CA1032286A - Storage stable binders containing alcoyl silicates and titanates and/or their polymers and film forming resins - Google Patents

Storage stable binders containing alcoyl silicates and titanates and/or their polymers and film forming resins

Info

Publication number: CA1032286A
Authority: CA; Canada
Prior art keywords: parties; les; des; par; une
Prior art date: 1972-03-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA167,336A

Other languages

English (en)

French (fr)

Other versions

CA167336S (en

Inventor

Paul Rostaing

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Rhone Poulenc SA

Original Assignee

Rhone Poulenc SA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1972-03-28

Filing date

1973-03-27

Publication date

1978-05-30

1972-03-28 Priority claimed from FR7210820A external-priority patent/FR2177513A1/fr

1972-12-05 Priority claimed from FR7243189A external-priority patent/FR2208951A2/fr

1973-03-27 Application filed by Rhone Poulenc SA filed Critical Rhone Poulenc SA

1978-05-30 Application granted granted Critical

1978-05-30 Publication of CA1032286A publication Critical patent/CA1032286A/en

Status Expired legal-status Critical Current

Links

150000004760 silicates Chemical class 0.000 title claims abstract description 9
239000011230 binding agent Substances 0.000 title abstract 3
229920005989 resin Polymers 0.000 title abstract 2
239000011347 resin Substances 0.000 title abstract 2
229920000642 polymer Polymers 0.000 title 1
239000000203 mixture Substances 0.000 claims description 35
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 26
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 14
235000012239 silicon dioxide Nutrition 0.000 claims description 14
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 13
229910052725 zinc Inorganic materials 0.000 claims description 13
239000011701 zinc Substances 0.000 claims description 13
229910052681 coesite Inorganic materials 0.000 claims description 12
229910052906 cristobalite Inorganic materials 0.000 claims description 12
239000000377 silicon dioxide Substances 0.000 claims description 12
229910052682 stishovite Inorganic materials 0.000 claims description 12
229910052905 tridymite Inorganic materials 0.000 claims description 12
241000862632 Soja Species 0.000 claims description 10
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 9
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 7
238000013019 agitation Methods 0.000 claims description 5
229920000728 polyester Polymers 0.000 claims description 5
108010039491 Ricin Proteins 0.000 claims description 4
239000003795 chemical substances by application Substances 0.000 claims description 4
150000002148 esters Chemical class 0.000 claims description 4
229920005862 polyol Polymers 0.000 claims description 4
150000003077 polyols Chemical class 0.000 claims description 4
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 3
229910052793 cadmium Inorganic materials 0.000 claims description 3
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 3
239000011575 calcium Substances 0.000 claims description 3
229910052791 calcium Inorganic materials 0.000 claims description 3
229920001296 polysiloxane Polymers 0.000 claims description 3
229910019142 PO4 Inorganic materials 0.000 claims description 2
239000004952 Polyamide Substances 0.000 claims description 2
239000004642 Polyimide Substances 0.000 claims description 2
239000010452 phosphate Substances 0.000 claims description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
239000000049 pigment Substances 0.000 claims description 2
229920002647 polyamide Polymers 0.000 claims description 2
229920000768 polyamine Polymers 0.000 claims description 2
229920000515 polycarbonate Polymers 0.000 claims description 2
239000004417 polycarbonate Substances 0.000 claims description 2
229920001721 polyimide Polymers 0.000 claims description 2
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 1
239000008096 xylene Substances 0.000 claims 1
238000004519 manufacturing process Methods 0.000 abstract description 2
238000000034 method Methods 0.000 abstract description 2
125000000217 alkyl group Chemical group 0.000 abstract 2
125000004432 carbon atom Chemical group C* 0.000 abstract 2
239000000470 constituent Substances 0.000 abstract 2
239000003960 organic solvent Substances 0.000 abstract 1
238000003756 stirring Methods 0.000 abstract 1
239000000243 solution Substances 0.000 description 20
150000003254 radicals Chemical class 0.000 description 8
238000005260 corrosion Methods 0.000 description 6
230000007797 corrosion Effects 0.000 description 6
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
206010001497 Agitation Diseases 0.000 description 4
UDHXJZHVNHGCEC-UHFFFAOYSA-N Chlorophacinone Chemical compound C1=CC(Cl)=CC=C1C(C=1C=CC=CC=1)C(=O)C1C(=O)C2=CC=CC=C2C1=O UDHXJZHVNHGCEC-UHFFFAOYSA-N 0.000 description 4
241001080024 Telles Species 0.000 description 4
240000008042 Zea mays Species 0.000 description 4
239000010445 mica Substances 0.000 description 3
229910052618 mica group Inorganic materials 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical compound C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 3
KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
241001212606 Ambia Species 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
TZRXHJWUDPFEEY-UHFFFAOYSA-N Pentaerythritol Tetranitrate Chemical compound [O-][N+](=O)OCC(CO[N+]([O-])=O)(CO[N+]([O-])=O)CO[N+]([O-])=O TZRXHJWUDPFEEY-UHFFFAOYSA-N 0.000 description 2
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
238000002485 combustion reaction Methods 0.000 description 2
JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
BGTOWKSIORTVQH-UHFFFAOYSA-N cyclopentanone Chemical compound O=C1CCCC1 BGTOWKSIORTVQH-UHFFFAOYSA-N 0.000 description 2
239000000727 fraction Substances 0.000 description 2
230000004224 protection Effects 0.000 description 2
239000010453 quartz Substances 0.000 description 2
229910000077 silane Inorganic materials 0.000 description 2
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 1
FBEHFRAORPEGFH-UHFFFAOYSA-N Allyxycarb Chemical compound CNC(=O)OC1=CC(C)=C(N(CC=C)CC=C)C(C)=C1 FBEHFRAORPEGFH-UHFFFAOYSA-N 0.000 description 1
101100322245 Caenorhabditis elegans des-2 gene Proteins 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
239000005046 Chlorosilane Substances 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
101100421144 Danio rerio selenoo1 gene Proteins 0.000 description 1
101100326341 Drosophila melanogaster brun gene Proteins 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 description 1
240000000233 Melia azedarach Species 0.000 description 1
101100202896 Mus musculus Selenoo gene Proteins 0.000 description 1
229910003910 SiCl4 Inorganic materials 0.000 description 1
229910004738 SiO1 Inorganic materials 0.000 description 1
240000003801 Sigesbeckia orientalis Species 0.000 description 1
235000003407 Sigesbeckia orientalis Nutrition 0.000 description 1
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
239000002671 adjuvant Substances 0.000 description 1
229920000180 alkyd Polymers 0.000 description 1
HIGRAKVNKLCVCA-UHFFFAOYSA-N alumine Chemical compound C1=CC=[Al]C=C1 HIGRAKVNKLCVCA-UHFFFAOYSA-N 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
239000004411 aluminium Substances 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical class Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
-1 des silicates Chemical class 0.000 description 1
229940082150 encore Drugs 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
229940035339 tri-chlor Drugs 0.000 description 1
239000010455 vermiculite Substances 0.000 description 1
229910052902 vermiculite Inorganic materials 0.000 description 1
235000019354 vermiculite Nutrition 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/10—Block or graft copolymers containing polysiloxane sequences

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Paints Or Removers (AREA)
Compositions Of Macromolecular Compounds (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

CA167,336A 1972-03-28 1973-03-27 Storage stable binders containing alcoyl silicates and titanates and/or their polymers and film forming resins Expired CA1032286A (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR7210820A FR2177513A1 (en)	1972-03-28	1972-03-28	Paint binder - consisting of mixture of (poly) alkyl silicate (poly) alkyl titanate, organic or organosilicon resin, and organic so
FR7243189A FR2208951A2 (en)	1972-12-05	1972-12-05	Paint binder - consisting of mixture of (poly) alkyl silicate (poly) alkyl titanate, organic or organosilicon resin, and organic so

Publications (1)

Publication Number	Publication Date
CA1032286A true CA1032286A (en)	1978-05-30

Family

ID=26217003

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA167,336A Expired CA1032286A (en)	1972-03-28	1973-03-27	Storage stable binders containing alcoyl silicates and titanates and/or their polymers and film forming resins

Country Status (12)

Country	Link
US (1)	US3846359A (de)
JP (1)	JPS5130884B2 (de)
AT (1)	AT323856B (de)
CA (1)	CA1032286A (de)
CH (1)	CH561771A5 (de)
ES (2)	ES413088A1 (de)
FI (1)	FI56547C (de)
GB (1)	GB1386546A (de)
IT (1)	IT973303B (de)
NL (1)	NL7303902A (de)
NO (1)	NO141562C (de)
SE (2)	SE390418B (de)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS4841086B1 (de) *	1970-12-23	1973-12-04
US4094853A (en) *	1975-05-15	1978-06-13	Kenrich Petrochemicals, Inc.	Alkoxy titanate salts useful as coupling agents
US4344763A (en) *	1977-11-15	1982-08-17	The Gillette Company	Reactive silicone hair setting compositions
US4224213A (en) *	1978-06-09	1980-09-23	Cook Paint And Varnish Company	Single package inorganic zinc rich paints having a silicate and titanate ester copolymer binder
JPS584937B2 (ja) *	1978-09-29	1983-01-28	東芝シリコ−ン株式会社	ポリオルガノシロキサン組成物
US4221693A (en) *	1979-03-02	1980-09-09	Getson John C	Composition free of surface cure inhibition and method for preparing the same
JPS57121068A (en) *	1981-01-21	1982-07-28	Chisso Corp	Coating solution for forming silica film and its preparation
GB2150581B (en) *	1983-12-05	1987-09-30	Nagy Jozsef	Silicone base artist's paints and their preparation
US4544581A (en) *	1984-09-25	1985-10-01	Depor Industries	Black corrosion resistant coating and method for a metal substrate
US6300404B2 (en) *	1995-08-10	2001-10-09	Kanegafuchi Chemical Industry Co. Ltd.	Curable polymer composition
KR100364064B1 (ko) *	1996-11-22	2005-04-06	에스케이 카켄 가부시끼가이샤	비오염도료조성물
US6395226B1 (en) *	1999-04-06	2002-05-28	Medtronic, Inc.	Alkoxysilane/alkysilane copolymer coating of medical devices
ATE339476T1 (de) *	2000-05-11	2006-10-15	Dow Corning	Antikorrosive überzugszusammensetzung
KR100743955B1 (ko) *	2000-06-09	2007-07-30	랜팩 코포레이션	이동 그리퍼가 있는 깔개 전환 장치, 그 방법 및 제품
US7309528B2 (en) *	2001-05-01	2007-12-18	Dow Corning Gmbh	Protective coating composition
WO2006069376A2 (en) *	2004-12-22	2006-06-29	University Of Cincinnati	Improved superprimer
EP1788042A3 (de) *	2005-09-29	2009-09-09	Mustafa Keddo	Antifouling-Beschichtungszusammensetzung für Wasserfahrzeuge
MY151875A (en) *	2006-01-02	2014-07-14	Akzo Nobel Coatings Int Bv	Heat resistant coating
EA015892B1 (ru) *	2006-01-02	2011-12-30	Акцо Нобель Коатингс Интернэшнл Б.В.	Жаростойкая композиция для покрытия (варианты) и покрытый субстрат
WO2009093319A1 (ja) †	2008-01-24	2009-07-30	Yuken Industry Co., Ltd.	防錆塗料組成物およびその組成物を用いた防錆塗膜を有する部材の製造方法
WO2009093318A1 (ja) *	2008-01-24	2009-07-30	Yuken Industry Co., Ltd.	耐食性塗膜を有する部材、その製造方法、およびそれを製造するための塗料組成物
EP2415844B1 (de) *	2009-03-31	2018-09-12	Daikin Industries, Ltd.	Bei raumtemperatur härtbare harzbeschichtungszusammensetzung
DE102010041676A1 (de)	2010-09-29	2012-03-29	Wacker Chemie Ag	Vernetzbare Organopolysiloxanzusammensetzung
BR112015015029A2 (pt) *	2013-01-04	2017-07-11	Akzo Nobel Coatings Int Bv	composição de revestimento de cura ambiente; composição de revestimento de uma embalagem; resina de poliéster modificada por silicato; processo de preparação de resina de poliéster modificada por silicato; utilização da resina de poliéster modificada por silicato; processo de revestimento de um substrato; e substrato revestido
DE102013204296A1 (de)	2013-03-12	2014-09-18	Wacker Chemie Ag	Flüssige vernetzbare Metall-Siliconharz-Zusammensetzungen
CN114806691B (zh) *	2022-05-25	2023-04-14	中国科学院兰州化学物理研究所	一种室温固化干膜润滑剂及其制备方法和应用

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL84141C (de) *	1951-02-26	1900-01-01
US2736721A (en) *	1952-10-08	1956-02-28		Optionally
US2716656A (en) *	1953-01-21	1955-08-30	Monsanto Chemicals	Organo titanium-silicon copolymer preparation

1972
- 1972-12-29 IT IT33997/72A patent/IT973303B/it active
1973
- 1973-03-20 NL NL7303902A patent/NL7303902A/xx unknown
- 1973-03-26 JP JP48033633A patent/JPS5130884B2/ja not_active Expired
- 1973-03-27 CA CA167,336A patent/CA1032286A/en not_active Expired
- 1973-03-27 SE SE7304313A patent/SE390418B/xx unknown
- 1973-03-27 NO NO1267/73A patent/NO141562C/no unknown
- 1973-03-27 US US00345331A patent/US3846359A/en not_active Expired - Lifetime
- 1973-03-27 GB GB1472573A patent/GB1386546A/en not_active Expired
- 1973-03-27 CH CH442573A patent/CH561771A5/xx not_active IP Right Cessation
- 1973-03-28 ES ES413088A patent/ES413088A1/es not_active Expired
- 1973-03-28 AT AT272173A patent/AT323856B/de not_active IP Right Cessation
- 1973-03-28 FI FI958/73A patent/FI56547C/fi active
1975
- 1975-06-17 SE SE7506960A patent/SE390639B/xx not_active IP Right Cessation
- 1975-09-09 ES ES440813A patent/ES440813A1/es not_active Expired

Also Published As

Publication number	Publication date
NO141562B (no)	1979-12-27
AT323856B (de)	1975-08-11
DE2315539A1 (de)	1973-10-18
NO141562C (no)	1980-04-09
SE7506960L (sv)	1975-06-17
DE2315539B2 (de)	1977-04-07
ES440813A1 (es)	1977-06-01
JPS5130884B2 (de)	1976-09-03
FI56547C (fi)	1980-02-11
ES413088A1 (es)	1976-05-16
GB1386546A (en)	1975-03-05
IT973303B (it)	1974-06-10
SE390418B (sv)	1976-12-20
JPS498544A (de)	1974-01-25
US3846359A (en)	1974-11-05
CH561771A5 (de)	1975-05-15
NL7303902A (de)	1973-10-02
SE390639B (sv)	1977-01-03
FI56547B (fi)	1979-10-31

Publication	Publication Date	Title
CA1032286A (en)	1978-05-30	Storage stable binders containing alcoyl silicates and titanates and/or their polymers and film forming resins
EP0429325B1 (de)	1994-06-15	Verfahren zur Herstellung einer Beschichtungszusammensetzung mit hohem Brechungsindex auf Basis von Polysiloxanen und Titanaten und die so hergestellte Zusammensetzung
EP1140716B1 (de)	2003-11-05	Verfahren zur herstellung eines organosilicium-sols und daraus erhaltene materialien
CA1272327A (fr)	1990-07-31	Vernis a haute durete, resistant a l'abrasion, procede pour leur preparation, et application de ces vernis au revetement de substrats solides
FR2483422A1 (fr)	1981-12-04	Agents absorbant la lumiere ultraviolette ainsi que compositions et articles les utilisant
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