BRPI0606424A2 - componente catalisador de titánio sólido, catalisador para polimeração de olefina e processo para produzir um polìmero de olefina - Google Patents
componente catalisador de titánio sólido, catalisador para polimeração de olefina e processo para produzir um polìmero de olefinaInfo
- Publication number
- BRPI0606424A2 BRPI0606424A2 BRPI0606424-8A BRPI0606424A BRPI0606424A2 BR PI0606424 A2 BRPI0606424 A2 BR PI0606424A2 BR PI0606424 A BRPI0606424 A BR PI0606424A BR PI0606424 A2 BRPI0606424 A2 BR PI0606424A2
- Authority
- BR
- Brazil
- Prior art keywords
- solid titanium
- catalyst component
- titanium catalyst
- independently
- producing
- Prior art date
Links
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title abstract 5
- 229910052719 titanium Inorganic materials 0.000 title abstract 5
- 239000010936 titanium Substances 0.000 title abstract 5
- 239000003054 catalyst Substances 0.000 title abstract 4
- 239000007787 solid Substances 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- 239000002685 polymerization catalyst Substances 0.000 title abstract 2
- 229920000098 polyolefin Polymers 0.000 title abstract 2
- 150000001336 alkenes Chemical class 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- -1 cyclic ester compound Chemical class 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 150000002430 hydrocarbons Chemical group 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0209—Esters of carboxylic or carbonic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0212—Alkoxylates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/128—Mixtures of organometallic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/08—Butenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
COMPONENTE CATALISADOR DE TITáNIO SóLIDO, CATALISADOR PARA POLIMERIZAçãO DE OLEFINA E PROCESSO PARA PRODUZIR UM POLìMERO DE OLEFINA. Componente catalisador de titânio sólido (I) da presente invenção é caracterizado pelo fato de conter titânio, magnésio, halogênio, e um composto de éster cíclico (a) representado pela seguinte fórmula (1) Onde n é um número inteiro de 5 a 10, R² e R³ são individualmente independentemente COOR¹ ou R, e pelo menos um entre R² e R³ é COOR¹; uma ligação única (excluindo ligações C^ a^-C^ a^, e uma ligação C^ a^-C^ b^ no caso onde R3 é R) na estrutura cíclica pode ser substituida com uma ligação dupla, uma pluralidade de R¹'s é, individualmente independentemente um grupo de hidrocarboneto monovalente tendo 1 a 20 átomos de carbono; e uma pluralidade de R's é individualmente, independentemente, um átomo ou um substituinte, porém pelo menos um de R's não é um átomo de hidrogênio. Ao utilizar esse componente catalisador de titânio sólido (1), um polímero de olefina tendo uma distribuição de peso molecular ampla pode ser produzido.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005011513 | 2005-01-19 | ||
| JP2005011512 | 2005-01-19 | ||
| JP2005011514 | 2005-01-19 | ||
| PCT/JP2006/300773 WO2006077945A1 (ja) | 2005-01-19 | 2006-01-19 | 固体状チタン触媒成分、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0606424A2 true BRPI0606424A2 (pt) | 2009-06-30 |
| BRPI0606424B1 BRPI0606424B1 (pt) | 2017-03-14 |
Family
ID=36692327
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0606453A BRPI0606453B1 (pt) | 2005-01-19 | 2006-01-19 | processo para a produção de um polímero de olefina |
| BRPI0606424A BRPI0606424B1 (pt) | 2005-01-19 | 2006-01-19 | componente catalisador de titânio sólido, catalisador para polimerizaação de olefina e processo para produzir um polímero de olefina |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0606453A BRPI0606453B1 (pt) | 2005-01-19 | 2006-01-19 | processo para a produção de um polímero de olefina |
Country Status (9)
| Country | Link |
|---|---|
| US (3) | US7888437B2 (pt) |
| EP (3) | EP1845113B1 (pt) |
| JP (5) | JP5530054B2 (pt) |
| KR (3) | KR100928374B1 (pt) |
| BR (2) | BRPI0606453B1 (pt) |
| ES (3) | ES2537554T3 (pt) |
| HU (2) | HUE025752T2 (pt) |
| TW (2) | TWI315318B (pt) |
| WO (2) | WO2006077946A1 (pt) |
Families Citing this family (55)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5530054B2 (ja) * | 2005-01-19 | 2014-06-25 | 三井化学株式会社 | オレフィン重合体製造用固体状チタン触媒成分、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
| US7888438B2 (en) * | 2005-01-19 | 2011-02-15 | Mitsui Chemicals, Inc. | Catalyst for olefin polymerization and process for olefin polymerization |
| EP2048166B1 (en) * | 2006-07-18 | 2014-02-26 | Mitsui Chemicals, Inc. | Solid titanium catalyst ingredient, catalyst for olefin polymerization, and method of olefin polymerization |
| JP5159215B2 (ja) * | 2007-08-31 | 2013-03-06 | 三井化学株式会社 | ポリプロピレン樹脂からなるキャパシタフィルム用原反シート、キャパシタフィルム及びそれらの製造方法 |
| KR20100070379A (ko) * | 2007-11-01 | 2010-06-25 | 미쓰이 가가쿠 가부시키가이샤 | 고체상 타이타늄 촉매 성분, 올레핀 중합용 촉매 및 올레핀의 중합 방법 |
| CN101874046B (zh) * | 2007-11-27 | 2013-03-20 | 三井化学株式会社 | 固态钛催化剂成分、烯烃聚合用催化剂以及烯烃聚合方法 |
| CN101945897B (zh) | 2007-12-21 | 2014-08-20 | 陶氏环球技术有限责任公司 | 具有双齿内部供体的自限制催化剂组合物 |
| US9593175B2 (en) | 2008-04-08 | 2017-03-14 | Mitsui Chemicals, Inc. | Solid titanium catalyst component for ethylene polymerization, ethylene polymerization catalyst and ethylene polymerization method |
| JP5110589B2 (ja) * | 2008-06-23 | 2012-12-26 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分、その製造方法、触媒及びこれを用いたオレフィン類重合体の製造方法 |
| WO2010032793A1 (ja) * | 2008-09-22 | 2010-03-25 | 三井化学株式会社 | プロピレン系ブロック共重合体、該共重合体を含む組成物およびこれらから得られる成形体 |
| JP5689232B2 (ja) * | 2009-03-24 | 2015-03-25 | 三井化学株式会社 | 固体状チタン触媒成分、オレフィン重合用触媒およびオレフィンの重合方法 |
| KR101207628B1 (ko) * | 2010-01-13 | 2012-12-03 | 삼성토탈 주식회사 | 프로필렌 중합용 고체촉매 및 그 제조 방법 |
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| JP5624680B2 (ja) | 2011-09-20 | 2014-11-12 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分、オレフィン類重合用触媒及びオレフィン類重合体の製造方法 |
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| US8575283B1 (en) | 2012-06-28 | 2013-11-05 | Formosa Plastics Corporation, U.S.A. | Heterocyclic organic compounds as electron donors for polyolefin catalysts |
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| WO2018067367A1 (en) | 2016-10-06 | 2018-04-12 | W.R. Grace & Co.-Conn. | Procatalyst composition made with a combination of internal electron donors |
| US9815920B1 (en) | 2016-10-14 | 2017-11-14 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
| US10124324B1 (en) | 2017-05-09 | 2018-11-13 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
| US10822438B2 (en) | 2017-05-09 | 2020-11-03 | Formosa Plastics Corporation | Catalyst system for enhanced stereo-specificity of olefin polymerization and method for producing olefin polymer |
| KR20260021818A (ko) * | 2018-09-17 | 2026-02-13 | 셰브론 필립스 케미컬 컴퍼니 엘피 | 크롬 촉매의 광 처리, 관련 촉매 제조 시스템 및 중합 공정 |
| JP7228447B2 (ja) * | 2019-03-29 | 2023-02-24 | 三井化学株式会社 | エチレン重合用固体状チタン触媒成分の製造方法 |
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| JPWO2024204845A1 (pt) | 2023-03-30 | 2024-10-03 | ||
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| US20250066513A1 (en) | 2023-08-23 | 2025-02-27 | Formosa Plastics Corporation, U.S.A. | Catalyst System For Enhanced Stereo-Specificity Of Olefin Polymerization |
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| US20250115687A1 (en) | 2023-10-06 | 2025-04-10 | Formosa Plastics Corporation, U.S.A. | Production method for solid catalyst component for polymerizing olefins, and catalyst for polymerizaing olefins |
| US20250115686A1 (en) | 2023-10-09 | 2025-04-10 | Formosa Plastics Corporation, U.S.A. | Olefin polymerization catalyst components containing silane and process for the production of polypropylene having high isotacticity at high melt flow rate |
| US20250297039A1 (en) | 2024-03-19 | 2025-09-25 | Formosa Plastics Corporation, U.S.A. | Olefin polymerization catalyst components containing diglycidylester components and its use for the production of polypropylene having high isotacticity at high melt flow rate |
| WO2026063967A1 (en) | 2024-09-19 | 2026-03-26 | Formosa Plastics Corporation, Usa | Olefin polymerization ziegler-natta catalyst components and process for the production of olefin polymers therewith |
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| EP1613670B1 (en) * | 2003-03-26 | 2017-05-10 | Ineos Technologies USA LLC | Olefin polymerisation catalyst component containing a bicyclic cycloakane dicarboxylate as electron donor |
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