BRPI0718191A2 - Materiais de coordenação de metal e de formação de filme - Google Patents
Materiais de coordenação de metal e de formação de filme Download PDFInfo
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- BRPI0718191A2 BRPI0718191A2 BRPI0718191-4A BRPI0718191A BRPI0718191A2 BR PI0718191 A2 BRPI0718191 A2 BR PI0718191A2 BR PI0718191 A BRPI0718191 A BR PI0718191A BR PI0718191 A2 BRPI0718191 A2 BR PI0718191A2
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- film
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 26
- 239000002184 metal Substances 0.000 title claims abstract description 26
- 239000000463 material Substances 0.000 title claims abstract description 21
- 230000015572 biosynthetic process Effects 0.000 title description 2
- 239000003446 ligand Substances 0.000 claims abstract description 6
- 230000000269 nucleophilic effect Effects 0.000 claims abstract description 5
- 239000003054 catalyst Substances 0.000 claims abstract description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 8
- 229920005989 resin Polymers 0.000 claims 8
- 239000011347 resin Substances 0.000 claims 8
- 125000000524 functional group Chemical group 0.000 claims 6
- 150000002924 oxiranes Chemical group 0.000 claims 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 4
- 125000002947 alkylene group Chemical group 0.000 claims 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 4
- 150000001721 carbon Chemical class 0.000 claims 4
- 150000002148 esters Chemical class 0.000 claims 4
- 150000002576 ketones Chemical class 0.000 claims 4
- 125000005647 linker group Chemical group 0.000 claims 4
- 229910052757 nitrogen Inorganic materials 0.000 claims 4
- 229910052760 oxygen Inorganic materials 0.000 claims 4
- 239000001301 oxygen Substances 0.000 claims 4
- 229910052698 phosphorus Inorganic materials 0.000 claims 4
- 239000011574 phosphorus Substances 0.000 claims 4
- 239000010703 silicon Substances 0.000 claims 4
- 229910052710 silicon Inorganic materials 0.000 claims 4
- 239000011593 sulfur Substances 0.000 claims 4
- 229910052717 sulfur Inorganic materials 0.000 claims 4
- 239000004971 Cross linker Substances 0.000 claims 3
- 229910052739 hydrogen Inorganic materials 0.000 claims 3
- 239000001257 hydrogen Substances 0.000 claims 3
- 150000002736 metal compounds Chemical class 0.000 claims 3
- GYCKQBWUSACYIF-UHFFFAOYSA-N Ethyl salicylate Chemical compound CCOC(=O)C1=CC=CC=C1O GYCKQBWUSACYIF-UHFFFAOYSA-N 0.000 claims 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims 2
- 229910052797 bismuth Inorganic materials 0.000 claims 2
- 239000012039 electrophile Substances 0.000 claims 2
- NUVBSKCKDOMJSU-UHFFFAOYSA-N ethylparaben Chemical compound CCOC(=O)C1=CC=C(O)C=C1 NUVBSKCKDOMJSU-UHFFFAOYSA-N 0.000 claims 2
- 150000002431 hydrogen Chemical class 0.000 claims 2
- 239000012038 nucleophile Substances 0.000 claims 2
- -1 polysiloxane Polymers 0.000 claims 2
- UENLHUMCIOWYQN-UHFFFAOYSA-N 2'-Hydroxy-6'-methoxyacetophenone Chemical compound COC1=CC=CC(O)=C1C(C)=O UENLHUMCIOWYQN-UHFFFAOYSA-N 0.000 claims 1
- RFQDWHAYZBEQBY-UHFFFAOYSA-N 2-(3-methylbut-3-enyl)oxirane Chemical compound CC(=C)CCC1CO1 RFQDWHAYZBEQBY-UHFFFAOYSA-N 0.000 claims 1
- OQJCEBJGAFVNRY-UHFFFAOYSA-N 4-hydroxy-1-(4-hydroxyphenyl)pentan-2-one Chemical compound CC(O)CC(=O)CC1=CC=C(O)C=C1 OQJCEBJGAFVNRY-UHFFFAOYSA-N 0.000 claims 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims 1
- 239000005751 Copper oxide Substances 0.000 claims 1
- 239000004593 Epoxy Substances 0.000 claims 1
- GOMAKLPNAAZVCJ-UHFFFAOYSA-N Ethyl phenylglycidate Chemical compound CCOC(=O)C1OC1C1=CC=CC=C1 GOMAKLPNAAZVCJ-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 125000003277 amino group Chemical group 0.000 claims 1
- 229910052787 antimony Inorganic materials 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 239000008199 coating composition Substances 0.000 claims 1
- 229910000431 copper oxide Inorganic materials 0.000 claims 1
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 claims 1
- 239000012975 dibutyltin dilaurate Substances 0.000 claims 1
- 235000010228 ethyl p-hydroxybenzoate Nutrition 0.000 claims 1
- 150000004820 halides Chemical class 0.000 claims 1
- ORTFAQDWJHRMNX-UHFFFAOYSA-N hydroxidooxidocarbon(.) Chemical compound O[C]=O ORTFAQDWJHRMNX-UHFFFAOYSA-N 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 229910052745 lead Inorganic materials 0.000 claims 1
- ORTFAQDWJHRMNX-UHFFFAOYSA-M oxidooxomethyl Chemical compound [O-][C]=O ORTFAQDWJHRMNX-UHFFFAOYSA-M 0.000 claims 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims 1
- 229920000515 polycarbonate Polymers 0.000 claims 1
- 239000004417 polycarbonate Substances 0.000 claims 1
- 229920001225 polyester resin Polymers 0.000 claims 1
- 239000004645 polyester resin Substances 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 229920002635 polyurethane Polymers 0.000 claims 1
- 239000004814 polyurethane Substances 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 229910052718 tin Inorganic materials 0.000 claims 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims 1
- 229910001887 tin oxide Inorganic materials 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 229910052727 yttrium Inorganic materials 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 239000011787 zinc oxide Substances 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 2
- 150000002118 epoxides Chemical class 0.000 abstract description 2
- 150000002739 metals Chemical class 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract description 2
- 229910052755 nonmetal Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
- C08L101/02—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
- C09D5/4465—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4081—Mixtures of compounds of group C08G18/64 with other macromolecular compounds
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
- C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
- C08G18/6233—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols the monomers or polymers being esterified with carboxylic acids or lactones
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6283—Polymers of nitrogen containing compounds having carbon-to-carbon double bonds
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
- C08G18/6415—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63 having nitrogen
- C08G18/643—Reaction products of epoxy resins with at least equivalent amounts of amines
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/8064—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with monohydroxy compounds
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- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/182—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing using pre-adducts of epoxy compounds with curing agents
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2150/00—Compositions for coatings
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Description
RESUMO Patente de Invenção: "MATERIAIS DE COORDENAÇÃO DE METAL E DE FORMAÇÃO DE FILME".
Materiais formadores de filme incluem estruturas de coordena- ção de metal não-iônico. Estruturas de coordenação de metal não-iônico po- dem coordenar metais, tais como catalisadores de metal e substratos de me- tal. Materiais formadores de filme exemplares podem ser o produto de um epóxido polifuncional e um Iigante nucleofílico tendo uma estrutura de coor- denação de metal não-iônico, ou o produto de um álcool polifuncional e um Iigante eletrofílico tendo uma estrutura de coordenação de metal não-iônico.
Claims (15)
1. Material de formação de filme caracterizado pelo fato de que compreende: uma resina, em que a resina inclui pelo menos um grupo pen- dente compreendendo uma estrutura de coordenação de metal não-iônico e pelo menos um grupo reativo com um reticulador, estrutura de coordenação de metal não-iônico compreendendo pelo menos dois grupos funcionais ri- cos em elétrons, independentemente selecionados do grupo que consiste em: nitrogênio, oxigênio, fósforo, enxofre, silício, carbono insaturado, éster, cetona, éter e hidroxila; e um reticulador compreendendo pelo menos dois grupos funcio- nais reativos com a resina.
2. Material de formação de filme de acordo com a reivindicação 1, caracterizado pelo fato de que a resina é uma resina epóxi, acrílica, poliu- retano, policarbonato, polissiloxano, aminoplástico, ou poliéster.
3. Material de formação de filme de acordo com a reivindicação 1 ou 2, caracterizado pelo fato de que pelo menos um grupo reativo com um reticulador é um grupo epóxido, hidroxila, carboxila, carbamato, ou amina.
4. Material de formação de filme de acordo com qualquer uma das reivindicações 1 a 3, caracterizado pelo fato de que a resina compreen- de a fórmula: <formula>formula see original document page 58</formula> em que, X1 e X2 são independentemente radicais monovalentes funcionais de hidrogênio, hidroxila, epóxido, ou amina; cada R1 e R2 é independentemente radicais divalentes de alqui- Ieno ou arileno; R3 é um radical divalente de alquileno ou arileno compreenden- do uma estrutura de coordenação de metal não-iônico, compreendendo pelo menos dois grupos funcionais ricos em elétrons, independentemente sele- cionados do grupo que consiste em: nitrogênio, oxigênio, fósforo, enxofre, silício, carbono insaturado, éster, cetona, éter e hidroxila; η é um número de 1 a cerca de 12; m é um número de 0 a cerca de 12; e ρ é um número de 1 a cerca de 12.
5. Material de formação de filme de acordo com a reivindicação4, caracterizado pelo fato de que R1 e R2 são radicais divalentes de 2,2- difenilpropano.
6. Material de formação de filme de acordo com qualquer um das reivindicações 1 a 5, caracterizado pelo fato de que dois dos grupos funcio- nais ricos em elétrons, estão em uma posição alfa ou beta um em relação ao outro.
7. Material de formação de filme de acordo com qualquer um das reivindicações 1 a 6,caracterizado pelo fato de que adicionalmente compre- ende um metal ou um composto de metal coordenado pela estrutura de co- ordenação de metal não-iônico.
8. Material de formação de filme de acordo com a reivindicação7, caracterizado pelo fato de que o metal ou composto de metal é seleciona- do de um grupo que consiste em M, MO, M2O3, M(OH)n, RxMO, e combina- ções dos mesmos; em que, M é um metal selecionado do grupo que consis- te em Al, Bi, Ce, Cu, Fe, Pb, Sn, Sb, Ti, Y, Zn, e Zr; η é um número inteiro satisfazendo a valência de M; R é um grupo alquila ou aromático; e χ é um número inteiro de 1 a 6.
9. Material de formação de filme de acordo com a reivindicação7, caracterizado pelo fato de que o metal ou composto de metal compreende um catalisador de metal selecionado de um grupo que consiste em óxido de dibutilestanho, dilaurato de dibutilestanho, óxido de zinco, óxido de bismuto, óxido de estanho, óxido de ítrio, óxido de cobre, e combinações dos mes- mos.
10. Material de formação de filme de acordo com qualquer um das reivindicações 1 a 9, caracterizado pelo fato de que a resina compreen- de pelo menos: (a) um produto de uma reação de: uma resina, em que a resina tem pelo menos um grupo reativo com um nucleófilo, e - um Iigante nucleofílico, em que o Iigante nucleofílico tem a fórmula:X3-R4-X4 em que,X3 é um radical monovalente de hidroxila ou carbo- xila; R4 é um radical divalente de alquileno ou arileno tendo um peso molecu- lar de cerca de 90 g/mol a cerca de 5000 g/mol e uma estrutura de coorde- nação de metal não-iônico compreendendo pelo menos dois grupos funcio- nais ricos em elétrons, independentemente selecionados do grupo que con- siste em: nitrogênio, oxigênio, fósforo, enxofre, silício, carbono insaturado, éster, cetona, éter e hidroxila; e X4 é um radical monovalente de hidrogênio, hidroxila, ou carboxila; (b) um produto de uma reação de: - uma resina que tem pelo menos um grupo reativo com um eletrófilo, e um Iigante eletrofílico, em que o Iigante eletrofílico tem a fórmula:X5-R5-X6 em que, X5 é um radical monovalente de epóxido ou haleto; R5 é um radical divalente de alquileno ou arileno tendo um peso molecular de cerca de 90 g/mol a cerca de 5000 g/mol e uma estrutura de coordenação de metal não-iônico compreendendo pelo menos dois grupos funcionais ri- cos em elétrons, independentemente selecionados do grupo que consiste em: nitrogênio, oxigênio, fósforo, enxofre, silício, carbono insaturado, éster, cetona, éter e hidroxila; e X6 é um radical monovalente de hidrogênio, epóxi- do, ou haleto.
11. Material de formação de filme de acordo com a reivindicação 10, caracterizado pelo fato de que pelo menos um grupo reativo com um nu- cleófilo é um grupo epóxido.
12. Material de formação de filme de acordo com a reivindicação 10 ou 11, caracterizado pelo fato de que o Iigante nucleofílico é selecionado de um grupo que consiste em etil-2-hidroxibenzoato, etil-4-hidroxibenzoato, 4-hidróxi-1-(4-hidroxifenil)pentan-2-ona, 1-(2- hidróxi-6-metoxifenil)etanona, e combinações dos mesmos.
13. Material de formação de filme de acordo com a reivindicação10, caracterizado pelo fato de que o pelo menos um grupo reativo com um eletrófilo é um grupo hidroxila.
14. Material de formação de filme de acordo com a reivindicação ou 13, caracterizado pelo fato de que o Iigante eletrofílico é selecionado de um grupo que consiste em 3-metil-1-(oxiran-2-il)but-3-en-2-ona, etilfenil- glicidato, e combinações dos mesmos.
15. Composição de revestimento, caracterizada pelo fato de que compreende um material de formação de filme como definido em qualquer uma das reivindicações 1 a 14. ι
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/553,185 US7759436B2 (en) | 2006-10-26 | 2006-10-26 | Film-former of resin with nonionic metal coordinating structure and crosslinker-reactive group |
| US11/553,185 | 2006-10-26 | ||
| PCT/US2007/075764 WO2008051648A1 (en) | 2006-10-26 | 2007-08-13 | Metal coordinating and film-forming materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0718191A2 true BRPI0718191A2 (pt) | 2013-11-05 |
Family
ID=38657539
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0718191-4A BRPI0718191A2 (pt) | 2006-10-26 | 2007-08-13 | Materiais de coordenação de metal e de formação de filme |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7759436B2 (pt) |
| EP (1) | EP2076555B1 (pt) |
| JP (1) | JP5383494B2 (pt) |
| KR (1) | KR20090080099A (pt) |
| CN (1) | CN101528795B (pt) |
| AT (1) | ATE494317T1 (pt) |
| BR (1) | BRPI0718191A2 (pt) |
| CA (1) | CA2629072A1 (pt) |
| DE (1) | DE602007011794D1 (pt) |
| WO (1) | WO2008051648A1 (pt) |
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| US7772334B2 (en) * | 2006-10-26 | 2010-08-10 | Basf Coatings Gmbh | Crosslinker of reactive functional groups and nonionic metal coordinating structure-containing alkyl or aromatic compound |
| US7867570B2 (en) * | 2006-10-26 | 2011-01-11 | Basf Coatings Gmbh | Method of producing a coating having metal coordinating and film-forming materials |
| US20080194843A1 (en) * | 2007-02-08 | 2008-08-14 | Basf Corporation | Crosslinkers containing phosphorous |
| US7674874B2 (en) * | 2007-02-08 | 2010-03-09 | Basf Coatings Ag | Methods of producing coating compositions containing phosphorous |
| US7671170B2 (en) * | 2007-02-08 | 2010-03-02 | Basf Coatings Ag | Film-forming material containing phosphorous |
| US8961768B2 (en) * | 2008-12-29 | 2015-02-24 | Basf Corporation | Metal containing integrated electrocoat for better corrosion resistance |
| US8354471B2 (en) * | 2008-12-29 | 2013-01-15 | Basf Coatings Gmbh | Acrylic electrocoat composition and process replacing phosphate pretreatment |
| EP2384358B1 (en) | 2008-12-29 | 2017-05-24 | BASF Coatings GmbH | Electrocoat composition and process replacing phosphate pretreatment |
| US8702943B2 (en) * | 2008-12-29 | 2014-04-22 | Basf Coatings Gmbh | Electrocoat composition and process replacing phosphate pretreatment |
| US20100163423A1 (en) * | 2008-12-29 | 2010-07-01 | Basf Corporation | Electrocoat composition and process replacing phosphate pretreatment |
| US8192603B2 (en) | 2008-12-29 | 2012-06-05 | Basf Coatings Gmbh | Electrocoat composition and process replacing phosphate pretreatment |
| US9382638B2 (en) * | 2008-12-29 | 2016-07-05 | Basf Corporation | Electrocoat composition and process replacing phosphate pretreatment |
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| JP5778954B2 (ja) * | 2011-03-16 | 2015-09-16 | イビデン株式会社 | 排気管 |
| US9062162B2 (en) * | 2013-03-15 | 2015-06-23 | Prc-Desoto International, Inc. | Metal ligand-containing prepolymers, methods of synthesis, and compositions thereof |
| WO2015065977A2 (en) * | 2013-10-29 | 2015-05-07 | Prc-Desoto International, Inc. | Adhesion promoting adducts containing metal ligands, compositions thereof, and uses thereof |
| AU2014342464B2 (en) * | 2013-10-29 | 2017-08-24 | Prc-Desoto International, Inc. | Metal ligand-containing prepolymers, methods of synthesis, and compositions thereof |
| KR102072223B1 (ko) | 2016-10-20 | 2020-01-31 | 주식회사 엘지화학 | 코폴리카보네이트 및 이를 포함하는 수지 조성물 |
| CN109749103B (zh) * | 2018-12-13 | 2021-11-19 | 东华大学 | 一种不溶不熔的金属改性十字型酯化物及其制备方法 |
| CN111978513A (zh) * | 2019-06-14 | 2020-11-24 | 上海雄润树脂有限公司 | 一种高压电开关浇注用环氧树脂及其制备方法 |
| CN110256678A (zh) * | 2019-06-24 | 2019-09-20 | 界首万昌新材料技术有限公司 | 一种成膜时间短的改性硅油的制备方法 |
| CN111909336B (zh) * | 2020-07-15 | 2022-11-04 | 芦娜 | 一种聚氨酯固体废弃物的降解方法 |
| CN112126073B (zh) * | 2020-09-17 | 2021-06-08 | 华南农业大学 | 一种多功能性荧光识别Ag配位聚合物及其制备方法与应用 |
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-
2006
- 2006-10-26 US US11/553,185 patent/US7759436B2/en not_active Expired - Fee Related
-
2007
- 2007-08-13 KR KR1020097010614A patent/KR20090080099A/ko not_active Withdrawn
- 2007-08-13 JP JP2009534730A patent/JP5383494B2/ja not_active Expired - Fee Related
- 2007-08-13 WO PCT/US2007/075764 patent/WO2008051648A1/en not_active Ceased
- 2007-08-13 EP EP07814009A patent/EP2076555B1/en not_active Not-in-force
- 2007-08-13 CA CA002629072A patent/CA2629072A1/en not_active Abandoned
- 2007-08-13 DE DE602007011794T patent/DE602007011794D1/de active Active
- 2007-08-13 AT AT07814009T patent/ATE494317T1/de not_active IP Right Cessation
- 2007-08-13 BR BRPI0718191-4A patent/BRPI0718191A2/pt not_active IP Right Cessation
- 2007-08-13 CN CN2007800397071A patent/CN101528795B/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| KR20090080099A (ko) | 2009-07-23 |
| US7759436B2 (en) | 2010-07-20 |
| EP2076555B1 (en) | 2011-01-05 |
| CN101528795B (zh) | 2012-02-29 |
| CN101528795A (zh) | 2009-09-09 |
| EP2076555A1 (en) | 2009-07-08 |
| CA2629072A1 (en) | 2008-05-02 |
| US20080103268A1 (en) | 2008-05-01 |
| DE602007011794D1 (pt) | 2011-02-17 |
| JP5383494B2 (ja) | 2014-01-08 |
| JP2010508396A (ja) | 2010-03-18 |
| WO2008051648A1 (en) | 2008-05-02 |
| ATE494317T1 (de) | 2011-01-15 |
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