BRPI1009577B1 - processo para preparar uma mistura de gás rica em hidrogênio - Google Patents

processo para preparar uma mistura de gás rica em hidrogênio Download PDF

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Publication number
BRPI1009577B1
BRPI1009577B1 BRPI1009577A BRPI1009577A BRPI1009577B1 BR PI1009577 B1 BRPI1009577 B1 BR PI1009577B1 BR PI1009577 A BRPI1009577 A BR PI1009577A BR PI1009577 A BRPI1009577 A BR PI1009577A BR PI1009577 B1 BRPI1009577 B1 BR PI1009577B1
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BR
Brazil
Prior art keywords
mixture
gas
gas mixture
halogen
hydrogen rich
Prior art date
Application number
BRPI1009577A
Other languages
English (en)
Inventor
Jan Prins Mark
Simon Henri Fleys Matthieu
Van Den Berg Robert
Original Assignee
Air Prod & Chem
Shell Int Research
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Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=40912110&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BRPI1009577(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Air Prod & Chem, Shell Int Research filed Critical Air Prod & Chem
Publication of BRPI1009577A2 publication Critical patent/BRPI1009577A2/pt
Publication of BRPI1009577B1 publication Critical patent/BRPI1009577B1/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/06—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents
    • C01B3/12—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/52—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by contacting with liquids; Regeneration of used liquids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/466—Entrained flow processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/101—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C01B2203/0288—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing two CO-shift steps
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415—Purification by absorption in liquids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Industrial Gases (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

processo para preparar uma mistura de gás rica em hidrogênio processo para preparar uma mistura de gás rica em hidrogênio a partir de uma mistura de gás contendo halogênio compreendendo hidrogênio e pelo menos 50% em volume de monóxido de carbono, em uma base seca, contatando a mistura de gás contendo halogênio com água tendo uma temperatura de entre 150 e 250 °c para obter uma mistura de gás pobre em halogênio e tendo uma relação molar de monóxido de carbono para vapor de entre 0,2:1 e 0,9:1 e submetendo dita mistura de gás pobre em halogênio a uma reação de deslocamento do gás de água em que parte todo o monóxido de carbono é convertido com o vapor em hidrogênio e dióxido de carbono na presença de um catalisador como presente em um reator de leito fixo ou em uma série de mais que um reator de leito fixo e em que a temperatura da mistura de gás conforme ela entra no reator ou reatores está entre 190 e 230 °c.
BRPI1009577A 2009-03-19 2010-03-18 processo para preparar uma mistura de gás rica em hidrogênio BRPI1009577B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09155616 2009-03-19
PCT/EP2010/053560 WO2010106148A1 (en) 2009-03-19 2010-03-18 Process to prepare a hydrogen rich gas mixture

Publications (2)

Publication Number Publication Date
BRPI1009577A2 BRPI1009577A2 (pt) 2016-03-08
BRPI1009577B1 true BRPI1009577B1 (pt) 2020-04-28

Family

ID=40912110

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI1009577A BRPI1009577B1 (pt) 2009-03-19 2010-03-18 processo para preparar uma mistura de gás rica em hidrogênio

Country Status (12)

Country Link
US (1) US8679450B2 (pt)
EP (1) EP2408709B2 (pt)
JP (1) JP2012520819A (pt)
KR (1) KR101751076B1 (pt)
AU (1) AU2010224845B2 (pt)
BR (1) BRPI1009577B1 (pt)
CA (1) CA2755325C (pt)
MY (1) MY154030A (pt)
PL (1) PL215440B1 (pt)
RU (1) RU2515967C2 (pt)
UA (1) UA103079C2 (pt)
WO (1) WO2010106148A1 (pt)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102471713B (zh) * 2009-06-30 2015-11-25 国际壳牌研究有限公司 制备富氢气体混合物的方法
GB201119960D0 (en) 2011-11-18 2012-01-04 Johnson Matthey Plc Process
GB201119957D0 (en) 2011-11-18 2012-01-04 Johnson Matthey Plc Process
GB201119962D0 (en) 2011-11-18 2012-01-04 Johnson Matthey Plc Process
US9023243B2 (en) * 2012-08-27 2015-05-05 Proton Power, Inc. Methods, systems, and devices for synthesis gas recapture
US9458014B2 (en) * 2012-12-28 2016-10-04 General Electronic Company Sytems and method for CO2 capture and H2 separation with three water-gas shift reactions and warm desulfurization
RU2755470C1 (ru) * 2020-08-04 2021-09-16 Федеральное государственное автономное образовательное учреждение высшего образования "Сибирский федеральный университет" Способ получения газа, обогащенного водородом, из газообразного углеводородного сырья

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Also Published As

Publication number Publication date
UA103079C2 (uk) 2013-09-10
KR20110139746A (ko) 2011-12-29
PL215440B1 (pl) 2013-12-31
US20120001126A1 (en) 2012-01-05
EP2408709B1 (en) 2013-01-30
AU2010224845A1 (en) 2011-09-22
JP2012520819A (ja) 2012-09-10
CA2755325C (en) 2019-05-28
US8679450B2 (en) 2014-03-25
BRPI1009577A2 (pt) 2016-03-08
EP2408709B2 (en) 2017-11-01
RU2011142140A (ru) 2013-04-27
KR101751076B1 (ko) 2017-06-26
PL396441A1 (pl) 2012-04-23
WO2010106148A1 (en) 2010-09-23
EP2408709A1 (en) 2012-01-25
CA2755325A1 (en) 2010-09-23
RU2515967C2 (ru) 2014-05-20
MY154030A (en) 2015-04-30
AU2010224845B2 (en) 2013-08-22

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Legal Events

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B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B25A Requested transfer of rights approved

Owner name: AIR PRODUCTS AND CHEMICALS, INC. (US)

B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 28/04/2020, OBSERVADAS AS CONDICOES LEGAIS.