BRPI0911733A8 - Método para produzir uma amida cíclica, método para produzir uma poliamida, método para produzir a-amino-e-caprolactama, método para produzir e-caprolactama, método para produzir policaprolactama, processo para a síntese de a-amino-e-caprolactama, processo para a síntese da e-caprolactama e método para produzir nylon 6 - Google Patents

Método para produzir uma amida cíclica, método para produzir uma poliamida, método para produzir a-amino-e-caprolactama, método para produzir e-caprolactama, método para produzir policaprolactama, processo para a síntese de a-amino-e-caprolactama, processo para a síntese da e-caprolactama e método para produzir nylon 6

Info

Publication number
BRPI0911733A8
BRPI0911733A8 BRPI0911733A BRPI0911733A BRPI0911733A8 BR PI0911733 A8 BRPI0911733 A8 BR PI0911733A8 BR PI0911733 A BRPI0911733 A BR PI0911733A BR PI0911733 A BRPI0911733 A BR PI0911733A BR PI0911733 A8 BRPI0911733 A8 BR PI0911733A8
Authority
BR
Brazil
Prior art keywords
caprolactam
producing
amino
lysine
alpha
Prior art date
Application number
BRPI0911733A
Other languages
English (en)
Inventor
A Wicks Douglas
Original Assignee
Amyris Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Amyris Inc filed Critical Amyris Inc
Publication of BRPI0911733A2 publication Critical patent/BRPI0911733A2/pt
Publication of BRPI0911733A8 publication Critical patent/BRPI0911733A8/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P13/00—Preparation of nitrogen-containing organic compounds
    • C12P13/02—Amides, e.g. chloramphenicol or polyamides; Imides or polyimides; Urethanes, i.e. compounds comprising N-C=O structural element or polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
    • C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D223/06—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D223/12—Nitrogen atoms not forming part of a nitro radical
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
    • C07D201/02—Preparation of lactams
    • C07D201/08—Preparation of lactams from carboxylic acids or derivatives thereof, e.g. hydroxy carboxylic acids, lactones or nitriles
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P17/00—Preparation of heterocyclic carbon compounds with only O, N, S, Se or Te as ring hetero atoms
    • C12P17/10—Nitrogen as only ring hetero atom
    • C12P17/12—Nitrogen as only ring hetero atom containing a six-membered hetero ring

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biotechnology (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Microbiology (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Polyamides (AREA)
  • Other In-Based Heterocyclic Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

MÉTODO PARA PRODUZIR UMA AMIDA CÍCLICA, MÉTODO PARA PRODUZIR UMA POLIAMIDA, MÉTODO PARA PRODUZIR A-AMINO-ECAPROLACTAMA, MÉTODO PARA PRODUZIR E-CAPROLACTAMA, MÉTODO PARA PRODUZIR POLICAPROLACTAMA, PROCESSO PARA A SÍNTESE DE AAMINO-E-CAPROLACTAMA, PROCESSO PARA A SÍNTESE DA E - CAPROLACTAMA E MÉTODO PARA PRODUZIR NYLON 6. A presente invenção se refere a métodos de fazer uma amida cíclica. Os métodos incluem a etapa de aquecimento de um caldo de fermentação de uma forma eficaz de produzir uma amida cíclica (por exemplo, a-amino-e-caprolactama), onde o caldo de fermentação inclui um aminoácido ou sal do mesmo (por exemplo lisina (por exemplo, L-(alpha)-lisina, D-(alpha)-lisina, L(beta)-lisina, e D-(beta)-lisina) ou um sal do mesmo). Os monômeros de amida cíclica podem ser polimerizados de uma maneira eficaz de forma uma poliamida. Por exemplo, um método de policaprolactona fazer (por exemplo, nylon 6) inclui as etapas de (a) aquecimento de um- caldo de fermentação de uma forma eficaz para produzir um (alpha)-amino-(epsilon)-caprolactama, onde o caldo de fermentação inclui lisina ou um sal do mesmo; (b) remoção (deaminating) do c-amino de um grupo (alpha)-amino-(epsilon)-caprolactama de uma forma eficaz para produzir uma pluralidade de monômeros e-caprolactama, e (c) a pluralidade de polimerização de monômeros de caprolactama e, de maneira eficiente para a produção poliprolactama. Uma das vantagens da presente invenção é que a lisina e / ou seu sal pode ser aquecido para formar uma (alpha)-amino-(epsilon)-caprolactama, enquanto a lisina ainda está no caldo de fermentação e na presença de um ou mais aminoácidos adicionais e / ou outros produtos de fermentação. A lisina e / ou seu sal, não precisa ser purificado a partir do caldo de fermentação antes de ser aquecida para formar uma (alpha)-amino-(epsilon)-caprolactama. Por exemplo, o caldo fermentado, não precisa ser submetido a um processo de troca iônica, antes de ser aquecida para formar uma (alpha)-amino-(epsilon)-caprolactama. Evitando tal processo de troca iônica pode reduzir substancialmente os custos de fabricação.
BRPI0911733A 2008-07-24 2009-07-24 Método para produzir uma amida cíclica, método para produzir uma poliamida, método para produzir a-amino-e-caprolactama, método para produzir e-caprolactama, método para produzir policaprolactama, processo para a síntese de a-amino-e-caprolactama, processo para a síntese da e-caprolactama e método para produzir nylon 6 BRPI0911733A8 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13583508P 2008-07-24 2008-07-24
PCT/US2009/051753 WO2010011967A1 (en) 2008-07-24 2009-07-24 Methods of making cyclic amide monomers, and related derivatives and methods

Publications (2)

Publication Number Publication Date
BRPI0911733A2 BRPI0911733A2 (pt) 2017-06-13
BRPI0911733A8 true BRPI0911733A8 (pt) 2017-10-03

Family

ID=41382488

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0911733A BRPI0911733A8 (pt) 2008-07-24 2009-07-24 Método para produzir uma amida cíclica, método para produzir uma poliamida, método para produzir a-amino-e-caprolactama, método para produzir e-caprolactama, método para produzir policaprolactama, processo para a síntese de a-amino-e-caprolactama, processo para a síntese da e-caprolactama e método para produzir nylon 6

Country Status (7)

Country Link
US (1) US20110190488A1 (pt)
EP (1) EP2318373A1 (pt)
JP (1) JP2011529087A (pt)
KR (1) KR20110046487A (pt)
CN (1) CN102105450A (pt)
BR (1) BRPI0911733A8 (pt)
WO (1) WO2010011967A1 (pt)

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EP2301919A1 (en) 2004-06-10 2011-03-30 Board of Trustees of Michigan State University Synthesis of caprolactam from lysine
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US8826499B2 (en) 2011-06-06 2014-09-09 Nike, Inc. Closure system
JP6030397B2 (ja) * 2012-09-28 2016-11-24 ユニチカ株式会社 カプロラクタム及びその製造法
US9850512B2 (en) 2013-03-15 2017-12-26 The Research Foundation For The State University Of New York Hydrolysis of cellulosic fines in primary clarified sludge of paper mills and the addition of a surfactant to increase the yield
US9951363B2 (en) 2014-03-14 2018-04-24 The Research Foundation for the State University of New York College of Environmental Science and Forestry Enzymatic hydrolysis of old corrugated cardboard (OCC) fines from recycled linerboard mill waste rejects
EP3253799B1 (en) 2015-02-05 2020-12-02 Molecular Templates, Inc. Multivalent cd20-binding molecules comprising shiga toxin a subunit effector regions and enriched compositions thereof

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Also Published As

Publication number Publication date
WO2010011967A1 (en) 2010-01-28
EP2318373A1 (en) 2011-05-11
BRPI0911733A2 (pt) 2017-06-13
CN102105450A (zh) 2011-06-22
US20110190488A1 (en) 2011-08-04
JP2011529087A (ja) 2011-12-01
KR20110046487A (ko) 2011-05-04

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Legal Events

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B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]
B25D Requested change of name of applicant approved

Owner name: EXCO GREEN, INC. (US)

B25A Requested transfer of rights approved

Owner name: AMYRIS, INC. (US)

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]