |
| AT (1) | ATE488477T1 (pt) |
| BR (1) | BRPI0417912A (pt) |
| DE (1) | DE602004030157D1 (pt) |
| ES (1) | ES2354886T3 (pt) |
| RU (1) | RU2006130864A (pt) |
| TW (1) | TW200530423A (pt) |
| WO (1) | WO2005075370A1 (pt) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7670694B2 (en) | 2006-12-22 | 2010-03-02 | Hitachi Global Storage Technologies Netherlands B.V. | Media for recording devices |
| ITPD20110285A1 (it) | 2011-09-08 | 2013-03-09 | Univ Padova | Metodo per preparare nanomateriali supportati a base di ossido di ferro (iii) con tecnica cvd e metodo di sintesi di fe(hfa)2tmeda |
| US8955357B2 (en) * | 2013-03-15 | 2015-02-17 | Lighting Science Group Corporation | System and methods of embedding material in a glass substrate |
| US9738971B2 (en) * | 2015-12-31 | 2017-08-22 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Vapor deposition methods to form group 8-containing films |
Family Cites Families (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3695908A (en) * | 1970-06-29 | 1972-10-03 | Raymond E Szupillo | Thin films of alpha fe2o3 and method of forming |
| DE2047813B2 (de) | 1970-09-29 | 1971-10-07 | Battelle Institut e V , 6000 Frank fürt | Verfahren zur abscheidung von ueberzuegen |
| US3892888A (en) * | 1971-06-09 | 1975-07-01 | Corning Glass Works | Method of making a magnetic recording and storage device |
| US3996395A (en) * | 1972-05-26 | 1976-12-07 | Corning Glass Works | Method of increasing the coercivity of magnetite films |
| US3852098A (en) * | 1972-12-15 | 1974-12-03 | Ppg Industries Inc | Method for increasing rate of coating using vaporized reactants |
| US3920454A (en) * | 1973-05-09 | 1975-11-18 | Bell Telephone Labor Inc | Fabrication of iron oxide pattern |
| US4027056A (en) * | 1973-05-09 | 1977-05-31 | Bell Telephone Laboratories, Incorporated | Fabrication of an iron oxide film |
| US4217392A (en) * | 1979-06-18 | 1980-08-12 | Ford Motor Company | Coated glass article |
| JPH0627329B2 (ja) * | 1984-02-13 | 1994-04-13 | シュミット,ジェロウム・ジェイ・ザ・サ−ド | 導電および誘電性固体薄膜のガスジェット付着方法および装置とそれによって製造される生産物 |
| US4717584A (en) * | 1985-02-07 | 1988-01-05 | Matsushita Electric Industrial Co., Ltd. | Method of manufacturing a magnetic thin film |
| US4975324A (en) * | 1986-10-21 | 1990-12-04 | Matsushita Electric Industrial Co., Ltd. | Perpendicular magnetic film of spinel type iron oxide compound and its manufacturing process |
| JPS63181305A (ja) * | 1987-01-22 | 1988-07-26 | Matsushita Electric Ind Co Ltd | 酸化鉄垂直磁化薄膜の製造方法 |
| US5006395A (en) * | 1987-05-12 | 1991-04-09 | Matsushita Electric Industrial Co., Ltd. | Iron carbide thin film magnetic recording medium |
| US5133805A (en) * | 1987-08-28 | 1992-07-28 | Toda Kogyo Corp. | Plate-like hematite particles, a pigment comprising the same and showing a golden color, and a process for producing the same |
| JPH02150040A (ja) * | 1988-11-30 | 1990-06-08 | Fujitsu Ltd | 気相成長装置 |
| JPH02254155A (ja) | 1989-03-27 | 1990-10-12 | Daido Steel Co Ltd | 赤色系装飾部品 |
| JP2547251B2 (ja) * | 1989-04-20 | 1996-10-23 | 日鉄鉱業株式会社 | 集塵機に用いるフイルタエレメントの製造方法 |
| US5686178A (en) * | 1989-12-11 | 1997-11-11 | Advanced Technology Materials, Inc. | Metal-coated substrate articles responsive to electromagnetic radiation, and method of making the same |
| EP0564709B1 (de) * | 1991-12-13 | 1996-01-24 | Balzers Aktiengesellschaft | Beschichtetes transparentes Substrat, Verwendung hiervon, Verfahren und Anlage zur Herstellung der Schichten, und Hafnium-Oxinitrid (HfOxNy) mit 1,5 x/y 3 und 2,6 n 2,8 |
| US5235936A (en) * | 1992-12-04 | 1993-08-17 | Kracklauer John J | Ferrocene injection system |
| US5780372A (en) * | 1996-02-21 | 1998-07-14 | Libbey-Owens-Ford Co. | Colored glass compositions |
| US5753371A (en) * | 1996-06-03 | 1998-05-19 | The Mearl Corporation | Pearlescent glass pigment |
| US6238738B1 (en) * | 1996-08-13 | 2001-05-29 | Libbey-Owens-Ford Co. | Method for depositing titanium oxide coatings on flat glass |
| DE69721054D1 (de) * | 1997-01-17 | 2003-05-22 | Nippon Sheet Glass Co Ltd | Wärmestrahlung reflektierendes glas |
| SG87798A1 (en) * | 1998-03-20 | 2002-04-16 | Toda Kogyo Corp | Magnetic recording medium and process for producing the same |
| JP2000119856A (ja) * | 1998-10-13 | 2000-04-25 | Central Glass Co Ltd | Cvd法による被膜形成法およびその装置 |
| JP2000281384A (ja) * | 1999-03-30 | 2000-10-10 | Asahi Glass Co Ltd | 着色膜形成用塗布液、着色膜、着色膜付きガラス物品とその製造方法 |
| US6274207B1 (en) * | 1999-05-21 | 2001-08-14 | The Board Of Regents, The University Of Texas System | Method of coating three dimensional objects with molecular sieves |
| US6037091A (en) * | 1999-08-30 | 2000-03-14 | Xerox Corporation | Carrier with ferrocene containing polymer |
| DE19951869A1 (de) * | 1999-10-28 | 2001-05-03 | Merck Patent Gmbh | Farbstarke Interferenzpigmente |
| DE19951871A1 (de) * | 1999-10-28 | 2001-05-03 | Merck Patent Gmbh | Farbstarke Interferenzpigmente |
| JP2001206736A (ja) * | 1999-11-19 | 2001-07-31 | Nippon Sheet Glass Co Ltd | 着色膜被覆ガラス物品の製造方法および着色膜被覆ガラス物品 |
| US20020136905A1 (en) * | 1999-11-24 | 2002-09-26 | Medwick Paul A. | Low shading coefficient and low emissivity coatings and coated articles |
| US20010039771A1 (en) * | 1999-12-13 | 2001-11-15 | Thinking Lightly, Inc. | Light dispersive insulated glazing unit |
| US6524647B1 (en) * | 2000-03-24 | 2003-02-25 | Pilkington Plc | Method of forming niobium doped tin oxide coatings on glass and coated glass formed thereby |
| EP1288174A4 (en) * | 2000-04-28 | 2005-06-08 | Asahi Glass Co Ltd | GLASS COATED GLASS AND METHOD OF MANUFACTURING THEREOF WITH A HEAT-FINISHING, COLORED FILM |
| US6821618B2 (en) * | 2000-12-22 | 2004-11-23 | Toda Kogyo Corporation | Magnetic recording medium and process for producing the same |
| US6783719B2 (en) * | 2001-01-19 | 2004-08-31 | Korry Electronics, Co. | Mold with metal oxide surface compatible with ionic release agents |
| JP2004210573A (ja) * | 2002-12-27 | 2004-07-29 | Mitsuboshi Belting Ltd | 酸化鉄膜付きガラスの製造方法 |
-
2004
- 2004-01-26 US US10/765,256 patent/US7939129B2/en not_active Expired - Lifetime
- 2004-12-09 ES ES04813386T patent/ES2354886T3/es not_active Expired - Lifetime
- 2004-12-09 JP JP2006551063A patent/JP5188712B2/ja not_active Expired - Lifetime
- 2004-12-09 CN CN2004800409376A patent/CN1906135B/zh not_active Expired - Lifetime
- 2004-12-09 BR BRPI0417912-9A patent/BRPI0417912A/pt not_active IP Right Cessation
- 2004-12-09 RU RU2006130864/03A patent/RU2006130864A/ru not_active Application Discontinuation
- 2004-12-09 KR KR1020067014978A patent/KR20060127085A/ko not_active Withdrawn
- 2004-12-09 EP EP04813386A patent/EP1708972B1/en not_active Expired - Lifetime
- 2004-12-09 DE DE602004030157T patent/DE602004030157D1/de not_active Expired - Lifetime
- 2004-12-09 AT AT04813386T patent/ATE488477T1/de not_active IP Right Cessation
- 2004-12-09 WO PCT/US2004/041061 patent/WO2005075370A1/en not_active Ceased
- 2004-12-17 TW TW093139474A patent/TW200530423A/zh unknown
-
2011
- 2011-04-04 US US13/079,129 patent/US8465841B2/en not_active Expired - Fee Related
- 2011-11-04 JP JP2011242277A patent/JP2012020936A/ja active Pending
- 2011-11-04 JP JP2011242278A patent/JP2012020937A/ja not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| ATE488477T1 (de) | 2010-12-15 |
| KR20060127085A (ko) | 2006-12-11 |
| JP2012020936A (ja) | 2012-02-02 |
| EP1708972B1 (en) | 2010-11-17 |
| TW200530423A (en) | 2005-09-16 |
| EP1708972A1 (en) | 2006-10-11 |
| JP2007518663A (ja) | 2007-07-12 |
| RU2006130864A (ru) | 2008-03-10 |
| US20110281109A1 (en) | 2011-11-17 |
| JP5188712B2 (ja) | 2013-04-24 |
| US7939129B2 (en) | 2011-05-10 |
| CN1906135A (zh) | 2007-01-31 |
| ES2354886T3 (es) | 2011-03-18 |
| US20050164011A1 (en) | 2005-07-28 |
| US8465841B2 (en) | 2013-06-18 |
| DE602004030157D1 (de) | 2010-12-30 |
| CN1906135B (zh) | 2011-09-21 |
| WO2005075370A1 (en) | 2005-08-18 |
| JP2012020937A (ja) | 2012-02-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 6A E 7A ANUIDADE(S). |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2173 DE 28/08/2012. |