CA1099785A - Dosage a l'hydrogene - Google Patents

Dosage a l'hydrogene

Info

Publication number: CA1099785A
Authority: CA; Canada
Prior art keywords: solid electrolyte; probe; substance; metal; hydride
Prior art date: 1977-01-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA295,419A

Other languages

English (en)

Inventor

Derek J. Fray

Robert Gee

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

National Research Development Corp UK

Original Assignee

National Research Development Corp UK

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-01-21

Filing date

1978-01-20

Publication date

1981-04-21

1978-01-20 Application filed by National Research Development Corp UK filed Critical National Research Development Corp UK

1981-04-21 Application granted granted Critical

1981-04-21 Publication of CA1099785A publication Critical patent/CA1099785A/fr

Status Expired legal-status Critical Current

Links

UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 32
239000001257 hydrogen Substances 0.000 title claims abstract description 31
229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 31
239000000523 sample Substances 0.000 claims abstract description 42
239000007784 solid electrolyte Substances 0.000 claims abstract description 23
239000000126 substance Substances 0.000 claims abstract description 18
239000012925 reference material Substances 0.000 claims abstract description 16
229910052987 metal hydride Inorganic materials 0.000 claims abstract description 13
150000004681 metal hydrides Chemical class 0.000 claims abstract description 13
238000000034 method Methods 0.000 claims abstract description 12
238000012544 monitoring process Methods 0.000 claims abstract description 3
229910052751 metal Inorganic materials 0.000 claims description 30
239000002184 metal Substances 0.000 claims description 30
CSDQQAQKBAQLLE-UHFFFAOYSA-N 4-(4-chlorophenyl)-4,5,6,7-tetrahydrothieno[3,2-c]pyridine Chemical compound C1=CC(Cl)=CC=C1C1C(C=CS2)=C2CCN1 CSDQQAQKBAQLLE-UHFFFAOYSA-N 0.000 claims description 12
239000003792 electrolyte Substances 0.000 claims description 10
239000000203 mixture Substances 0.000 claims description 10
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 7
229910052791 calcium Inorganic materials 0.000 claims description 6
239000011575 calcium Substances 0.000 claims description 6
229910045601 alloy Inorganic materials 0.000 claims description 5
239000000956 alloy Substances 0.000 claims description 5
239000008188 pellet Substances 0.000 claims description 5
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
229910010293 ceramic material Inorganic materials 0.000 claims description 3
239000003513 alkali Substances 0.000 claims description 2
150000001342 alkaline earth metals Chemical class 0.000 claims description 2
238000009413 insulation Methods 0.000 claims description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 2
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 2
229910052788 barium Inorganic materials 0.000 claims 2
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims 2
229910052744 lithium Inorganic materials 0.000 claims 2
229910052708 sodium Inorganic materials 0.000 claims 2
239000011734 sodium Substances 0.000 claims 2
239000011888 foil Substances 0.000 claims 1
239000004411 aluminium Substances 0.000 description 10
229910052782 aluminium Inorganic materials 0.000 description 10
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
150000002739 metals Chemical class 0.000 description 6
150000004678 hydrides Chemical class 0.000 description 5
239000005030 aluminium foil Substances 0.000 description 4
239000007789 gas Substances 0.000 description 4
OJHZNMVJJKMFGX-BWCYBWMMSA-N (4r,4ar,7ar,12bs)-9-methoxy-3-methyl-1,2,4,4a,5,6,7a,13-octahydro-4,12-methanobenzofuro[3,2-e]isoquinoline-7-one;(2r,3r)-2,3-dihydroxybutanedioic acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O.C([C@H]1[C@H](N(CC[C@@]112)C)C3)CC(=O)[C@@H]1OC1=C2C3=CC=C1OC OJHZNMVJJKMFGX-BWCYBWMMSA-N 0.000 description 3
229910000971 Silver steel Inorganic materials 0.000 description 3
229910000831 Steel Inorganic materials 0.000 description 3
239000000853 adhesive Substances 0.000 description 3
230000001070 adhesive effect Effects 0.000 description 3
239000010410 layer Substances 0.000 description 3
239000000463 material Substances 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
239000010959 steel Substances 0.000 description 3
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
SIAPCJWMELPYOE-UHFFFAOYSA-N lithium hydride Chemical compound [LiH] SIAPCJWMELPYOE-UHFFFAOYSA-N 0.000 description 2
229910000103 lithium hydride Inorganic materials 0.000 description 2
239000000155 melt Substances 0.000 description 2
229910000104 sodium hydride Inorganic materials 0.000 description 2
101100219382 Caenorhabditis elegans cah-2 gene Proteins 0.000 description 1
239000004821 Contact adhesive Substances 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
ZGLFRTJDWWKIAK-UHFFFAOYSA-M [2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]-triphenylphosphanium;bromide Chemical compound [Br-].C=1C=CC=CC=1[P+](C=1C=CC=CC=1)(CC(=O)OC(C)(C)C)C1=CC=CC=C1 ZGLFRTJDWWKIAK-UHFFFAOYSA-M 0.000 description 1
239000012790 adhesive layer Substances 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
RWASOQSEFLDYLC-UHFFFAOYSA-N beryllium dihydride Chemical compound [BeH2] RWASOQSEFLDYLC-UHFFFAOYSA-N 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000005266 casting Methods 0.000 description 1
239000004568 cement Substances 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
238000010276 construction Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
238000010586 diagram Methods 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
230000003292 diminished effect Effects 0.000 description 1
230000003467 diminishing effect Effects 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000004927 fusion Effects 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000012212 insulator Substances 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229910012375 magnesium hydride Inorganic materials 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
238000000053 physical method Methods 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000007789 sealing Methods 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
239000012312 sodium hydride Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1

Classifications

- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/411—Cells and probes with solid electrolytes for investigating or analysing of liquid metals
- G01N27/4112—Composition or fabrication of the solid electrolyte
- G01N27/4114—Composition or fabrication of the solid electrolyte for detection of gases other than oxygen
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/411—Cells and probes with solid electrolytes for investigating or analysing of liquid metals
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
Molecular Biology (AREA)
Physics & Mathematics (AREA)
Analytical Chemistry (AREA)
Biochemistry (AREA)
General Health & Medical Sciences (AREA)
General Physics & Mathematics (AREA)
Immunology (AREA)
Pathology (AREA)
General Chemical & Material Sciences (AREA)
Manufacturing & Machinery (AREA)
Engineering & Computer Science (AREA)
Investigating And Analyzing Materials By Characteristic Methods (AREA)
Measuring Oxygen Concentration In Cells (AREA)

CA295,419A 1977-01-21 1978-01-20 Dosage a l'hydrogene Expired CA1099785A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GB02533/77		1977-01-21
GB253377A GB1594223A (en)	1977-01-21	1977-01-21	Determination of hydrogen

Publications (1)

Publication Number	Publication Date
CA1099785A true CA1099785A (fr)	1981-04-21

Family

ID=9741247

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA295,419A Expired CA1099785A (fr)	1977-01-21	1978-01-20	Dosage a l'hydrogene

Country Status (4)

Country	Link
JP (1)	JPS53106091A (fr)
CA (1)	CA1099785A (fr)
DE (1)	DE2802518A1 (fr)
GB (1)	GB1594223A (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL8301538A (nl) *	1982-06-08	1984-01-02	Tno	Elektrochemische sensor, werkwijze voor het meten van waterstofactiviteit in een metaalmonster of andere stroomgeleider, werkwijze voor het onderzoeken van lasconstructies, alsmede werkwijze voor het onderzoeken van een metaal, dat een deklaag vormt op een metaal of een ander substraat.
JPS59125055A (ja) *	1983-01-05	1984-07-19	Toyo Soda Mfg Co Ltd	高温水素センサ−
JPS6281560A (ja) *	1985-10-04	1987-04-15	Tokyo Yogyo Co Ltd	溶融金属用水素センサ−
JPS6262255U (fr) *	1985-10-07	1987-04-17
JPH0632614Y2 (ja) *	1985-10-14	1994-08-24	東京窯業株式会社	溶融金属用水素センサ−のセンサ−素子
IT1215932B (it) *	1988-02-22	1990-02-22	Eniricerche Spa	Sensore a stato solido per determinare la concentrazione di gas.
IT1215930B (it) *	1988-02-22	1990-02-22	Eniricerche Spa	Sensore a stato solido per determinare la concentrazione di gas con un elettrodo di riferimento solido.
GB2324372A (en) *	1997-04-17	1998-10-21	British Steel Plc	Determining hydrogen content of liquid metal
DE19909614C1 (de)	1999-03-05	2000-08-03	Heraeus Electro Nite Int	Eintauchsensor, Meßanordnung und Meßverfahren zur Überwachung von Aluminium-Elektrolysezellen
DE10255282B4 (de) *	2002-11-26	2005-07-14	Specialty Minerals Michigan Inc., Bingham Farms	Sonde zur Ermittlung der Sauerstoffaktivität von Metallschmelzen und Verfahren zu ihrer Herstellung
GB0421868D0 (en) *	2004-10-01	2004-11-03	Environmental Monitoring And C	Apparatus and method for measuring hydrogen concentration
CN110109001B (zh) *	2019-04-30	2024-03-15	北京大学	一种原位气氛热电两场测试用样品台及芯片电极自密封结构

1977
- 1977-01-21 GB GB253377A patent/GB1594223A/en not_active Expired
1978
- 1978-01-20 CA CA295,419A patent/CA1099785A/fr not_active Expired
- 1978-01-20 DE DE19782802518 patent/DE2802518A1/de not_active Ceased
- 1978-01-21 JP JP572378A patent/JPS53106091A/ja active Pending

Also Published As

Publication number	Publication date
GB1594223A (en)	1981-07-30
DE2802518A1 (de)	1978-07-27
JPS53106091A (en)	1978-09-14

Legal Events

Date	Code	Title	Description
1998-04-21	MKEX	Expiry

Publication	Publication Date	Title
CA1099785A (fr)	1981-04-21	Dosage a l'hydrogene
Yajima et al.	1995	Application of hydrogen sensor using proton conductive ceramics as a solid electrolyte to aluminum casting industries
US9028671B2 (en)	2015-05-12	Hydrogen sensing apparatus and method
US4003814A (en)	1977-01-18	Apparatus for the continuous measurement of the oxygen content of molten copper or alloys thereof
US20120279860A1 (en)	2012-11-08	Apparatus and method for measuring hydrogen concentration in molten metals
US3883408A (en)	1975-05-13	Furnace atmosphere oxygen analysis apparatus
US3661749A (en)	1972-05-09	Apparatus for measuring in a continuous manner the oxygen in a molten metal
US4882032A (en)	1989-11-21	Hydrogen probe
US4045319A (en)	1977-08-30	Electrochemical gage for measuring partial pressures of oxygen
US3980543A (en)	1976-09-14	Electrochemical cell structure
EP1060392B1 (fr)	2001-12-12	Sonde pour metaux en fusion
US3657094A (en)	1972-04-18	Device for measuring oxygen concentration in a metallic bath
Gee et al.	1978	Instantaneous determination of hydrogen content in molten aluminum and its alloys
JPH01129156A (ja)	1989-05-22	水素用電気化学的センサー
Lapham et al.	2002	The detection of hydrogen in molten aluminium
US3755126A (en)	1973-08-28	System for determining amount of an element dissolved in a molten metal
US4468009A (en)	1984-08-28	Refractory protection tube for immersion molten metal devices
WO1983003007A1 (fr)	1983-09-01	Procede et dispositif de determination d'un flux d'hydrogene
Egami et al.	1981	Solid electrolyte for the determination of sulfur in liquid iron
JP2878603B2 (ja)	1999-04-05	溶融金属中の水素溶解量測定用センサ
GB2167867A (en)	1986-06-04	Probe for determining lithium content
JPH08505472A (ja)	1996-06-11	溶融金属分析用センサー
JPH0829379A (ja)	1996-02-02	溶融金属中の水素溶解量測定用センサ
SU1138728A1 (ru)	1985-02-07	Устройство дл определени содержани газов в металлах
JPS5973763A (ja)	1984-04-26	溶融金属中の珪素量迅速測定方法