BRPI0520401A2 - catalisador de metal de transição com base em arilfenóxi, sistema catalisador de arilfenóxi para a produção de um homopolìmero, método de produção de um homopolìmero e método de produção de um copolìmero - Google Patents
catalisador de metal de transição com base em arilfenóxi, sistema catalisador de arilfenóxi para a produção de um homopolìmero, método de produção de um homopolìmero e método de produção de um copolìmeroInfo
- Publication number
- BRPI0520401A2 BRPI0520401A2 BRPI0520401-1A BRPI0520401A BRPI0520401A2 BR PI0520401 A2 BRPI0520401 A2 BR PI0520401A2 BR PI0520401 A BRPI0520401 A BR PI0520401A BR PI0520401 A2 BRPI0520401 A2 BR PI0520401A2
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst
- homopolymer
- production
- arylphenoxy
- ethylene
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 11
- 238000004519 manufacturing process Methods 0.000 title abstract 8
- 229920001519 homopolymer Polymers 0.000 title abstract 7
- 150000003624 transition metals Chemical class 0.000 title abstract 4
- 229920001577 copolymer Polymers 0.000 title abstract 3
- 229910052723 transition metal Inorganic materials 0.000 title abstract 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 6
- 239000005977 Ethylene Substances 0.000 abstract 6
- 238000000034 method Methods 0.000 abstract 3
- 229920000089 Cyclic olefin copolymer Polymers 0.000 abstract 2
- 239000003446 ligand Substances 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical class C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 230000000704 physical effect Effects 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 230000007704 transition Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/03—Cp or analog not bridged to a non-Cp X ancillary neutral donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
CATALISADOR DE METAL DE TRANSIçãO COM BASE EM ARILFENóXI, SISTEMA CATALISADOR DE ARILFENóXI PARA A PRODUçãO DE UM HOMOPOLìMERO, MéTODO DE PRODUçãO DE UM HOMOPOLìMERO E MéTODO DE PRODUçãO DE UM COPOLìMERO. Onde é proposto um sistema catalisador arilfenóxi para a produção de um homopolimero de etileno ou copolímeros de etileno e x-olefina, e um método de produção de um homopolímero de etileno ou copolímeros de etileno e colefina possuindo um peso molecular alto sob uma condição de polimerização em solução de alta temperatura utilizando o mesmo; o sistema catalisador inclui um catalisador de metal com transição baseada em arilfenóxi de 4 grupos e um co-catalisador aluminoxano ou um co-catalisador composto de boro; no catalisador de transição de metal, um derivado de ciclopentadieno e um arilfenóxido na forma de ligantes fixos são localizados ao redor do 40 grupo de metal de transição, o arilfenóxido é substituido com pelo menos um derivado de arila e é localizado na posição perpendicular do mesmo, e os ligantes não são cruzados entre si; o catalisador inclui uma matéria prima que não prejudica o meio-ambiente, a síntese do catalisador é económica e a estabilidade térmica do catalisador é excelente; ele é útil para a produção de um homopolímero de etileno ou copolimeros de etileno e <244>- olefina possuindo diversas propriedades físicas nos processos de polimerização comercial.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020050059354A KR100639696B1 (ko) | 2005-07-01 | 2005-07-01 | 에틸렌 단독중합체 또는 α-올레핀과의 공중합체 제조용아릴페녹시 촉매계 |
| PCT/KR2005/003441 WO2007040294A1 (en) | 2005-07-01 | 2005-10-14 | Arylphenoxy catalyst system for producing ethylene homopolymer or copolymers of ethylene and alpha-olefins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0520401A2 true BRPI0520401A2 (pt) | 2009-05-05 |
| BRPI0520401B1 BRPI0520401B1 (pt) | 2017-02-14 |
Family
ID=37590368
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0520401A BRPI0520401B1 (pt) | 2005-07-01 | 2005-10-14 | método de produção de um homopolímero de etileno ou um copolímero de etileno e alfa-olefina |
Country Status (10)
| Country | Link |
|---|---|
| US (3) | US20070004586A1 (pt) |
| EP (1) | EP1910427B1 (pt) |
| JP (1) | JP5288181B2 (pt) |
| KR (1) | KR100639696B1 (pt) |
| CN (1) | CN101213217B (pt) |
| BR (1) | BRPI0520401B1 (pt) |
| CA (1) | CA2615215C (pt) |
| ES (1) | ES2545262T3 (pt) |
| RU (1) | RU2374267C2 (pt) |
| WO (1) | WO2007040294A1 (pt) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101060838B1 (ko) * | 2006-04-24 | 2011-08-30 | 에스케이이노베이션 주식회사 | 에틸렌 단독중합체 또는 α-올레핀과의 공중합체 제조용비스-아릴아릴옥시 촉매계 |
| ES2534469T3 (es) * | 2006-05-17 | 2015-04-23 | Dow Global Technologies Llc | Procedimiento de polimerización de polietileno en disolución a alta temperatura |
| CN101522727B (zh) * | 2006-10-18 | 2011-07-20 | Sk能源株式会社 | 用来制备乙烯均聚物或乙烯与α-烯烃的共聚物的芳基苯氧基催化剂体系 |
| KR101141494B1 (ko) * | 2007-09-05 | 2012-05-03 | 에스케이이노베이션 주식회사 | 다봉 분자량 분포를 갖는 에틸렌 공중합체 및 이의제조방법 |
| US8558379B2 (en) * | 2007-09-28 | 2013-10-15 | Tessera, Inc. | Flip chip interconnection with double post |
| KR101151606B1 (ko) | 2007-12-31 | 2012-06-08 | 에스케이이노베이션 주식회사 | 전이금속 화합물, 이를 포함하는 촉매조성물 및 이를이용한 올레핀 단독중합 또는 공중합체의 제조방법 |
| KR101186489B1 (ko) * | 2008-01-07 | 2012-09-27 | 에스케이이노베이션 주식회사 | 전이금속 화합물 및 이를 포함하는 에틸렌 단독중합체 또는공중합체 제조용 전이금속 촉매 조성물 |
| KR101152413B1 (ko) * | 2008-09-12 | 2012-06-05 | 에스케이이노베이션 주식회사 | 에틸렌 공중합체 및 이의 제조방법 |
| KR101142117B1 (ko) * | 2008-09-25 | 2012-05-09 | 에스케이이노베이션 주식회사 | 전이금속 촉매계 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체 제조방법 |
| KR101142122B1 (ko) * | 2008-09-30 | 2012-05-09 | 에스케이이노베이션 주식회사 | 새로운 전이금속 촉매계 및 이를 이용한 에틸렌 단독중합체또는 에틸렌과 α-올레핀의 공중합체 제조방법 |
| KR101077071B1 (ko) * | 2008-11-03 | 2011-10-26 | 에스케이이노베이션 주식회사 | 내충격성이 우수한 에틸렌 공중합체 |
| KR101167082B1 (ko) * | 2008-11-05 | 2012-07-20 | 에스케이이노베이션 주식회사 | 에틸렌과 α-올레핀의 탄성 공중합체 제조방법 |
| KR101149755B1 (ko) * | 2009-01-06 | 2012-06-01 | 에스케이종합화학 주식회사 | 에틸렌-프로필렌-디엔 공중합체 제조방법 |
| KR101271395B1 (ko) * | 2009-12-21 | 2013-06-05 | 에스케이종합화학 주식회사 | 메탈로센 촉매를 이용한 에틸렌과 알파-올레핀의 공중합체를 제조하는 방법 |
| KR101470532B1 (ko) * | 2009-12-23 | 2014-12-08 | 에스케이이노베이션 주식회사 | 새로운 전이금속 촉매계 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체 제조방법 |
| CN103483390A (zh) * | 2012-06-13 | 2014-01-01 | 中国石油天然气集团公司 | 一种邻苯醌亚胺镍配合物及其制备和应用 |
| CN103242464A (zh) * | 2013-05-31 | 2013-08-14 | 东北石油大学 | 一种多用途聚合催化剂及其聚合体系应用 |
| KR102299848B1 (ko) * | 2014-05-28 | 2021-09-09 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 전이금속 착체의 제조방법 |
| CN112745444B (zh) * | 2019-10-31 | 2023-02-28 | 中国石油化工股份有限公司 | 一种烯烃聚合反应及烯烃聚合物 |
| CN112745365B (zh) * | 2019-10-31 | 2023-10-10 | 中国石油化工股份有限公司 | 一种含茂环苯酚类金属配合物及其制备方法和应用 |
| CN112358498B (zh) * | 2020-10-27 | 2023-03-03 | 万华化学集团股份有限公司 | 一种四芳氧基ivb族双核金属配合物及其制备和应用 |
| CN115160472B (zh) * | 2022-08-09 | 2023-07-11 | 万华化学集团股份有限公司 | 一种高插入率的乙烯共聚物溶液聚合方法 |
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| US4752597A (en) * | 1985-12-12 | 1988-06-21 | Exxon Chemical Patents Inc. | New polymerization catalyst |
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| GB8828206D0 (en) | 1988-12-02 | 1989-01-05 | Shell Int Research | Process for conversion of hydrocarbonaceous feedstock |
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| JP3934768B2 (ja) * | 1997-01-29 | 2007-06-20 | 住友化学株式会社 | オレフィン重合用触媒成分、オレフィン重合用触媒、及びオレフィン系重合体の製造方法 |
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| JP2001261730A (ja) * | 2000-01-11 | 2001-09-26 | Asahi Kasei Corp | スチレン系共重合体の製造方法及びスチレン系共重合体 |
| US6723807B2 (en) | 2000-11-13 | 2004-04-20 | Sumitomo Chemical Company, Limited | Catalyst component and catalyst for addition polymerization, and process for producing addition polymer |
| JP2004123994A (ja) * | 2002-10-07 | 2004-04-22 | Asahi Kasei Chemicals Corp | 環状オレフィン共重合体の製造方法 |
| CN1200007C (zh) * | 2003-01-10 | 2005-05-04 | 吉林大学 | 含苯氧基侧链茂金属催化剂及其用途 |
| JP2005314504A (ja) * | 2004-04-28 | 2005-11-10 | Asahi Kasei Chemicals Corp | エチレン／α−オレフィン類／非共役ジエン共重合体の製造方法 |
-
2005
- 2005-07-01 KR KR1020050059354A patent/KR100639696B1/ko not_active Expired - Lifetime
- 2005-10-14 WO PCT/KR2005/003441 patent/WO2007040294A1/en not_active Ceased
- 2005-10-14 ES ES05856549.0T patent/ES2545262T3/es not_active Expired - Lifetime
- 2005-10-14 CN CN2005800509434A patent/CN101213217B/zh not_active Expired - Lifetime
- 2005-10-14 BR BRPI0520401A patent/BRPI0520401B1/pt active IP Right Grant
- 2005-10-14 CA CA2615215A patent/CA2615215C/en not_active Expired - Lifetime
- 2005-10-14 RU RU2007148028/04A patent/RU2374267C2/ru active
- 2005-10-14 EP EP20050856549 patent/EP1910427B1/en not_active Expired - Lifetime
- 2005-10-14 JP JP2008519155A patent/JP5288181B2/ja not_active Expired - Fee Related
- 2005-11-15 US US11/280,930 patent/US20070004586A1/en not_active Abandoned
-
2007
- 2007-02-06 US US11/671,794 patent/US7589042B2/en active Active
-
2009
- 2009-07-31 US US12/533,816 patent/US7833926B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| RU2374267C2 (ru) | 2009-11-27 |
| EP1910427A4 (en) | 2013-04-03 |
| JP5288181B2 (ja) | 2013-09-11 |
| CA2615215A1 (en) | 2007-04-12 |
| US20090326175A1 (en) | 2009-12-31 |
| BRPI0520401B1 (pt) | 2017-02-14 |
| EP1910427A1 (en) | 2008-04-16 |
| WO2007040294A1 (en) | 2007-04-12 |
| RU2007148028A (ru) | 2009-08-10 |
| US7833926B2 (en) | 2010-11-16 |
| KR100639696B1 (ko) | 2006-10-30 |
| US20070135297A1 (en) | 2007-06-14 |
| EP1910427B1 (en) | 2015-05-13 |
| JP2008545040A (ja) | 2008-12-11 |
| CN101213217A (zh) | 2008-07-02 |
| ES2545262T3 (es) | 2015-09-09 |
| US7589042B2 (en) | 2009-09-15 |
| US20070004586A1 (en) | 2007-01-04 |
| CA2615215C (en) | 2013-03-26 |
| CN101213217B (zh) | 2011-03-16 |
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