CA1136314A - Composition de moulage, et article moule par injection - Google Patents

Composition de moulage, et article moule par injection

Info

Publication number: CA1136314A
Authority: CA; Canada
Prior art keywords: molding composition; molding; composition according; monomer; phase
Prior art date: 1979-12-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000350042A

Other languages

English (en)

Inventor

John J. Charles

Robert C. Gasman

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

GAF Corp

Original Assignee

GAF Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-12-26

Filing date

1980-04-17

Publication date

1982-11-23

1979-12-26 Priority claimed from US06/101,950 external-priority patent/US4283326A/en

1980-04-17 Application filed by GAF Corp filed Critical GAF Corp

1982-11-23 Application granted granted Critical

1982-11-23 Publication of CA1136314A publication Critical patent/CA1136314A/fr

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 90
238000000465 moulding Methods 0.000 title claims abstract description 66
238000002347 injection Methods 0.000 title claims description 10
239000007924 injection Substances 0.000 title claims description 10
239000000178 monomer Substances 0.000 claims abstract description 49
-1 alkylene terephthalate Chemical compound 0.000 claims abstract description 25
229920000642 polymer Polymers 0.000 claims abstract description 24
239000010445 mica Substances 0.000 claims abstract description 20
229910052618 mica group Inorganic materials 0.000 claims abstract description 20
239000012783 reinforcing fiber Substances 0.000 claims abstract description 16
238000004132 cross linking Methods 0.000 claims abstract description 12
239000003365 glass fiber Substances 0.000 claims abstract description 11
229920001169 thermoplastic Polymers 0.000 claims abstract description 11
239000004416 thermosoftening plastic Substances 0.000 claims abstract description 11
239000002131 composite material Substances 0.000 claims abstract description 6
229920001707 polybutylene terephthalate Polymers 0.000 claims description 26
239000002245 particle Substances 0.000 claims description 9
229920000139 polyethylene terephthalate Polymers 0.000 claims description 9
239000005020 polyethylene terephthalate Substances 0.000 claims description 9
239000002253 acid Substances 0.000 claims description 7
238000006243 chemical reaction Methods 0.000 claims description 6
229940063557 methacrylate Drugs 0.000 claims description 6
238000006116 polymerization reaction Methods 0.000 claims description 6
JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical group C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 claims description 5
ZPOLOEWJWXZUSP-WAYWQWQTSA-N bis(prop-2-enyl) (z)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C/C(=O)OCC=C ZPOLOEWJWXZUSP-WAYWQWQTSA-N 0.000 claims description 5
239000011521 glass Substances 0.000 claims description 5
FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 claims description 5
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 3
230000009477 glass transition Effects 0.000 claims description 3
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
229920000728 polyester Polymers 0.000 claims description 3
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
125000003368 amide group Chemical group 0.000 claims description 2
239000003795 chemical substances by application Substances 0.000 claims description 2
239000003431 cross linking reagent Substances 0.000 claims description 2
VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
239000002667 nucleating agent Substances 0.000 claims description 2
RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 claims description 2
125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
125000003700 epoxy group Chemical group 0.000 claims 2
229940048053 acrylate Drugs 0.000 claims 1
125000005399 allylmethacrylate group Chemical group 0.000 claims 1
229920000136 polysorbate Polymers 0.000 claims 1
125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 1
239000000835 fiber Substances 0.000 description 10
239000004593 Epoxy Substances 0.000 description 8
238000002156 mixing Methods 0.000 description 8
239000000654 additive Substances 0.000 description 6
239000000463 material Substances 0.000 description 6
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 5
239000004615 ingredient Substances 0.000 description 5
238000001746 injection moulding Methods 0.000 description 5
238000004519 manufacturing process Methods 0.000 description 5
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
229920001971 elastomer Polymers 0.000 description 4
239000000806 elastomer Substances 0.000 description 4
238000000034 method Methods 0.000 description 4
230000000704 physical effect Effects 0.000 description 4
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
239000004609 Impact Modifier Substances 0.000 description 3
125000002947 alkylene group Chemical group 0.000 description 3
238000001125 extrusion Methods 0.000 description 3
239000003063 flame retardant Substances 0.000 description 3
ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
241000422980 Marietta Species 0.000 description 2
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
125000005250 alkyl acrylate group Chemical group 0.000 description 2
ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
230000008602 contraction Effects 0.000 description 2
239000011152 fibreglass Substances 0.000 description 2
229940090044 injection Drugs 0.000 description 2
239000000314 lubricant Substances 0.000 description 2
239000003607 modifier Substances 0.000 description 2
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 2
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 2
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
WVAFEFUPWRPQSY-UHFFFAOYSA-N 1,2,3-tris(ethenyl)benzene Chemical compound C=CC1=CC=CC(C=C)=C1C=C WVAFEFUPWRPQSY-UHFFFAOYSA-N 0.000 description 1
STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
XOJWAAUYNWGQAU-UHFFFAOYSA-N 4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCOC(=O)C(C)=C XOJWAAUYNWGQAU-UHFFFAOYSA-N 0.000 description 1
OMIHGPLIXGGMJB-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]hepta-1,3,5-triene Chemical class C1=CC=C2OC2=C1 OMIHGPLIXGGMJB-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
GXBYFVGCMPJVJX-UHFFFAOYSA-N Epoxybutene Chemical compound C=CC1CO1 GXBYFVGCMPJVJX-UHFFFAOYSA-N 0.000 description 1
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 1
239000004677 Nylon Substances 0.000 description 1
LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
229920000800 acrylic rubber Polymers 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
230000003466 anti-cipated effect Effects 0.000 description 1
239000004760 aramid Substances 0.000 description 1
229920003235 aromatic polyamide Polymers 0.000 description 1
239000010425 asbestos Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
ZPOLOEWJWXZUSP-AATRIKPKSA-N bis(prop-2-enyl) (e)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C\C(=O)OCC=C ZPOLOEWJWXZUSP-AATRIKPKSA-N 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
239000003086 colorant Substances 0.000 description 1
229940000425 combination drug Drugs 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000012937 correction Methods 0.000 description 1
WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 1
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
VVYDVQWJZWRVPE-UHFFFAOYSA-L dimethyltin(2+);diiodide Chemical compound C[Sn](C)(I)I VVYDVQWJZWRVPE-UHFFFAOYSA-L 0.000 description 1
150000002009 diols Chemical class 0.000 description 1
NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
238000009826 distribution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000006735 epoxidation reaction Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
BLCTWBJQROOONQ-UHFFFAOYSA-N ethenyl prop-2-enoate Chemical compound C=COC(=O)C=C BLCTWBJQROOONQ-UHFFFAOYSA-N 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical compound OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000000155 melt Substances 0.000 description 1
125000005395 methacrylic acid group Chemical group 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
229920001778 nylon Polymers 0.000 description 1
GYDSPAVLTMAXHT-UHFFFAOYSA-N pentyl 2-methylprop-2-enoate Chemical compound CCCCCOC(=O)C(C)=C GYDSPAVLTMAXHT-UHFFFAOYSA-N 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
239000004417 polycarbonate Substances 0.000 description 1
229920000515 polycarbonate Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920005862 polyol Polymers 0.000 description 1
150000003077 polyols Chemical class 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
230000002787 reinforcement Effects 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
229910052895 riebeckite Inorganic materials 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
238000010998 test method Methods 0.000 description 1
238000012360 testing method Methods 0.000 description 1
230000000007 visual effect Effects 0.000 description 1
238000011179 visual inspection Methods 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

CA000350042A 1979-12-26 1980-04-17 Composition de moulage, et article moule par injection Expired CA1136314A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US06/101,950 US4283326A (en)	1977-07-11	1979-12-26	PBT Molding compositions containing mica and a composite polymer
US101,950		1979-12-29

Publications (1)

Publication Number	Publication Date
CA1136314A true CA1136314A (fr)	1982-11-23

Family

ID=22287338

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000350042A Expired CA1136314A (fr)	1979-12-26	1980-04-17	Composition de moulage, et article moule par injection

Country Status (2)

Country	Link
JP (1)	JPS5693751A (fr)
CA (1)	CA1136314A (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4393153A (en) *	1981-10-30	1983-07-12	General Electric Company	Impact modified glass/mineral reinforced polyester blends

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5128141A (ja) *	1974-09-03	1976-03-09	Asahi Chemical Ind	Mukijutenzaiganjusenjohoriesuterujushisoseibutsu no seizoho
US4096202A (en) *	1976-06-09	1978-06-20	Rohm And Haas Company	Impact modified poly(alkylene terephthalates)
CA1130945A (fr) *	1979-01-18	1982-08-31	John J. Charles	Substance profilable renforcee de terephtalate de polybutylene

1980
- 1980-02-25 JP JP2174180A patent/JPS5693751A/ja active Pending
- 1980-04-17 CA CA000350042A patent/CA1136314A/fr not_active Expired

Also Published As

Publication number	Publication date
JPS5693751A (en)	1981-07-29

Legal Events

Date	Code	Title	Description
1999-11-23	MKEX	Expiry

Publication	Publication Date	Title
CA1166388A (fr)	1984-04-24	Compositions de polyester thermoplastique aux polyacrylates greffes pour le moulage
GB1590549A (en)	1981-06-03	Thermoplastic moulding compositions of high impact strength
US4689365A (en)	1987-08-25	High temperature resistant polyester compositions
EP0329468A2 (fr)	1989-08-23	Composition à mouler de polyester
JPH0352494B2 (fr)	1991-08-12
CA1272538A (fr)	1990-08-07	Compositions de polyester modifie
CA1272537A (fr)	1990-08-07	Compositions de polyester
KR102001482B1 (ko)	2019-07-18	열가소성 수지 조성물 및 이를 이용한 성형품
US4666972A (en)	1987-05-19	Thermoplastic moulding compositions based on polyalkylene terephthalate and polymer and a process for the production thereof
EP0327300B1 (fr)	1996-04-03	Composition de polyarylène sulfure
US3857812A (en)	1974-12-31	Unsaturated polyester compositions and thermoset articles prepared therefrom
US4283326A (en)	1981-08-11	PBT Molding compositions containing mica and a composite polymer
EP0033393A2 (fr)	1981-08-12	Masse à mouler et produit à base de polyester
US4317764A (en)	1982-03-02	Polybutylene terephthalate molding blends
CA1130945A (fr)	1982-08-31	Substance profilable renforcee de terephtalate de polybutylene
CA1119740A (fr)	1982-03-09	Resine de polyester a retention amelioree de ses proprietes
US5326822A (en)	1994-07-05	Heat-curable molding material
JPS59531B2 (ja)	1984-01-07	ポリエステル樹脂組成物
CA1136314A (fr)	1982-11-23	Composition de moulage, et article moule par injection
KR920004813B1 (ko)	1992-06-18	열가소성 폴리에스테르 수지 조성물
JPH0328463B2 (fr)	1991-04-19
US4145331A (en)	1979-03-20	Thermoplastic polyester molding compositions with improved heat distortion point
KR930010235B1 (ko)	1993-10-15	폴리에스테르/폴리카보네이트 합금 수지 조성물
JPS58204020A (ja)	1983-11-28	強化ポリオレフイン系樹脂組成物
JP3487035B2 (ja)	2004-01-13	Ｐｅｔ樹脂成形材料