CA1119084A - Sonde de gaz d'echappement faite de matiere catalytique poreuse impregnee, a resistance variable, et methode d'impregnation connexe - Google Patents
Sonde de gaz d'echappement faite de matiere catalytique poreuse impregnee, a resistance variable, et methode d'impregnation connexeInfo
- Publication number
- CA1119084A CA1119084A CA000310561A CA310561A CA1119084A CA 1119084 A CA1119084 A CA 1119084A CA 000310561 A CA000310561 A CA 000310561A CA 310561 A CA310561 A CA 310561A CA 1119084 A CA1119084 A CA 1119084A
- Authority
- CA
- Canada
- Prior art keywords
- platinum
- ceramic
- particles
- grains
- ceramic material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims description 11
- 230000003197 catalytic effect Effects 0.000 title description 24
- 238000005470 impregnation Methods 0.000 title description 3
- 239000007789 gas Substances 0.000 claims abstract description 55
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 55
- 239000002245 particle Substances 0.000 claims abstract description 32
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 26
- 229910010293 ceramic material Inorganic materials 0.000 claims abstract description 24
- 239000001301 oxygen Substances 0.000 claims abstract description 20
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 20
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910001260 Pt alloy Inorganic materials 0.000 claims abstract description 9
- 239000000919 ceramic Substances 0.000 claims description 46
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 38
- 230000004044 response Effects 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 7
- 239000006193 liquid solution Substances 0.000 claims description 6
- 230000008859 change Effects 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 230000006872 improvement Effects 0.000 claims description 2
- 230000003028 elevating effect Effects 0.000 claims 1
- 238000005245 sintering Methods 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 3
- 229910045601 alloy Inorganic materials 0.000 abstract 2
- 239000000956 alloy Substances 0.000 abstract 2
- 239000012530 fluid Substances 0.000 abstract 2
- 238000002485 combustion reaction Methods 0.000 description 20
- 239000003795 chemical substances by application Substances 0.000 description 17
- 239000000446 fuel Substances 0.000 description 15
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 12
- 239000000203 mixture Substances 0.000 description 10
- 239000000843 powder Substances 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 7
- 239000003344 environmental pollutant Substances 0.000 description 7
- 231100000719 pollutant Toxicity 0.000 description 7
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 239000006227 byproduct Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 238000012545 processing Methods 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 230000002939 deleterious effect Effects 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- -1 oxygen ions Chemical class 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical class Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 235000012431 wafers Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
- G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
- G01N27/12—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid, for detecting components in the fluid
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/04—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material having negative temperature coefficient
- H01C7/042—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material having negative temperature coefficient mainly consisting of inorganic non-metallic substances
- H01C7/043—Oxides or oxidic compounds
- H01C7/045—Perovskites, e.g. titanates
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Analytical Chemistry (AREA)
- Electromagnetism (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Materials By The Use Of Fluid Adsorption Or Reactions (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US83970177A | 1977-10-05 | 1977-10-05 | |
| US839,701 | 1977-10-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1119084A true CA1119084A (fr) | 1982-03-02 |
Family
ID=25280436
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000310561A Expired CA1119084A (fr) | 1977-10-05 | 1978-09-01 | Sonde de gaz d'echappement faite de matiere catalytique poreuse impregnee, a resistance variable, et methode d'impregnation connexe |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0001509B1 (fr) |
| JP (1) | JPS5463896A (fr) |
| CA (1) | CA1119084A (fr) |
| DE (1) | DE2861990D1 (fr) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5558447A (en) * | 1978-10-25 | 1980-05-01 | Nippon Soken Inc | Gas constituent detector |
| US4225559A (en) * | 1979-01-22 | 1980-09-30 | Ford Motor Company | Ceramic element sensor |
| EP0140340B1 (fr) * | 1983-10-28 | 1989-07-19 | NGK Spark Plug Co. Ltd. | Capteur de gaz avec un substrat en céramique et méthode pour le fabriquer |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3893230A (en) * | 1971-11-15 | 1975-07-08 | Ford Motor Co | Method of manufacture of an exhaust gas sensor for an air-fuel ratio sensing system |
| BE794909A (fr) * | 1972-02-11 | 1973-05-29 | Renault | Dispositif de detection et de dosage d'un constituant de melange gazeux |
| GB1437075A (en) * | 1972-06-30 | 1976-05-26 | Nat Res Dev | Gas detectors |
| JPS5625616B2 (fr) * | 1973-10-08 | 1981-06-13 | ||
| US4011655A (en) * | 1974-06-27 | 1977-03-15 | Ford Motor Company | Exhaust gas sensor probe method of manufacture |
| JPS5273089A (en) * | 1975-12-15 | 1977-06-18 | Nippon Soken | Detector for gas composition |
-
1978
- 1978-09-01 CA CA000310561A patent/CA1119084A/fr not_active Expired
- 1978-10-05 JP JP12208378A patent/JPS5463896A/ja active Pending
- 1978-10-05 DE DE7878300463T patent/DE2861990D1/de not_active Expired
- 1978-10-05 EP EP19780300463 patent/EP0001509B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| EP0001509A1 (fr) | 1979-04-18 |
| JPS5463896A (en) | 1979-05-23 |
| EP0001509B1 (fr) | 1982-08-04 |
| DE2861990D1 (en) | 1982-09-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |