CA1065272A - Treatment of dilute cyanide solutions - Google Patents

Treatment of dilute cyanide solutions

Info

Publication number: CA1065272A
Authority: CA; Canada
Prior art keywords: anode; cathode; cell; bed; cyanide
Prior art date: 1975-01-03
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA242,861A

Other languages

English (en)

French (fr)

Other versions

CA242861S (en

Inventor

Maurice R. Hillis

Carlos Lopez-Cacicedo

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Electricity Council

Original Assignee

Electricity Council

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-01-03

Filing date

1975-12-31

Publication date

1979-10-30

1975-12-31 Application filed by Electricity Council filed Critical Electricity Council

1979-10-30 Application granted granted Critical

1979-10-30 Publication of CA1065272A publication Critical patent/CA1065272A/en

Status Expired legal-status Critical Current

Links

XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 title claims abstract description 50
238000011282 treatment Methods 0.000 title claims abstract description 29
229910052751 metal Inorganic materials 0.000 claims abstract description 27
239000002184 metal Substances 0.000 claims abstract description 27
239000002245 particle Substances 0.000 claims abstract description 14
238000000034 method Methods 0.000 claims abstract description 11
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 12
229910052802 copper Inorganic materials 0.000 claims description 12
239000010949 copper Substances 0.000 claims description 12
150000002825 nitriles Chemical class 0.000 claims description 12
239000003792 electrolyte Substances 0.000 claims description 10
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 claims description 8
239000010936 titanium Substances 0.000 claims description 6
229910052719 titanium Inorganic materials 0.000 claims description 4
230000001788 irregular Effects 0.000 abstract 1
239000000243 solution Substances 0.000 description 53
238000007747 plating Methods 0.000 description 10
239000000463 material Substances 0.000 description 8
238000009713 electroplating Methods 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
239000011701 zinc Substances 0.000 description 6
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
229910001385 heavy metal Inorganic materials 0.000 description 5
229910052725 zinc Inorganic materials 0.000 description 5
DOBRDRYODQBAMW-UHFFFAOYSA-N copper(i) cyanide Chemical compound [Cu+].N#[C-] DOBRDRYODQBAMW-UHFFFAOYSA-N 0.000 description 4
239000010802 sludge Substances 0.000 description 4
150000001913 cyanates Chemical class 0.000 description 3
238000000151 deposition Methods 0.000 description 3
230000008021 deposition Effects 0.000 description 3
230000003134 recirculating effect Effects 0.000 description 3
239000000126 substance Substances 0.000 description 3
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
KXZJHVJKXJLBKO-UHFFFAOYSA-N chembl1408157 Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=CC=1C1=CC=C(O)C=C1 KXZJHVJKXJLBKO-UHFFFAOYSA-N 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
230000006378 damage Effects 0.000 description 2
230000000694 effects Effects 0.000 description 2
230000005611 electricity Effects 0.000 description 2
229910052709 silver Inorganic materials 0.000 description 2
239000004332 silver Substances 0.000 description 2
239000002344 surface layer Substances 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
231100000331 toxic Toxicity 0.000 description 2
230000002588 toxic effect Effects 0.000 description 2
238000005406 washing Methods 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
239000005708 Sodium hypochlorite Substances 0.000 description 1
239000003513 alkali Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
238000005660 chlorination reaction Methods 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
238000011109 contamination Methods 0.000 description 1
XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
238000005868 electrolysis reaction Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
231100000086 high toxicity Toxicity 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
238000011221 initial treatment Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000011244 liquid electrolyte Substances 0.000 description 1
231100000053 low toxicity Toxicity 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
229910000000 metal hydroxide Inorganic materials 0.000 description 1
150000004692 metal hydroxides Chemical class 0.000 description 1
238000001465 metallisation Methods 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
239000000203 mixture Substances 0.000 description 1
231100000252 nontoxic Toxicity 0.000 description 1
230000003000 nontoxic effect Effects 0.000 description 1
230000002572 peristaltic effect Effects 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920000136 polysorbate Polymers 0.000 description 1
NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 description 1
LJCNRYVRMXRIQR-OLXYHTOASA-L potassium sodium L-tartrate Chemical compound [Na+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O LJCNRYVRMXRIQR-OLXYHTOASA-L 0.000 description 1
238000005086 pumping Methods 0.000 description 1
238000011084 recovery Methods 0.000 description 1
239000004576 sand Substances 0.000 description 1
230000035939 shock Effects 0.000 description 1
LFAGQMCIGQNPJG-UHFFFAOYSA-N silver cyanide Chemical compound [Ag+].N#[C-] LFAGQMCIGQNPJG-UHFFFAOYSA-N 0.000 description 1
229940098221 silver cyanide Drugs 0.000 description 1
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
235000011006 sodium potassium tartrate Nutrition 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000012798 spherical particle Substances 0.000 description 1
239000003643 water by type Substances 0.000 description 1
GTLDTDOJJJZVBW-UHFFFAOYSA-N zinc cyanide Chemical compound [Zn+2].N#[C-].N#[C-] GTLDTDOJJJZVBW-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F1/46114—Electrodes in particulate form or with conductive and/or non conductive particles between them
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/16—Regeneration of process solutions
- C25D21/20—Regeneration of process solutions of rinse-solutions
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
- C02F1/4672—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
- C02F1/4676—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electroreduction
- C02F1/4678—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electroreduction of metals
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F2001/46133—Electrodes characterised by the material
- C02F2001/46138—Electrodes comprising a substrate and a coating
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F2001/46152—Electrodes characterised by the shape or form
- C02F2001/46157—Perforated or foraminous electrodes
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
- C02F2101/18—Cyanides

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Electrochemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Hydrology & Water Resources (AREA)
Environmental & Geological Engineering (AREA)
Water Supply & Treatment (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Electrolytic Production Of Metals (AREA)
Water Treatment By Electricity Or Magnetism (AREA)

CA242,861A 1975-01-03 1975-12-31 Treatment of dilute cyanide solutions Expired CA1065272A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GB267/75A GB1483126A (en)	1975-01-03	1975-01-03	Electrolytic treatment of dilute cyanide solution and cell therefor

Publications (1)

Publication Number	Publication Date
CA1065272A true CA1065272A (en)	1979-10-30

Family

ID=9701349

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA242,861A Expired CA1065272A (en)	1975-01-03	1975-12-31	Treatment of dilute cyanide solutions

Country Status (7)

Country	Link
JP (1)	JPS51125674A (it)
CA (1)	CA1065272A (it)
DE (1)	DE2600084A1 (it)
FR (1)	FR2296597A1 (it)
GB (1)	GB1483126A (it)
IT (1)	IT1052773B (it)
ZA (1)	ZA757840B (it)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5342449A (en) *	1990-12-11	1994-08-30	Holbein Bruce E	Process for the decontamination of toxic, heavy-metal containing soils

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE2836720C2 (de) *	1978-08-22	1986-06-26	Okubo, Katsuhiro, Tokio/Tokyo	Verfahren zur kontinuierlichen elektrolytischen Regenerierung einer Silbercyanid enthaltenden, bei Galvanisierungsprozessen anfallenden Waschlösung und Vorrichtung zur Durchführung des Verfahrens
GB2098238B (en) *	1981-05-07	1984-10-24	Electricity Council	An electrochemical cell
JPS6077937A (ja) *	1983-10-03	1985-05-02	Toppan Printing Co Ltd	金属回収装置
DE4218916C2 (de) *	1992-06-10	1996-03-21	Heraeus Elektrochemie	Verwendung einer Gitteranode zur elektrolytische Entgiftung oder Regeneration einer Cyanid enthaltenden wäßrigen Lösung
DE4233721A1 (de) *	1992-10-07	1994-04-14	Ceotronics Gmbh Elektronische	Kommunikationseinrichtung für den Einsatz in Polizei-Motorrädern
US6280594B1 (en) *	1998-12-01	2001-08-28	Tateki Yamaoka	Device for producing ion water and partition wall for device for producing ion water
US6277266B1 (en) *	1999-03-23	2001-08-21	Tateki Yamaoka	Device for producing ion water and partition wall for device for producing ion water
DE102009013380A1 (de)	2009-03-09	2010-09-16	Hansgrohe Ag	Verfahren zum Abbau von teilfluorierten und perfluorierten Tensiden
DE102010021424A1 (de) *	2010-05-26	2011-12-01	Gerald Metge	Anode zum galvanischen Beschichten
CN106006946A (zh) *	2016-05-26	2016-10-12	南京大学	一种电解改性石英砂滤床及其应用
CN112830556A (zh) *	2021-01-20	2021-05-25	苏州融和福天宝环保科技有限责任公司	一种联合处理氰化镀铜废水和酸性镀铜废水的方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CH302143A (de) *	1951-07-28	1954-10-15	Bamag Meguin Aktiengesellschaf	Vorelektrode für Elektrolysezellen und Verfahren zur Herstellung einer solchen Elektrode.
IT953307B (it) *	1971-04-14	1973-08-10	Hooker Chemical Corp	Procedimento per ridurre il conte nuto di cianuro di una soluzione mediante una tecnica elettrochimica
FR2190743A1 (en) *	1972-06-28	1974-02-01	Studelec	Electrolytic destruction of cyanides - in waste water and industrial effluents
GB1415000A (en) *	1972-12-15	1975-11-26	Pacific Eng Production Co Of N	Method and apparatus for removing solids from electrolytic cells

1975
- 1975-01-03 GB GB267/75A patent/GB1483126A/en not_active Expired
- 1975-12-17 ZA ZA7840A patent/ZA757840B/xx unknown
- 1975-12-23 FR FR7539439A patent/FR2296597A1/fr active Granted
- 1975-12-31 CA CA242,861A patent/CA1065272A/en not_active Expired
- 1975-12-31 IT IT70233/75A patent/IT1052773B/it active
1976
- 1976-01-02 DE DE19762600084 patent/DE2600084A1/de not_active Withdrawn
- 1976-01-05 JP JP51000408A patent/JPS51125674A/ja active Pending

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5342449A (en) *	1990-12-11	1994-08-30	Holbein Bruce E	Process for the decontamination of toxic, heavy-metal containing soils

Also Published As

Publication number	Publication date
GB1483126A (en)	1977-08-17
FR2296597B1 (it)	1982-10-08
JPS51125674A (en)	1976-11-02
FR2296597A1 (fr)	1976-07-30
ZA757840B (en)	1977-01-26
IT1052773B (it)	1981-07-20
DE2600084A1 (de)	1976-07-15

Publication	Publication Date	Title
US4306952A (en)	1981-12-22	Electrolytic process and apparatus
US4436601A (en)	1984-03-13	Metal removal process
US3616356A (en)	1971-10-26	Electrolysis in a particulate carbon packing
CA1065272A (en)	1979-10-30	Treatment of dilute cyanide solutions
KR100740817B1 (ko)	2007-07-19	전해질 내의 금속 이온 농도의 조절 방법 및 장치, 및그의 용도
JPS5833036B2 (ja)	1983-07-16	スイヨウエキチユウノシアンカブツオヨビジユキンゾクノドウジジヨキヨノホウホウナラビニソウチ
JP3783972B2 (ja)	2006-06-07	シアン含有水の処理方法
US4123340A (en)	1978-10-31	Method and apparatus for treating metal containing waste water
US3899404A (en)	1975-08-12	Method of removing mercury from an aqueous solution
US4029557A (en)	1977-06-14	Treatment of water containing cyanide
KR19990064833A (ko)	1999-08-05	전기분해를 이용한 시안계 도금폐수의 처리장치 및 그 처리방법
US5230782A (en)	1993-07-27	Electrolytic process for reducing the organic content of an aqueous composition and apparatus therefore
JPS5919994B2 (ja)	1984-05-10	金属の稀薄溶液から金属粉末を製造する方法
US3645867A (en)	1972-02-29	Method of treating cyanide-containing liquors in surface treatment installations
US4145268A (en)	1979-03-20	Method of conducting an electrolysis
KR101912205B1 (ko)	2018-10-26	수 처리용 전해-전착조
Hillis	1975	Treatment of Cyanide Wastes by Electrolysis
EP0483332B1 (en)	1994-09-21	Electrolytic cell for waste water treatment
JPH06510332A (ja)	1994-11-17	多孔質攪拌電極を有する電解装置及び方法
CN112830556A (zh)	2021-05-25	一种联合处理氰化镀铜废水和酸性镀铜废水的方法
JP2745278B2 (ja)	1998-04-28	貴金属シアン浴めっき廃水及び水洗水の処理方法
JP4446760B2 (ja)	2010-04-07	電解法によるシアン化合物除去方法とその装置
JPH08299963A (ja)	1996-11-19	シアン含有水の処理方法
CA1047966A (en)	1979-02-06	Method of removing mercury from solution using particulate zinc cathode
JPH10202243A (ja)	1998-08-04	放電電解加熱による廃水処理方法及び装置

CA1065272A - Treatment of dilute cyanide solutions - Google Patents

Info

Links

Classifications

Landscapes

Applications Claiming Priority (1)

Publications (1)

Family

ID=9701349

Family Applications (1)

Country Status (7)

Cited By (1)

Families Citing this family (11)

Family Cites Families (4)

Cited By (1)

Also Published As

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