BRPI0516625A - composto tensoativo, métodos de produção de um composto, de polimerização em emulsão, de inibição da formação de hidrato de gás, de polimerização ou copolimerização de acrilamida, de desemulsificação de uma corrente contendo água emulsificada em óleo, e de produção de um oligoéster, emulsão, dispersão de um sólido em um meio aquoso, formulação detergente para a lavagem de roupas, formulação agroquìmica, fluido de perfuração, dispersão de um sólido em um meio não- aquoso, emulsão explosiva, emulsão ou dispersão para o cuidado pessoal, e, fluido para trabalho em metal - Google Patents
composto tensoativo, métodos de produção de um composto, de polimerização em emulsão, de inibição da formação de hidrato de gás, de polimerização ou copolimerização de acrilamida, de desemulsificação de uma corrente contendo água emulsificada em óleo, e de produção de um oligoéster, emulsão, dispersão de um sólido em um meio aquoso, formulação detergente para a lavagem de roupas, formulação agroquìmica, fluido de perfuração, dispersão de um sólido em um meio não- aquoso, emulsão explosiva, emulsão ou dispersão para o cuidado pessoal, e, fluido para trabalho em metalInfo
- Publication number
- BRPI0516625A BRPI0516625A BRPI0516625-0A BRPI0516625A BRPI0516625A BR PI0516625 A BRPI0516625 A BR PI0516625A BR PI0516625 A BRPI0516625 A BR PI0516625A BR PI0516625 A BRPI0516625 A BR PI0516625A
- Authority
- BR
- Brazil
- Prior art keywords
- emulsion
- dispersion
- solid
- fluid
- producing
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
- C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/916—Dicarboxylic acids and dihydroxy compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/85—Polyesters
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B47/14—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase comprising a solid component and an aqueous phase
- C06B47/145—Water in oil emulsion type explosives in which a carbonaceous fuel forms the continuous phase
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/34—Higher-molecular-weight carboxylic acid esters
- C09K23/36—Esters of polycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
- C10L1/328—Oil emulsions containing water or any other hydrophilic phase
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/003—Additives for gaseous fuels
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/68—Esters
- C10M129/78—Complex esters, i.e. compounds containing at least three esterified carboxyl groups and derived from the combination of at least three different types of the following five types of compound: monohydroxy compounds, polyhydroxy compounds, monocarboxylic acids, polycarboxylic acids, hydroxy carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3715—Polyesters or polycarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/52—Aqueous emulsion or latex, e.g. containing polymers of a glass transition temperature (Tg) below 20°C
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/30—Complex esters, i.e. compounds containing at leasst three esterified carboxyl groups and derived from the combination of at least three different types of the following five types of compounds: monohydroxyl compounds, polyhydroxy xompounds, monocarboxylic acids, polycarboxylic acids or hydroxy carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/24—Emulsion properties
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Veterinary Medicine (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Pest Control & Pesticides (AREA)
- Environmental Sciences (AREA)
- Dermatology (AREA)
- Plant Pathology (AREA)
- Toxicology (AREA)
- Dentistry (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
- Lubricants (AREA)
Abstract
COMPOSTO TENSOATIVO, MéTODOS DE PRODUçãO DE UM COMPOSTO, DE POLIMERIZAçãO EM EMULSãO, DE INIBIçãO DA FORMAçãO DE HIDRATO DE GáS, DE POLIMERIZAçãO OU COPOLIMERIZAçãO DE ACRILAMIDA, DE DESEMULSIFICAçãO DE UMA CORRENTE CONTENDO áGUA EMULSIFICADA EM óLEO, E DE PRODUçãO DE UM OLIGOéSTER, EMULSãO, DISPERSãO DE UM SóLIDO EM UM MEIO AQUOSO, FORMULAçãO DETERGENTE PARA A LAVAGEM DE ROUPAS, FORMULAçãO AGROQUìMICA, FLUIDO DE PERFURAçãO, DISPERSãO DE UM SóLIDO EM UM MEIO NãO- AQUOSO, EMULSãO EXPLOSIVA, EMULSãO OU DISPERSãO PARA O CUIDADO PESSOAL, E, FLUIDO PARA TRABALHO EM METAL. ésteres graxos de oligoésteres de um ácido dicarboxílico e de um poliol retendo pelo menos um grupo hidroxila, em particular da fórmula (1): R¹-¢OR²O-C(O)-R³-(O)C-!m-R¬ 4¬ (I) em que R¹ é H, um grupo de ácido monocarboxílico, ou R¬ 6¬O-¢C(O)-R³-(O)C!-R² são os resíduos de polióis tendo pelo menos um hidroxila isento de substituinte; R³ é hidrocarbileno; R¬ 4¬ é -OH, -OM, em que M é um metal formador de sal, amina ou amónio, -0R¬ 6¬ ou -OR²O-R¬ 7¬; R¬ 5¬ é hidrocarbila C~ 7~ a C~ 21~; R¬ 6¬ é hidrocarbila C~ 8~ a C~ 22~; R¬ 7¬ é H, ou -C(O)R¬ 5¬; e m é de 1 a 20; contanto que pelo menos um de R' e R¬ 4¬ seja ou inclua um grupo C~ 8~ a C~ 22~, são tensoativos. Uma faixa de propriedades de tensoativo pode ser obtida pela variação das moléculas dentro destas faixas. Em especial, em que R² é derivado de um poliol superior, por exemplo sorbitol, R³ é C~ 2~ a C~ 6~ e o grupo terminal graxo é C~ 8~ a C~ 14~, os produtos podendo ser altamente solúveis em água e emulsificantes óleo em água efetivos.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0423072.8A GB0423072D0 (en) | 2004-10-18 | 2004-10-18 | Surfactant compounds |
| PCT/GB2005/004014 WO2006043048A1 (en) | 2004-10-18 | 2005-10-18 | Surfactant compounds |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0516625A true BRPI0516625A (pt) | 2008-09-16 |
| BRPI0516625B1 BRPI0516625B1 (pt) | 2016-10-04 |
Family
ID=33462890
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0516625A BRPI0516625B1 (pt) | 2004-10-18 | 2005-10-18 | composto tensoativo, método de produção de um composto e uso de compostos como tensoativos |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US8603959B2 (pt) |
| EP (1) | EP1824955B2 (pt) |
| JP (1) | JP5519107B2 (pt) |
| KR (1) | KR101108824B1 (pt) |
| CN (1) | CN101068913B (pt) |
| AU (1) | AU2005297047B2 (pt) |
| BR (1) | BRPI0516625B1 (pt) |
| CA (1) | CA2582598C (pt) |
| ES (1) | ES2573846T3 (pt) |
| GB (1) | GB0423072D0 (pt) |
| MX (1) | MX2007004654A (pt) |
| WO (1) | WO2006043048A1 (pt) |
Families Citing this family (24)
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| US7373982B2 (en) * | 2006-03-21 | 2008-05-20 | Halliburton Energy Services, Inc. | Cements for use across formations containing gas hydrates |
| US8399012B2 (en) * | 2006-04-17 | 2013-03-19 | Kimberly-Clark Worldwide, Inc. | Degradable therapeutic delivery device |
| WO2010017651A1 (de) * | 2008-08-15 | 2010-02-18 | Dr. W. Kolb Ag | Peg-freie emulgatoren |
| FR2973034B1 (fr) * | 2011-03-21 | 2014-05-02 | Ard Sa | Nouvelles compositions d'oligomeres polyesters et utilisation comme agents tensioactifs |
| EP2702049B1 (en) * | 2011-04-26 | 2016-11-02 | Dow Global Technologies LLC | Renewable surfactants derived from sugar alcohols |
| US9861119B2 (en) * | 2012-06-15 | 2018-01-09 | Arkema Inc. | Peroxide dispersions |
| EP2861688B1 (en) * | 2012-06-15 | 2019-04-24 | Arkema, Inc. | Peroxide dispersions |
| CN103013465B (zh) * | 2012-12-27 | 2014-11-05 | 中国石油集团渤海钻探工程有限公司 | 一种含有多羟基结构乳化剂的油基钻井液 |
| CA2901625C (en) * | 2013-02-20 | 2022-04-19 | Orica International Pte Ltd | Method and device for conducting commercial blasting operations |
| EP3030597B1 (en) * | 2013-08-09 | 2017-09-13 | Silgan Holdings Inc. | Chain-terminated polymeric composition, use thereof and method for its preparation |
| GB201320627D0 (en) | 2013-11-22 | 2014-01-08 | Croda Int Plc | Agrochemical concentrates |
| US9505971B2 (en) | 2014-05-16 | 2016-11-29 | Momentive Performance Materials Inc. | Stabilization of polyacrylamide emulsion formulations |
| US9828571B2 (en) * | 2015-06-05 | 2017-11-28 | Illinois Tool Works, Inc. | Heavy duty laundry detergent |
| CA2994681A1 (en) | 2015-08-07 | 2017-02-16 | Ecolab Usa Inc. | Nonionic inversion agents for water-in-oil latices and methods of use |
| BR112018002467A2 (pt) * | 2015-08-07 | 2018-09-18 | Ecolab Usa Inc | látex de água em óleo, métodos para formar um látex reversível e para recuperar compostos de hidrocarboneto, e, uso de um látex |
| WO2019051415A1 (en) * | 2017-09-11 | 2019-03-14 | Honeywell International Inc. | PAINT COMPOSITIONS CONTAINING COPOLYMER FORMULATIONS FOR ENHANCING ADHESION ON METALLIC SUBSTRATES |
| KR102063789B1 (ko) * | 2018-04-04 | 2020-01-13 | 한국에너지기술연구원 | 천연물 유래의 가스 하이드레이트 생성 억제용 조성물 및 이를 이용한 가스하이드레이트 생성 억제 방법 |
| RU2755074C2 (ru) * | 2019-05-21 | 2021-09-13 | Михаил Николаевич Оверченко | Эмульгатор для промышленных эмульсионных взрывчатых веществ |
| RU2761063C2 (ru) * | 2019-05-21 | 2021-12-02 | Михаил Николаевич Оверченко | Эмульгатор для промышленных эмульсионных взрывчатых веществ |
| CN110818567A (zh) * | 2019-11-20 | 2020-02-21 | 赛科思能源技术(重庆)有限责任公司 | 一种提高天然气采收率方法及其产品生产工艺 |
| WO2022225898A1 (en) * | 2021-04-19 | 2022-10-27 | Decon Water Technologies, LLC | Industrial laundry systems and methods |
| CA3257415A1 (en) * | 2022-05-26 | 2023-11-30 | Ruby Bio Inc. | EMULSIFIERS FORMED FROM POLYOL ESTERS OF FATTY ACIDS |
| US12187819B1 (en) | 2023-11-15 | 2025-01-07 | Tpc Group, Llc | Compound, its preparation and use |
| US20260092151A1 (en) | 2024-10-02 | 2026-04-02 | Tpc Group Llc | Compounds, their Preparation and Use |
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| DE10223055A1 (de) | 2002-05-24 | 2003-12-11 | Basf Ag | Verfahren zur Herstellung von Polyesterpolyolen mehrwertiger Alkohole |
| DE10240817A1 (de) | 2002-08-30 | 2004-03-11 | Basf Ag | Verfahren zur Herstellung hyperverzweigter, wasserlöslicher Polyester |
| JP4284147B2 (ja) | 2003-10-10 | 2009-06-24 | 日清オイリオグループ株式会社 | 化粧料原料用紫外線防御製剤及び当該製剤を含有する化粧料の製造方法 |
-
2004
- 2004-10-18 GB GBGB0423072.8A patent/GB0423072D0/en not_active Ceased
-
2005
- 2005-10-18 JP JP2007536267A patent/JP5519107B2/ja not_active Expired - Fee Related
- 2005-10-18 CN CN200580041266.XA patent/CN101068913B/zh not_active Expired - Fee Related
- 2005-10-18 US US11/665,695 patent/US8603959B2/en not_active Expired - Fee Related
- 2005-10-18 WO PCT/GB2005/004014 patent/WO2006043048A1/en not_active Ceased
- 2005-10-18 ES ES05794731.9T patent/ES2573846T3/es not_active Expired - Lifetime
- 2005-10-18 KR KR1020077008719A patent/KR101108824B1/ko not_active Expired - Fee Related
- 2005-10-18 CA CA2582598A patent/CA2582598C/en not_active Expired - Fee Related
- 2005-10-18 MX MX2007004654A patent/MX2007004654A/es active IP Right Grant
- 2005-10-18 BR BRPI0516625A patent/BRPI0516625B1/pt not_active IP Right Cessation
- 2005-10-18 AU AU2005297047A patent/AU2005297047B2/en not_active Ceased
- 2005-10-18 EP EP05794731.9A patent/EP1824955B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| KR101108824B1 (ko) | 2012-01-31 |
| AU2005297047A1 (en) | 2006-04-27 |
| BRPI0516625B1 (pt) | 2016-10-04 |
| EP1824955B2 (en) | 2019-03-06 |
| CN101068913B (zh) | 2014-01-29 |
| ES2573846T3 (es) | 2016-06-10 |
| WO2006043048A1 (en) | 2006-04-27 |
| CA2582598A1 (en) | 2006-04-27 |
| KR20070085261A (ko) | 2007-08-27 |
| AU2005297047B2 (en) | 2011-07-07 |
| EP1824955A1 (en) | 2007-08-29 |
| JP2008516940A (ja) | 2008-05-22 |
| JP5519107B2 (ja) | 2014-06-11 |
| CA2582598C (en) | 2015-12-22 |
| US20090215629A1 (en) | 2009-08-27 |
| EP1824955B1 (en) | 2016-03-16 |
| US8603959B2 (en) | 2013-12-10 |
| GB0423072D0 (en) | 2004-11-17 |
| MX2007004654A (es) | 2008-01-16 |
| CN101068913A (zh) | 2007-11-07 |
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