CA1097152A - Stabilized red phosphorus and process for making it - Google Patents

Stabilized red phosphorus and process for making it

Info

Publication number: CA1097152A
Authority: CA; Canada
Prior art keywords: red phosphorus; melamine; phosphorus; mono; etherified
Prior art date: 1976-12-09
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA292,173A

Other languages

English (en)

French (fr)

Inventor

Horst Staendeke

Franz-Josef Dany

Joachim Kandler

Wilhelm Adam

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Hoechst AG

Original Assignee

Hoechst AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-12-09

Filing date

1977-12-01

Publication date

1981-03-10

1976-12-09 Priority claimed from DE2655739A external-priority patent/DE2655739C2/de

1977-02-08 Priority claimed from DE19772705042 external-priority patent/DE2705042A1/de

1977-12-01 Application filed by Hoechst AG filed Critical Hoechst AG

1981-03-10 Application granted granted Critical

1981-03-10 Publication of CA1097152A publication Critical patent/CA1097152A/en

Status Expired legal-status Critical Current

Links

OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims abstract description 118
238000000034 method Methods 0.000 title claims description 39
230000008569 process Effects 0.000 title claims description 28
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 51
230000003647 oxidation Effects 0.000 claims abstract description 42
238000007254 oxidation reaction Methods 0.000 claims abstract description 42
229920000877 Melamine resin Polymers 0.000 claims abstract description 37
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 36
229910052698 phosphorus Inorganic materials 0.000 claims abstract description 34
239000011574 phosphorus Substances 0.000 claims abstract description 34
239000002245 particle Substances 0.000 claims abstract description 29
239000003381 stabilizer Substances 0.000 claims abstract description 22
238000006068 polycondensation reaction Methods 0.000 claims abstract description 20
239000010409 thin film Substances 0.000 claims abstract description 3
239000007859 condensation product Substances 0.000 claims description 23
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 22
239000000047 product Substances 0.000 claims description 20
MBHRHUJRKGNOKX-UHFFFAOYSA-N [(4,6-diamino-1,3,5-triazin-2-yl)amino]methanol Chemical class NC1=NC(N)=NC(NCO)=N1 MBHRHUJRKGNOKX-UHFFFAOYSA-N 0.000 claims description 18
239000007864 aqueous solution Substances 0.000 claims description 16
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
-1 trimethylol-melamine trimethylether Chemical class 0.000 claims description 14
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
125000001931 aliphatic group Chemical group 0.000 claims description 12
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 12
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 12
USDJGQLNFPZEON-UHFFFAOYSA-N [[4,6-bis(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(NCO)=NC(NCO)=N1 USDJGQLNFPZEON-UHFFFAOYSA-N 0.000 claims description 11
239000007900 aqueous suspension Substances 0.000 claims description 11
239000000203 mixture Substances 0.000 claims description 10
239000000243 solution Substances 0.000 claims description 10
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
239000000725 suspension Substances 0.000 claims description 9
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 8
AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 8
XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 claims description 8
ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 8
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 8
239000003795 chemical substances by application Substances 0.000 claims description 6
ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims description 6
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 5
BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 claims description 5
WEAJVJTWVRAPED-UHFFFAOYSA-N [[4-amino-6-[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol Chemical compound NC1=NC(N(CO)CO)=NC(N(CO)CO)=N1 WEAJVJTWVRAPED-UHFFFAOYSA-N 0.000 claims description 5
238000009736 wetting Methods 0.000 claims description 5
PCWGTDULNUVNBN-UHFFFAOYSA-N 4-methylpentan-1-ol Chemical compound CC(C)CCCO PCWGTDULNUVNBN-UHFFFAOYSA-N 0.000 claims description 4
YGCOKJWKWLYHTG-UHFFFAOYSA-N [[4,6-bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol Chemical compound OCN(CO)C1=NC(N(CO)CO)=NC(N(CO)CO)=N1 YGCOKJWKWLYHTG-UHFFFAOYSA-N 0.000 claims description 4
SYDYRFPJJJPJFE-UHFFFAOYSA-N [[4,6-bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(N(CO)CO)=NC(N(CO)CO)=N1 SYDYRFPJJJPJFE-UHFFFAOYSA-N 0.000 claims description 4
SUPOBRXPULIDDX-UHFFFAOYSA-N [[4-amino-6-(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound NC1=NC(NCO)=NC(NCO)=N1 SUPOBRXPULIDDX-UHFFFAOYSA-N 0.000 claims description 4
238000001035 drying Methods 0.000 claims description 4
PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 claims description 4
229960004592 isopropanol Drugs 0.000 claims description 4
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 4
238000002156 mixing Methods 0.000 claims description 4
230000000051 modifying effect Effects 0.000 claims description 4
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 4
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
229920003180 amino resin Polymers 0.000 claims description 3
SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 3
QPJQPYQZFKFTHG-UHFFFAOYSA-N n-(formamidomethyl)formamide Chemical compound O=CNCNC=O QPJQPYQZFKFTHG-UHFFFAOYSA-N 0.000 claims description 3
239000000600 sorbitol Substances 0.000 claims description 3
229940000425 combination drug Drugs 0.000 claims description 2
LMYRWZFENFIFIT-UHFFFAOYSA-N toluene-4-sulfonamide Chemical compound CC1=CC=C(S(N)(=O)=O)C=C1 LMYRWZFENFIFIT-UHFFFAOYSA-N 0.000 claims description 2
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims 2
239000010408 film Substances 0.000 claims 1
235000014786 phosphorus Nutrition 0.000 description 22
229940091868 melamine Drugs 0.000 description 21
229960004279 formaldehyde Drugs 0.000 description 11
235000019256 formaldehyde Nutrition 0.000 description 11
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 7
JMHCCAYJTTWMCX-QWPJCUCISA-M sodium;(2s)-2-amino-3-[4-(4-hydroxy-3,5-diiodophenoxy)-3,5-diiodophenyl]propanoate;pentahydrate Chemical compound O.O.O.O.O.[Na+].IC1=CC(C[C@H](N)C([O-])=O)=CC(I)=C1OC1=CC(I)=C(O)C(I)=C1 JMHCCAYJTTWMCX-QWPJCUCISA-M 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
230000000087 stabilizing effect Effects 0.000 description 5
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
235000011007 phosphoric acid Nutrition 0.000 description 4
229920005989 resin Polymers 0.000 description 4
239000011347 resin Substances 0.000 description 4
239000002253 acid Substances 0.000 description 3
238000007792 addition Methods 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
239000006185 dispersion Substances 0.000 description 3
239000007789 gas Substances 0.000 description 3
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
LWJROJCJINYWOX-UHFFFAOYSA-L mercury dichloride Chemical compound Cl[Hg]Cl LWJROJCJINYWOX-UHFFFAOYSA-L 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
229910000147 aluminium phosphate Inorganic materials 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
239000001273 butane Substances 0.000 description 2
CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 2
150000003951 lactams Chemical class 0.000 description 2
239000000463 material Substances 0.000 description 2
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
ABOYDMHGKWRPFD-UHFFFAOYSA-N phenylmethanesulfonamide Chemical class NS(=O)(=O)CC1=CC=CC=C1 ABOYDMHGKWRPFD-UHFFFAOYSA-N 0.000 description 2
150000003016 phosphoric acids Chemical class 0.000 description 2
239000004033 plastic Substances 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
230000002035 prolonged effect Effects 0.000 description 2
238000010992 reflux Methods 0.000 description 2
USQCUKQZXOWUDF-YWZLYKJASA-N 6-chloro-n-[(3s)-1-[(2s)-1-(4-methyl-5-oxo-1,4-diazepan-1-yl)-1-oxopropan-2-yl]-2-oxopyrrolidin-3-yl]naphthalene-2-sulfonamide Chemical compound O=C([C@@H](N1C([C@@H](NS(=O)(=O)C=2C=C3C=CC(Cl)=CC3=CC=2)CC1)=O)C)N1CCN(C)C(=O)CC1 USQCUKQZXOWUDF-YWZLYKJASA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
125000000174 L-prolyl group Chemical group [H]N1C([H])([H])C([H])([H])C([H])([H])[C@@]1([H])C(*)=O 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
RCTYPNKXASFOBE-UHFFFAOYSA-M chloromercury Chemical compound [Hg]Cl RCTYPNKXASFOBE-UHFFFAOYSA-M 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
238000007323 disproportionation reaction Methods 0.000 description 1
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
238000001879 gelation Methods 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
150000004715 keto acids Chemical class 0.000 description 1
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
239000000347 magnesium hydroxide Substances 0.000 description 1
229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
230000036647 reaction Effects 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
229910001388 sodium aluminate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000006557 surface reaction Methods 0.000 description 1
229920003002 synthetic resin Polymers 0.000 description 1
239000000057 synthetic resin Substances 0.000 description 1
238000004448 titration Methods 0.000 description 1
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
150000005219 trimethyl ethers Chemical class 0.000 description 1
238000005406 washing Methods 0.000 description 1
229940007718 zinc hydroxide Drugs 0.000 description 1
229910021511 zinc hydroxide Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/003—Phosphorus
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/003—Phosphorus
- C01B25/006—Stabilisation
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/01—Treating phosphate ores or other raw phosphate materials to obtain phosphorus or phosphorus compounds

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Geochemistry & Mineralogy (AREA)
Geology (AREA)
Life Sciences & Earth Sciences (AREA)
General Life Sciences & Earth Sciences (AREA)
Environmental & Geological Engineering (AREA)
Phenolic Resins Or Amino Resins (AREA)
Compositions Of Macromolecular Compounds (AREA)
Fireproofing Substances (AREA)
Sampling And Sample Adjustment (AREA)
Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)

CA292,173A 1976-12-09 1977-12-01 Stabilized red phosphorus and process for making it Expired CA1097152A (en)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
DEP2655739.1		1976-12-09
DE2655739A DE2655739C2 (de)	1976-12-09	1976-12-09	Stabilisierter roter Phosphor sowie Verfahren zu seiner Herstellung
DE19772705042 DE2705042A1 (de)	1977-02-08	1977-02-08	Stabilisierter roter phosphor sowie verfahren zu seiner herstellung
DEP2705042.6		1977-02-08

Publications (1)

Publication Number	Publication Date
CA1097152A true CA1097152A (en)	1981-03-10

Family

ID=25771229

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA292,173A Expired CA1097152A (en)	1976-12-09	1977-12-01	Stabilized red phosphorus and process for making it

Country Status (7)

Country	Link
JP (1)	JPS5375317A (de)
CA (1)	CA1097152A (de)
DD (1)	DD133141A5 (de)
GB (1)	GB1545716A (de)
IN (1)	IN147048B (de)
IT (1)	IT1092166B (de)
SE (1)	SE416541B (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4489183A (en) *	1983-12-13	1984-12-18	Erco Industries Limited	Stabilization of red phosphorus

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1134333B (it) *	1980-11-19	1986-08-13	F F A Spa Sa	Processo per stabilizzare mediante incapsulamento il fosforo rosso per impiego come ritardante di fiamma dei materiali polimerici e prodotto cosi' ottenuto
IT1137409B (it)	1981-03-05	1986-09-10	Saffa Spa	Materiali cartari autoestinguenti
CA1196437A (en) *	1981-12-19	1985-11-05	Kazushi Hirobe	Flame resistant resin composition
GB8326053D0 (en) *	1983-09-29	1983-11-02	Bryant & May Ltd	Striking composition and surface for safety matches
DE3710170A1 (de) *	1987-03-27	1988-10-13	Hoechst Ag	Stabilisierter roter phosphor sowie verfahren zu seiner herstellung
CN110330000A (zh) *	2019-04-01	2019-10-15	复旦大学	一种纳米红磷的制备方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS51105996A (en) *	1975-03-14	1976-09-20	Phosphorus Chem Ind	Sekirinno kaishitsuhoho

1977
- 1977-12-01 CA CA292,173A patent/CA1097152A/en not_active Expired
- 1977-12-03 IN IN1685/CAL/77A patent/IN147048B/en unknown
- 1977-12-06 IT IT52080/77A patent/IT1092166B/it active
- 1977-12-06 GB GB50719/77A patent/GB1545716A/en not_active Expired
- 1977-12-07 DD DD7700202451A patent/DD133141A5/de unknown
- 1977-12-08 SE SE7713951A patent/SE416541B/sv not_active IP Right Cessation
- 1977-12-09 JP JP14870877A patent/JPS5375317A/ja active Pending

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4489183A (en) *	1983-12-13	1984-12-18	Erco Industries Limited	Stabilization of red phosphorus

Also Published As

Publication number	Publication date
SE7713951L (sv)	1978-06-10
SE416541B (sv)	1981-01-19
GB1545716A (en)	1979-05-16
IN147048B (de)	1979-10-27
JPS5375317A (en)	1978-07-04
DD133141A5 (de)	1978-12-13
IT1092166B (it)	1985-07-06

Legal Events

Date	Code	Title	Description
1998-03-10	MKEX	Expiry

Publication	Publication Date	Title
JP2759077B2 (ja)	1998-05-28	安定した粉末状赤燐並びにその製造法
CA1097152A (en)	1981-03-10	Stabilized red phosphorus and process for making it
CA1128292A (en)	1982-07-27	Stabilized red phosphorus and process for its manufacture
JPH10510797A (ja)	1998-10-20	ジアゾニウム塩と反応させた炭素材料
JPH0386715A (ja)	1991-04-11	水溶性レゾール樹脂の製造方法
JPH021717A (ja)	1990-01-08	ホルマリンの放出が極めて少ないアミノプラスト樹脂の新規な製造方法
ES2240309T3 (es)	2005-10-16	Fosforo rojo estabilizado y un procedimiento para su preparacion.
CA1171634A (en)	1984-07-31	Process for making long-chain ammonium polyphosphate
US3425819A (en)	1969-02-04	Method of preparing a complex fertilizer comprising urea coated with ammonium phosphate
US4115522A (en)	1978-09-19	Stabilized red phosphorus and process for making it
US4505849A (en)	1985-03-19	Polyol pre-mixture for making flame-retardant poly-urethane foam plastics
US3449068A (en)	1969-06-10	Process for the manufacture of polyphosphates
US4113841A (en)	1978-09-12	Stabilized red phosphorus and process for making it
US20040260089A1 (en)	2004-12-23	Method for producing polyphosphates of organic bases
US4098872A (en)	1978-07-04	Stabilized red phosphorus and process for making it
KR0156365B1 (ko)	1999-02-18	Ii형 결정성 폴리인산암모늄의 제조방법
US3457199A (en)	1969-07-22	Improved urea-formaldehyde foams
NZ227488A (en)	1991-07-26	Manufacture of urea-formaldehyde resins and particle boards incorporating such resins
DE2705042A1 (de)	1978-08-10	Stabilisierter roter phosphor sowie verfahren zu seiner herstellung
US4180630A (en)	1979-12-25	Phosphorus-nitrogen-silica composition as a flame retardant
JP2904839B2 (ja)	1999-06-14	安定化された赤リンおよびその製造方法
US2596937A (en)	1952-05-13	Intumescing composition composed of a nitrogen phosphorus compound with an aldehyde resin
US3787561A (en)	1974-01-22	Loosely aggregated 100 millimicron micellular silica
US3846453A (en)	1974-11-05	Spheroidal shaped particles of aminoresin-silica polymeric composite
JPS58213030A (ja)	1983-12-10	低ホルムアルデヒドの尿素・ホルムアルデヒド複合フオ−ムの製造方法

CA1097152A - Stabilized red phosphorus and process for making it - Google Patents

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