BRPI0418062A - processo para a produção de biodiesel a partir de óleo renovável na presença de catálise por lipase em um sistema de reação em meio orgánico - Google Patents

processo para a produção de biodiesel a partir de óleo renovável na presença de catálise por lipase em um sistema de reação em meio orgánico

Info

Publication number
BRPI0418062A
BRPI0418062A BRPI0418062-3A BRPI0418062A BRPI0418062A BR PI0418062 A BRPI0418062 A BR PI0418062A BR PI0418062 A BRPI0418062 A BR PI0418062A BR PI0418062 A BRPI0418062 A BR PI0418062A
Authority
BR
Brazil
Prior art keywords
biodiesel
renewable oil
lipase
production
reaction system
Prior art date
Application number
BRPI0418062-3A
Other languages
English (en)
Inventor
Wei Du
Dehua Liu
Lilin Li
Yuanyuan Xu
Li Wang
Original Assignee
Univ Tsinghua
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Tsinghua filed Critical Univ Tsinghua
Publication of BRPI0418062A publication Critical patent/BRPI0418062A/pt
Publication of BRPI0418062B1 publication Critical patent/BRPI0418062B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/64—Fats; Fatty oils; Ester-type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
    • C12P7/6436—Fatty acid esters
    • C12P7/649—Biodiesel, i.e. fatty acid alkyl esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/62—Carboxylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/64—Fats; Fatty oils; Ester-type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
    • C12P7/6436—Fatty acid esters
    • C12P7/6445—Glycerides
    • C12P7/6458—Glycerides by transesterification, e.g. interesterification, ester interchange, alcoholysis or acidolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Zoology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Microbiology (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Biotechnology (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Fats And Perfumes (AREA)
  • Apparatus Associated With Microorganisms And Enzymes (AREA)
  • Enzymes And Modification Thereof (AREA)

Abstract

"PROCESSO PARA A PRODUçãO DE BIODIESEL A PARTIR DE óLEO RENOVáVEL NA PRESENçA DE CATáLISE POR LIPASE EM UM SISTEMA DE REAçãO EM MEIO ORGáNICO". A presente invenção prove um novo processo para a produção de biodiesel a partir de óleo renovável na presença de catálise por lipase em um sistema de reação em meio orgânico. Nesse processo, é usado um álcool de cadeia curta ROH como um receptor de acila, sendo usado como meio de reação um solvente orgânico relativamente hidrofílico sem efeito negativo na reatividade da lipase, e matéria-prima de óleo renovável sendo catalisada por uma lipase para sintetizar o biodiesel por meio de uma reação de transesterificação. No processo da presente invenção, a material-prima de óleo renovável pode ser quase completamente convertida em biodiesel e um subproduto glicerina, e a produção do biodiesel é de 94% ou mais. Esse novo tipo de sistema de reação em meio orgânico promove a solubilidade do álcool de cadeia curta na matéria-prima do óleo renovável e dissolve parte do subproduto glicerina. Como conseqüência, o tempo de reação é reduzido, a produtividade do biodiesel aumenta e a reatividade e tempo de vida da lipase são aperfeiçoadas no processo da presente invenção.
BRPI0418062A 2004-01-16 2004-11-29 processo para a produção de biodiesel a partir de óleo renovável na presença de catálise por lipase em um sistema de reação em meio orgânico BRPI0418062B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CNB2004100006979A CN1238469C (zh) 2004-01-16 2004-01-16 有机介质反应体系中脂肪酶转化油脂生产生物柴油新工艺
PCT/CN2004/001372 WO2005075615A1 (en) 2004-01-16 2004-11-29 A new process for producing biodiesel from oils and fats catalyzed by lipase in organic medium reaction system

Publications (2)

Publication Number Publication Date
BRPI0418062A true BRPI0418062A (pt) 2007-04-17
BRPI0418062B1 BRPI0418062B1 (pt) 2016-06-28

Family

ID=34350467

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0418062A BRPI0418062B1 (pt) 2004-01-16 2004-11-29 processo para a produção de biodiesel a partir de óleo renovável na presença de catálise por lipase em um sistema de reação em meio orgânico

Country Status (8)

Country Link
US (1) US7550278B2 (pt)
EP (1) EP1705238B1 (pt)
CN (1) CN1238469C (pt)
AT (1) ATE446353T1 (pt)
BR (1) BRPI0418062B1 (pt)
CA (1) CA2553653C (pt)
DE (1) DE602004023761D1 (pt)
WO (1) WO2005075615A1 (pt)

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EP1838860B1 (en) * 2005-01-10 2011-03-23 Novozymes A/S Process for the production of fatty acid alkyl esters from triglycerides and alcohols employing a combination of two lipolytic enzymes
BRPI0520104A (pt) * 2005-02-17 2008-06-10 Fraunhofer Ges Forschung mistura de bio-combustìvel, e, processo e dispositivo para a preparação da mesma
CN100375781C (zh) * 2005-11-09 2008-03-19 中国科学院广州能源研究所 一种生产生物柴油的方法
CN100404643C (zh) * 2006-07-07 2008-07-23 清华大学 有机介质反应体系中微生物细胞转化油脂生产生物柴油的工艺
ES2289943B1 (es) * 2006-07-21 2008-12-16 Universidad De Cordoba Procedimiento de produccion de biodiesel mediante el uso de lipasa pancreatica de cerdo como biocatalizador enzimatico.
CN1928116B (zh) * 2006-08-25 2010-07-21 江南大学 一种非水相中脂肪酶合成酶活力的快速测定方法
CN100455656C (zh) * 2006-10-26 2009-01-28 中国农业科学院油料作物研究所 胞内分泌脂肪酶型全细胞催化剂的制备方法
CN104212844A (zh) * 2007-06-01 2014-12-17 索拉兹米公司 在微生物中生产油
US8617866B2 (en) 2007-11-28 2013-12-31 Sobhi Basheer Robust multi-enzyme preparation for the synthesis of fatty acid alkyl esters
US7790429B2 (en) 2007-11-28 2010-09-07 Transbiodiesel Ltd. Robust multi-enzyme preparation for the synthesis of fatty acid alkyl esters
CN101215233B (zh) * 2008-01-09 2012-05-23 江门市江海区嘉诺化工发展有限公司 脂肪酸甲酯生产工艺
KR100956414B1 (ko) 2008-02-25 2010-05-06 한국신발피혁연구소 플레싱 스크랩으로부터 바이오디젤의 제조방법
CN101235351B (zh) * 2008-02-27 2012-07-18 浙江大学 一种固定化酶膜反应器及其制备和用其生产生物柴油的方法
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CN101358216B (zh) * 2008-08-06 2011-11-09 清华大学 一种利用膜在线脱水的酶法制备生物柴油工艺
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CN101418322B (zh) * 2008-12-11 2011-09-14 清华大学 膜回收脂肪酶催化可再生油脂制备生物柴油的方法
JP5770178B2 (ja) * 2009-07-17 2015-08-26 コリア アドバンスド インスティチュート オブ サイエンス アンド テクノロジィ オイル生成能を有する微生物を用いた脂肪酸アルキルエステルの製造方法
KR20110035612A (ko) * 2009-09-30 2011-04-06 한국생산기술연구원 액체 이산화탄소 상태에서 효소적 바이오 디젤 제조방법
GB2478137A (en) * 2010-02-25 2011-08-31 Hycagen Ltd Biodiesel compositions
EP2576800B1 (en) 2010-05-28 2019-01-30 Corbion Biotech, Inc. Method for producing oils from Prototheca
CN101838670A (zh) * 2010-06-11 2010-09-22 贵州师范大学 制备生物柴油的方法
RU2440416C1 (ru) * 2010-09-28 2012-01-20 Федеральное Государственное Образовательное Учреждение Высшего Профессионального Образования "Саратовский Государственный Аграрный Университет Имени Н.И. Вавилова" Способ получения биодизельного топлива
AU2011323288B2 (en) 2010-11-03 2016-05-26 Corbion Biotech, Inc. Microbial oils with lowered pour points, dielectric fluids produced therefrom, and related methods
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US6398707B1 (en) * 2001-05-31 2002-06-04 Wen-Teng Wu Method of preparing lower alkyl fatty acids esters and in particular biodiesel

Also Published As

Publication number Publication date
EP1705238B1 (en) 2009-10-21
BRPI0418062B1 (pt) 2016-06-28
US20080038804A1 (en) 2008-02-14
CA2553653C (en) 2011-06-28
CN1557913A (zh) 2004-12-29
CA2553653A1 (en) 2005-08-18
ATE446353T1 (de) 2009-11-15
WO2005075615A1 (en) 2005-08-18
HK1094229A1 (en) 2007-03-23
EP1705238A4 (en) 2007-04-11
EP1705238A1 (en) 2006-09-27
DE602004023761D1 (de) 2009-12-03
US7550278B2 (en) 2009-06-23
CN1238469C (zh) 2006-01-25

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Legal Events

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B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 28/06/2016, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time
B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)
B21H Decision of lapse of a patent or of a certificate of addition of invention cancelled [chapter 21.8 patent gazette]
B24E Patent annual fee: resolution cancelled
B24B Patent annual fee: requirement for complementing annual fee
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