CA1047735A - Synthese de silane - Google Patents

Synthese de silane

Info

Publication number: CA1047735A
Authority: CA; Canada
Prior art keywords: bed; hsicl3; sih4; resin; boiling point
Prior art date: 1975-01-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA218,542A

Other languages

English (en)

Other versions

CA218542S (en

Inventor

Carl J. Bakay

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Union Carbide Corp

Original Assignee

Union Carbide Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-01-23

Filing date

1975-01-23

Publication date

1979-02-06

1975-01-23 Application filed by Union Carbide Corp filed Critical Union Carbide Corp

1975-01-23 Priority to CA218,542A priority Critical patent/CA1047735A/fr

1979-02-06 Application granted granted Critical

1979-02-06 Publication of CA1047735A publication Critical patent/CA1047735A/fr

Status Expired legal-status Critical Current

Links

BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 title claims abstract description 34
238000000034 method Methods 0.000 title claims abstract description 25
229910000077 silane Inorganic materials 0.000 title abstract description 14
ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 claims abstract description 18
238000009835 boiling Methods 0.000 claims abstract description 13
229910004721 HSiCl3 Inorganic materials 0.000 claims abstract description 11
239000007788 liquid Substances 0.000 claims abstract description 10
239000003957 anion exchange resin Substances 0.000 claims abstract description 9
125000001453 quaternary ammonium group Chemical group 0.000 claims abstract description 9
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 8
229910052799 carbon Inorganic materials 0.000 claims abstract description 8
KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical class Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 claims abstract description 7
125000001302 tertiary amino group Chemical group 0.000 claims abstract description 7
239000007787 solid Substances 0.000 claims abstract description 4
229910003910 SiCl4 Inorganic materials 0.000 claims abstract 2
FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 claims abstract 2
239000011347 resin Substances 0.000 claims description 28
229920005989 resin Polymers 0.000 claims description 28
238000006243 chemical reaction Methods 0.000 claims description 15
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 3
229940116441 divinylbenzene Drugs 0.000 claims description 2
238000007323 disproportionation reaction Methods 0.000 abstract description 12
238000004519 manufacturing process Methods 0.000 abstract description 5
238000010992 reflux Methods 0.000 abstract description 5
239000005046 Chlorosilane Substances 0.000 abstract description 2
239000000047 product Substances 0.000 description 15
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 10
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 7
239000003456 ion exchange resin Substances 0.000 description 7
229920003303 ion-exchange polymer Polymers 0.000 description 7
239000007791 liquid phase Substances 0.000 description 7
229910052710 silicon Inorganic materials 0.000 description 7
239000010703 silicon Substances 0.000 description 7
239000005052 trichlorosilane Substances 0.000 description 7
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
239000011324 bead Substances 0.000 description 6
-1 nochlorosilane Chemical compound 0.000 description 5
MROCJMGDEKINLD-UHFFFAOYSA-N dichlorosilane Chemical compound Cl[SiH2]Cl MROCJMGDEKINLD-UHFFFAOYSA-N 0.000 description 5
239000000463 material Substances 0.000 description 5
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 5
NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical group Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
150000001412 amines Chemical class 0.000 description 4
229920001577 copolymer Polymers 0.000 description 4
230000000694 effects Effects 0.000 description 4
239000007789 gas Substances 0.000 description 4
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 4
229910000041 hydrogen chloride Inorganic materials 0.000 description 4
239000012535 impurity Substances 0.000 description 4
239000000178 monomer Substances 0.000 description 4
230000000704 physical effect Effects 0.000 description 4
239000011148 porous material Substances 0.000 description 4
229920006395 saturated elastomer Polymers 0.000 description 4
230000008961 swelling Effects 0.000 description 4
VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 3
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
125000003277 amino group Chemical group 0.000 description 3
125000004432 carbon atom Chemical group C* 0.000 description 3
229920001429 chelating resin Polymers 0.000 description 3
230000008021 deposition Effects 0.000 description 3
239000012458 free base Substances 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
239000000203 mixture Substances 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
239000005049 silicon tetrachloride Substances 0.000 description 3
150000003512 tertiary amines Chemical class 0.000 description 3
239000012808 vapor phase Substances 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
SLLGVCUQYRMELA-UHFFFAOYSA-N chlorosilicon Chemical compound Cl[Si] SLLGVCUQYRMELA-UHFFFAOYSA-N 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000000354 decomposition reaction Methods 0.000 description 2
125000000524 functional group Chemical group 0.000 description 2
239000011521 glass Substances 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000002245 particle Substances 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
238000005029 sieve analysis Methods 0.000 description 2
238000009834 vaporization Methods 0.000 description 2
230000008016 vaporization Effects 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
WVAFEFUPWRPQSY-UHFFFAOYSA-N 1,2,3-tris(ethenyl)benzene Chemical compound C=CC1=CC=CC(C=C)=C1C=C WVAFEFUPWRPQSY-UHFFFAOYSA-N 0.000 description 1
QLLUAUADIMPKIH-UHFFFAOYSA-N 1,2-bis(ethenyl)naphthalene Chemical class C1=CC=CC2=C(C=C)C(C=C)=CC=C21 QLLUAUADIMPKIH-UHFFFAOYSA-N 0.000 description 1
WEERVPDNCOGWJF-UHFFFAOYSA-N 1,4-bis(ethenyl)benzene Chemical compound C=CC1=CC=C(C=C)C=C1 WEERVPDNCOGWJF-UHFFFAOYSA-N 0.000 description 1
BOVQCIDBZXNFEJ-UHFFFAOYSA-N 1-chloro-3-ethenylbenzene Chemical compound ClC1=CC=CC(C=C)=C1 BOVQCIDBZXNFEJ-UHFFFAOYSA-N 0.000 description 1
KTZVZZJJVJQZHV-UHFFFAOYSA-N 1-chloro-4-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C=C1 KTZVZZJJVJQZHV-UHFFFAOYSA-N 0.000 description 1
IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
FCMUPMSEVHVOSE-UHFFFAOYSA-N 2,3-bis(ethenyl)pyridine Chemical compound C=CC1=CC=CN=C1C=C FCMUPMSEVHVOSE-UHFFFAOYSA-N 0.000 description 1
KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
DZGGGLJOCYPKHN-UHFFFAOYSA-N 4-ethenylquinoline Chemical compound C1=CC=C2C(C=C)=CC=NC2=C1 DZGGGLJOCYPKHN-UHFFFAOYSA-N 0.000 description 1
LKLNVHRUXQQEII-UHFFFAOYSA-N 5-ethenyl-2,3-dimethylpyridine Chemical compound CC1=CC(C=C)=CN=C1C LKLNVHRUXQQEII-UHFFFAOYSA-N 0.000 description 1
VJOWMORERYNYON-UHFFFAOYSA-N 5-ethenyl-2-methylpyridine Chemical compound CC1=CC=C(C=C)C=N1 VJOWMORERYNYON-UHFFFAOYSA-N 0.000 description 1
SFIFMPZUHOERJV-UHFFFAOYSA-N 5-ethenyl-3-ethyl-2-methylpyridine Chemical compound CCC1=CC(C=C)=CN=C1C SFIFMPZUHOERJV-UHFFFAOYSA-N 0.000 description 1
IWLYAVJYGSHMLI-UHFFFAOYSA-N 5-ethenyl-3-methylisoquinoline Chemical compound C1=CC=C2C=NC(C)=CC2=C1C=C IWLYAVJYGSHMLI-UHFFFAOYSA-N 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
241001174990 Boros Species 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
125000003282 alkyl amino group Chemical group 0.000 description 1
125000005210 alkyl ammonium group Chemical group 0.000 description 1
230000029936 alkylation Effects 0.000 description 1
238000005804 alkylation reaction Methods 0.000 description 1
238000005576 amination reaction Methods 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
150000004982 aromatic amines Chemical group 0.000 description 1
150000001502 aryl halides Chemical class 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
HYGWNUKOUCZBND-UHFFFAOYSA-N azanide Chemical group [NH2-] HYGWNUKOUCZBND-UHFFFAOYSA-N 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
235000010290 biphenyl Nutrition 0.000 description 1
239000004305 biphenyl Substances 0.000 description 1
125000006267 biphenyl group Chemical group 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
RBHJBMIOOPYDBQ-UHFFFAOYSA-N carbon dioxide;propan-2-one Chemical compound O=C=O.CC(C)=O RBHJBMIOOPYDBQ-UHFFFAOYSA-N 0.000 description 1
239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
239000003518 caustics Substances 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
230000001143 conditioned effect Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
125000004663 dialkyl amino group Chemical group 0.000 description 1
125000005265 dialkylamine group Chemical group 0.000 description 1
229960004132 diethyl ether Drugs 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
238000004821 distillation Methods 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
150000004678 hydrides Chemical class 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical group [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
230000002427 irreversible effect Effects 0.000 description 1
239000012263 liquid product Substances 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
125000004433 nitrogen atom Chemical group N* 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
DBSDMAPJGHBWAL-UHFFFAOYSA-N penta-1,4-dien-3-ylbenzene Chemical class C=CC(C=C)C1=CC=CC=C1 DBSDMAPJGHBWAL-UHFFFAOYSA-N 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
239000012071 phase Substances 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
125000004076 pyridyl group Chemical group 0.000 description 1
238000005956 quaternization reaction Methods 0.000 description 1
238000007342 radical addition reaction Methods 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
238000012827 research and development Methods 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
238000005070 sampling Methods 0.000 description 1
150000003335 secondary amines Chemical class 0.000 description 1
239000004065 semiconductor Substances 0.000 description 1
125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
239000004416 thermosoftening plastic Substances 0.000 description 1
229930195735 unsaturated hydrocarbon Natural products 0.000 description 1

Landscapes

Silicon Compounds (AREA)

CA218,542A 1975-01-23 1975-01-23 Synthese de silane Expired CA1047735A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA218,542A CA1047735A (fr)	1975-01-23	1975-01-23	Synthese de silane

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA218,542A CA1047735A (fr)	1975-01-23	1975-01-23	Synthese de silane

Publications (1)

Publication Number	Publication Date
CA1047735A true CA1047735A (fr)	1979-02-06

Family

ID=4102133

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA218,542A Expired CA1047735A (fr)	1975-01-23	1975-01-23	Synthese de silane

Country Status (1)

Country	Link
CA (1)	CA1047735A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN115023407A (zh) *	2020-11-05	2022-09-06	瓦克化学股份公司	用于从氯硅烷混合物中除去杂质的方法

1975
- 1975-01-23 CA CA218,542A patent/CA1047735A/fr not_active Expired

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN115023407A (zh) *	2020-11-05	2022-09-06	瓦克化学股份公司	用于从氯硅烷混合物中除去杂质的方法
CN115023407B (zh) *	2020-11-05	2024-05-24	瓦克化学股份公司	用于从氯硅烷混合物中除去杂质的方法

Publication	Publication Date	Title
US3968199A (en)	1976-07-06	Process for making silane
US4113845A (en)	1978-09-12	Disproportionation of chlorosilane
EP0405780B1 (fr)	1995-02-15	Procédé intégré d'alkylation et redistribution de silanes halogénés
US4946980A (en)	1990-08-07	Preparation of organosilanes
CA2025864C (fr)	1995-12-05	Extraction de silanes contenant de l'hydrogene d'un melange d'organosilanes
US3928542A (en)	1975-12-23	Process for the preparation of anion exchange resin for use in the redistribution of chlorosilanes
JPS6096520A (ja)	1985-05-30	メチルジクロルシラン及びクロルシランからシランを製造する方法
US5252768A (en)	1993-10-12	Process for preparing a dimethylchlorosilane
Hollandsworth et al.	1968	Chlorodisilanes. Preparation and silicon-hydrogen stretching frequencies
KR870003124A (ko)	1987-04-15	실란의 제조방법
JPH05194548A (ja)	1993-08-03	３−クロルプロピルシランの製造方法
US4224233A (en)	1980-09-23	Process for the production of alkylsilanes
GB1603760A (en)	1981-11-25	Method of preparing methylsiloxanes and methylchloride
EP0365207B1 (fr)	1995-02-15	Préparation d'organosilanes
JPH0829929B2 (ja)	1996-03-27	ハロゲン化水素化シランの製造方法
US4985580A (en)	1991-01-15	Alkylation of silanes
KR102795503B1 (ko)	2025-04-11	클로로실란 혼합물로부터 불순물을 제거하는 방법
JPS6042216A (ja)	1985-03-06	トリクロロシラン・ジクロロシラン・モノクロロシランの不均斉化方法
JPS643807B2 (fr)	1989-01-23
US3627803A (en)	1971-12-14	High temperature method of preparing organosilicon hydride compounds
US3706777A (en)	1972-12-19	Process for the production of alkyl silanes
US2546330A (en)	1951-03-27	Synthesis of aromatic silane
EP0383566A2 (fr)	1990-08-22	Procédé de préparation de composés organiques du silicium
US5118829A (en)	1992-06-02	Process for cycloalkyl substitution of hydrogen containing silanes
US2591668A (en)	1952-04-08	Preparation of phenyl silicon trichloride