BRPI0908982A2 - síntese de carbonetos cíclicos - Google Patents

síntese de carbonetos cíclicos

Info

Publication number
BRPI0908982A2
BRPI0908982A2 BRPI0908982A BRPI0908982A BRPI0908982A2 BR PI0908982 A2 BRPI0908982 A2 BR PI0908982A2 BR PI0908982 A BRPI0908982 A BR PI0908982A BR PI0908982 A BRPI0908982 A BR PI0908982A BR PI0908982 A2 BRPI0908982 A2 BR PI0908982A2
Authority
BR
Brazil
Prior art keywords
cyclic
carbide synthesis
carbide
synthesis
cyclic carbide
Prior art date
Application number
BRPI0908982A
Other languages
English (en)
Inventor
Michael North
Original Assignee
Univ Newcastle
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB0804345A external-priority patent/GB0804345D0/en
Priority claimed from GB0821092A external-priority patent/GB0821092D0/en
Application filed by Univ Newcastle filed Critical Univ Newcastle
Publication of BRPI0908982A2 publication Critical patent/BRPI0908982A2/pt
Publication of BRPI0908982B1 publication Critical patent/BRPI0908982B1/pt
Publication of BRPI0908982B8 publication Critical patent/BRPI0908982B8/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/32—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D317/34—Oxygen atoms
    • C07D317/36—Alkylene carbonates; Substituted alkylene carbonates
    • C07D317/38—Ethylene carbonate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B01J31/1625—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups
    • B01J31/1633—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups covalent linkages via silicon containing groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/32—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D317/34—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/32—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D317/34—Oxygen atoms
    • C07D317/36—Alkylene carbonates; Substituted alkylene carbonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/069—Aluminium compounds without C-aluminium linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B01J2231/341—1,2-additions, e.g. aldol or Knoevenagel condensations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0213—Complexes without C-metal linkages
    • B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0252—Salen ligands or analogues, e.g. derived from ethylenediamine and salicylaldehyde
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/31—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/40—Non-coordinating groups comprising nitrogen
    • B01J2540/42—Quaternary ammonium groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/11—Compounds covalently bound to a solid support

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyesters Or Polycarbonates (AREA)
BRPI0908982A 2008-03-07 2009-03-06 síntese de carbonatos cíclicos BRPI0908982B8 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GB0804345A GB0804345D0 (en) 2008-03-07 2008-03-07 synthesis of cyclic carbonates
GB0804345.7 2008-03-07
GB0821092.4 2008-11-18
GB0821092A GB0821092D0 (en) 2008-11-18 2008-11-18 Sythesis of cyclic carbonates
PCT/GB2009/000624 WO2009109765A1 (en) 2008-03-07 2009-03-06 Synthesis of cyclic carbonates

Publications (3)

Publication Number Publication Date
BRPI0908982A2 true BRPI0908982A2 (pt) 2016-07-19
BRPI0908982B1 BRPI0908982B1 (pt) 2017-10-24
BRPI0908982B8 BRPI0908982B8 (pt) 2018-08-07

Family

ID=40578727

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0908982A BRPI0908982B8 (pt) 2008-03-07 2009-03-06 síntese de carbonatos cíclicos

Country Status (6)

Country Link
US (2) US20110015409A1 (pt)
EP (1) EP2257559B1 (pt)
CN (1) CN102015732A (pt)
BR (1) BRPI0908982B8 (pt)
ES (1) ES2527520T3 (pt)
WO (1) WO2009109765A1 (pt)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0708016D0 (en) 2007-04-25 2007-06-06 Univ Newcastle Synthesis of cyclic carbonates
WO2009109765A1 (en) 2008-03-07 2009-09-11 University Of Newcastle Upon Tyne Synthesis of cyclic carbonates
JP5665734B2 (ja) 2008-05-09 2015-02-04 コーネル ユニバーシティー エチレンオキシドと二酸化炭素とのポリマー
ES2879498T3 (es) 2008-08-22 2021-11-22 Saudi Aramco Tech Co Catalizadores y métodos para la síntesis de polímeros
KR20120034813A (ko) 2008-09-08 2012-04-12 노보머, 인코포레이티드 폴리카보네이트 폴리올 조성물
KR101812466B1 (ko) 2008-09-17 2018-01-30 사우디 아람코 테크놀로지스 컴퍼니 지방족 폴리카보네이트 켄치 방법
CA2742119C (en) 2008-11-01 2018-05-29 Novomer, Inc. Polycarbonate block copolymers
GB0904654D0 (en) * 2009-03-18 2009-04-29 Univ Newcastle Synthesis of cyclic carbonates
CN102665406B (zh) 2009-12-24 2016-03-09 诺沃梅尔公司 合成多环胍化合物的方法
KR101805648B1 (ko) 2010-09-14 2017-12-14 사우디 아람코 테크놀로지스 컴퍼니 중합체 합성용의 촉매 및 방법
CN103228137B (zh) 2010-09-22 2018-11-27 沙特阿美技术公司 取代的水杨醛衍生物的合成
JP6054950B2 (ja) 2011-05-09 2016-12-27 ノボマー, インコーポレイテッド ポリマー組成物および方法
CN102304062B (zh) * 2011-06-09 2013-11-06 山东省化工研究院 一种Salen Ni的制备方法
WO2013016331A2 (en) 2011-07-25 2013-01-31 Novomer, Inc. Polymer compositions and methods
US9394326B2 (en) * 2011-08-08 2016-07-19 Novomer, Inc. Catalysts and methods for polymer synthesis
WO2013090276A1 (en) 2011-12-11 2013-06-20 Novomer, Inc. Salen complexes with dianionic counterions
ES2963032T3 (es) 2011-12-20 2024-03-25 Saudi Aramco Tech Co Métodos para la síntesis de polímeros
CN110791246B (zh) 2012-04-16 2022-04-22 沙特阿美技术公司 粘合剂组合物和方法
US8921580B2 (en) 2012-05-09 2014-12-30 Massachusetts Institute Of Technology Methods and systems for the formation of cyclic carbonates
US9771388B2 (en) 2012-08-24 2017-09-26 Saudi Aramco Technologies Company Metal complexes
WO2014074706A1 (en) 2012-11-07 2014-05-15 Novomer, Inc. High strength polyurethane foam compositions and methods
CN104030975B (zh) * 2014-06-25 2016-06-01 福州大学 一种Mn(Ⅲ)-Salen催化剂及其制备方法与应用
CN104399414A (zh) * 2014-12-19 2015-03-11 海南大学 一种催化转化co2的装置及方法
NL2020163B1 (en) * 2017-12-22 2019-05-22 Alta Innovation Support B V Process to continuously prepare a cyclic carbonate
KR102747154B1 (ko) 2018-04-18 2024-12-31 사우디 아람코 테크놀로지스 컴퍼니 폴리(알킬렌 카보네이트) 중합체의 말단 그룹 이성질체화
US11180609B2 (en) 2018-08-02 2021-11-23 Saudi Aramco Technologies Company Sustainable polymer compositions and methods
US11634539B2 (en) 2018-09-24 2023-04-25 Saudi Aramco Technologies Company Polycarbonate block copolymers and methods thereof
WO2021094447A1 (en) 2019-11-15 2021-05-20 New Green World B.V. Process to continuously prepare a cyclic carbonate
NL2024243B1 (en) 2019-11-15 2021-07-29 New Green World B V Process to continuously prepare a cyclic carbonate
NL2024242B1 (en) * 2019-11-15 2021-07-29 New Green World B V Process to continuously prepare a cyclic carbonate
TWI751744B (zh) * 2020-10-16 2022-01-01 國立臺灣大學 一種用於合成環狀碳酸酯的觸媒組成物及其應用在製備源自聚對苯二甲酸乙二酯之環狀碳酸酯
KR20230088465A (ko) * 2020-11-12 2023-06-19 뉴 그린 월드 비.브이. 사이클릭 카보네이트의 제조방법
TW202302704A (zh) 2021-06-23 2023-01-16 沙烏地阿拉伯商沙烏地阿美科技公司 多元醇組合物及方法
WO2024170708A1 (en) 2023-02-17 2024-08-22 New Green World B.V. Salen aluminium complex and its use as a catalyst
NL2037715B1 (en) * 2023-05-19 2025-04-28 New Green World B V A heterogeneous catalyst
WO2025238174A1 (en) 2024-05-17 2025-11-20 New Green World B.V. Diaminotrisphenol compound, its metal complexes and a supported catalyst
WO2026038956A1 (en) 2024-08-16 2026-02-19 New Green World B.V. Process to prepare an aluminium salphen complex

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2773070A (en) * 1952-10-31 1956-12-04 Jefferson Chem Co Inc Catalytic process for producing alkylene carbonates
JPS58222079A (ja) 1982-06-18 1983-12-23 Mitsubishi Petrochem Co Ltd 環状有機カ−ボネ−ト類の製造方法
JP2732475B2 (ja) 1988-08-09 1998-03-30 三井化学株式会社 亜鉛含有固体触媒およびこの触媒を用いたポリアルキレンカーボネートの製法
US6521561B1 (en) 1998-05-01 2003-02-18 President And Fellows Of Harvard College Main-group metal based asymmetric catalysts and applications thereof
SK284530B6 (sk) 1998-08-10 2005-06-02 Chemickotechnologická Fakulta Stu Spôsob prípravy cyklických karbonátov
JP2001003043A (ja) * 1999-06-16 2001-01-09 Mitsumi Electric Co Ltd 有機電界発光体及びそれを用いた電界発光素子
JP2001129397A (ja) 1999-11-09 2001-05-15 Lion Corp 炭酸エステル化触媒、および環状炭酸エステルの製造方法
DE10147712A1 (de) 2001-09-27 2003-04-17 Basf Ag Verfahren zur Herstellung aliphatischer Polycarbonate
JP3987040B2 (ja) 2004-01-14 2007-10-03 シャープ株式会社 電子写真感光体及びそれを備えた画像形成装置
WO2005084801A1 (ja) 2004-03-04 2005-09-15 National Institute Of Advanced Industrial Science And Technology 環状カーボネート製造用触媒
US20080214386A1 (en) * 2004-03-01 2008-09-04 Toshikazu Takahashi Catalyst for Cyclic Carbonate Synthesis
JP4155212B2 (ja) 2004-03-09 2008-09-24 ダイソー株式会社 環状カーボネート用触媒及びその製法、並びに該触媒を用いた環状カーボネートの製造法
ES2263346B1 (es) 2004-08-25 2007-12-16 Consejo Superior De Investigaciones Cientificas Uso de una composicion catalitica en la insercion de dioxido de carbo no en acetales, ortoesteres y epoxidos.
CN100343244C (zh) 2004-12-17 2007-10-17 中国科学院兰州化学物理研究所 环氧化合物与二氧化碳环加成制备环状碳酸酯的方法
CN100410247C (zh) 2004-12-24 2008-08-13 中国科学院兰州化学物理研究所 二氧化碳和环氧化合物通过环加成反应合成环状碳酸酯的方法
US7871149B2 (en) 2007-03-12 2011-01-18 Brother Kogyo Kabushiki Kaisha Head unit and ink-jet recording apparatus having the same
CN100494248C (zh) * 2007-03-21 2009-06-03 大连理工大学 用于合成聚碳酸酯的双功能催化剂
GB0708016D0 (en) 2007-04-25 2007-06-06 Univ Newcastle Synthesis of cyclic carbonates
WO2009109765A1 (en) 2008-03-07 2009-09-11 University Of Newcastle Upon Tyne Synthesis of cyclic carbonates

Also Published As

Publication number Publication date
CN102015732A (zh) 2011-04-13
EP2257559B1 (en) 2014-10-15
US9273024B2 (en) 2016-03-01
US20130317237A1 (en) 2013-11-28
WO2009109765A1 (en) 2009-09-11
US20110015409A1 (en) 2011-01-20
ES2527520T3 (es) 2015-01-26
BRPI0908982B8 (pt) 2018-08-07
EP2257559A1 (en) 2010-12-08
BRPI0908982B1 (pt) 2017-10-24

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B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]
B16C Correction of notification of the grant [chapter 16.3 patent gazette]
B25G Requested change of headquarter approved
B25A Requested transfer of rights approved