CA1062838A - Catalyseurs au cobalt dans un compose de moulage (en feuilles et en vrac) de resines de polyester insature - Google Patents

Catalyseurs au cobalt dans un compose de moulage (en feuilles et en vrac) de resines de polyester insature

Info

Publication number: CA1062838A
Authority: CA; Canada
Prior art keywords: cobaltic; molding compound; promoter; molding; polyester resin
Prior art date: 1975-04-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA250,096A

Other languages

English (en)

Inventor

Melville W. Uffner

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Air Products and Chemicals Inc

Original Assignee

Air Products and Chemicals Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-04-30

Filing date

1976-04-12

Publication date

1979-09-18

1975-04-30 Priority claimed from US05/572,957 external-priority patent/US3988290A/en

1975-06-03 Priority claimed from US05/583,500 external-priority patent/US4048086A/en

1976-04-12 Application filed by Air Products and Chemicals Inc filed Critical Air Products and Chemicals Inc

1979-09-18 Application granted granted Critical

1979-09-18 Publication of CA1062838A publication Critical patent/CA1062838A/fr

Status Expired legal-status Critical Current

Links

229920006337 unsaturated polyester resin Polymers 0.000 title claims abstract description 21
239000004412 Bulk moulding compound Substances 0.000 title abstract description 17
239000003677 Sheet moulding compound Substances 0.000 title abstract description 17
238000000465 moulding Methods 0.000 claims abstract description 86
150000001875 compounds Chemical class 0.000 claims abstract description 69
239000000178 monomer Substances 0.000 claims abstract description 28
239000002562 thickening agent Substances 0.000 claims abstract description 27
238000000034 method Methods 0.000 claims abstract description 17
230000008569 process Effects 0.000 claims abstract description 14
239000000126 substance Substances 0.000 claims abstract description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims abstract description 8
229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 6
229910000000 metal hydroxide Inorganic materials 0.000 claims abstract description 5
150000004706 metal oxides Chemical class 0.000 claims abstract description 5
239000003054 catalyst Substances 0.000 claims description 17
229910052751 metal Inorganic materials 0.000 claims description 15
239000002184 metal Substances 0.000 claims description 15
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 9
230000002708 enhancing effect Effects 0.000 claims description 8
238000004519 manufacturing process Methods 0.000 claims description 8
239000000395 magnesium oxide Substances 0.000 claims description 7
POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 claims description 6
-1 acetonyl acetonate Chemical compound 0.000 claims description 6
150000002976 peresters Chemical class 0.000 claims description 6
150000002978 peroxides Chemical class 0.000 claims description 6
229910017052 cobalt Inorganic materials 0.000 claims description 5
239000010941 cobalt Substances 0.000 claims description 5
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
229920001169 thermoplastic Polymers 0.000 claims description 5
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
OOMOMODKLPLOKW-UHFFFAOYSA-H cobalt(3+);trisulfate Chemical compound [Co+3].[Co+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O OOMOMODKLPLOKW-UHFFFAOYSA-H 0.000 claims description 4
230000006872 improvement Effects 0.000 claims description 4
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 4
239000004416 thermosoftening plastic Substances 0.000 claims description 4
230000008719 thickening Effects 0.000 claims description 4
125000004432 carbon atom Chemical group C* 0.000 claims description 3
150000004820 halides Chemical class 0.000 claims description 3
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 3
239000000347 magnesium hydroxide Substances 0.000 claims description 3
229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 3
GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical group CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 claims description 3
238000002156 mixing Methods 0.000 claims description 2
125000005594 diketone group Chemical group 0.000 claims 3
150000002681 magnesium compounds Chemical group 0.000 claims 2
150000002763 monocarboxylic acids Chemical class 0.000 claims 2
229920005989 resin Polymers 0.000 description 28
239000011347 resin Substances 0.000 description 28
239000000203 mixture Substances 0.000 description 21
239000004645 polyester resin Substances 0.000 description 16
229920001225 polyester resin Polymers 0.000 description 15
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 11
239000000306 component Substances 0.000 description 11
125000002524 organometallic group Chemical group 0.000 description 8
YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 6
229920002554 vinyl polymer Polymers 0.000 description 6
239000002253 acid Substances 0.000 description 5
229920000728 polyester Polymers 0.000 description 5
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
239000000314 lubricant Substances 0.000 description 4
239000011777 magnesium Substances 0.000 description 4
238000012360 testing method Methods 0.000 description 4
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 3
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
150000001868 cobalt Chemical class 0.000 description 3
MPMSMUBQXQALQI-UHFFFAOYSA-N cobalt phthalocyanine Chemical compound [Co+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 MPMSMUBQXQALQI-UHFFFAOYSA-N 0.000 description 3
JAWGVVJVYSANRY-UHFFFAOYSA-N cobalt(3+) Chemical compound [Co+3] JAWGVVJVYSANRY-UHFFFAOYSA-N 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000011521 glass Substances 0.000 description 3
230000001965 increasing effect Effects 0.000 description 3
229920006395 saturated elastomer Polymers 0.000 description 3
229920006305 unsaturated polyester Polymers 0.000 description 3
WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
239000004698 Polyethylene Substances 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
239000011575 calcium Substances 0.000 description 2
229910000019 calcium carbonate Inorganic materials 0.000 description 2
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
239000000292 calcium oxide Substances 0.000 description 2
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
238000013329 compounding Methods 0.000 description 2
238000004132 cross linking Methods 0.000 description 2
239000000945 filler Substances 0.000 description 2
238000001879 gelation Methods 0.000 description 2
150000002334 glycols Chemical class 0.000 description 2
150000002432 hydroperoxides Chemical class 0.000 description 2
150000002576 ketones Chemical class 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
239000000463 material Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
VLKZOEOYAKHREP-UHFFFAOYSA-N methyl pentane Natural products CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
239000003921 oil Substances 0.000 description 2
125000000962 organic group Chemical group 0.000 description 2
UPWOEMHINGJHOB-UHFFFAOYSA-N oxo(oxocobaltiooxy)cobalt Chemical compound O=[Co]O[Co]=O UPWOEMHINGJHOB-UHFFFAOYSA-N 0.000 description 2
125000000864 peroxy group Chemical group O(O*)* 0.000 description 2
229920000573 polyethylene Polymers 0.000 description 2
230000001737 promoting effect Effects 0.000 description 2
YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
230000009257 reactivity Effects 0.000 description 2
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
230000002195 synergetic effect Effects 0.000 description 2
239000006188 syrup Substances 0.000 description 2
235000020357 syrup Nutrition 0.000 description 2
IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
MIRQGKQPLPBZQM-UHFFFAOYSA-N 2-hydroperoxy-2,4,4-trimethylpentane Chemical compound CC(C)(C)CC(C)(C)OO MIRQGKQPLPBZQM-UHFFFAOYSA-N 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
MYFBFOCSISINPS-UHFFFAOYSA-N 2-tert-butylbenzenecarboperoxoic acid Chemical compound CC(C)(C)C1=CC=CC=C1C(=O)OO MYFBFOCSISINPS-UHFFFAOYSA-N 0.000 description 1
QISOBCMNUJQOJU-UHFFFAOYSA-N 4-bromo-1h-pyrazole-5-carboxylic acid Chemical compound OC(=O)C=1NN=CC=1Br QISOBCMNUJQOJU-UHFFFAOYSA-N 0.000 description 1
YPIFGDQKSSMYHQ-UHFFFAOYSA-M 7,7-dimethyloctanoate Chemical compound CC(C)(C)CCCCCC([O-])=O YPIFGDQKSSMYHQ-UHFFFAOYSA-M 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
241000331231 Amorphocerini gen. n. 1 DAD-2008 Species 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
241000905957 Channa melasoma Species 0.000 description 1
229910021581 Cobalt(III) chloride Inorganic materials 0.000 description 1
229910021583 Cobalt(III) fluoride Inorganic materials 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
244000068988 Glycine max Species 0.000 description 1
235000010469 Glycine max Nutrition 0.000 description 1
240000006240 Linum usitatissimum Species 0.000 description 1
235000004431 Linum usitatissimum Nutrition 0.000 description 1
235000010678 Paulownia tomentosa Nutrition 0.000 description 1
240000002834 Paulownia tomentosa Species 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
240000001987 Pyrus communis Species 0.000 description 1
235000004443 Ricinus communis Nutrition 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
XJGUKDJAOUXADK-UHFFFAOYSA-N [difluoro(naphthalen-2-yl)methyl]phosphonic acid Chemical compound C1=CC=CC2=CC(C(F)(F)P(O)(=O)O)=CC=C21 XJGUKDJAOUXADK-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
229920000180 alkyd Polymers 0.000 description 1
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
238000010420 art technique Methods 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
229910001863 barium hydroxide Inorganic materials 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
235000013539 calcium stearate Nutrition 0.000 description 1
239000008116 calcium stearate Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000002738 chelating agent Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
ZUKDFIXDKRLHRB-UHFFFAOYSA-K cobalt(3+);triacetate Chemical compound [Co+3].CC([O-])=O.CC([O-])=O.CC([O-])=O ZUKDFIXDKRLHRB-UHFFFAOYSA-K 0.000 description 1
FXVNMSSSMOVRTC-UHFFFAOYSA-K cobalt(3+);trihydroxide Chemical compound [OH-].[OH-].[OH-].[Co+3] FXVNMSSSMOVRTC-UHFFFAOYSA-K 0.000 description 1
WZJQNLGQTOCWDS-UHFFFAOYSA-K cobalt(iii) fluoride Chemical compound F[Co](F)F WZJQNLGQTOCWDS-UHFFFAOYSA-K 0.000 description 1
FJDJVBXSSLDNJB-LNTINUHCSA-N cobalt;(z)-4-hydroxypent-3-en-2-one Chemical compound [Co].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O FJDJVBXSSLDNJB-LNTINUHCSA-N 0.000 description 1
239000002131 composite material Substances 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007906 compression Methods 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
230000008878 coupling Effects 0.000 description 1
238000010168 coupling process Methods 0.000 description 1
238000005859 coupling reaction Methods 0.000 description 1
GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 1
230000003292 diminished effect Effects 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
238000005886 esterification reaction Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
230000007717 exclusion Effects 0.000 description 1
239000011152 fibreglass Substances 0.000 description 1
235000004426 flaxseed Nutrition 0.000 description 1
PTCGDEVVHUXTMP-UHFFFAOYSA-N flutolanil Chemical compound CC(C)OC1=CC=CC(NC(=O)C=2C(=CC=CC=2)C(F)(F)F)=C1 PTCGDEVVHUXTMP-UHFFFAOYSA-N 0.000 description 1
239000001530 fumaric acid Substances 0.000 description 1
235000011087 fumaric acid Nutrition 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
239000003365 glass fiber Substances 0.000 description 1
125000001867 hydroperoxy group Chemical group [*]OO[H] 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
229940070765 laurate Drugs 0.000 description 1
HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 1
YEXPOXQUZXUXJW-UHFFFAOYSA-N lead(II) oxide Inorganic materials [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
BTAUEIDLAAYHSL-UHFFFAOYSA-M lithium;octanoate Chemical compound [Li+].CCCCCCCC([O-])=O BTAUEIDLAAYHSL-UHFFFAOYSA-M 0.000 description 1
ZJZXSOKJEJFHCP-UHFFFAOYSA-M lithium;thiocyanate Chemical compound [Li+].[S-]C#N ZJZXSOKJEJFHCP-UHFFFAOYSA-M 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
SGLXWMAOOWXVAM-UHFFFAOYSA-L manganese(2+);octanoate Chemical compound [Mn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O SGLXWMAOOWXVAM-UHFFFAOYSA-L 0.000 description 1
MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 description 1
125000005474 octanoate group Chemical group 0.000 description 1
NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
239000008188 pellet Substances 0.000 description 1
HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
239000004926 polymethyl methacrylate Substances 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
239000011118 polyvinyl acetate Substances 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
239000002990 reinforced plastic Substances 0.000 description 1
230000002787 reinforcement Effects 0.000 description 1
239000012744 reinforcing agent Substances 0.000 description 1
239000012763 reinforcing filler Substances 0.000 description 1
IOVGROKTTNBUGK-SJCJKPOMSA-N ritodrine Chemical compound N([C@@H](C)[C@H](O)C=1C=CC(O)=CC=1)CCC1=CC=C(O)C=C1 IOVGROKTTNBUGK-SJCJKPOMSA-N 0.000 description 1
235000013580 sausages Nutrition 0.000 description 1
239000000344 soap Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
238000010998 test method Methods 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
239000011800 void material Substances 0.000 description 1
239000011701 zinc Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical compound [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
- C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
- C08F299/04—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyesters
- C08F299/0442—Catalysts
- C08F299/0464—Metals or metal containing compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Macromonomer-Based Addition Polymer (AREA)
Reinforced Plastic Materials (AREA)
Compositions Of Macromolecular Compounds (AREA)
Polymerization Catalysts (AREA)

CA250,096A 1975-04-30 1976-04-12 Catalyseurs au cobalt dans un compose de moulage (en feuilles et en vrac) de resines de polyester insature Expired CA1062838A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US05/572,957 US3988290A (en)	1975-04-30	1975-04-30	Cobaltic promoters in unsaturated polyester resin sheet molding and bulk molding compound
US05/583,500 US4048086A (en)	1975-06-03	1975-06-03	Cobaltic accelerators with group II metal oxides and hydroxides

Publications (1)

Publication Number	Publication Date
CA1062838A true CA1062838A (fr)	1979-09-18

Family

ID=27075991

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA250,096A Expired CA1062838A (fr)	1975-04-30	1976-04-12	Catalyseurs au cobalt dans un compose de moulage (en feuilles et en vrac) de resines de polyester insature

Country Status (7)

Country	Link
JP (1)	JPS6038408B2 (fr)
CA (1)	CA1062838A (fr)
DE (1)	DE2618997A1 (fr)
FR (1)	FR2309589A1 (fr)
GB (1)	GB1541655A (fr)
IT (1)	IT1059423B (fr)
NL (1)	NL7604587A (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0190004U (fr) *	1987-12-07	1989-06-14
PL172625B1 (pl) *	1993-06-25	1997-10-31	Marceli Cyrkiewicz	Sposób otrzymywania masy ceramicznopodobnej i masa ceramicznopodobna PL PL
PL172616B1 (pl) *	1993-06-25	1997-10-31	Marceli Cyrkiewicz	Sposób otrzymywania masy ceramicznopodobnej o wlasnosciach magnetycznych i masa ceramicznopodobna o wlasnosciach magnetycznych PL PL PL
CN115710332B (zh) *	2022-10-21	2025-07-04	浙江省乐清树脂厂	一种不饱和聚酯团状模塑料及其生产工艺

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1052268A (fr) *	1952-03-10	1954-01-22	Onera (Off Nat Aerospatiale)	Procédé de polymérisation et matériaux obtenus par ce procede
FR1567022A (fr) *	1966-02-24	1969-05-16
US3653954A (en) *	1970-05-04	1972-04-04	Woolsey Marine Ind Inc	Method of coating with slow-gelling polyester composition
US3804799A (en) *	1972-09-01	1974-04-16	Air Prod & Chem	Metal-amine complex accelerator for polyester resin curing

1976
- 1976-04-12 CA CA250,096A patent/CA1062838A/fr not_active Expired
- 1976-04-22 FR FR7611841A patent/FR2309589A1/fr active Granted
- 1976-04-28 JP JP51047939A patent/JPS6038408B2/ja not_active Expired
- 1976-04-29 GB GB17589/76A patent/GB1541655A/en not_active Expired
- 1976-04-29 IT IT49246/76A patent/IT1059423B/it active
- 1976-04-29 NL NL7604587A patent/NL7604587A/xx not_active Application Discontinuation
- 1976-04-29 DE DE19762618997 patent/DE2618997A1/de not_active Withdrawn

Also Published As

Publication number	Publication date
JPS6038408B2 (ja)	1985-08-31
IT1059423B (it)	1982-05-31
FR2309589B1 (fr)	1981-04-17
JPS51131589A (en)	1976-11-16
DE2618997A1 (de)	1976-11-11
FR2309589A1 (fr)	1976-11-26
GB1541655A (en)	1979-03-07
NL7604587A (nl)	1976-11-02

Publication	Publication Date	Title
EP0271816B1 (fr)	1992-03-11	Compositions à mouler de polyester durcissables
EP2688949B1 (fr)	2015-05-06	Accélérateur de durcissement de résines
CN101484529B (zh)	2013-02-06	乙烯基酯树脂组合物
GB2165251A (en)	1986-04-09	Low viscosity epoxy resin compositions
US5932666A (en)	1999-08-03	Low profile additives for polyester resin systems based on asymmetric glycols and aromatic diacids
CA1062838A (fr)	1979-09-18	Catalyseurs au cobalt dans un compose de moulage (en feuilles et en vrac) de resines de polyester insature
WO1990012825A1 (fr)	1990-11-01	Cocatalyseurs de polymerisation contenant de l'oxygene organique
US4138385A (en)	1979-02-06	Substituted acetylacetonate cobaltic promoters for unsaturated polyester resin
WO1997028204A9 (fr)	1997-10-30	Additives a tres faible retrait pour systemes de resine de polyester a base de glycols asymetriques et de diacides aromatiques
AU634413B2 (en)	1993-02-18	Thermoplastic low-profile additives and use thereof in unsaturated polyester resin compositions
US3988290A (en)	1976-10-26	Cobaltic promoters in unsaturated polyester resin sheet molding and bulk molding compound
CN103975031A (zh)	2014-08-06	树脂组合物
US3804799A (en)	1974-04-16	Metal-amine complex accelerator for polyester resin curing
US3904591A (en)	1975-09-09	Primary accelerators for sulfur-cured elastomers
EP0251067A2 (fr)	1988-01-07	Compositions à mouler renforcées par des fibres et ayant des propriétés de surface améliorées
JP3207502B2 (ja)	2001-09-10	共重合体の製造方法
EP0153193A2 (fr)	1985-08-28	Charges finement divisées traitées en surface
US4048086A (en)	1977-09-13	Cobaltic accelerators with group II metal oxides and hydroxides
JP2521592B2 (ja)	1996-08-07	金型内被覆組成物
KR100201802B1 (ko)	1999-06-15	폴리에스테르 수지계를 위한 비대칭 글리콜 및 방향족 이가산 기재의 저 프로필 첨가제
JPS5917732B2 (ja)	1984-04-23	ポリエステル樹脂硬化用の金属−アミン錯塩促進剤
US4009145A (en)	1977-02-22	Filling compounds
US3503920A (en)	1970-03-31	Process for increasing viscosity of uncured alkyd copolymer resinous mixtures and product
EP0376662B1 (fr)	1994-08-10	Matière première pour la prégélification, méthode de préparation de prégel, méthode de préparation de matière moulée et matière moulée
US3886113A (en)	1975-05-27	Metal-amine complex accelerator for polyester resin curing