BRPI0922443A2 - processos para a produção continuamente de corpos de catalisador de forma geométrica k, e para a oxidação parcial em fase gasosa heterogeneamente catalisada de um composto orgânico. - Google Patents

processos para a produção continuamente de corpos de catalisador de forma geométrica k, e para a oxidação parcial em fase gasosa heterogeneamente catalisada de um composto orgânico.

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Publication number
BRPI0922443A2
BRPI0922443A2 BRPI0922443A BRPI0922443A BRPI0922443A2 BR PI0922443 A2 BRPI0922443 A2 BR PI0922443A2 BR PI0922443 A BRPI0922443 A BR PI0922443A BR PI0922443 A BRPI0922443 A BR PI0922443A BR PI0922443 A2 BRPI0922443 A2 BR PI0922443A2
Authority
BR
Brazil
Prior art keywords
processes
organic compound
gas phase
continuous production
geometric shape
Prior art date
Application number
BRPI0922443A
Other languages
English (en)
Inventor
Andreas Raichle
Catharina Horstmann
Holger Borchert
Josef Macht
Klaus Joachim Müller-Engel
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of BRPI0922443A2 publication Critical patent/BRPI0922443A2/pt
Publication of BRPI0922443B1 publication Critical patent/BRPI0922443B1/pt

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/009—Preparation by separation, e.g. by filtration, decantation, screening
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
BRPI0922443-2A 2008-12-12 2009-12-04 Processos para a produção continuamente de corpos de catalisador de forma geométrica k, e para a oxidação parcial em fase gasosa heterogeneamente catalisada de um composto orgânico. BRPI0922443B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US12212908P 2008-12-12 2008-12-12
US61/122129 2008-12-12
DE102008054586.4 2008-12-12
DE102008054586A DE102008054586A1 (de) 2008-12-12 2008-12-12 Verfahren zur kontinuierlichen Herstellung von geometrischen Katalysatorformkörpern K
PCT/EP2009/066430 WO2010066645A2 (de) 2008-12-12 2009-12-04 Verfahren zur kontinuierlichen herstellung von geometrischen katalysatorformkörpern k

Publications (2)

Publication Number Publication Date
BRPI0922443A2 true BRPI0922443A2 (pt) 2015-12-15
BRPI0922443B1 BRPI0922443B1 (pt) 2018-02-06

Family

ID=42168291

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0922443-2A BRPI0922443B1 (pt) 2008-12-12 2009-12-04 Processos para a produção continuamente de corpos de catalisador de forma geométrica k, e para a oxidação parcial em fase gasosa heterogeneamente catalisada de um composto orgânico.

Country Status (12)

Country Link
US (2) US8298980B2 (pt)
EP (1) EP2376223B1 (pt)
JP (1) JP5456055B2 (pt)
KR (1) KR101727334B1 (pt)
CN (1) CN102316978B (pt)
BR (1) BRPI0922443B1 (pt)
DE (1) DE102008054586A1 (pt)
MY (1) MY154008A (pt)
RU (1) RU2507001C2 (pt)
TW (1) TWI460014B (pt)
WO (1) WO2010066645A2 (pt)
ZA (1) ZA201105083B (pt)

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KR20130131306A (ko) * 2010-07-30 2013-12-03 바스프 에스이 o-자일렌 및/또는 나프탈렌의 프탈산 무수물로의 산화를 위한 촉매
DE102010048405A1 (de) 2010-10-15 2011-05-19 Basf Se Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation von Proben zu Acrolein
BR112014000343B1 (pt) 2011-07-12 2019-12-24 Basf Se composição de óxido multimetálico, catalisador revestido, corpo de catalisador formado todo ativo, processo para preparar unia composição de óxido multimetálico, e, uso de pelo menos um óxido multimetálico
DE102011084040A1 (de) 2011-10-05 2012-01-05 Basf Se Mo, Bi und Fe enthaltende Multimetalloxidmasse
DE102011079035A1 (de) 2011-07-12 2013-01-17 Basf Se Mo, Bi und Fe enthaltende Multimetalloxidmassen
CN103769134B (zh) * 2012-10-24 2015-09-30 中国石油化工股份有限公司 异丁烯部分氧化制甲基丙烯醛催化剂的制备方法
CN103769135B (zh) * 2012-10-24 2015-11-18 中国石油化工股份有限公司 一种异丁烯部分氧化制甲基丙烯醛催化剂的制备方法
DE102013202048A1 (de) 2013-02-07 2013-04-18 Basf Se Verfahren zur Herstellung einer katalytisch aktiven Masse, die ein Gemisch aus einem die Elemente Mo und V enthaltenden Multielementoxid und wenigstens einem Oxid des Molybdäns ist
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US10525448B2 (en) 2015-07-22 2020-01-07 Basf Corporation High geometric surface area catalysts for vinyl acetate monomer production
CA3060680A1 (en) 2016-05-06 2017-11-09 Whole Bath, Llc A medicine delivery, wash, clean and air dry system
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DE102018200841A1 (de) 2018-01-19 2019-07-25 Basf Se Mo, Bi, Fe und Cu enthaltende Multimetalloxidmassen
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EP3770145A1 (en) 2019-07-24 2021-01-27 Basf Se A process for the continuous production of either acrolein or acrylic acid as the target product from propene
WO2021152916A1 (ja) * 2020-01-31 2021-08-05 三菱ケミカル株式会社 触媒の製造方法及びアクリル酸の製造方法
US12343708B2 (en) 2020-04-21 2025-07-01 Basf Se Method for producing a catalytically active multi-element oxide containing the elements Mo, W, V and Cu
US20240091756A1 (en) 2020-10-29 2024-03-21 Basf Se Method for producing a core-shell catalyst
KR20250049400A (ko) 2022-08-16 2025-04-11 바스프 에스이 알켄 및/또는 알코올을 기체상 산화시켜 α,β-불포화 알데히드 및/또는 α,β-불포화 카복실산을 형성하기 위한 벌크 촉매 성형 바디를 제조하는 방법
JP2025541831A (ja) 2022-12-07 2025-12-23 ベーアーエスエフ・エスエー 元素Ｍｏ、Ｗ、Ｖ、Ｃｕ、およびＳｂを含有する触媒活性多元素酸化物を製造するための方法
WO2025125092A1 (de) 2023-12-14 2025-06-19 Basf Se Verfahren zur herstellung eines die elemente mo, w, v, cu und sb enthaltenden katalytisch aktiven multielementoxids
WO2025172145A1 (de) 2024-02-16 2025-08-21 Basf Se Anorganische faser-haltiger multi-element-vollkatalysatorformkörper zur herstellung von ungesättigten aldehyden und ungesättigten carbonsäuren; dessen herstellungsverfahren sowie verwendung in der gasphasenoxidation
WO2025176520A1 (de) 2024-02-23 2025-08-28 Basf Se Verfahren zur herstellung eines ethylenisch ungesättigten aldehyds und/oder einer ethylenisch ungesättigten carbonsäure an einem katalysatorfestbett eines rohrbündelreaktors
WO2026017456A1 (de) 2024-07-15 2026-01-22 Basf Se Verfahren zur herstellung eines katalysators umfassend eine wasserbehandlung

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DE102008054586A1 (de) 2010-06-17
CN102316978A (zh) 2012-01-11
EP2376223B1 (de) 2016-03-16
JP2012511412A (ja) 2012-05-24
ZA201105083B (en) 2012-10-31
RU2507001C2 (ru) 2014-02-20
TW201029741A (en) 2010-08-16
WO2010066645A3 (de) 2011-06-16
KR20110098949A (ko) 2011-09-02
BRPI0922443B1 (pt) 2018-02-06
TWI460014B (zh) 2014-11-11
JP5456055B2 (ja) 2014-03-26
RU2011128398A (ru) 2013-01-20
US20100152475A1 (en) 2010-06-17
MY154008A (en) 2015-04-30
KR101727334B1 (ko) 2017-04-14
US8546293B2 (en) 2013-10-01
US20130006009A1 (en) 2013-01-03
WO2010066645A2 (de) 2010-06-17
CN102316978B (zh) 2014-03-05
US8298980B2 (en) 2012-10-30

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