CA1052050A - Cellular moulded articles produced from synthetic resin emulsion - Google Patents

Cellular moulded articles produced from synthetic resin emulsion

Info

Publication number: CA1052050A
Authority: CA; Canada
Prior art keywords: emulsion; flame; water; weight; retarding
Prior art date: 1973-11-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA213,157A

Other languages

English (en)

French (fr)

Other versions

CA213157S (en

Inventor

Gunther Will

Herbert Will

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Individual

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1973-11-07

Filing date

1974-11-06

Publication date

1979-04-03

1974-11-06 Application filed by Individual filed Critical Individual

1979-04-03 Application granted granted Critical

1979-04-03 Publication of CA1052050A publication Critical patent/CA1052050A/en

Status Expired legal-status Critical Current

Links

239000000839 emulsion Substances 0.000 title claims description 93
230000001413 cellular effect Effects 0.000 title description 5
229920003002 synthetic resin Polymers 0.000 title description 2
239000000057 synthetic resin Substances 0.000 title description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 67
238000000034 method Methods 0.000 claims abstract description 49
230000008569 process Effects 0.000 claims abstract description 47
238000001035 drying Methods 0.000 claims abstract description 18
210000003850 cellular structure Anatomy 0.000 claims abstract description 10
238000007493 shaping process Methods 0.000 claims abstract description 5
239000000843 powder Substances 0.000 claims abstract description 3
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 38
239000006185 dispersion Substances 0.000 claims description 31
239000000945 filler Substances 0.000 claims description 30
239000003995 emulsifying agent Substances 0.000 claims description 26
239000000203 mixture Substances 0.000 claims description 20
239000000178 monomer Substances 0.000 claims description 17
239000002245 particle Substances 0.000 claims description 14
239000004033 plastic Substances 0.000 claims description 12
229920003023 plastic Polymers 0.000 claims description 12
229920006305 unsaturated polyester Polymers 0.000 claims description 11
229920001577 copolymer Polymers 0.000 claims description 9
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 8
239000010451 perlite Substances 0.000 claims description 8
235000019362 perlite Nutrition 0.000 claims description 8
239000000126 substance Substances 0.000 claims description 8
239000010425 asbestos Substances 0.000 claims description 7
239000003054 catalyst Substances 0.000 claims description 7
239000011521 glass Substances 0.000 claims description 7
229910010272 inorganic material Inorganic materials 0.000 claims description 7
229910052895 riebeckite Inorganic materials 0.000 claims description 7
150000002484 inorganic compounds Chemical class 0.000 claims description 6
239000007788 liquid Substances 0.000 claims description 6
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 5
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 4
150000001875 compounds Chemical class 0.000 claims description 4
125000005395 methacrylic acid group Chemical group 0.000 claims description 4
125000005396 acrylic acid ester group Chemical group 0.000 claims description 3
229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 3
229910021538 borax Inorganic materials 0.000 claims description 3
239000000499 gel Substances 0.000 claims description 3
239000003112 inhibitor Substances 0.000 claims description 3
239000010453 quartz Substances 0.000 claims description 3
150000003839 salts Chemical class 0.000 claims description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
239000004328 sodium tetraborate Substances 0.000 claims description 3
235000010339 sodium tetraborate Nutrition 0.000 claims description 3
239000000080 wetting agent Substances 0.000 claims description 3
239000005995 Aluminium silicate Substances 0.000 claims description 2
235000012211 aluminium silicate Nutrition 0.000 claims description 2
229910000323 aluminium silicate Inorganic materials 0.000 claims description 2
229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
239000001569 carbon dioxide Substances 0.000 claims description 2
229910002092 carbon dioxide Inorganic materials 0.000 claims description 2
239000004927 clay Substances 0.000 claims description 2
238000004132 cross linking Methods 0.000 claims description 2
238000002425 crystallisation Methods 0.000 claims description 2
239000000975 dye Substances 0.000 claims description 2
239000004615 ingredient Substances 0.000 claims description 2
239000000391 magnesium silicate Substances 0.000 claims description 2
229910052919 magnesium silicate Inorganic materials 0.000 claims description 2
235000019792 magnesium silicate Nutrition 0.000 claims description 2
235000019353 potassium silicate Nutrition 0.000 claims description 2
239000008262 pumice Substances 0.000 claims description 2
239000002893 slag Substances 0.000 claims description 2
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
239000010455 vermiculite Substances 0.000 claims description 2
229910052902 vermiculite Inorganic materials 0.000 claims description 2
235000019354 vermiculite Nutrition 0.000 claims description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims 2
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims 2
238000010348 incorporation Methods 0.000 claims 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims 1
239000001175 calcium sulphate Substances 0.000 claims 1
235000011132 calcium sulphate Nutrition 0.000 claims 1
239000002657 fibrous material Substances 0.000 claims 1
239000011236 particulate material Substances 0.000 claims 1
229910000030 sodium bicarbonate Inorganic materials 0.000 claims 1
235000017557 sodium bicarbonate Nutrition 0.000 claims 1
239000011148 porous material Substances 0.000 abstract description 16
239000007762 w/o emulsion Substances 0.000 abstract description 9
239000006260 foam Substances 0.000 description 18
239000000463 material Substances 0.000 description 16
210000004027 cell Anatomy 0.000 description 13
229920005989 resin Polymers 0.000 description 13
239000011347 resin Substances 0.000 description 13
230000000694 effects Effects 0.000 description 11
239000000047 product Substances 0.000 description 11
238000012360 testing method Methods 0.000 description 9
-1 epoxide compounds Chemical class 0.000 description 8
239000012071 phase Substances 0.000 description 7
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
239000002253 acid Substances 0.000 description 6
238000007792 addition Methods 0.000 description 6
238000002474 experimental method Methods 0.000 description 6
229920000728 polyester Polymers 0.000 description 6
229920000642 polymer Polymers 0.000 description 6
230000008901 benefit Effects 0.000 description 5
150000002148 esters Chemical class 0.000 description 5
238000004519 manufacturing process Methods 0.000 description 5
239000007787 solid Substances 0.000 description 5
150000001298 alcohols Chemical class 0.000 description 4
230000000875 corresponding effect Effects 0.000 description 4
230000002209 hydrophobic effect Effects 0.000 description 4
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
230000009471 action Effects 0.000 description 3
239000000654 additive Substances 0.000 description 3
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
230000008859 change Effects 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
238000009415 formwork Methods 0.000 description 3
238000009413 insulation Methods 0.000 description 3
229920001225 polyester resin Polymers 0.000 description 3
239000004645 polyester resin Substances 0.000 description 3
AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
PGSWEKYNAOWQDF-UHFFFAOYSA-N 3-methylcatechol Chemical compound CC1=CC=CC(O)=C1O PGSWEKYNAOWQDF-UHFFFAOYSA-N 0.000 description 2
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
239000004342 Benzoyl peroxide Substances 0.000 description 2
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
239000003513 alkali Substances 0.000 description 2
230000004075 alteration Effects 0.000 description 2
239000005030 aluminium foil Substances 0.000 description 2
ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
239000002585 base Substances 0.000 description 2
GCAIEATUVJFSMC-UHFFFAOYSA-N benzene-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1C(O)=O GCAIEATUVJFSMC-UHFFFAOYSA-N 0.000 description 2
235000019400 benzoyl peroxide Nutrition 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000004566 building material Substances 0.000 description 2
YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
239000004568 cement Substances 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
239000011362 coarse particle Substances 0.000 description 2
IFDVQVHZEKPUSC-UHFFFAOYSA-N cyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCC=CC1C(O)=O IFDVQVHZEKPUSC-UHFFFAOYSA-N 0.000 description 2
230000007423 decrease Effects 0.000 description 2
230000018044 dehydration Effects 0.000 description 2
238000006297 dehydration reaction Methods 0.000 description 2
235000014113 dietary fatty acids Nutrition 0.000 description 2
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
238000009826 distribution Methods 0.000 description 2
239000000194 fatty acid Substances 0.000 description 2
229930195729 fatty acid Natural products 0.000 description 2
150000004665 fatty acids Chemical class 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
238000001914 filtration Methods 0.000 description 2
239000011888 foil Substances 0.000 description 2
230000014509 gene expression Effects 0.000 description 2
238000005470 impregnation Methods 0.000 description 2
238000011835 investigation Methods 0.000 description 2
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
GYVGXEWAOAAJEU-UHFFFAOYSA-N n,n,4-trimethylaniline Chemical compound CN(C)C1=CC=C(C)C=C1 GYVGXEWAOAAJEU-UHFFFAOYSA-N 0.000 description 2
150000002825 nitriles Chemical class 0.000 description 2
150000002894 organic compounds Chemical class 0.000 description 2
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 2
150000002978 peroxides Chemical class 0.000 description 2
JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
239000011574 phosphorus Substances 0.000 description 2
229910052698 phosphorus Inorganic materials 0.000 description 2
229920001983 poloxamer Polymers 0.000 description 2
229920001451 polypropylene glycol Polymers 0.000 description 2
229960004063 propylene glycol Drugs 0.000 description 2
239000003340 retarding agent Substances 0.000 description 2
150000004760 silicates Chemical class 0.000 description 2
239000000243 solution Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 2
UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 2
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
230000004580 weight loss Effects 0.000 description 2
UICXTANXZJJIBC-UHFFFAOYSA-N 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(OO)CCCCC1 UICXTANXZJJIBC-UHFFFAOYSA-N 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
VFZKVQVQOMDJEG-UHFFFAOYSA-N 2-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(=O)C=C VFZKVQVQOMDJEG-UHFFFAOYSA-N 0.000 description 1
VQMIUUBKKPIDBN-UHFFFAOYSA-N 4-(hydroxymethyl)cyclohexane-1-carboxylic acid Chemical compound OCC1CCC(C(O)=O)CC1 VQMIUUBKKPIDBN-UHFFFAOYSA-N 0.000 description 1
HFLGBNBLMBSXEM-UHFFFAOYSA-N 4-Ethyl-1,2-benzenediol Chemical compound CCC1=CC=C(O)C(O)=C1 HFLGBNBLMBSXEM-UHFFFAOYSA-N 0.000 description 1
YHAUWIDCXVQMPN-UHFFFAOYSA-N 4-methyl-n,n-di(propan-2-yl)aniline Chemical compound CC(C)N(C(C)C)C1=CC=C(C)C=C1 YHAUWIDCXVQMPN-UHFFFAOYSA-N 0.000 description 1
JKTORXLUQLQJCM-UHFFFAOYSA-N 4-phosphonobutylphosphonic acid Chemical compound OP(O)(=O)CCCCP(O)(O)=O JKTORXLUQLQJCM-UHFFFAOYSA-N 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
239000004908 Emulsion polymer Substances 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 1
WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
229920000877 Melamine resin Polymers 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical group CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
ATTZFSUZZUNHBP-UHFFFAOYSA-N Piperonyl sulfoxide Chemical group CCCCCCCCS(=O)C(C)CC1=CC=C2OCOC2=C1 ATTZFSUZZUNHBP-UHFFFAOYSA-N 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
229920001328 Polyvinylidene chloride Polymers 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
229920001807 Urea-formaldehyde Polymers 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
230000004308 accommodation Effects 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000008186 active pharmaceutical agent Substances 0.000 description 1
239000013543 active substance Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
239000001361 adipic acid Substances 0.000 description 1
235000011037 adipic acid Nutrition 0.000 description 1
239000000956 alloy Substances 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 description 1
150000001463 antimony compounds Chemical class 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
UJMDYLWCYJJYMO-UHFFFAOYSA-N benzene-1,2,3-tricarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1C(O)=O UJMDYLWCYJJYMO-UHFFFAOYSA-N 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
150000001639 boron compounds Chemical class 0.000 description 1
239000001273 butane Substances 0.000 description 1
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000001110 calcium chloride Substances 0.000 description 1
229910001628 calcium chloride Inorganic materials 0.000 description 1
PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 description 1
239000004202 carbamide Substances 0.000 description 1
235000014633 carbohydrates Nutrition 0.000 description 1
150000001720 carbohydrates Chemical class 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
150000003857 carboxamides Chemical class 0.000 description 1
150000007942 carboxylates Chemical class 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000000969 carrier Substances 0.000 description 1
238000005266 casting Methods 0.000 description 1
210000002421 cell wall Anatomy 0.000 description 1
238000012512 characterization method Methods 0.000 description 1
DJKGDNKYTKCJKD-UHFFFAOYSA-N chlorendic acid Chemical compound ClC1=C(Cl)C2(Cl)C(C(=O)O)C(C(O)=O)C1(Cl)C2(Cl)Cl DJKGDNKYTKCJKD-UHFFFAOYSA-N 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
230000001276 controlling effect Effects 0.000 description 1
230000002596 correlated effect Effects 0.000 description 1
OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
239000002274 desiccant Substances 0.000 description 1
150000001991 dicarboxylic acids Chemical class 0.000 description 1
QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
GGSUCNLOZRCGPQ-UHFFFAOYSA-N diethylaniline Chemical compound CCN(CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-N 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
230000001804 emulsifying effect Effects 0.000 description 1
239000003822 epoxy resin Substances 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
229940093476 ethylene glycol Drugs 0.000 description 1
239000004794 expanded polystyrene Substances 0.000 description 1
239000001530 fumaric acid Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
239000003365 glass fiber Substances 0.000 description 1
150000002334 glycols Chemical class 0.000 description 1
229920000578 graft copolymer Polymers 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002366 halogen compounds Chemical class 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
238000006703 hydration reaction Methods 0.000 description 1
150000002433 hydrophilic molecules Chemical class 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
230000006872 improvement Effects 0.000 description 1
150000007529 inorganic bases Chemical class 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
230000001788 irregular Effects 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000004922 lacquer Substances 0.000 description 1
150000002605 large molecules Chemical class 0.000 description 1
HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
238000005259 measurement Methods 0.000 description 1
125000005397 methacrylic acid ester group Chemical group 0.000 description 1
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
239000011707 mineral Substances 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
150000007530 organic bases Chemical class 0.000 description 1
239000012074 organic phase Substances 0.000 description 1
125000006353 oxyethylene group Chemical group 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
238000005192 partition Methods 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
230000035699 permeability Effects 0.000 description 1
239000005011 phenolic resin Substances 0.000 description 1
WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
150000003014 phosphoric acid esters Chemical class 0.000 description 1
LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical compound C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
239000002985 plastic film Substances 0.000 description 1
229920000233 poly(alkylene oxides) Polymers 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920000647 polyepoxide Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920000193 polymethacrylate Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
239000005033 polyvinylidene chloride Substances 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
235000019260 propionic acid Nutrition 0.000 description 1
235000013772 propylene glycol Nutrition 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
230000002787 reinforcement Effects 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
230000000979 retarding effect Effects 0.000 description 1
239000005060 rubber Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000007573 shrinkage measurement Methods 0.000 description 1
239000005368 silicate glass Substances 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000004289 sodium hydrogen sulphite Substances 0.000 description 1
235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
239000002937 thermal insulation foam Substances 0.000 description 1
CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 1
210000001364 upper extremity Anatomy 0.000 description 1
238000009423 ventilation Methods 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
- C08J9/283—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum a discontinuous liquid phase emulsified in a continuous macromolecular phase
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/36—After-treatment
- C08J9/40—Impregnation

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)
Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Processes Of Treating Macromolecular Substances (AREA)

CA213,157A 1973-11-07 1974-11-06 Cellular moulded articles produced from synthetic resin emulsion Expired CA1052050A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE19732355597 DE2355597A1 (de)	1973-11-07	1973-11-07	Verfahren zur herstellung von formteilen mit zellstruktur

Publications (1)

Publication Number	Publication Date
CA1052050A true CA1052050A (en)	1979-04-03

Family

ID=5897423

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA213,157A Expired CA1052050A (en)	1973-11-07	1974-11-06	Cellular moulded articles produced from synthetic resin emulsion

Country Status (14)

Country	Link
AT (1)	AT353014B (da)
AU (1)	AU499809B2 (da)
BE (1)	BE821954A (da)
BR (1)	BR7409315A (da)
CA (1)	CA1052050A (da)
CH (1)	CH624693A5 (da)
DE (1)	DE2355597A1 (da)
DK (1)	DK581074A (da)
ES (1)	ES431685A1 (da)
FR (1)	FR2249762B1 (da)
GB (1)	GB1494739A (da)
IT (1)	IT1025477B (da)
NL (1)	NL7414510A (da)
SE (1)	SE409997B (da)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4473611A (en) *	1982-11-26	1984-09-25	Lever Brothers Company	Porous polymeric material containing a reinforcing and heat-sealable material
US4775502A (en) *	1986-08-01	1988-10-04	Chafvin Jr Harry H	Process for production of microcellular resin castings
US5973031A (en) *	1996-06-14	1999-10-26	Balmoral Group Ltd	Buoyancy material

1973
- 1973-11-07 DE DE19732355597 patent/DE2355597A1/de not_active Ceased
1974
- 1974-11-05 AT AT884574A patent/AT353014B/de not_active IP Right Cessation
- 1974-11-06 CH CH1485474A patent/CH624693A5/de not_active IP Right Cessation
- 1974-11-06 IT IT29172/74A patent/IT1025477B/it active
- 1974-11-06 SE SE7413937A patent/SE409997B/xx unknown
- 1974-11-06 CA CA213,157A patent/CA1052050A/en not_active Expired
- 1974-11-06 ES ES431685A patent/ES431685A1/es not_active Expired
- 1974-11-06 BR BR9315/74A patent/BR7409315A/pt unknown
- 1974-11-07 NL NL7414510A patent/NL7414510A/xx not_active Application Discontinuation
- 1974-11-07 BE BE150299A patent/BE821954A/xx not_active IP Right Cessation
- 1974-11-07 AU AU75128/74A patent/AU499809B2/en not_active Expired
- 1974-11-07 FR FR7436999A patent/FR2249762B1/fr not_active Expired
- 1974-11-07 GB GB48316/74A patent/GB1494739A/en not_active Expired
- 1974-11-07 DK DK581074A patent/DK581074A/da not_active Application Discontinuation

Also Published As

Publication number	Publication date
DK581074A (da)	1975-07-07
AU7512874A (en)	1976-05-13
SE409997B (sv)	1979-09-17
GB1494739A (en)	1977-12-14
BR7409315A (pt)	1976-05-18
DE2355597A1 (de)	1975-05-15
AT353014B (de)	1979-10-25
SE7413937L (da)	1975-05-09
ATA884574A (de)	1979-03-15
BE821954A (fr)	1975-03-03
CH624693A5 (en)	1981-08-14
FR2249762B1 (da)	1978-10-27
ES431685A1 (es)	1976-09-01
FR2249762A1 (da)	1975-05-30
IT1025477B (it)	1978-08-10
NL7414510A (nl)	1975-05-12
AU499809B2 (en)	1979-05-03

Publication	Publication Date	Title
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US4330634A (en)	1982-05-18	Foam composites
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US5110839A (en)	1992-05-05	Foamed cementitious compositions comprising low water and poly(carboxylic)acid stabilizer
US3050476A (en)	1962-08-21	Method of making a self extinguishing expandable polymer of styrene by bromination
US3864137A (en)	1975-02-04	Hydrogen peroxide blowing agent for silicate foams
US5985943A (en)	1999-11-16	Expandable polystyrene particles
US4804688A (en)	1989-02-14	Open-cell foamed gypsum insulation
US9506244B2 (en)	2016-11-29	High-performance heat-insulating materials
CA1193149A (en)	1985-09-10	Fire resistant materials
US4425440A (en)	1984-01-10	Flame retardant thermally insulating material
JPH04292643A (ja)	1992-10-16	発泡性熱可塑性微小球ならびにその製造および使用方法
JPH0649260A (ja)	1994-02-22	熱可塑性微小球、その製造方法、ならびにその使用
CN108641033A (zh)	2018-10-12	一种阻燃性热膨胀微胶囊及其制备方法
KR20110002019A (ko)	2011-01-06	높은 난연성 및 낮은 밀도를 갖는 발포체
KR101489583B1 (ko)	2015-02-09	발포 폴리스타이렌 폼 난연성 조성물 및 그 제조방법
EP1997849A1 (en)	2008-12-03	Fire retardant polystyrene
RU2082695C1 (ru)	1997-06-27	Способ изготовления экологически чистых, легких полистиролбетонных изделий
US3817766A (en)	1974-06-18	Hardening of waterglass solutions using pyrocarbonic acid esters and/or carboxylic-carbonic acid ester anhydrides
EP1155068B1 (en)	2003-05-21	Flame resistant polyvinylarene polymer compositions
AU2017218451A1 (en)	2018-08-30	Foam composites
US4426462A (en)	1984-01-17	Method for the preparation of highly absorbent phenolic resin foams
JPH11255946A (ja)	1999-09-21	難燃性を有する発泡性スチレン系樹脂粒子およびその製造方法
DE2355597A1 (de)	1975-05-15	Verfahren zur herstellung von formteilen mit zellstruktur
EP0430575A1 (en)	1991-06-05	Cellular or foamed hydraulic compositions