CA1177464A - Methode et catalyseur de conversion d'un gaz de synthese en un melange liquide d'hydrocarbures - Google Patents

Methode et catalyseur de conversion d'un gaz de synthese en un melange liquide d'hydrocarbures

Info

Publication number: CA1177464A
Authority: CA; Canada
Prior art keywords: catalyst; weight; cobalt; thoria; mixture
Prior art date: 1981-10-09
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000412380A

Other languages

English (en)

Inventor

V. Udaya S. Rao

Robert J. Gormley

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

US Department of Energy

Original Assignee

US Department of Energy

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-10-09

Filing date

1982-09-28

Publication date

1984-11-06

1982-09-28 Application filed by US Department of Energy filed Critical US Department of Energy

1984-11-06 Application granted granted Critical

1984-11-06 Publication of CA1177464A publication Critical patent/CA1177464A/fr

Status Expired legal-status Critical Current

Links

229930195733 hydrocarbon Natural products 0.000 title claims abstract description 32
150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 31
239000007788 liquid Substances 0.000 title claims abstract description 31
239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 19
239000003054 catalyst Substances 0.000 title claims description 58
238000000034 method Methods 0.000 title claims description 30
239000000203 mixture Substances 0.000 title claims description 18
230000015572 biosynthetic process Effects 0.000 title abstract description 13
238000003786 synthesis reaction Methods 0.000 title abstract description 13
230000008569 process Effects 0.000 title description 12
229910017052 cobalt Inorganic materials 0.000 claims abstract description 26
239000010941 cobalt Substances 0.000 claims abstract description 26
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 26
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 24
ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 claims abstract description 24
239000010457 zeolite Substances 0.000 claims abstract description 22
229910021536 Zeolite Inorganic materials 0.000 claims abstract description 20
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims abstract description 19
238000009835 boiling Methods 0.000 claims abstract description 16
239000003502 gasoline Substances 0.000 claims abstract description 15
239000002808 molecular sieve Substances 0.000 claims abstract description 6
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 6
239000006069 physical mixture Substances 0.000 claims abstract description 3
239000007789 gas Substances 0.000 claims description 26
238000006243 chemical reaction Methods 0.000 claims description 16
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 14
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 14
229910002091 carbon monoxide Inorganic materials 0.000 claims description 14
229910052739 hydrogen Inorganic materials 0.000 claims description 13
239000001257 hydrogen Substances 0.000 claims description 13
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
239000008187 granular material Substances 0.000 claims description 7
150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 5
239000011148 porous material Substances 0.000 claims description 5
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
239000002253 acid Substances 0.000 claims description 3
239000008188 pellet Substances 0.000 claims description 3
239000000377 silicon dioxide Substances 0.000 claims description 2
239000002638 heterogeneous catalyst Substances 0.000 abstract description 2
239000000047 product Substances 0.000 description 23
229910052751 metal Inorganic materials 0.000 description 9
239000002184 metal Substances 0.000 description 9
150000001336 alkenes Chemical class 0.000 description 8
239000000446 fuel Substances 0.000 description 6
238000004519 manufacturing process Methods 0.000 description 6
150000002739 metals Chemical class 0.000 description 6
230000003197 catalytic effect Effects 0.000 description 5
239000000463 material Substances 0.000 description 5
239000000243 solution Substances 0.000 description 5
ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
229910052776 Thorium Inorganic materials 0.000 description 4
229910000323 aluminium silicate Inorganic materials 0.000 description 4
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
239000012263 liquid product Substances 0.000 description 3
230000002829 reductive effect Effects 0.000 description 3
239000001993 wax Substances 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
229910004369 ThO2 Inorganic materials 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
150000004649 carbonic acid derivatives Chemical class 0.000 description 2
239000003245 coal Substances 0.000 description 2
238000002309 gasification Methods 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
230000009467 reduction Effects 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
150000001218 Thorium Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
230000001668 ameliorated effect Effects 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
238000001354 calcination Methods 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
239000000969 carrier Substances 0.000 description 1
229910000428 cobalt oxide Inorganic materials 0.000 description 1
IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
230000002844 continuous effect Effects 0.000 description 1
239000002283 diesel fuel Substances 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000002737 fuel gas Substances 0.000 description 1
230000008821 health effect Effects 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
239000011572 manganese Substances 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
229910052762 osmium Inorganic materials 0.000 description 1
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000012466 permeate Substances 0.000 description 1
239000008262 pumice Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
230000004044 response Effects 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
239000010948 rhodium Substances 0.000 description 1
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
150000003586 thorium compounds Chemical class 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

CA000412380A 1981-10-09 1982-09-28 Methode et catalyseur de conversion d'un gaz de synthese en un melange liquide d'hydrocarbures Expired CA1177464A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US31024681A	1981-10-09	1981-10-09
US310,246		1981-10-09

Publications (1)

Publication Number	Publication Date
CA1177464A true CA1177464A (fr)	1984-11-06

Family

ID=23201621

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000412380A Expired CA1177464A (fr)	1981-10-09	1982-09-28	Methode et catalyseur de conversion d'un gaz de synthese en un melange liquide d'hydrocarbures

Country Status (3)

Country	Link
JP (1)	JPS5871987A (fr)
AU (1)	AU575016B2 (fr)
CA (1)	CA1177464A (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2561640A1 (fr) *	1984-03-22	1985-09-27	Shell Int Research	Procede de production d'hydrocarbures a partir de gaz de synthese
US4579830A (en) *	1984-06-27	1986-04-01	Union Carbide Corporation	Enhanced catalyst for converting synthesis gas to liquid motor fuels
JP4920597B2 (ja)	2004-12-08	2012-04-18	エル・ピー・ピーコンバスションエル・エル・シー	液体炭化水素燃料を調整する方法および装置
US8529646B2 (en) *	2006-05-01	2013-09-10	Lpp Combustion Llc	Integrated system and method for production and vaporization of liquid hydrocarbon fuels for combustion

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3702886A (en) *	1969-10-10	1972-11-14	Mobil Oil Corp	Crystalline zeolite zsm-5 and method of preparing the same
CA1062285A (fr) *	1974-04-24	1979-09-11	Mobil Oil Corporation	Conversion de gaz de synthese en melanges d'hydrocarbure
US4086262A (en) *	1976-09-20	1978-04-25	Mobil Oil Corporation	Conversion of synthesis gas to hydrocarbon mixtures
US4207248A (en) *	1978-12-18	1980-06-10	Mobil Oil Corporation	Conversion of synthesis gas with cobalt-containing fluid catalyst
NZ201262A (en) *	1981-07-17	1984-12-14	British Petroleum Co	Catalytic conversion of synthesis gas to hydrocarbons

1982
- 1982-09-28 CA CA000412380A patent/CA1177464A/fr not_active Expired
- 1982-09-30 AU AU88929/82A patent/AU575016B2/en not_active Ceased
- 1982-10-08 JP JP57177465A patent/JPS5871987A/ja active Pending

Also Published As

Publication number	Publication date
AU8892982A (en)	1983-04-14
AU575016B2 (en)	1988-07-21
JPS5871987A (ja)	1983-04-28

Legal Events

Date	Code	Title	Description
2001-11-07	MKEC	Expiry (correction)
2002-09-28	MKEX	Expiry

Publication	Publication Date	Title
US4542122A (en)	1985-09-17	Cobalt catalysts for the preparation of hydrocarbons from synthesis gas and from methanol
CA1156265A (fr)	1983-11-01	Methodes de conversion catalytique
CA1077067A (fr)	1980-05-06	Production d'olefines
CA1156266A (fr)	1983-11-01	Methode de preparation de distillats moyens
EP0020140B1 (fr)	1983-04-13	Conversion de gaz de synthèse en mélanges d'hydrocarbures en utilisant des réacteurs jumelés
US4659743A (en)	1987-04-21	Process and catalyst for converting synthesis gas to liquid hydrocarbon mixture
US4039302A (en)	1977-08-02	Process and catalyst for synthesizing low boiling (C1 to C3) aliphatic hydrocarbons from carbon monoxide and hydrogen
JPS5839131B2 (ja)	1983-08-27	ゴウセイガスオタンカスイソコンゴウブツヘテンカスルホウホウ
US4617288A (en)	1986-10-14	Low nitrogen iron-containing Fischer-Tropsch catalyst for conversion of synthesis gas and process for preparing the catalyst
US4686313A (en)	1987-08-11	Low nitrogen iron-containing Fischer-Tropsch catalyst and conversion of synthesis gas therewith
US5126377A (en)	1992-06-30	Catalyst for conversion of synthesis gas into hydrocarbons
US4371628A (en)	1983-02-01	Process for the preparation of aromatic hydrocarbons using crystalline silicates as catalyst
US4906671A (en)	1990-03-06	Fischer-tropsch process
EP0167353B1 (fr)	1988-05-11	Procédé pour la conversion catalytique de méthanol en hydrocarbures
US6730708B2 (en)	2004-05-04	Fischer-Tropsch processes and catalysts using aluminum borate supports
US4652538A (en)	1987-03-24	Catalysts for conversion of syngas to liquid motor fuels
NZ202146A (en)	1985-07-31	Production of oxygenated hydrocarbons from synthesis gas
CA1177464A (fr)	1984-11-06	Methode et catalyseur de conversion d'un gaz de synthese en un melange liquide d'hydrocarbures
CA1232292A (fr)	1988-02-02	Production de melanges d'hydrocarbures
Fujiwara et al.	1992	Hydrocarbon synthesis from carbon dioxide and hydrogen over Cu–Zn–Cr oxide/zeolite hybrid catalysts
EP0153517A1 (fr)	1985-09-04	Catalyseur, sa préparation, et procédé pour la production de paraffines liquides
CA1225982A (fr)	1987-08-25	Conversion du gaz de synthese en carburant liquide pour l'automobile
CA1081196A (fr)	1980-07-08	Production d'hydrocarbures et catalyseur
CA1198451A (fr)	1985-12-24	Methode de production d'hydrocarbures
EP0051326B1 (fr)	1984-07-04	Procédé pour la préparation d'hydrocarbures