BRPI0922092A2 - processo integrado para a produção de acetato de vinila partir do ácido acético via etileno - Google Patents
processo integrado para a produção de acetato de vinila partir do ácido acético via etilenoInfo
- Publication number
- BRPI0922092A2 BRPI0922092A2 BRPI0922092A BRPI0922092A BRPI0922092A2 BR PI0922092 A2 BRPI0922092 A2 BR PI0922092A2 BR PI0922092 A BRPI0922092 A BR PI0922092A BR PI0922092 A BRPI0922092 A BR PI0922092A BR PI0922092 A2 BRPI0922092 A2 BR PI0922092A2
- Authority
- BR
- Brazil
- Prior art keywords
- production
- acetic acid
- vinyl acetate
- integrated process
- acid via
- Prior art date
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title 1
- 239000005977 Ethylene Substances 0.000 title 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
- B01J29/46—Iron group metals or copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/12—Acetic acid esters
- C07C69/14—Acetic acid esters of monohydroxylic compounds
- C07C69/145—Acetic acid esters of monohydroxylic compounds of unsaturated alcohols
- C07C69/15—Vinyl acetate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/291,949 US7855303B2 (en) | 2008-11-14 | 2008-11-14 | Integrated process for the production of vinyl acetate from acetic acid via ethylene |
| PCT/US2009/006016 WO2010056299A1 (en) | 2008-11-14 | 2009-11-06 | Integrated process for the production of vinyl acetate from acetic acid via ethylene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0922092A2 true BRPI0922092A2 (pt) | 2015-12-15 |
Family
ID=42062417
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0922092A BRPI0922092A2 (pt) | 2008-11-14 | 2009-11-06 | processo integrado para a produção de acetato de vinila partir do ácido acético via etileno |
Country Status (16)
| Country | Link |
|---|---|
| US (3) | US7855303B2 (pt) |
| EP (1) | EP2349972B1 (pt) |
| JP (1) | JP2012508736A (pt) |
| KR (1) | KR20110082631A (pt) |
| CN (1) | CN102264686A (pt) |
| AU (1) | AU2009314619A1 (pt) |
| BR (1) | BRPI0922092A2 (pt) |
| CA (1) | CA2743448A1 (pt) |
| CL (1) | CL2011001095A1 (pt) |
| CO (1) | CO6420334A2 (pt) |
| IL (1) | IL212861A0 (pt) |
| MX (1) | MX2011005091A (pt) |
| NZ (1) | NZ592785A (pt) |
| RU (1) | RU2011123906A (pt) |
| WO (1) | WO2010056299A1 (pt) |
| ZA (1) | ZA201103413B (pt) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8680317B2 (en) * | 2008-07-31 | 2014-03-25 | Celanese International Corporation | Processes for making ethyl acetate from acetic acid |
| US8309773B2 (en) | 2010-02-02 | 2012-11-13 | Calanese International Corporation | Process for recovering ethanol |
| US8304586B2 (en) | 2010-02-02 | 2012-11-06 | Celanese International Corporation | Process for purifying ethanol |
| US8546622B2 (en) | 2008-07-31 | 2013-10-01 | Celanese International Corporation | Process for making ethanol from acetic acid using acidic catalysts |
| US7855303B2 (en) | 2008-11-14 | 2010-12-21 | Celanese International Corporation | Integrated process for the production of vinyl acetate from acetic acid via ethylene |
| NZ599463A (en) * | 2009-10-26 | 2014-05-30 | Celanese Int Corp | Process for making ethanol from acetic acid using acidic catalysts |
| US8541633B2 (en) | 2010-02-02 | 2013-09-24 | Celanese International Corporation | Processes for producing anhydrous ethanol compositions |
| US8932372B2 (en) | 2010-02-02 | 2015-01-13 | Celanese International Corporation | Integrated process for producing alcohols from a mixed acid feed |
| US8728179B2 (en) | 2010-02-02 | 2014-05-20 | Celanese International Corporation | Ethanol compositions |
| US8344186B2 (en) * | 2010-02-02 | 2013-01-01 | Celanese International Corporation | Processes for producing ethanol from acetaldehyde |
| US8314272B2 (en) | 2010-02-02 | 2012-11-20 | Celanese International Corporation | Process for recovering ethanol with vapor separation |
| US8460405B2 (en) | 2010-02-02 | 2013-06-11 | Celanese International Corporation | Ethanol compositions |
| US8680343B2 (en) | 2010-02-02 | 2014-03-25 | Celanese International Corporation | Process for purifying ethanol |
| US8747492B2 (en) | 2010-02-02 | 2014-06-10 | Celanese International Corporation | Ethanol/fuel blends for use as motor fuels |
| US8668750B2 (en) | 2010-02-02 | 2014-03-11 | Celanese International Corporation | Denatured fuel ethanol compositions for blending with gasoline or diesel fuel for use as motor fuels |
| US8222466B2 (en) | 2010-02-02 | 2012-07-17 | Celanese International Corporation | Process for producing a water stream from ethanol production |
| US8858659B2 (en) * | 2010-02-02 | 2014-10-14 | Celanese International Corporation | Processes for producing denatured ethanol |
| US8754267B2 (en) | 2010-05-07 | 2014-06-17 | Celanese International Corporation | Process for separating acetaldehyde from ethanol-containing mixtures |
| US8680342B2 (en) | 2010-05-07 | 2014-03-25 | Celanese International Corporation | Process for recovering alcohol produced by hydrogenating an acetic acid feed stream comprising water |
| US20130035517A1 (en) * | 2011-08-03 | 2013-02-07 | Celanese International Corporation | Production of alcohols |
| DE102011085165A1 (de) | 2011-10-25 | 2013-04-25 | Wacker Chemie Ag | Verfahren zur Herstellung von Vinylacetat |
| US8703868B2 (en) | 2011-11-28 | 2014-04-22 | Celanese International Corporation | Integrated process for producing polyvinyl alcohol or a copolymer thereof and ethanol |
| US8697802B2 (en) | 2011-11-28 | 2014-04-15 | Celanese International Corporation | Process for producing polyvinyl alcohol or a copolymer thereof |
| US9556100B2 (en) * | 2012-07-02 | 2017-01-31 | Basf Corporation | Method and catalyst composite for production of vinyl acetate monomer |
| ES2608341T3 (es) * | 2012-08-30 | 2017-04-07 | Celanese International Corporation | Procedimiento para la producción de acetato de vinilo que tiene reactor colateral para columna de predeshidratación |
| DE102013006794A1 (de) * | 2013-04-19 | 2014-10-23 | Thyssenkrupp Industrial Solutions Ag | Verfahren und Vorrichtung zur Herstellung von Schalenkatalysatoren |
| US20160237005A1 (en) * | 2013-10-25 | 2016-08-18 | Shell Oil Company | Process for the oxidative dehydrogenation of ethane to ethylene |
| CN104672046B (zh) * | 2015-03-20 | 2017-01-11 | 中国石油大学(华东) | 一种将碳四烯烃分离后回炼在催化裂化或裂解过程中增产乙烯和丙烯的方法 |
| GB201509019D0 (en) * | 2015-05-27 | 2015-07-08 | Johnson Matthey Plc | Process and catalyst |
| CN106622283A (zh) * | 2016-11-30 | 2017-05-10 | 山东玉皇化工有限公司 | 乙醇一步法合成乙酸乙酯联产正丁醇所用催化剂制备方法 |
| TWI923590B (zh) | 2020-06-11 | 2026-05-01 | 美商瑟蘭斯國際股份有限公司 | 用於乙酸乙烯酯製造之催化劑的製備方法 |
| CN114425454B (zh) * | 2020-10-14 | 2024-02-02 | 中国石油化工股份有限公司 | 醋酸乙烯催化剂及醋酸乙烯合成方法 |
| US20240270923A1 (en) * | 2021-06-11 | 2024-08-15 | Eastman Chemical Company | Recycled content polyvinyl alcohol |
| WO2025188777A1 (en) * | 2024-03-04 | 2025-09-12 | New Product Innovations, Llc | Processes for making vinyl acetate from ethylene glycol diacetate |
Family Cites Families (60)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2021698A (en) | 1935-11-19 | Vinyl ester | ||
| US2425389A (en) | 1947-08-12 | Manufacture of vinyl esters | ||
| US2859241A (en) | 1958-11-04 | Production of vinyl esters | ||
| US2607807A (en) * | 1950-02-24 | 1952-08-19 | Du Pont | Preparation of alcohols from carboxylic acids |
| US2882244A (en) | 1953-12-24 | 1959-04-14 | Union Carbide Corp | Molecular sieve adsorbents |
| US3130007A (en) | 1961-05-12 | 1964-04-21 | Union Carbide Corp | Crystalline zeolite y |
| US3702886A (en) | 1969-10-10 | 1972-11-14 | Mobil Oil Corp | Crystalline zeolite zsm-5 and method of preparing the same |
| US4048096A (en) | 1976-04-12 | 1977-09-13 | E. I. Du Pont De Nemours And Company | Surface impregnated catalyst |
| US4126539A (en) * | 1977-12-05 | 1978-11-21 | Mobil Oil Corporation | Method and arrangement of apparatus for hydrogenating hydrocarbons |
| US4270015A (en) | 1979-02-05 | 1981-05-26 | Texaco Inc. | Manufacture of ethylene from synthesis gas (D#75,673-C1) |
| JPS5657735A (en) | 1979-10-18 | 1981-05-20 | Mitsubishi Gas Chem Co Inc | Preparation of vinyl acetate |
| DE3168329D1 (en) | 1980-09-16 | 1985-02-28 | Mitsubishi Gas Chemical Co | One step process for producing vinyl acetate |
| US4398039A (en) | 1981-05-18 | 1983-08-09 | The Standard Oil Company | Hydrogenation of carboxylic acids |
| DE3221077A1 (de) * | 1982-06-04 | 1983-12-08 | Basf Ag, 6700 Ludwigshafen | Verfahren zur kontinuierlichen herstellung von ethanol |
| US4421939A (en) | 1982-10-15 | 1983-12-20 | Union Carbide Corporation | Production of ethanol from acetic acid |
| US4399305A (en) | 1982-10-18 | 1983-08-16 | Union Carbide Corporation | Production of ethylene by the pyrolysis of ethyl acetate |
| US4480115A (en) | 1983-03-17 | 1984-10-30 | Celanese Corporation | Direct hydrogenation of carboxylic acids to alcohol and esters |
| GB2162572B (en) | 1984-06-16 | 1988-12-14 | Vinten Ltd | Improvements in or relating to interface mechanisms |
| FR2570370B1 (fr) | 1984-09-17 | 1987-03-20 | Atochem | Procede de fabrication d'ethylene a partir d'esters ethyliques |
| EP0175558A1 (en) | 1984-09-17 | 1986-03-26 | EASTMAN KODAK COMPANY (a New Jersey corporation) | Process for the vapor phase hydrogenation of carboxylic acids to esters and alcohols |
| FR2577217B1 (fr) | 1985-02-08 | 1987-02-20 | Rhone Poulenc Chim Base | Procede d'hydrogenation de l'acide acetique |
| GB8509530D0 (en) * | 1985-04-13 | 1985-05-15 | Bp Chem Int Ltd | Hydrogenation of carboxylic acids |
| JPS63179845A (ja) * | 1986-08-14 | 1988-07-23 | Idemitsu Kosan Co Ltd | カルボン酸エステルの製造方法 |
| US5149680A (en) | 1987-03-31 | 1992-09-22 | The British Petroleum Company P.L.C. | Platinum group metal alloy catalysts for hydrogenation of carboxylic acids and their anhydrides to alcohols and/or esters |
| DE3803900A1 (de) | 1988-02-09 | 1989-08-17 | Hoechst Ag | Verfahren zur herstellung von vinylacetat |
| US4873392A (en) * | 1988-04-25 | 1989-10-10 | Concordia University | Catalytic conversion of aqueous ethanol to ethylene |
| US4933204A (en) | 1988-09-23 | 1990-06-12 | Rockwell International Corporation | Method of producing a gold film |
| US5185308A (en) | 1991-05-06 | 1993-02-09 | Bp Chemicals Limited | Catalysts and processes for the manufacture of vinyl acetate |
| EP0644866B1 (en) * | 1992-05-27 | 1996-08-14 | Exxon Chemical Patents Inc. | Use of acid extracted molecular sieve catalysts in oxygenate conversion |
| US5821111A (en) | 1994-03-31 | 1998-10-13 | Bioengineering Resources, Inc. | Bioconversion of waste biomass to useful products |
| USRE35377E (en) | 1993-05-27 | 1996-11-12 | Steinberg; Meyer | Process and apparatus for the production of methanol from condensed carbonaceous material |
| DE4323981C1 (de) * | 1993-07-16 | 1995-03-09 | Hoechst Ag | Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat |
| DE19613791C2 (de) | 1996-04-04 | 2002-01-31 | Celanese Chem Europe Gmbh | Katalysator, Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Vinylacetat |
| US5691267A (en) | 1996-04-16 | 1997-11-25 | Hoechst Celanese Corporation | Two step gold addition method for preparing a vinyl acetate catalyst |
| GB9616573D0 (en) * | 1996-08-07 | 1996-09-25 | Bp Chem Int Ltd | Process |
| US5731456A (en) | 1996-12-13 | 1998-03-24 | Eastman Chemical Company | Preparation of vinyl acetate |
| US5719315A (en) | 1996-12-13 | 1998-02-17 | Eastman Chemical Company | Process for the preparation of vinyl acetate |
| DE19734974A1 (de) | 1997-08-13 | 1999-02-25 | Hoechst Ag | Verfahren zur Herstellung von porös geträgerten Metall-Nanopartikel-haltigen Katalysatoren, insbesondere für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat |
| US6121498A (en) * | 1998-04-30 | 2000-09-19 | Eastman Chemical Company | Method for producing acetaldehyde from acetic acid |
| DE19914066A1 (de) * | 1999-03-27 | 2000-10-05 | Celanese Chem Europe Gmbh | Katalysatoren für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE19920390C2 (de) * | 1999-05-04 | 2002-08-01 | Celanese Chem Europe Gmbh | Katalysator und Verfahren zur Herstellung von Vinylacetat |
| US6232352B1 (en) | 1999-11-01 | 2001-05-15 | Acetex Limited | Methanol plant retrofit for acetic acid manufacture |
| ES2265943T3 (es) | 2000-05-19 | 2007-03-01 | Celanese International Corporation | Proceso para la produccion de acetato de vinilo. |
| GB0014583D0 (en) * | 2000-06-14 | 2000-08-09 | Bp Chem Int Ltd | Process |
| WO2002028792A1 (en) * | 2000-09-29 | 2002-04-11 | Koa Glass Co., Ltd. | Antibacterial glass and method for production thereof |
| GB0026241D0 (en) * | 2000-10-26 | 2000-12-13 | Bp Chem Int Ltd | Process |
| US6657078B2 (en) | 2001-02-07 | 2003-12-02 | Celanese International Corporation | Low energy carbonylation process |
| US6685754B2 (en) | 2001-03-06 | 2004-02-03 | Alchemix Corporation | Method for the production of hydrogen-containing gaseous mixtures |
| US6673978B2 (en) | 2001-05-11 | 2004-01-06 | Exxonmobil Chemical Patents Inc. | Process for making olefins |
| EP1421044B1 (en) | 2001-07-02 | 2007-03-07 | Exxonmobil Chemical Patents Inc. | Inhibiting catalyst coke formation in the manufacture of an olefin |
| JP2006116439A (ja) | 2004-10-21 | 2006-05-11 | National Institute Of Advanced Industrial & Technology | エチレン製造用触媒およびこの触媒を用いるエチレンの製造方法 |
| US7700801B2 (en) * | 2004-11-15 | 2010-04-20 | Celanese International Corporation | Co-production of vinyl acetate and ethyl acetate |
| CN101535217B (zh) * | 2006-04-13 | 2014-08-27 | 陶氏环球技术有限责任公司 | 碳值利用提高的混合醇合成方法 |
| CN1974007A (zh) * | 2006-12-21 | 2007-06-06 | 复旦大学 | 一种改性无粘结剂zsm－5沸石催化剂及其制备方法 |
| US8471075B2 (en) * | 2008-07-31 | 2013-06-25 | Celanese International Corporation | Processes for making ethanol from acetic acid |
| US20100030002A1 (en) | 2008-07-31 | 2010-02-04 | Johnston Victor J | Ethylene production from acetic acid utilizing dual reaction zone process |
| US7820852B2 (en) * | 2008-07-31 | 2010-10-26 | Celanese International Corporation | Direct and selective production of ethyl acetate from acetic acid utilizing a bimetal supported catalyst |
| US20100030001A1 (en) | 2008-07-31 | 2010-02-04 | Laiyuan Chen | Process for catalytically producing ethylene directly from acetic acid in a single reaction zone |
| US7855303B2 (en) | 2008-11-14 | 2010-12-21 | Celanese International Corporation | Integrated process for the production of vinyl acetate from acetic acid via ethylene |
| US8178715B2 (en) | 2008-12-31 | 2012-05-15 | Celanese International Corporation | Integrated process for the production of vinyl acetate from acetic acid via acetaldehyde |
-
2008
- 2008-11-14 US US12/291,949 patent/US7855303B2/en not_active Expired - Fee Related
-
2009
- 2009-11-06 MX MX2011005091A patent/MX2011005091A/es active IP Right Grant
- 2009-11-06 EP EP20090756584 patent/EP2349972B1/en not_active Not-in-force
- 2009-11-06 CN CN2009801525517A patent/CN102264686A/zh active Pending
- 2009-11-06 WO PCT/US2009/006016 patent/WO2010056299A1/en not_active Ceased
- 2009-11-06 AU AU2009314619A patent/AU2009314619A1/en not_active Abandoned
- 2009-11-06 BR BRPI0922092A patent/BRPI0922092A2/pt not_active IP Right Cessation
- 2009-11-06 KR KR1020117013484A patent/KR20110082631A/ko not_active Withdrawn
- 2009-11-06 RU RU2011123906/04A patent/RU2011123906A/ru not_active Application Discontinuation
- 2009-11-06 JP JP2011536313A patent/JP2012508736A/ja not_active Ceased
- 2009-11-06 CA CA2743448A patent/CA2743448A1/en not_active Abandoned
- 2009-11-06 NZ NZ592785A patent/NZ592785A/xx not_active IP Right Cessation
-
2010
- 2010-12-02 US US12/959,024 patent/US8071806B2/en not_active Expired - Fee Related
-
2011
- 2011-05-10 ZA ZA2011/03413A patent/ZA201103413B/en unknown
- 2011-05-12 IL IL212861A patent/IL212861A0/en unknown
- 2011-05-13 CL CL2011001095A patent/CL2011001095A1/es unknown
- 2011-05-26 CO CO11065367A patent/CO6420334A2/es not_active Application Discontinuation
- 2011-12-02 US US13/310,290 patent/US8309757B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2012508736A (ja) | 2012-04-12 |
| KR20110082631A (ko) | 2011-07-19 |
| MX2011005091A (es) | 2011-07-20 |
| US20110071312A1 (en) | 2011-03-24 |
| US20120078006A1 (en) | 2012-03-29 |
| NZ592785A (en) | 2012-10-26 |
| CN102264686A (zh) | 2011-11-30 |
| US8309757B2 (en) | 2012-11-13 |
| IL212861A0 (en) | 2011-07-31 |
| US8071806B2 (en) | 2011-12-06 |
| US20100125148A1 (en) | 2010-05-20 |
| CA2743448A1 (en) | 2010-05-20 |
| AU2009314619A1 (en) | 2010-05-20 |
| ZA201103413B (en) | 2012-07-25 |
| RU2011123906A (ru) | 2012-12-20 |
| CL2011001095A1 (es) | 2011-10-14 |
| US7855303B2 (en) | 2010-12-21 |
| EP2349972A1 (en) | 2011-08-03 |
| WO2010056299A1 (en) | 2010-05-20 |
| CO6420334A2 (es) | 2012-04-16 |
| EP2349972B1 (en) | 2015-05-20 |
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