BRPI0720573A2 - Uso de polialquilenoiminas c2-4 hidrofobicamente modificadas - Google Patents

Uso de polialquilenoiminas c2-4 hidrofobicamente modificadas Download PDF

Info

Publication number: BRPI0720573A2
Authority: BR; Brazil
Prior art keywords: polyalkyleneimine; use according; hydrophobically modified; acid; weight
Prior art date: 2006-12-22

Application number

BRPI0720573-2A

Other languages

English (en)

Portuguese (pt)

Inventor

Gero Nordmann

Juergen Detering

Heike Becker

Richard Baur

Original Assignee

Basf Se

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2006-12-22

Filing date

2007-12-21

Publication date

2014-02-04

2007-12-21 Application filed by Basf Se filed Critical Basf Se

2014-02-04 Publication of BRPI0720573A2 publication Critical patent/BRPI0720573A2/pt

Links

238000012546 transfer Methods 0.000 claims abstract description 20
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QTTDXDAWQMDLOF-UHFFFAOYSA-J tetrasodium 3-[[4-[[4-[(6-amino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-6-sulfonatonaphthalen-1-yl]diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].Nc1ccc2c(O)c(N=Nc3ccc(N=Nc4ccc(N=Nc5cc(c6cccc(c6c5)S([O-])(=O)=O)S([O-])(=O)=O)c5ccccc45)c4ccc(cc34)S([O-])(=O)=O)c(cc2c1)S([O-])(=O)=O QTTDXDAWQMDLOF-UHFFFAOYSA-J 0.000 description 3
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RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
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YXHKONLOYHBTNS-UHFFFAOYSA-N Diazomethane Chemical compound C=[N+]=[N-] YXHKONLOYHBTNS-UHFFFAOYSA-N 0.000 description 1
ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical class CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 1
IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical group OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
239000004606 Fillers/Extenders Substances 0.000 description 1
CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
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238000001792 White test Methods 0.000 description 1
YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 1
IENXJNLJEDMNTE-UHFFFAOYSA-N acetic acid;ethane-1,2-diamine Chemical compound CC(O)=O.NCCN IENXJNLJEDMNTE-UHFFFAOYSA-N 0.000 description 1
SWLWZVHQLWXZTQ-UHFFFAOYSA-N acetonitrile;4-methylmorpholin-4-ium;methyl sulfate Chemical compound CC#N.COS([O-])(=O)=O.C[NH+]1CCOCC1 SWLWZVHQLWXZTQ-UHFFFAOYSA-N 0.000 description 1
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DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
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239000002585 base Substances 0.000 description 1
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OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 description 1
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 1
HJMZMZRCABDKKV-UHFFFAOYSA-N carbonocyanidic acid Chemical compound OC(=O)C#N HJMZMZRCABDKKV-UHFFFAOYSA-N 0.000 description 1
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239000001768 carboxy methyl cellulose Substances 0.000 description 1
235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
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239000008112 carboxymethyl-cellulose Substances 0.000 description 1
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150000001768 cations Chemical class 0.000 description 1
229940080284 cetyl sulfate Drugs 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
SECPZKHBENQXJG-UHFFFAOYSA-N cis-palmitoleic acid Natural products CCCCCCC=CCCCCCCCC(O)=O SECPZKHBENQXJG-UHFFFAOYSA-N 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
150000008050 dialkyl sulfates Chemical class 0.000 description 1
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239000003085 diluting agent Substances 0.000 description 1
XQRLCLUYWUNEEH-UHFFFAOYSA-N diphosphonic acid Chemical compound OP(=O)OP(O)=O XQRLCLUYWUNEEH-UHFFFAOYSA-N 0.000 description 1
238000002845 discoloration Methods 0.000 description 1
SCJSLULDABCBLN-UHFFFAOYSA-L disodium;carbonate;pentahydrate Chemical compound O.O.O.O.O.[Na+].[Na+].[O-]C([O-])=O SCJSLULDABCBLN-UHFFFAOYSA-L 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
125000005066 dodecenyl group Chemical group C(=CCCCCCCCCCC)* 0.000 description 1
MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical class CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
238000002296 dynamic light scattering Methods 0.000 description 1
NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 1
230000002708 enhancing effect Effects 0.000 description 1
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238000007306 functionalization reaction Methods 0.000 description 1
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125000003563 glycoside group Chemical group 0.000 description 1
LPTIRUACFKQDHZ-UHFFFAOYSA-N hexadecyl sulfate;hydron Chemical compound CCCCCCCCCCCCCCCCOS(O)(=O)=O LPTIRUACFKQDHZ-UHFFFAOYSA-N 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
229910000041 hydrogen chloride Inorganic materials 0.000 description 1
125000004356 hydroxy functional group Chemical group O* 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
FPBBPRPSGHHFSV-UHFFFAOYSA-N icos-1-en-1-one Chemical compound CCCCCCCCCCCCCCCCCCC=C=O FPBBPRPSGHHFSV-UHFFFAOYSA-N 0.000 description 1
VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 1
150000002460 imidazoles Chemical class 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
YAQXGBBDJYBXKL-UHFFFAOYSA-N iron(2+);1,10-phenanthroline;dicyanide Chemical compound [Fe+2].N#[C-].N#[C-].C1=CN=C2C3=NC=CC=C3C=CC2=C1.C1=CN=C2C3=NC=CC=C3C=CC2=C1 YAQXGBBDJYBXKL-UHFFFAOYSA-N 0.000 description 1
239000012948 isocyanate Substances 0.000 description 1
150000004658 ketimines Chemical group 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
150000007517 lewis acids Chemical class 0.000 description 1
229960004488 linolenic acid Drugs 0.000 description 1
KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
235000019421 lipase Nutrition 0.000 description 1
229910003002 lithium salt Inorganic materials 0.000 description 1
159000000002 lithium salts Chemical class 0.000 description 1
239000001630 malic acid Substances 0.000 description 1
235000011090 malic acid Nutrition 0.000 description 1
239000000463 material Substances 0.000 description 1
229940102396 methyl bromide Drugs 0.000 description 1
MBXNQZHITVCSLJ-UHFFFAOYSA-N methyl fluorosulfonate Chemical compound COS(F)(=O)=O MBXNQZHITVCSLJ-UHFFFAOYSA-N 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
XONPDZSGENTBNJ-UHFFFAOYSA-N molecular hydrogen;sodium Chemical compound [Na].[H][H] XONPDZSGENTBNJ-UHFFFAOYSA-N 0.000 description 1
SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical compound CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
125000005064 octadecenyl group Chemical group C(=CCCCCCCCCCCCCCCCC)* 0.000 description 1
229960002446 octanoic acid Drugs 0.000 description 1
239000003921 oil Substances 0.000 description 1
235000019198 oils Nutrition 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
239000010502 orange oil Substances 0.000 description 1
125000005740 oxycarbonyl group Chemical group [*:1]OC([*:2])=O 0.000 description 1
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
238000005191 phase separation Methods 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
229910052615 phyllosilicate Inorganic materials 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
239000001205 polyphosphate Substances 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
239000011591 potassium Substances 0.000 description 1
238000011002 quantification Methods 0.000 description 1
238000013139 quantization Methods 0.000 description 1
229920005604 random copolymer Polymers 0.000 description 1
125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
239000000344 soap Substances 0.000 description 1
235000019795 sodium metasilicate Nutrition 0.000 description 1
URLJMZWTXZTZRR-UHFFFAOYSA-N sodium myristyl sulfate Chemical compound CCCCCCCCCCCCCCOS(O)(=O)=O URLJMZWTXZTZRR-UHFFFAOYSA-N 0.000 description 1
229950005425 sodium myristyl sulfate Drugs 0.000 description 1
239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
235000019832 sodium triphosphate Nutrition 0.000 description 1
IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
KVSYNOOPFSVLNF-UHFFFAOYSA-M sodium;4-nonanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)OC1=CC=C(S([O-])(=O)=O)C=C1 KVSYNOOPFSVLNF-UHFFFAOYSA-M 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000010186 staining Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
235000011044 succinic acid Nutrition 0.000 description 1
RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical class O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 description 1
230000019635 sulfation Effects 0.000 description 1
238000005670 sulfation reaction Methods 0.000 description 1
239000003760 tallow Substances 0.000 description 1
239000011975 tartaric acid Substances 0.000 description 1
235000002906 tartaric acid Nutrition 0.000 description 1
TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
QDNCLIPKBNMUPP-UHFFFAOYSA-N trimethyloxidanium Chemical compound C[O+](C)C QDNCLIPKBNMUPP-UHFFFAOYSA-N 0.000 description 1
239000001226 triphosphate Substances 0.000 description 1
230000037303 wrinkles Effects 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)
Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

BRPI0720573-2A 2006-12-22 2007-12-21 Uso de polialquilenoiminas c2-4 hidrofobicamente modificadas BRPI0720573A2 (pt)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
EP06127179		2006-12-22
EP06127179.7		2006-12-22
PCT/EP2007/064486 WO2008077952A1 (de)	2006-12-22	2007-12-21	Hydrophob modifizierte polyaklylenimine als farbübertragungsinhibitoren

Publications (1)

Publication Number	Publication Date
BRPI0720573A2 true BRPI0720573A2 (pt)	2014-02-04

Family

ID=39367715

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
BRPI0720573-2A BRPI0720573A2 (pt)	2006-12-22	2007-12-21	Uso de polialquilenoiminas c2-4 hidrofobicamente modificadas

Country Status (12)

Country	Link
US (1)	US20100017973A1 (pl)
EP (1)	EP2126020B1 (pl)
JP (1)	JP2010513644A (pl)
KR (1)	KR20090096723A (pl)
CN (1)	CN101568630B (pl)
AT (1)	ATE534722T1 (pl)
BR (1)	BRPI0720573A2 (pl)
CA (1)	CA2671878A1 (pl)
ES (1)	ES2376369T3 (pl)
MX (1)	MX2009005829A (pl)
PL (1)	PL2126020T3 (pl)
WO (1)	WO2008077952A1 (pl)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE102005049015A1 (de) *	2005-10-11	2006-03-30	Gebr. Becker Gmbh	Kationisch ausgerüstetes Textilmaterial und seine Verwendung
JP5766203B2 (ja) *	2009-12-16	2015-08-19	ビーエーエスエフソシエタス・ヨーロピアＢａｓｆＳｅ	官能化された高分岐のメラミン−ポリアミン−ポリマー
WO2011082981A1 (de) *	2009-12-17	2011-07-14	Basf Se	Wässrige beschichtungsformulierung
CN103199865B (zh) *	2012-01-10	2016-06-15	武汉凯默电气有限公司	一种光串口自适应解码电路
TWI643884B (zh)	2013-09-06	2018-12-11	盧伯利索先進材料有限公司	多元酸多元鹼接枝共聚物分散劑
CN106415086B (zh) *	2014-02-21	2019-10-08	柯科纳股份有限公司	活性颗粒至基质中的引入
WO2016094026A1 (en)	2014-12-09	2016-06-16	Lubrizol Advanced Materials, Inc.	Additive to prevent phase separation of low profile additive in unsaturated thermoset polyester compositions
US10537187B2 (en) *	2015-10-02	2020-01-21	Walmart Apollo, Llc	Augmented refrigerated display unit
US11453843B2 (en)	2016-12-15	2022-09-27	Colgate-Palmolive Company	Color protection in fabrics using citric acid and iminodisuccinate in fine fabric liquid detergent
EP3421583A1 (en)	2017-06-26	2019-01-02	Basf Se	Use of cationic vinylcarboxamide/vinylamine copolymers as a color care agent for laundering formulations
ES2925507T3 (es)	2017-09-19	2022-10-18	Lubrizol Advanced Mat Inc	Dispersante de poliéster multiamínico fabricado a través de un anhídrido intermedio
KR102763205B1 (ko)	2018-09-10	2025-02-04	루브리졸 어드밴스드 머티어리얼스, 인코포레이티드	다중-아민 폴리에스테르 분산제 및 제조 방법
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2007
- 2007-12-21 EP EP07858097A patent/EP2126020B1/de not_active Not-in-force
- 2007-12-21 ES ES07858097T patent/ES2376369T3/es active Active
- 2007-12-21 KR KR1020097014867A patent/KR20090096723A/ko not_active Withdrawn
- 2007-12-21 MX MX2009005829A patent/MX2009005829A/es active IP Right Grant
- 2007-12-21 CN CN2007800475653A patent/CN101568630B/zh not_active Expired - Fee Related
- 2007-12-21 BR BRPI0720573-2A patent/BRPI0720573A2/pt not_active IP Right Cessation
- 2007-12-21 AT AT07858097T patent/ATE534722T1/de active
- 2007-12-21 JP JP2009542102A patent/JP2010513644A/ja active Pending
- 2007-12-21 PL PL07858097T patent/PL2126020T3/pl unknown
- 2007-12-21 CA CA002671878A patent/CA2671878A1/en not_active Abandoned
- 2007-12-21 US US12/519,379 patent/US20100017973A1/en not_active Abandoned
- 2007-12-21 WO PCT/EP2007/064486 patent/WO2008077952A1/de not_active Ceased

Also Published As

Publication number	Publication date
EP2126020A1 (de)	2009-12-02
EP2126020B1 (de)	2011-11-23
WO2008077952A1 (de)	2008-07-03
JP2010513644A (ja)	2010-04-30
CN101568630B (zh)	2012-02-08
ES2376369T3 (es)	2012-03-13
PL2126020T3 (pl)	2012-04-30
CA2671878A1 (en)	2008-07-03
US20100017973A1 (en)	2010-01-28
MX2009005829A (es)	2009-06-16
CN101568630A (zh)	2009-10-28
KR20090096723A (ko)	2009-09-14
ATE534722T1 (de)	2011-12-15

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2014-12-16	B08K	Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]	Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2277 DE 26/08/2014.

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