BRPI0607726A2 - processo para fabricar acroleìna - Google Patents

processo para fabricar acroleìna

Info

Publication number
BRPI0607726A2
BRPI0607726A2 BRPI0607726-9A BRPI0607726A BRPI0607726A2 BR PI0607726 A2 BRPI0607726 A2 BR PI0607726A2 BR PI0607726 A BRPI0607726 A BR PI0607726A BR PI0607726 A2 BRPI0607726 A2 BR PI0607726A2
Authority
BR
Brazil
Prior art keywords
acrolein
manufacturing
manufacturing acrolein
hammet
acidity
Prior art date
Application number
BRPI0607726-9A
Other languages
English (en)
Inventor
Christophe Duquenne
Wolfgang Hoelderich
Jacques Kervennal
Jean-Luc Dubois
Original Assignee
Arkema France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=35169625&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BRPI0607726(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Arkema France filed Critical Arkema France
Publication of BRPI0607726A2 publication Critical patent/BRPI0607726A2/pt
Publication of BRPI0607726B1 publication Critical patent/BRPI0607726B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/053—Sulfates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C47/22—Acryaldehyde; Methacryaldehyde
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

PROCESSO PARA FABRICAR ACROLEìNA. A presente invenção se refere a um processo para fabricar acroleina pela desidratação em fase gasosa de glicerol na presença de catalisadores sólidos fortemente ácidos com uma acidez de Hammet H0 de entre -9 e -18 e preferivelmente entre -10 e -16.
BRPI0607726-9A 2005-02-15 2006-01-06 Processo para fabricar acroleína BRPI0607726B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
FR05/01500 2005-02-15
FR0501500A FR2882053B1 (fr) 2005-02-15 2005-02-15 Procede de deshydratation du glycerol en acrolene
US68931805P 2005-06-10 2005-06-10
US60/689.318 2005-06-10
PCT/EP2006/000736 WO2006087084A2 (en) 2005-02-15 2006-01-06 Process for dehydrating glycerol to acrolein

Publications (2)

Publication Number Publication Date
BRPI0607726A2 true BRPI0607726A2 (pt) 2009-10-06
BRPI0607726B1 BRPI0607726B1 (pt) 2015-06-09

Family

ID=35169625

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0607726-9A BRPI0607726B1 (pt) 2005-02-15 2006-01-06 Processo para fabricar acroleína

Country Status (13)

Country Link
US (1) US7655818B2 (pt)
EP (1) EP1848681B1 (pt)
JP (1) JP5107060B2 (pt)
KR (1) KR101249632B1 (pt)
CN (1) CN101119956B (pt)
AT (1) ATE399751T1 (pt)
BR (1) BRPI0607726B1 (pt)
DE (1) DE602006001638D1 (pt)
ES (1) ES2308717T3 (pt)
FR (1) FR2882053B1 (pt)
PL (1) PL1848681T3 (pt)
PT (1) PT1848681E (pt)
WO (1) WO2006087084A2 (pt)

Families Citing this family (89)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2882052B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acroleine
WO2007058221A1 (ja) * 2005-11-15 2007-05-24 Nippon Shokubai Co., Ltd. 多価アルコールの脱水方法
JP2008088149A (ja) * 2006-01-04 2008-04-17 Nippon Shokubai Co Ltd アクロレイン製造用触媒及びそれを用いたアクロレイン製造方法
PL213939B1 (pl) * 2006-03-24 2013-05-31 Inst Chemii Przemyslowej Im Prof Ignacego Moscickiego Sposób przerobu frakcji glicerynowej z procesu transestryfikacji triglicerydów kwasów tluszczowych
CN100420518C (zh) * 2006-09-08 2008-09-24 华东理工大学 用于制备异丁烯的固体酸催化剂及其制备方法
WO2008052993A2 (en) * 2006-11-01 2008-05-08 Bioecon International Holding N.V. Process for production of acrolein and other oxygenated compounds from glycerol in a transported bed reactor
JP2008115103A (ja) * 2006-11-02 2008-05-22 Nippon Shokubai Co Ltd アクリル酸の製造方法、アクリル酸製造用装置、およびアクリル酸製造用組成物
WO2008066082A1 (en) 2006-12-01 2008-06-05 Nippon Shokubai Co., Ltd. Method for producing acrolein and glycerin-containing composition
WO2008066079A1 (en) 2006-12-01 2008-06-05 Nippon Shokubai Co., Ltd. Method for producing acrylic acid
JP5162128B2 (ja) * 2006-12-27 2013-03-13 株式会社日本触媒 グリセリンからのアクロレインの製造方法
US20100094066A1 (en) * 2007-01-17 2010-04-15 The Curators Of The University Of Missouri Gas phase reaction process for polyhydric compounds
DE102007004351A1 (de) 2007-01-29 2008-07-31 Evonik Degussa Gmbh Neue Katalysatoren und Verfahren zur Dehydratisierung von Glycerin
DE102007004350A1 (de) 2007-01-29 2008-07-31 Evonik Degussa Gmbh Verfahren zur Regenerierung eines Katalysators
FR2913974A1 (fr) 2007-03-19 2008-09-26 Arkema France Procede de vaporisation de glycerol
US8507736B2 (en) 2007-05-18 2013-08-13 Biofuel-Solution I Malmo Ab Gas phase process for monoalcohol production from glycerol
CN101070276B (zh) * 2007-05-31 2010-05-19 上海华谊丙烯酸有限公司 一种甘油脱水制丙烯醛的方法
US7872159B2 (en) * 2007-08-24 2011-01-18 Battelle Memorial Institute Chemical production processes, systems, and catalyst compositions
US20090054538A1 (en) * 2007-08-24 2009-02-26 Peterson Thomas H Chemical production processes, systems, and catalyst compositions
US7872158B2 (en) 2007-08-24 2011-01-18 Battelle Memorial Institute Chemical production processes, systems, and catalyst compositions
JP5401024B2 (ja) * 2007-08-29 2014-01-29 昭和電工株式会社 アクロレインの製造方法およびアクリル酸の製造方法
JP5401022B2 (ja) * 2007-08-29 2014-01-29 昭和電工株式会社 アクロレインの製造方法およびアクリル酸の製造方法
EP2186790B1 (en) * 2007-08-29 2016-04-13 Showa Denko K.K. Acrolein production method and acrylic acid production method
JP5401023B2 (ja) * 2007-08-29 2014-01-29 昭和電工株式会社 アクロレインの製造方法およびアクリル酸の製造方法
FR2920767B1 (fr) * 2007-09-06 2009-12-18 Arkema France Procede de vaporisation reactive de glycerol
US8070836B2 (en) 2007-10-16 2011-12-06 Wayne State University Combined homogeneous and heterogeneous catalytic transesterification process for biodiesel production
FR2925490B1 (fr) * 2007-12-20 2009-12-25 Arkema France Procede de synthese d'acroleine a partir de glycerol
BRPI0910458A2 (pt) * 2008-04-16 2018-03-27 Arkema France catalisador para preparar acroleína ou ácido acrílico por reação de desidratação de glicerina e método para produzir o mesmo
WO2009127889A1 (en) 2008-04-16 2009-10-22 Arkema France Process for manufacturing acrolein from glycerol
WO2009143159A1 (en) 2008-05-19 2009-11-26 Wayne State University Methods and catalysts for making biodiesel from the transesterification and esterification of unrefined oils
US8975426B2 (en) 2008-05-19 2015-03-10 Wayne State University ZnO nanoparticle catalysts for use in transesterification and esterification reactions and method of making
US8895764B2 (en) 2008-05-19 2014-11-25 Wayne State University ZnO nanoparticle catalysts for use in biodiesel production and method of making
JP2008280349A (ja) * 2008-06-02 2008-11-20 Nippon Shokubai Co Ltd アクリル酸の製造方法、アクリル酸製造用装置、およびアクリル酸製造用組成物
FR2931820B1 (fr) * 2008-06-03 2010-05-14 Arkema France Procede de fabrication d'acroleine par deshydratation du glycerol
DE102008027350A1 (de) 2008-06-07 2009-12-17 Wolfgang Prof. Dr. Hölderich Heterogenkatalysatoren für die Dehydratisierung von Glycerin
FR2934261B1 (fr) * 2008-07-25 2015-04-10 Arkema France Procede de synthese d'esters de l'acide acrylique
DE102008038273A1 (de) 2008-08-18 2010-03-04 Evonik Stockhausen Gmbh Ein Verfahren zur Herstellung von Acrylsäure und daraus herstellbaren Verbindungen basierend auf Glycerin mit Wechselkatalysator
FR2935148B1 (fr) 2008-08-25 2010-08-27 Arkema France Procede de fabrication de fibres de carbone.
EP2179981A1 (en) 2008-10-24 2010-04-28 Arkema France Process for manufacturing acrolein from glycerol
JP2010099596A (ja) 2008-10-24 2010-05-06 Arkema France グリセリンの脱水反応によるアクロレイン及びアクリル酸の製造用触媒と、その製造法
FR2938535B1 (fr) * 2008-11-20 2012-08-17 Arkema France Procede de fabrication de methylmercaptopropionaldehyde et de methionine a partir de matieres renouvelables
FR2939791B1 (fr) * 2008-12-16 2011-01-14 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine brute
US8198477B2 (en) * 2008-12-24 2012-06-12 Rohm And Haas Company Process for production of acrolein from glycerol
US8404887B2 (en) 2008-12-26 2013-03-26 Nippon Shokubai Co., Ltd. Process for producing acrylic acid
FR2940801B1 (fr) * 2009-01-06 2012-08-17 Arkema France Procede de fabrication d'un methacrylate de methyle derive de la biomasse
DE102009006777A1 (de) 2009-01-30 2010-08-05 Wolfgang F. Prof. Dr. Hölderich Verfahren zur Herstellung von Fettsäureestern und Glycerin durch Umesterung von pflanzlichen und tierischen Fetten und Ölen
JP5718060B2 (ja) 2009-02-06 2015-05-13 株式会社日本触媒 ポリアクリル酸（塩）系親水性樹脂およびその製造方法
SG175379A1 (en) 2009-05-15 2011-12-29 Nippon Catalytic Chem Ind Process for producing (meth)acrylic acid and crystallization system
JP5580813B2 (ja) 2009-05-15 2014-08-27 株式会社日本触媒 （メタ）アクリル酸の製造方法
CN102428065B (zh) 2009-05-15 2014-02-26 株式会社日本触媒 制备(甲基)丙烯酸的方法
FR2946052B1 (fr) 2009-05-28 2011-05-27 Arkema France Polymere adhesif sensible a la pression contenant du methacrylate de tetrahydrofurfuryle.
DE102009027420A1 (de) 2009-07-02 2011-01-05 Evonik Degussa Gmbh Verfahren zur Herstellung von Acrolein
WO2011033689A1 (en) * 2009-09-18 2011-03-24 Nippon Kayaku Kabushiki Kaisha Catalyst and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin
JP5731390B2 (ja) 2009-09-30 2015-06-10 株式会社日本触媒 ポリアクリル酸（塩）系吸水性樹脂およびその製造方法
FR2953829B1 (fr) 2009-12-14 2011-12-09 Arkema France Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol
FR2953830B1 (fr) 2009-12-14 2012-01-20 Arkema France Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol
CA2841501A1 (en) * 2009-12-18 2011-06-23 Battelle Memorial Institute Multihydric compound dehydration systems, catalyst compositions, and methods
US8692028B2 (en) 2009-12-23 2014-04-08 Biofuel-Solution I Malmo Ab Method for hydrogenating 1,2-unsaturated carbonylic compounds
KR101148995B1 (ko) * 2010-03-09 2012-05-22 아주대학교산학협력단 글리세롤의 기상 탈수화 반응을 통한 아크롤레인 및 이의 제조방법
CN101829593B (zh) * 2010-04-13 2011-08-31 中国地质大学（武汉） 过硫酸基二氧化钛负载丝光沸石固体超强酸催化剂的制备方法
FR2961507B1 (fr) * 2010-06-17 2016-03-04 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine
CN103201031A (zh) * 2010-07-09 2013-07-10 日本化药株式会社 新型甘油脱水用催化剂及其制造方法
WO2012010923A1 (en) 2010-07-19 2012-01-26 Arkema France Process for manufacturing acrolein from glycerol
WO2013134385A1 (en) * 2012-03-07 2013-09-12 Myriant Corporation Preparation of alpha, beta-unsaturated carboxylic acids and esters thereof
FR2966456B1 (fr) * 2010-10-26 2013-03-15 Adisseo France Sas Procede d'obtention d'acroleine par deshydratation catalytique de glycerol ou de glycerine
EP2468709A1 (en) 2010-11-30 2012-06-27 BioFuel-Solution AB A process for producing acrolein
WO2012101471A1 (en) 2011-01-28 2012-08-02 Arkema France Improved process for manufacturing acrolein/acrylic acid
EP2669008A2 (en) 2011-01-28 2013-12-04 Nippon Kayaku Kabushiki Kaisha Catalyst for selectively reducing saturated aldehyde, and production method therefor
FR2975922B1 (fr) 2011-06-06 2013-05-31 Arkema France Reacteur a plaques avec injection in situ
FR2977809B1 (fr) 2011-07-12 2016-01-08 Arkema France Regeneration de catalyseur en continu dans un reacteur a lit fluidise
WO2013008279A1 (en) 2011-07-14 2013-01-17 Nippon Kayaku Kabushiki Kaisha Process for preparing catalyst used in production of acrolein and/or acrylic acid and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin
WO2013017904A1 (en) 2011-07-29 2013-02-07 Arkema France Improved process of dehydration reactions
US20140206527A1 (en) 2011-07-29 2014-07-24 Nippon Kayaku Kabushiki Kaisha Catalyst For Preparing Acrolein And Acrylic Acid By Dehydration Of Glycerin, And Its Production Process
FR2989684B1 (fr) 2012-04-18 2014-10-31 Arkema France Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol
WO2014209063A1 (ko) 2013-06-27 2014-12-31 주식회사 엘지화학 알릴알콜의 제조방법
WO2014209065A1 (ko) 2013-06-27 2014-12-31 주식회사 엘지화학 글리세롤로부터 아크릴산을 제조하는 방법
KR101679717B1 (ko) 2013-06-27 2016-11-25 주식회사 엘지화학 알릴 알코올의 제조방법 및 이에 의하여 제조된 알릴 알코올
CN103638965B (zh) * 2013-12-27 2015-12-30 复旦大学 用于甘油脱水制丙烯醛的多级孔zsm-5沸石催化剂及其制备方法和应用
FR3017617B1 (fr) 2014-02-19 2016-02-12 Arkema France Procede de production d'acide acrylique bio-source
JP6444986B2 (ja) * 2014-03-11 2018-12-26 国立研究開発法人科学技術振興機構 水媒体中ヒドリド異性化反応用固体触媒
US20150266756A1 (en) * 2014-03-19 2015-09-24 Enersciences Holdings, Llc Methods and apparatus for treating sulfides in produced fluids
FR3019545B1 (fr) 2014-04-04 2016-03-11 Arkema France Procede de synthese directe de (meth)acroleine a partir d'ethers et/ou acetals
WO2015168683A1 (en) 2014-05-02 2015-11-05 University Of Tennessee Research Foundation Novel glycerol dehydration methods and products thereof
KR102044428B1 (ko) 2015-12-23 2019-12-02 주식회사 엘지화학 글리세린으로부터 아크릴산의 제조방법
CN107812535A (zh) * 2016-09-12 2018-03-20 中国科学院青岛生物能源与过程研究所 一种适用于甘油脱水制丙烯醛反应中的抗结焦固体酸催化剂及其制备和应用
CN109304190B (zh) * 2017-07-28 2021-06-18 中国石油化工股份有限公司 甘油制丙烯醛用催化剂
US10647928B2 (en) 2017-11-20 2020-05-12 Ecolab Usa Inc. In-line chemical heating for in-situ generation of active chemicals
IT201800006967A1 (it) * 2018-07-05 2020-01-05 Composizione solida per la catalisi eterogenea e relativo procedimento di preparazione
CN110586066B (zh) * 2019-09-26 2022-06-14 中国天辰工程有限公司 一种用于合成羟基特戊醛的固体碱催化剂的制备及其应用
CN114160119B (zh) * 2021-11-15 2024-07-19 浙江工业大学 一种用于甘油脱水制备丙烯醛的白云石-三氧化钼复合催化剂及其制备方法

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR695931A (fr) * 1929-06-15 1930-12-23 Schering Kahlbaum Ag Procédé de fabrication d'acroléine
FR796553A (fr) * 1935-10-21 1936-04-10 Bataafsche Petroleum Procédé pour l'obtention de composés carbonyliques de valeur
US2558520A (en) * 1948-01-29 1951-06-26 Us Ind Chemicals Inc Production of acrolein from glycerol
JPH05293375A (ja) 1992-04-17 1993-11-09 Japan Energy Corp 固体超強酸触媒及びその製法
DE4238492C2 (de) * 1992-11-14 1995-06-14 Degussa Verfahren zur Herstellung von 1,2- und 1,3-Propandiol
DE4238493C1 (de) * 1992-11-14 1994-04-21 Degussa Verfahren zur Herstellung von Acrolein und dessen Verwendung
US5387721A (en) * 1993-12-21 1995-02-07 Texaco Inc. Methyl tertiary butyl ether process
JPH09100244A (ja) 1995-10-03 1997-04-15 Maruzen Petrochem Co Ltd オレフィン類の製造方法およびこれに用いる脱水反応触媒
TW476746B (en) * 1997-07-23 2002-02-21 Shell Int Research Hydrogenolysis of glycerol
DE19848208A1 (de) 1998-10-20 2000-04-27 Deg Engineering Gmbh Reaktor für die katalytische Umsetzung von Reaktionsmedien, insbesondere von gasförmigen Reaktionsmedien
DE10019381B4 (de) 2000-04-19 2006-05-18 Daun, Klaus-Dieter, Dipl.-Ing. Reaktor für die katalytische Umsetzung von Reaktionsmedien, insbesondere von gasförmigen Reaktionsmedien
CN1394839A (zh) * 2001-07-05 2003-02-05 嘉年生化产品有限公司 从甘油化学合成乳特宁的方法
DE10232482A1 (de) * 2002-07-17 2004-01-29 Basf Ag Verfahren zum sicheren Betreiben einer kontinuierlichen heterogen katalysierten Gasphasen-Partialoxidation wenigstens einer organischen Verbindung
WO2004094357A1 (ja) 2003-04-23 2004-11-04 Japan Energy Corporation 固体酸触媒を用いたエーテルの製造方法
US20050021851A1 (en) * 2003-06-09 2005-01-27 Kimmo Hamynen System, apparatus, and method for directional control input browsing in smart phones
JP5006507B2 (ja) * 2004-01-30 2012-08-22 株式会社日本触媒 アクリル酸の製造方法
FR2882052B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acroleine

Also Published As

Publication number Publication date
KR20070104413A (ko) 2007-10-25
KR101249632B1 (ko) 2013-04-02
CN101119956A (zh) 2008-02-06
DE602006001638D1 (de) 2008-08-14
EP1848681A2 (en) 2007-10-31
CN101119956B (zh) 2012-02-15
EP1848681B1 (en) 2008-07-02
ES2308717T3 (es) 2008-12-01
US20080214880A1 (en) 2008-09-04
JP5107060B2 (ja) 2012-12-26
BRPI0607726B1 (pt) 2015-06-09
WO2006087084A2 (en) 2006-08-24
JP2008530151A (ja) 2008-08-07
FR2882053B1 (fr) 2007-03-23
US7655818B2 (en) 2010-02-02
WO2006087084A3 (en) 2007-01-18
PT1848681E (pt) 2008-09-09
ATE399751T1 (de) 2008-07-15
PL1848681T3 (pl) 2009-03-31
FR2882053A1 (fr) 2006-08-18

Similar Documents

Publication Publication Date Title
BRPI0607727A2 (pt) processo para fabricar acroleìna
BRPI0607726A2 (pt) processo para fabricar acroleìna
BRPI0922885A2 (pt) anticorpos humanos de alta afinidade para a pcsk9.
BR112013028768A2 (pt) método para determinar uma força de atuação aplicada ao um freio de veículo que pode ser atuado de maneira e hidráulica e mecânica
BR112014031613A2 (pt) processo para preparação de conjugados de anticorpos e conjugados de anticorpos
BRPI0716597A2 (pt) Método para o isolamento de um produto; produto preparado pelo método; método para o isolamento de um anticorpo; método para reduzir a turvação de um eluído compreendendo em produto; e método para reduzir a turvação e impurezas de um eluído compreendendo um produto
ECSP088081A (es) Detección de un antigeno diana independientemente de la presencia o ausencia de un anticuerpo terapéutico correspondiente
BR112015031174A2 (pt) processo para a preparação de butadieno
BR112013000623A2 (pt) purificação de proteína.
BR112013001398A2 (pt) método, reagente e kit para medir hemoglobina glicada
BR112012002954A2 (pt) metodo para diagnosticar um disturbio de tireoide, metodo para determinar a capacidade de um composto de induzir um disturbio da tireoide metodo para identificar uma substancia para tratar um disturbio da tireoide, dispositivo para diagnosticar um disturbio da tireoide e uso de pelo menos um analito
BRPI0813292A2 (pt) Método de fabricação de gel de sílica cáustico compósito e géis produzidos pelo referido método.
FR2931820B1 (fr) Procede de fabrication d'acroleine par deshydratation du glycerol
WO2010087594A3 (ko) 시디９３ 또는 이의 가용성 단편의 용도
BR112013007871A2 (pt) quantificação e caracterização de alérgenos
BR112014033119A2 (pt) método e plataforma para determinar uma direção para um objeto emissor de sinal
BR112014009223A2 (pt) método para o diagnóstico da doença de niemann-pick
WO2012029224A8 (ja) 標的物質の検出方法、それに用いるアプタマーセット並びにセンサ及び装置
BRPI0907063A2 (pt) Método para a fabricação de produto alimentício coberto tendo cobertura suscetível ao calor
WO2008117027A3 (en) Altered mitochondrial activity in diseases resulting from oxidative stress
BRPI0914961A2 (pt) catalisador para oxidação de hidrocarboneto por contado em fase gasossa, método para sua preparação e método de oxidação em fase gasosa de hidrocarboneto utilizando o catalisador.
CL2008000365A1 (es) Compuestos derivados de indol-2-il piperazina-1-il- metanona; proceso para la obtencion de dichos compuestos; composicion farmaceutica que comprende a dichos compuestos; y su uso para tratar diabetes, obesidad y dislipidemia.
DK1893030T3 (da) Fremgangsmåde til fremstilling af fødevarer ved ko-ekstrudering, især pølser, og fødevarer, der opnås ved denne fremgangsmåde
MX2013005745A (es) Metodo in vitro para determinar la presencia de piretroides tipo ii.
BRPI0813153A2 (pt) Método de fabricação de gel de sílica cáustico e géis produzidos pelo referido método

Legal Events

Date Code Title Description
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 06/01/2006, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 14A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2547 DE 29-10-2019 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.