BRPI0709367B1 - Corante fluorescente, composições corante, processo de coloração de materiais de queratina, dispositivo com multicompartimentos e uso de corantes fluorescentes de tiol heterocíclicos - Google Patents

Corante fluorescente, composições corante, processo de coloração de materiais de queratina, dispositivo com multicompartimentos e uso de corantes fluorescentes de tiol heterocíclicos Download PDF

Info

Publication number: BRPI0709367B1
Authority: BR; Brazil
Prior art keywords: group; iii; formula; alkyl; petition
Prior art date: 2006-03-24

Application number

BRPI0709367-5A

Other languages

English (en)

Portuguese (pt)

Inventor

Andrew Greaves

Nicolas Daubresse

Original Assignee

L'oreal

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2006-03-24

Filing date

2007-03-23

Publication date

2020-01-07

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=43837737&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BRPI0709367(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

2006-03-24 Priority claimed from FR0651035A external-priority patent/FR2898903B1/fr

2007-02-05 Priority claimed from FR0753075A external-priority patent/FR2912141B1/fr

2007-03-23 Application filed by L'oreal filed Critical L'oreal

2007-03-23 Priority claimed from PCT/FR2007/050998 external-priority patent/WO2007110532A2/fr

2011-04-12 Publication of BRPI0709367A2 publication Critical patent/BRPI0709367A2/pt

2020-01-07 Publication of BRPI0709367B1 publication Critical patent/BRPI0709367B1/pt

Links

239000000203 mixture Substances 0.000 title claims abstract description 62
239000007850 fluorescent dye Substances 0.000 title claims abstract description 61
102000011782 Keratins Human genes 0.000 title claims abstract description 58
108010076876 Keratins Proteins 0.000 title claims abstract description 58
238000000034 method Methods 0.000 title claims abstract description 41
239000000463 material Substances 0.000 title claims abstract description 23
238000004040 coloring Methods 0.000 title claims description 21
-1 heterocyclic thiol Chemical class 0.000 claims abstract description 136
239000000975 dye Substances 0.000 claims abstract description 86
125000000623 heterocyclic group Chemical group 0.000 claims abstract description 60
239000000835 fiber Substances 0.000 claims abstract description 42
238000004043 dyeing Methods 0.000 claims abstract description 15
150000003573 thiols Chemical group 0.000 claims description 52
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 40
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 35
229910052757 nitrogen Inorganic materials 0.000 claims description 35
125000000217 alkyl group Chemical group 0.000 claims description 33
125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 29
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 28
239000003638 chemical reducing agent Substances 0.000 claims description 26
150000001875 compounds Chemical class 0.000 claims description 24
125000005842 heteroatom Chemical group 0.000 claims description 24
125000004433 nitrogen atom Chemical group N* 0.000 claims description 24
125000002091 cationic group Chemical group 0.000 claims description 23
150000003839 salts Chemical class 0.000 claims description 18
125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 17
125000001072 heteroaryl group Chemical group 0.000 claims description 16
125000002950 monocyclic group Chemical group 0.000 claims description 15
229910052783 alkali metal Inorganic materials 0.000 claims description 14
150000001340 alkali metals Chemical class 0.000 claims description 13
150000002148 esters Chemical class 0.000 claims description 13
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 12
125000003545 alkoxy group Chemical group 0.000 claims description 12
125000003282 alkyl amino group Chemical group 0.000 claims description 12
125000000129 anionic group Chemical group 0.000 claims description 12
125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims description 12
125000004663 dialkyl amino group Chemical group 0.000 claims description 12
125000005843 halogen group Chemical group 0.000 claims description 12
239000002253 acid Substances 0.000 claims description 11
229910052760 oxygen Inorganic materials 0.000 claims description 11
239000001301 oxygen Substances 0.000 claims description 11
229910052717 sulfur Inorganic materials 0.000 claims description 11
125000004432 carbon atom Chemical group C* 0.000 claims description 10
125000006239 protecting group Chemical group 0.000 claims description 10
229920006395 saturated elastomer Polymers 0.000 claims description 10
125000003277 amino group Chemical group 0.000 claims description 9
125000003710 aryl alkyl group Chemical group 0.000 claims description 8
125000000592 heterocycloalkyl group Chemical group 0.000 claims description 8
239000007800 oxidant agent Substances 0.000 claims description 8
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 8
CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 claims description 8
125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims description 7
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239000002537 cosmetic Substances 0.000 claims description 7
125000003107 substituted aryl group Chemical group 0.000 claims description 7
125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 7
PMNLUUOXGOOLSP-UHFFFAOYSA-N 2-mercaptopropanoic acid Chemical compound CC(S)C(O)=O PMNLUUOXGOOLSP-UHFFFAOYSA-N 0.000 claims description 6
125000004442 acylamino group Chemical group 0.000 claims description 6
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239000003795 chemical substances by application Substances 0.000 claims description 6
125000004122 cyclic group Chemical group 0.000 claims description 6
125000005113 hydroxyalkoxy group Chemical group 0.000 claims description 6
125000004434 sulfur atom Chemical group 0.000 claims description 6
YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical group C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims description 5
125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 5
125000005100 aryl amino carbonyl group Chemical group 0.000 claims description 5
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 4
125000003806 alkyl carbonyl amino group Chemical group 0.000 claims description 4
125000005196 alkyl carbonyloxy group Chemical group 0.000 claims description 4
QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
238000010511 deprotection reaction Methods 0.000 claims description 4
FFFHZYDWPBMWHY-VKHMYHEASA-N L-homocysteine Chemical compound OC(=O)[C@@H](N)CCS FFFHZYDWPBMWHY-VKHMYHEASA-N 0.000 claims description 3
229910000085 borane Inorganic materials 0.000 claims description 3
159000000007 calcium salts Chemical class 0.000 claims description 3
XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 claims description 3
235000018417 cysteine Nutrition 0.000 claims description 3
150000002019 disulfides Chemical class 0.000 claims description 3
125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 claims description 3
229910003002 lithium salt Inorganic materials 0.000 claims description 3
159000000002 lithium salts Chemical class 0.000 claims description 3
150000003003 phosphines Chemical class 0.000 claims description 3
159000000001 potassium salts Chemical class 0.000 claims description 3
159000000000 sodium salts Chemical class 0.000 claims description 3
150000004763 sulfides Chemical class 0.000 claims description 3
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
150000001342 alkaline earth metals Chemical class 0.000 claims description 2
125000004183 alkoxy alkyl group Chemical group 0.000 claims description 2
125000004691 alkyl thio carbonyl group Chemical group 0.000 claims description 2
125000004682 aminothiocarbonyl group Chemical group NC(=S)* 0.000 claims description 2
125000000151 cysteine group Chemical group N[C@@H](CS)C(=O)* 0.000 claims description 2
125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
150000004677 hydrates Chemical class 0.000 claims description 2
125000002768 hydroxyalkyl group Chemical group 0.000 claims description 2
229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
239000011707 mineral Substances 0.000 claims description 2
230000003287 optical effect Effects 0.000 claims description 2
125000005496 phosphonium group Chemical group 0.000 claims description 2
239000012453 solvate Substances 0.000 claims description 2
229910052751 metal Inorganic materials 0.000 claims 1
239000002184 metal Substances 0.000 claims 1
150000003242 quaternary ammonium salts Chemical class 0.000 claims 1
210000004209 hair Anatomy 0.000 abstract description 57
BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 abstract description 19
230000000694 effects Effects 0.000 abstract description 6
238000010186 staining Methods 0.000 abstract description 6
125000003396 thiol group Chemical class [H]S* 0.000 abstract description 4
239000000645 desinfectant Substances 0.000 abstract 1
150000003254 radicals Chemical class 0.000 description 33
150000001412 amines Chemical class 0.000 description 16
238000011282 treatment Methods 0.000 description 16
238000005406 washing Methods 0.000 description 16
230000000269 nucleophilic effect Effects 0.000 description 14
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
239000000982 direct dye Substances 0.000 description 12
238000003786 synthesis reaction Methods 0.000 description 12
125000003118 aryl group Chemical group 0.000 description 11
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 10
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 9
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
150000004820 halides Chemical class 0.000 description 9
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 8
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
150000001298 alcohols Chemical class 0.000 description 8
230000015572 biosynthetic process Effects 0.000 description 8
150000001735 carboxylic acids Chemical class 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 8
239000012038 nucleophile Substances 0.000 description 8
230000003647 oxidation Effects 0.000 description 8
238000007254 oxidation reaction Methods 0.000 description 8
150000003568 thioethers Chemical class 0.000 description 8
MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 description 7
239000002609 medium Substances 0.000 description 7
JOXIMZWYDAKGHI-UHFFFAOYSA-M toluene-4-sulfonate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-M 0.000 description 7
ZWLDEAXDKNCVDN-UHFFFAOYSA-O 2-[4-[4-[(e)-2-(1-methylpyridin-1-ium-4-yl)ethenyl]phenyl]piperazin-1-yl]ethanethiol Chemical compound C1=C[N+](C)=CC=C1\C=C\C1=CC=C(N2CCN(CCS)CC2)C=C1 ZWLDEAXDKNCVDN-UHFFFAOYSA-O 0.000 description 6
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 6
SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000002585 base Substances 0.000 description 6
150000003857 carboxamides Chemical class 0.000 description 6
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
239000012039 electrophile Substances 0.000 description 6
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
239000000047 product Substances 0.000 description 6
125000004076 pyridyl group Chemical group 0.000 description 6
ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 description 6
BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical compound C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 5
HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 5
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 5
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
238000004061 bleaching Methods 0.000 description 5
229910052799 carbon Inorganic materials 0.000 description 5
238000009833 condensation Methods 0.000 description 5
230000005494 condensation Effects 0.000 description 5
125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 5
JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 5
239000011593 sulfur Substances 0.000 description 5
WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 4
KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 4
150000007513 acids Chemical class 0.000 description 4
150000001350 alkyl halides Chemical class 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
238000007796 conventional method Methods 0.000 description 4
238000009967 direct dyeing Methods 0.000 description 4
125000002228 disulfide group Chemical group 0.000 description 4
125000002541 furyl group Chemical group 0.000 description 4
ZCQWOFVYLHDMMC-UHFFFAOYSA-O hydron;1,3-oxazole Chemical compound C1=COC=[NH+]1 ZCQWOFVYLHDMMC-UHFFFAOYSA-O 0.000 description 4
CZPWVGJYEJSRLH-UHFFFAOYSA-O hydron;pyrimidine Chemical compound C1=CN=C[NH+]=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-O 0.000 description 4
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 4
125000006684 polyhaloalkyl group Polymers 0.000 description 4
PBMFSQRYOILNGV-UHFFFAOYSA-N pyridazine Chemical compound C1=CC=NN=C1 PBMFSQRYOILNGV-UHFFFAOYSA-N 0.000 description 4
125000000168 pyrrolyl group Chemical group 0.000 description 4
150000003459 sulfonic acid esters Chemical class 0.000 description 4
150000003460 sulfonic acids Chemical class 0.000 description 4
125000001544 thienyl group Chemical group 0.000 description 4
YGTAZGSLCXNBQL-UHFFFAOYSA-N 1,2,4-thiadiazole Chemical compound C=1N=CSN=1 YGTAZGSLCXNBQL-UHFFFAOYSA-N 0.000 description 3
FQUYSHZXSKYCSY-UHFFFAOYSA-N 1,4-diazepane Chemical compound C1CNCCNC1 FQUYSHZXSKYCSY-UHFFFAOYSA-N 0.000 description 3
QWENRTYMTSOGBR-UHFFFAOYSA-N 1H-1,2,3-Triazole Chemical compound C=1C=NNN=1 QWENRTYMTSOGBR-UHFFFAOYSA-N 0.000 description 3
NSPMIYGKQJPBQR-UHFFFAOYSA-N 4H-1,2,4-triazole Chemical compound C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 description 3
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239000004215 Carbon black (E152) Substances 0.000 description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
229930182559 Natural dye Natural products 0.000 description 3
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
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235000011054 acetic acid Nutrition 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
150000001299 aldehydes Chemical class 0.000 description 3
150000008064 anhydrides Chemical class 0.000 description 3
IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 3
238000001035 drying Methods 0.000 description 3
150000002170 ethers Chemical class 0.000 description 3
229930195733 hydrocarbon Natural products 0.000 description 3
150000002430 hydrocarbons Chemical class 0.000 description 3
CTAPFRYPJLPFDF-UHFFFAOYSA-O hydron;1,2-oxazole Chemical compound C=1C=[NH+]OC=1 CTAPFRYPJLPFDF-UHFFFAOYSA-O 0.000 description 3
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150000002576 ketones Chemical class 0.000 description 3
239000000978 natural dye Substances 0.000 description 3
230000007935 neutral effect Effects 0.000 description 3
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125000004043 oxo group Chemical group O=* 0.000 description 3
235000011007 phosphoric acid Nutrition 0.000 description 3
125000004193 piperazinyl group Chemical group 0.000 description 3
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229910052700 potassium Inorganic materials 0.000 description 3
239000011591 potassium Substances 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
125000003373 pyrazinyl group Chemical group 0.000 description 3
125000001453 quaternary ammonium group Chemical group 0.000 description 3
229910052708 sodium Inorganic materials 0.000 description 3
239000011734 sodium Substances 0.000 description 3
125000000464 thioxo group Chemical group S=* 0.000 description 3
125000004169 (C1-C6) alkyl group Chemical group 0.000 description 2
UMZDENILBZKMFY-UHFFFAOYSA-N 1,2-dimethylpyridin-1-ium Chemical compound CC1=CC=CC=[N+]1C UMZDENILBZKMFY-UHFFFAOYSA-N 0.000 description 2
GFAZBXKENDSJEB-UHFFFAOYSA-N 2,5-dihydroxy-3-methoxy-6-methylcyclohexa-2,5-diene-1,4-dione Chemical compound COC1=C(O)C(=O)C(C)=C(O)C1=O GFAZBXKENDSJEB-UHFFFAOYSA-N 0.000 description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
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XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 description 2
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UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
229910019142 PO4 Inorganic materials 0.000 description 2
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical group [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
239000002535 acidifier Substances 0.000 description 2
DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 2
150000001264 acyl cyanides Chemical class 0.000 description 2
150000001266 acyl halides Chemical class 0.000 description 2
125000005073 adamantyl group Chemical group C12(CC3CC(CC(C1)C3)C2)* 0.000 description 2
239000002671 adjuvant Substances 0.000 description 2
150000003973 alkyl amines Chemical class 0.000 description 2
150000001408 amides Chemical class 0.000 description 2
150000001409 amidines Chemical class 0.000 description 2
150000001502 aryl halides Chemical class 0.000 description 2
150000005840 aryl radicals Chemical class 0.000 description 2
XYOVOXDWRFGKEX-UHFFFAOYSA-N azepine Chemical compound N1C=CC=CC=C1 XYOVOXDWRFGKEX-UHFFFAOYSA-N 0.000 description 2
239000002610 basifying agent Substances 0.000 description 2
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125000004857 imidazopyridinyl group Chemical group N1C(=NC2=C1C=CC=N2)* 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
229940097275 indigo Drugs 0.000 description 1
COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
230000003993 interaction Effects 0.000 description 1
239000011630 iodine Substances 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
230000001678 irradiating effect Effects 0.000 description 1
VURPSIJHXNVCNZ-UHFFFAOYSA-N isocyanic acid;urea Chemical class N=C=O.NC(N)=O VURPSIJHXNVCNZ-UHFFFAOYSA-N 0.000 description 1
125000001786 isothiazolyl group Chemical group 0.000 description 1
125000000842 isoxazolyl group Chemical group 0.000 description 1
150000003893 lactate salts Chemical class 0.000 description 1
QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000004895 liquid chromatography mass spectrometry Methods 0.000 description 1
238000002025 liquid chromatography-photodiode array detection Methods 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
125000005439 maleimidyl group Chemical class C1(C=CC(N1*)=O)=O 0.000 description 1
FMEJKACEWHCCNV-UHFFFAOYSA-N methoxy hydrogen sulfate Chemical compound COOS(O)(=O)=O FMEJKACEWHCCNV-UHFFFAOYSA-N 0.000 description 1
QFUDHWDUKUCCHZ-UHFFFAOYSA-N methyl hydrogen sulfite Chemical compound COS(O)=O QFUDHWDUKUCCHZ-UHFFFAOYSA-N 0.000 description 1
JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
UUCOIDIYWGRARD-UHFFFAOYSA-N methyl sulfate;pyridin-1-ium Chemical compound COS([O-])(=O)=O.C1=CC=[NH+]C=C1 UUCOIDIYWGRARD-UHFFFAOYSA-N 0.000 description 1
125000004674 methylcarbonyl group Chemical group CC(=O)* 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
239000000178 monomer Substances 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
125000001624 naphthyl group Chemical group 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
239000003605 opacifier Substances 0.000 description 1
125000001715 oxadiazolyl group Chemical group 0.000 description 1
230000000149 penetrating effect Effects 0.000 description 1
230000002085 persistent effect Effects 0.000 description 1
JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
125000001791 phenazinyl group Chemical group C1(=CC=CC2=NC3=CC=CC=C3N=C12)* 0.000 description 1
229960005323 phenoxyethanol Drugs 0.000 description 1
XRVQTYPOPTUZRF-UHFFFAOYSA-N phenyl hydrogen sulfite Chemical compound OS(=O)OC1=CC=CC=C1 XRVQTYPOPTUZRF-UHFFFAOYSA-N 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
125000003386 piperidinyl group Chemical group 0.000 description 1
229920000647 polyepoxide Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
150000003077 polyols Chemical class 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
HZZYSSHSLSZPDG-UHFFFAOYSA-N propane-1,2,3-triol;2-sulfanylacetic acid Chemical compound OC(=O)CS.OCC(O)CO HZZYSSHSLSZPDG-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
125000002098 pyridazinyl group Chemical group 0.000 description 1
125000000714 pyrimidinyl group Chemical group 0.000 description 1
125000000719 pyrrolidinyl group Chemical group 0.000 description 1
125000005493 quinolyl group Chemical group 0.000 description 1
230000005855 radiation Effects 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000011669 selenium Chemical group 0.000 description 1
239000003352 sequestering agent Substances 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
239000002904 solvent Substances 0.000 description 1
230000003335 steric effect Effects 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
150000003890 succinate salts Chemical class 0.000 description 1
KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
239000001384 succinic acid Substances 0.000 description 1
239000003774 sulfhydryl reagent Substances 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
150000003456 sulfonamides Chemical class 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
235000011149 sulphuric acid Nutrition 0.000 description 1
150000003892 tartrate salts Chemical class 0.000 description 1
DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
125000003718 tetrahydrofuranyl group Chemical group 0.000 description 1
125000001712 tetrahydronaphthyl group Chemical group C1(CCCC2=CC=CC=C12)* 0.000 description 1
125000001412 tetrahydropyranyl group Chemical group 0.000 description 1
125000003554 tetrahydropyrrolyl group Chemical group 0.000 description 1
125000003507 tetrahydrothiofenyl group Chemical group 0.000 description 1
125000005247 tetrazinyl group Chemical group N1=NN=NC(=C1)* 0.000 description 1
125000001113 thiadiazolyl group Chemical group 0.000 description 1
150000003567 thiocyanates Chemical class 0.000 description 1
150000003571 thiolactams Chemical group 0.000 description 1
125000005413 thiopyridyl group Chemical group 0.000 description 1
125000005490 tosylate group Chemical group 0.000 description 1
125000001425 triazolyl group Chemical group 0.000 description 1
AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
150000003673 urethanes Chemical class 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
230000000007 visual effect Effects 0.000 description 1
239000003643 water by type Substances 0.000 description 1
239000002888 zwitterionic surfactant Substances 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4933—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having sulfur as an exocyclic substituent, e.g. pyridinethione
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4953—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom containing pyrimidine ring derivatives, e.g. minoxidil
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes

Landscapes

Life Sciences & Earth Sciences (AREA)
Health & Medical Sciences (AREA)
Birds (AREA)
Epidemiology (AREA)
Animal Behavior & Ethology (AREA)
General Health & Medical Sciences (AREA)
Public Health (AREA)
Veterinary Medicine (AREA)
Cosmetics (AREA)

BRPI0709367-5A 2006-03-24 2007-03-23 Corante fluorescente, composições corante, processo de coloração de materiais de queratina, dispositivo com multicompartimentos e uso de corantes fluorescentes de tiol heterocíclicos BRPI0709367B1 (pt)

Applications Claiming Priority (9)

Application Number	Priority Date	Filing Date	Title
FR0651035A FR2898903B1 (fr)	2006-03-24	2006-03-24	Composition de teinture comprenant un colorant disulfure fluorescent, procede d'eclaircissement des matieres keratiniques a partir de ce colorant
FR0651035		2006-03-24
US79294106P	2006-04-19	2006-04-19
US60/792,941		2006-04-19
FR0753075		2007-02-05
FR0753075A FR2912141B1 (fr)	2007-02-05	2007-02-05	Composition de teinture comprenant un colorant fluorescent thiol a heterocycle et a charge cationique externe, procede d'eclaircissement des matieres keratiniques a partir de ce colorant
US90132207P	2007-02-15	2007-02-15
US60/901,322		2007-02-15
PCT/FR2007/050998 WO2007110532A2 (fr)	2006-03-24	2007-03-23	Composition de teinture comprenant un colorant fluorescent thiol/disulfure a heterocycle et a charge cationique externe, procede d'eclaircissement des matieres keratiniques a partir de ce colorant

Publications (2)

Publication Number	Publication Date
BRPI0709367A2 BRPI0709367A2 (pt)	2011-04-12
BRPI0709367B1 true BRPI0709367B1 (pt)	2020-01-07

Family

ID=43837737

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
BRPI0709367-5A BRPI0709367B1 (pt)	2006-03-24	2007-03-23	Corante fluorescente, composições corante, processo de coloração de materiais de queratina, dispositivo com multicompartimentos e uso de corantes fluorescentes de tiol heterocíclicos

Country Status (2)

Country	Link
AT (1)	ATE514754T1 (de)
BR (1)	BRPI0709367B1 (de)

2007
- 2007-03-23 BR BRPI0709367-5A patent/BRPI0709367B1/pt not_active IP Right Cessation
- 2007-03-23 AT AT07731810T patent/ATE514754T1/de not_active IP Right Cessation

Also Published As

Publication number	Publication date
ATE514754T1 (de)	2011-07-15
BRPI0709367A2 (pt)	2011-04-12

Legal Events

Date	Code	Title	Description
2018-04-24	B06F	Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
2018-09-04	B06T	Formal requirements before examination [chapter 6.20 patent gazette]
2019-07-30	B06A	Patent application procedure suspended [chapter 6.1 patent gazette]
2019-08-13	B15K	Others concerning applications: alteration of classification	Free format text: AS CLASSIFICACOES ANTERIORES ERAM: C09B 23/14 , C09B 49/12 , A61K 8/49 , A61Q 5/06 , A61Q 5/10 Ipc: A61K 8/46 (2006.01), A61K 8/49 (2006.01), A61Q 5/0
2019-12-17	B09A	Decision: intention to grant [chapter 9.1 patent gazette]
2020-01-07	B16A	Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]	Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 07/01/2020, OBSERVADAS AS CONDICOES LEGAIS.
2023-01-17	B21F	Lapse acc. art. 78, item iv - on non-payment of the annual fees in time	Free format text: REFERENTE A 16A ANUIDADE.
2023-05-02	B24J	Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)	Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2715 DE 17-01-2023 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.

Publication	Publication Date	Title
CN101454398B (zh)	2014-08-20	含有包含杂环和外部阳离子电荷的硫醇/二硫化物荧光染料的染料组合物、使用该染料让角蛋白材料变亮白的方法
KR101088335B1 (ko)	2011-11-30	티올/디술피드 나프틸이미드 형광 염료를 함유하는 염색 조성물, 및 상기 색소를 이용한 케라틴 물질의 미백 방법
CN101684203B (zh)	2014-09-17	苯乙烯基四氢喹啉鎓硫醇/二硫化物化合物及使用该染料使角蛋白材料变光泽的方法
EP2004758B1 (de)	2011-08-03	Färbezusammensetzung mit einem thiol/disulfid- leuchtfarbstoff mit einem heterozyklus und einer internen kationischen ladung sowie verfahren zur aufhellung von keratinmaterial mit diesem farbstoff
EP2193172B1 (de)	2013-05-01	Thiol/disulfidfarbstoff aus phenylpyrido [1,2-a]indolium, farbstoffzusammensetzung mit diesem farbstoff, verfahren zur aufhellung von keratinmaterial mit diesem farbstoff
BRPI0709366B1 (pt)	2018-05-15	Colorante fluorescente tiol, composições de tintura, processo de coloração de matérias queratínicas, dispositivo e uso dos corantes fluorescentes
BRPI0816004B1 (pt)	2018-08-28	processo para tingir as fibras queratínicas, compostos, composição cosmética e dispositivo com múltiplos compartimentos
WO2009037325A2 (en)	2009-03-26	Thiol/disulfide indole-derived, styryl dye, dye composition comprising said dye, process for lightening keratin materials using this dye
WO2009037348A1 (en)	2009-03-26	Indolinium-derived thiol/disulfide dye, dye composition comprisng this dye, process for lightening keratin materials using this dye
WO2009037350A2 (en)	2009-03-26	DIKETOPYRROLO[3,4-c]PYRROLE THIOL/DISULFIDE DYE, COMPOSITION COMPRISING THIS DYE, PROCESS FOR LIGHTENING KERATIN MATERIALS USING THIS DYE
BRPI0709367B1 (pt)	2020-01-07	Corante fluorescente, composições corante, processo de coloração de materiais de queratina, dispositivo com multicompartimentos e uso de corantes fluorescentes de tiol heterocíclicos
FR2912140A1 (fr)	2008-08-08	Composition de teinture comprenant un colorant fluorescent thiol a heterocycle et a charge cationique interne, procede d'eclaircissement des matieres keratiniques a partir de ce colorant
BRPI0709373B1 (pt)	2018-06-12	Corante fluorescente, composição de tintura, processo de coloração de matérias queratínicas , dispositivo multicompartimento e uso dos corantes fluorescentes
FR2912137A1 (fr)	2008-08-08	Composition tinctoriale comprenant un colorant fluorescent thiol/disulfure a groupe pyridinium et chaine alkylene interrompue,procede d'eclaircissement a partir de la composition
BRPI0709371B1 (pt)	2020-01-07	Corante fluorescente, composições de tintura, processo das coloração de matérias queratínicas, dispositivo e uso dos corantes fluorescentes
FR2912141A1 (fr)	2008-08-08	Composition de teinture comprenant un colorant fluorescent thiol a heterocycle et a charge cationique externe, procede d'eclaircissement des matieres keratiniques a partir de ce colorant
BRPI0709369B1 (pt)	2018-05-15	Corante fluorescente, composições de tintura, processo para a coloração dos materiais de queratínicos, dispositivo multicompartimento e uso dos corantes fluorescentes
FR2912142A1 (fr)	2008-08-08	Composition de teinture comprenant un colorant fluorescent naphtylimide, procede d'eclaircissement des matieres keratiniques a partir de ce colorant
FR2912135A1 (fr)	2008-08-08	Composition de teinture comprenant un colorant fluorescent, a charge cationique externe et chaine alkylene interrompue, procede d'eclaircissement des matieres keratiniques a partir de ce colorant
FR2912134A1 (fr)	2008-08-08	Composition de teinture comprenant un colorant fluorescent thiol a groupement alcoxy/hydroxy et a charge cationique interne, procede d'eclaircissement des matieres keratiniques a partir de ce colorant
FR2912138A1 (fr)	2008-08-08	Composition de teinture comprenant un colorant fluosrescent thiol a groupes amines et a charge cationique interne, procede d'eclaircissement des matieres keratiniques a partir de ce colorant
FR2912139A1 (fr)	2008-08-08	Composition de teinture comprenant un colorant fluorescent thiol masque a groupe dimhtylamino, a charge cationique interne, procede d'eclaircissement des matieres keratiniques a partir de ce colorant