CA1110018A - Methode et solution au peroxyde pour le blanchiment de la pate de cellulose en presence d'additifs metalliques - Google Patents

Methode et solution au peroxyde pour le blanchiment de la pate de cellulose en presence d'additifs metalliques

Info

Publication number: CA1110018A
Authority: CA; Canada
Prior art keywords: pulp; peroxide; slurry; lignocellulosic; weight based
Prior art date: 1978-04-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA319,918A

Other languages

English (en)

Inventor

Arthur W. Kempf

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

International Paper Co

Original Assignee

International Paper Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-04-07

Filing date

1979-01-18

Publication date

1981-10-06

1979-01-18 Application filed by International Paper Co filed Critical International Paper Co

1981-10-06 Application granted granted Critical

1981-10-06 Publication of CA1110018A publication Critical patent/CA1110018A/fr

Status Expired legal-status Critical Current

Links

150000002978 peroxides Chemical class 0.000 title claims abstract description 61
238000000034 method Methods 0.000 title claims abstract description 56
239000000654 additive Substances 0.000 title claims abstract description 27
229910052751 metal Inorganic materials 0.000 title claims abstract description 15
239000002184 metal Substances 0.000 title claims abstract description 15
238000004061 bleaching Methods 0.000 title description 24
239000013055 pulp slurry Substances 0.000 claims abstract description 23
229910052718 tin Inorganic materials 0.000 claims abstract description 23
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 22
239000002002 slurry Substances 0.000 claims abstract description 22
230000000996 additive effect Effects 0.000 claims abstract description 17
239000002253 acid Substances 0.000 claims abstract description 12
238000005282 brightening Methods 0.000 claims abstract description 12
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 9
239000010936 titanium Substances 0.000 claims abstract description 9
229910052719 titanium Inorganic materials 0.000 claims abstract description 9
229910052720 vanadium Inorganic materials 0.000 claims abstract description 8
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract 4
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 41
239000007844 bleaching agent Substances 0.000 claims description 6
TVQLLNFANZSCGY-UHFFFAOYSA-N disodium;dioxido(oxo)tin Chemical compound [Na+].[Na+].[O-][Sn]([O-])=O TVQLLNFANZSCGY-UHFFFAOYSA-N 0.000 claims description 6
229940079864 sodium stannate Drugs 0.000 claims description 6
230000015556 catabolic process Effects 0.000 claims description 4
229920002678 cellulose Polymers 0.000 claims description 4
239000001913 cellulose Substances 0.000 claims description 4
238000006731 degradation reaction Methods 0.000 claims description 4
230000003647 oxidation Effects 0.000 claims description 4
238000007254 oxidation reaction Methods 0.000 claims description 4
RCIVOBGSMSSVTR-UHFFFAOYSA-L stannous sulfate Chemical compound [SnH2+2].[O-]S([O-])(=O)=O RCIVOBGSMSSVTR-UHFFFAOYSA-L 0.000 claims description 3
229910000375 tin(II) sulfate Inorganic materials 0.000 claims description 3
239000000706 filtrate Substances 0.000 claims description 2
239000000243 solution Substances 0.000 description 19
229960002163 hydrogen peroxide Drugs 0.000 description 16
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 15
239000001301 oxygen Substances 0.000 description 15
229910052760 oxygen Inorganic materials 0.000 description 15
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfate Natural products OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 13
239000002655 kraft paper Substances 0.000 description 9
239000011121 hardwood Substances 0.000 description 8
229920005610 lignin Polymers 0.000 description 8
229940071182 stannate Drugs 0.000 description 8
239000000123 paper Substances 0.000 description 7
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
125000005402 stannate group Chemical group 0.000 description 6
239000000126 substance Substances 0.000 description 6
239000002023 wood Substances 0.000 description 6
229920001131 Pulp (paper) Polymers 0.000 description 5
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 5
239000007864 aqueous solution Substances 0.000 description 5
238000004076 pulp bleaching Methods 0.000 description 5
229910052708 sodium Inorganic materials 0.000 description 5
239000011734 sodium Substances 0.000 description 5
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 4
230000000694 effects Effects 0.000 description 4
229940038597 peroxide anti-acne preparations for topical use Drugs 0.000 description 4
229940045605 vanadium Drugs 0.000 description 4
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
240000001987 Pyrus communis Species 0.000 description 3
230000008901 benefit Effects 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
239000007800 oxidant agent Substances 0.000 description 3
230000001590 oxidative effect Effects 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
229940099408 Oxidizing agent Drugs 0.000 description 2
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
239000002585 base Substances 0.000 description 2
-1 borohydrides Chemical class 0.000 description 2
239000003638 chemical reducing agent Substances 0.000 description 2
239000000835 fiber Substances 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 description 2
238000004537 pulping Methods 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
230000009467 reduction Effects 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
229910021653 sulphate ion Inorganic materials 0.000 description 2
150000003606 tin compounds Chemical class 0.000 description 2
229910000348 titanium sulfate Inorganic materials 0.000 description 2
TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
101100347605 Arabidopsis thaliana VIII-A gene Proteins 0.000 description 1
101100347612 Arabidopsis thaliana VIII-B gene Proteins 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 description 1
229920000297 Rayon Polymers 0.000 description 1
229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
229920002522 Wood fibre Polymers 0.000 description 1
235000011054 acetic acid Nutrition 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
239000003513 alkali Substances 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
229910000085 borane Inorganic materials 0.000 description 1
239000007853 buffer solution Substances 0.000 description 1
150000001720 carbohydrates Chemical class 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000010276 construction Methods 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
230000006378 damage Effects 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000002939 deleterious effect Effects 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
230000029087 digestion Effects 0.000 description 1
230000001079 digestive effect Effects 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
GRWZHXKQBITJKP-UHFFFAOYSA-N dithionous acid Chemical class OS(=O)S(O)=O GRWZHXKQBITJKP-UHFFFAOYSA-N 0.000 description 1
238000001035 drying Methods 0.000 description 1
235000019253 formic acid Nutrition 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
235000011167 hydrochloric acid Nutrition 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
239000000463 material Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
239000000203 mixture Substances 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
238000009896 oxidative bleaching Methods 0.000 description 1
238000010979 pH adjustment Methods 0.000 description 1
150000004965 peroxy acids Chemical class 0.000 description 1
229960004838 phosphoric acid Drugs 0.000 description 1
235000011007 phosphoric acid Nutrition 0.000 description 1
238000002310 reflectometry Methods 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
239000001119 stannous chloride Substances 0.000 description 1
235000011150 stannous chloride Nutrition 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000002025 wood fiber Substances 0.000 description 1

Landscapes

Paper (AREA)

CA319,918A 1978-04-07 1979-01-18 Methode et solution au peroxyde pour le blanchiment de la pate de cellulose en presence d'additifs metalliques Expired CA1110018A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US89460578A	1978-04-07	1978-04-07
US894,605		1978-04-07

Publications (1)

Publication Number	Publication Date
CA1110018A true CA1110018A (fr)	1981-10-06

Family

ID=25403307

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA319,918A Expired CA1110018A (fr)	1978-04-07	1979-01-18	Methode et solution au peroxyde pour le blanchiment de la pate de cellulose en presence d'additifs metalliques

Country Status (1)

Country	Link
CA (1)	CA1110018A (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2022261743A1 (fr) *	2021-06-18	2022-12-22	Sixring Inc.	Délignification à température régulée de biomasse
EP4367173A4 (fr) *	2021-02-25	2025-07-30	Sixring Inc	Acide sulfurique modifié et ses utilisations

1979
- 1979-01-18 CA CA319,918A patent/CA1110018A/fr not_active Expired

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP4367173A4 (fr) *	2021-02-25	2025-07-30	Sixring Inc	Acide sulfurique modifié et ses utilisations
WO2022261743A1 (fr) *	2021-06-18	2022-12-22	Sixring Inc.	Délignification à température régulée de biomasse
JP2024523297A (ja) *	2021-06-18	2024-06-28	シックスリングインコーポレイテッド	バイオマスの温度制御された脱リグニン

Legal Events

Date	Code	Title	Description
1998-10-06	MKEX	Expiry

Publication	Publication Date	Title
US4410397A (en)	1983-10-18	Delignification and bleaching process and solution for lignocellulosic pulp with peroxide in the presence of metal additives
US4427490A (en)	1984-01-24	Delignification and bleaching process for lignocellulosic pulp with peroxide in the presence of metal additives
CA2067296C (fr)	1997-03-04	Procede de blanchiment de pate contenant de la lignocellulose
CA1249402A (fr)	1989-01-31	Avivage multi-etage des pates a fort et tres fort rendement
CA1129161A (fr)	1982-08-10	Methode et solution de defibrage et de blanchiment de la pate de lignocellulose au peroxyde, en presence d'additifs metalliques
US5785812A (en)	1998-07-28	Process for treating oxygen delignified pulp using an organic peracid or salt, complexing agent and peroxide bleach sequence
US6007678A (en)	1999-12-28	Process for delignification of lignocellulose-containing pulp with an organic peracid or salts thereof
CA1112813A (fr)	1981-11-24	Separation des matieres fibreuses traitees a l'ozone
US5685953A (en)	1997-11-11	Ozone bleaching with an organic solvent and mineral acid
US5766415A (en)	1998-06-16	Process for delignification and bleaching of chemical wood pulps with peroxide and dicyandiamide activator
JPH08511308A (ja)	1996-11-26	リグノセルロース材料を脱リグニン化する改良されたオゾン／過酸法
RU2439232C2 (ru)	2012-01-10	Способ отбеливания бумажной целлюлозной массы путем конечной обработки озоном при высокой температуре
US4141786A (en)	1979-02-27	Manganic ion delignification of lignocellulosic material
CA1110018A (fr)	1981-10-06	Methode et solution au peroxyde pour le blanchiment de la pate de cellulose en presence d'additifs metalliques
USH1690H (en)	1997-11-04	Process for bleaching kraft pulp
US10006168B2 (en)	2018-06-26	Method for treating chemical pulps by treatment with ozone in the presence of magnesium ions
CA2149649C (fr)	2000-09-19	Procede de blanchiment de pate contenant de la lignocellulose
US5268075A (en)	1993-12-07	High efficiency two-step, high-low pH chlorine dioxide pulp bleaching process
US5770011A (en)	1998-06-23	Neutral monoperoxysulfate bleaching process
CA2069322A1 (fr)	1991-04-20	Procede de blanchiment de pate au dioxyde de chlore a haute efficacite
US5330620A (en)	1994-07-19	Bleaching pulp with chloric acid
EP0931874A1 (fr)	1999-07-28	Procédé pour le blanchiment d'une pâte comprenant une étape finale de traitement avec un sel de l'acide peroxymonosulfurique
JP3697335B2 (ja)	2005-09-21	化学パルプの酸性漂白白水による処理方法
US5645688A (en)	1997-07-08	Bleaching compositions and processes employing sulfamates and polyaminocarboxylic acids
US5354423A (en)	1994-10-11	Ozone dioxane bleaching of chemical pulps