BRPI0507517A - composição de revestimento anticorrosão em dispersão aquosa compreendendo um titanato e/ou zirconato orgánico - Google Patents
composição de revestimento anticorrosão em dispersão aquosa compreendendo um titanato e/ou zirconato orgánicoInfo
- Publication number
- BRPI0507517A BRPI0507517A BRPI0507517-3A BRPI0507517A BRPI0507517A BR PI0507517 A BRPI0507517 A BR PI0507517A BR PI0507517 A BRPI0507517 A BR PI0507517A BR PI0507517 A BRPI0507517 A BR PI0507517A
- Authority
- BR
- Brazil
- Prior art keywords
- composition
- zirconate
- aqueous dispersion
- corrosion coating
- organic titanate
- Prior art date
Links
- 238000005260 corrosion Methods 0.000 title abstract 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title abstract 4
- 239000008199 coating composition Substances 0.000 title abstract 3
- 239000006185 dispersion Substances 0.000 title abstract 3
- 239000002184 metal Substances 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 4
- 239000011248 coating agent Substances 0.000 abstract 3
- 238000000576 coating method Methods 0.000 abstract 3
- 238000002360 preparation method Methods 0.000 abstract 2
- 239000000758 substrate Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 1
- 239000008346 aqueous phase Substances 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000012074 organic phase Substances 0.000 abstract 1
- 229910000077 silane Inorganic materials 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
- C09D201/02—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
- C09D201/10—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing hydrolysable silane groups
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/106—Anti-corrosive paints containing metal dust containing Zn
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/14—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
- C09D201/02—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/086—Organic or non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
- C23C22/83—Chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
- C08G77/58—Metal-containing linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
- C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/20—Use of solutions containing silanes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Paints Or Removers (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
Abstract
"COMPOSIçãO DE REVESTIMENTO ANTICORROSãO EM DISPERSãO AQUOSA COMPREENDENDO UM TITANATO E/OU ZIRCONATO ORGáNICO" A presente invenção se refere a uma composição anticorrosão para partes metálicas baseada em metal particulado em dispersão aquosa caracterizada pelo fato de compreender um titanato orgânico ou zirconato compatíveis na fase aquosa ou fase orgânica, opcionalmente um aglutinante baseado em silano e água. A presente invenção se refere, da mesma forma, a um revestimento anti-corrosão de partes metálicas obtido a partir da composição de revestimento de acordo com a invenção, bem como um substrato metálico proporcionado com esse revestimento anti-corrosão. A invenção se refere, adicionalmente, a uma composição aquosa de titanato de tetralquila C~ 1~ - C~ 8~, destinada ao preparo de uma composição de revestimento de um substrato metálico em dispersão aquosa, bem como ao processo para o preparo de tal composição.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0401349A FR2866029B1 (fr) | 2004-02-11 | 2004-02-11 | Composition de revetement anti-corrosion en dispersion aqueuse comprenant un titanate et/ou un zirconate organique |
| PCT/IB2005/000488 WO2005078026A1 (en) | 2004-02-11 | 2005-02-10 | Anticorrosion coating composition in aqueous dispersion comprising an organic titanate and/or zirconate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0507517A true BRPI0507517A (pt) | 2007-07-03 |
| BRPI0507517B1 BRPI0507517B1 (pt) | 2016-08-09 |
Family
ID=34778680
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0507517A BRPI0507517B1 (pt) | 2004-02-11 | 2005-02-10 | composição de revestimento anti -corrosão de partes metálicas baseada em metal particulado em dispersão aquosa, método de aplicação da composição de revestimento, e substrato metálico |
Country Status (19)
| Country | Link |
|---|---|
| US (3) | US20070134503A1 (pt) |
| EP (2) | EP1930383B1 (pt) |
| JP (2) | JP5008399B2 (pt) |
| KR (1) | KR101157534B1 (pt) |
| CN (1) | CN1918248B (pt) |
| AR (1) | AR047612A1 (pt) |
| AT (2) | ATE526375T1 (pt) |
| AU (1) | AU2005213540B2 (pt) |
| BR (1) | BRPI0507517B1 (pt) |
| CA (1) | CA2555321C (pt) |
| ES (2) | ES2371551T3 (pt) |
| FR (1) | FR2866029B1 (pt) |
| IN (1) | IN2012DN01247A (pt) |
| MY (1) | MY152932A (pt) |
| PL (2) | PL1930383T3 (pt) |
| PT (2) | PT1930383E (pt) |
| RU (1) | RU2396299C2 (pt) |
| TW (1) | TWI359178B (pt) |
| WO (1) | WO2005078026A1 (pt) |
Families Citing this family (69)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2866029B1 (fr) | 2004-02-11 | 2006-05-26 | Dacral | Composition de revetement anti-corrosion en dispersion aqueuse comprenant un titanate et/ou un zirconate organique |
| US9243150B2 (en) * | 2005-04-21 | 2016-01-26 | The United States Of America As Represented By The Secretary Of The Navy | Oxide coated metal pigments and film-forming compositions |
| AU2006286364B2 (en) * | 2005-08-31 | 2011-03-31 | Castrol Limited | Compositions and method for coating metal surfaces with an alkoxysilane coating |
| US20070256590A1 (en) * | 2006-05-02 | 2007-11-08 | Scott Matthew S | Coating compositions exhibiting corrosion resistance properties, related coated articles and methods |
| US8748007B2 (en) * | 2006-05-02 | 2014-06-10 | Ppg Industries Ohio, Inc. | Coating compositions exhibiting corrosion resistance properties, related coated articles and methods |
| US20070259172A1 (en) * | 2006-05-02 | 2007-11-08 | Scott Matthew S | Coating compositions exhibiting corrosion resistance properties, related coated articles and methods |
| US8592042B2 (en) | 2006-11-09 | 2013-11-26 | The Boeing Company | Sol-gel coating method and composition |
| CN101925659B (zh) * | 2008-01-24 | 2014-03-26 | 油研工业股份有限公司 | 防锈涂料组合物及具有使用该组合物的防锈涂膜的部件的制造方法 |
| EP2662210A1 (en) † | 2008-01-24 | 2013-11-13 | Yuken Industry Co., Ltd. | An anticorrosive coating comprising an alkali silicate and a silane coupling agent |
| JP2009185363A (ja) * | 2008-02-08 | 2009-08-20 | Matsumoto Fine Chemical Co Ltd | 表面処理組成物 |
| JP5479684B2 (ja) * | 2008-02-08 | 2014-04-23 | 日本ペイント株式会社 | 水系表面処理組成物 |
| JP5319929B2 (ja) * | 2008-02-08 | 2013-10-16 | マツモトファインケミカル株式会社 | 水系表面処理組成物 |
| KR20090098582A (ko) | 2008-03-14 | 2009-09-17 | 삼성전기주식회사 | 방열판 표면개질용 조성물 및 이를 이용한 인쇄회로기판용방열판의 표면 처리 방법 |
| FR2933424B1 (fr) * | 2008-07-07 | 2011-03-25 | Alcan Rhenalu | Procede de preparation avant soudage de produits en alliage aluminium-lithium |
| AT507187B1 (de) | 2008-10-23 | 2010-03-15 | Helmut Dr Buchberger | Inhalator |
| JP5859308B2 (ja) * | 2008-10-31 | 2016-02-10 | ユニバーシティ オブ フロリダ リサーチ ファンデーション インコーポレーティッド | 水性ゾル−ゲル法を用いた透明な無機−有機ハイブリッド材料 |
| KR100939165B1 (ko) * | 2009-08-10 | 2010-01-28 | 김정태 | 부식방지용 도료 조성물 및 이의 제조방법 |
| DE102010030115A1 (de) | 2009-08-11 | 2011-02-17 | Evonik Degussa Gmbh | Glycidyloxyalkylalkoxysilan-basierte wässrige Silansysteme für den Blankkorrosionsschutz und Korrosionsschutz von Metallen |
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| KR100970461B1 (ko) * | 2010-02-09 | 2010-07-16 | 엘베스트지에이티 주식회사 | 유무기 하이브리드 방식 코팅제 조성물 및 그 제조방법 |
| KR100970462B1 (ko) * | 2010-02-09 | 2010-07-16 | 엘베스트지에이티 주식회사 | 에너지 절감형 방식용 금속도막 조성물 및 그 제조방법 |
| US9656911B2 (en) | 2010-02-16 | 2017-05-23 | Ferro Corporation | Materials for improved adhesion relating to functional cold end coatings (CECs) and methods of detecting same |
| BR112013010384A2 (pt) * | 2010-10-27 | 2016-08-02 | Chemetall Gmbh | composição aquosa para o pré-tratamento de uma superfície metálica antes de outro revestimento ou para o tratamento dessa superfície |
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| AT510837B1 (de) | 2011-07-27 | 2012-07-15 | Helmut Dr Buchberger | Inhalatorkomponente |
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| EP2880103B1 (en) * | 2012-08-01 | 2019-12-04 | The United States Of America As Represented By The Secretary of the Navy | Oxide coated metal pigments and film-forming compositions |
| JP2013129846A (ja) * | 2013-03-08 | 2013-07-04 | Matsumoto Fine Chemical Co Ltd | 水系表面処理組成物 |
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- 2005-02-04 TW TW94103492A patent/TWI359178B/zh not_active IP Right Cessation
- 2005-02-07 MY MYPI20050464A patent/MY152932A/en unknown
- 2005-02-10 AT AT08103218T patent/ATE526375T1/de not_active IP Right Cessation
- 2005-02-10 US US10/589,040 patent/US20070134503A1/en not_active Abandoned
- 2005-02-10 JP JP2006552720A patent/JP5008399B2/ja not_active Expired - Lifetime
- 2005-02-10 EP EP08103218A patent/EP1930383B1/en not_active Expired - Lifetime
- 2005-02-10 CN CN2005800047666A patent/CN1918248B/zh not_active Expired - Lifetime
- 2005-02-10 PL PL08103218T patent/PL1930383T3/pl unknown
- 2005-02-10 PT PT08103218T patent/PT1930383E/pt unknown
- 2005-02-10 CA CA 2555321 patent/CA2555321C/en not_active Expired - Lifetime
- 2005-02-10 WO PCT/IB2005/000488 patent/WO2005078026A1/en not_active Ceased
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- 2005-02-10 PL PL05708604T patent/PL1713869T3/pl unknown
- 2005-02-10 RU RU2006132345A patent/RU2396299C2/ru not_active Application Discontinuation
- 2005-02-10 ES ES08103218T patent/ES2370055T3/es not_active Expired - Lifetime
- 2005-02-10 EP EP20050708604 patent/EP1713869B1/en not_active Expired - Lifetime
- 2005-02-10 KR KR1020067018536A patent/KR101157534B1/ko not_active Expired - Lifetime
- 2005-02-10 PT PT05708604T patent/PT1713869E/pt unknown
- 2005-02-10 BR BRPI0507517A patent/BRPI0507517B1/pt active IP Right Grant
- 2005-02-11 AR ARP050100494 patent/AR047612A1/es active IP Right Grant
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