CA1178003A - Methode d'ensimage de produits textiles - Google Patents
Methode d'ensimage de produits textilesInfo
- Publication number
- CA1178003A CA1178003A CA000401465A CA401465A CA1178003A CA 1178003 A CA1178003 A CA 1178003A CA 000401465 A CA000401465 A CA 000401465A CA 401465 A CA401465 A CA 401465A CA 1178003 A CA1178003 A CA 1178003A
- Authority
- CA
- Canada
- Prior art keywords
- weight
- composition
- grams
- copolymer
- acrylamide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 22
- 239000004753 textile Substances 0.000 title claims abstract description 22
- 238000004513 sizing Methods 0.000 title claims abstract description 13
- 239000000463 material Substances 0.000 title claims description 16
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 33
- 229920001577 copolymer Polymers 0.000 claims abstract description 25
- 239000000203 mixture Substances 0.000 claims description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 36
- 239000000243 solution Substances 0.000 claims description 33
- 239000000178 monomer Substances 0.000 claims description 23
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 14
- 239000007787 solid Substances 0.000 claims description 13
- 238000005299 abrasion Methods 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 11
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 11
- 239000000758 substrate Substances 0.000 claims description 10
- 229920000742 Cotton Polymers 0.000 claims description 9
- -1 alkyl methacrylate Chemical compound 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 6
- 229920002554 vinyl polymer Polymers 0.000 claims description 6
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 4
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 3
- 229940117913 acrylamide Drugs 0.000 claims 4
- SNVLJLYUUXKWOJ-UHFFFAOYSA-N methylidenecarbene Chemical compound C=[C] SNVLJLYUUXKWOJ-UHFFFAOYSA-N 0.000 claims 1
- 229920000642 polymer Polymers 0.000 abstract description 10
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 30
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 22
- 239000011541 reaction mixture Substances 0.000 description 17
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 15
- 229910052757 nitrogen Inorganic materials 0.000 description 11
- 229920002472 Starch Polymers 0.000 description 10
- 235000019698 starch Nutrition 0.000 description 10
- 239000008107 starch Substances 0.000 description 10
- 239000000443 aerosol Substances 0.000 description 8
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 7
- 229940001584 sodium metabisulfite Drugs 0.000 description 7
- 235000010262 sodium metabisulphite Nutrition 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 229920002401 polyacrylamide Polymers 0.000 description 6
- 229920005604 random copolymer Polymers 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 239000012298 atmosphere Substances 0.000 description 4
- 239000004014 plasticizer Substances 0.000 description 4
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 229940031098 ethanolamine Drugs 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- BHMLFPOTZYRDKA-IRXDYDNUSA-N (2s)-2-[(s)-(2-iodophenoxy)-phenylmethyl]morpholine Chemical compound IC1=CC=CC=C1O[C@@H](C=1C=CC=CC=1)[C@H]1OCCNC1 BHMLFPOTZYRDKA-IRXDYDNUSA-N 0.000 description 1
- NKYRAXWYDRHWOG-UHFFFAOYSA-N 12-hydroxydodecyl prop-2-enoate Chemical compound OCCCCCCCCCCCCOC(=O)C=C NKYRAXWYDRHWOG-UHFFFAOYSA-N 0.000 description 1
- OGVVEUNHYMQQPC-UHFFFAOYSA-N 12-methoxydodecyl 2-methylprop-2-enoate Chemical compound COCCCCCCCCCCCCOC(=O)C(C)=C OGVVEUNHYMQQPC-UHFFFAOYSA-N 0.000 description 1
- UDELLVVWDCMVRX-UHFFFAOYSA-N 14-(dimethylamino)-2-methylidenetetradecanoic acid Chemical compound CN(C)CCCCCCCCCCCCC(=C)C(O)=O UDELLVVWDCMVRX-UHFFFAOYSA-N 0.000 description 1
- SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 description 1
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
- WOQXJLWJCHWBBV-UHFFFAOYSA-N 2-(ethylamino)octyl prop-2-enoate Chemical compound CCCCCCC(NCC)COC(=O)C=C WOQXJLWJCHWBBV-UHFFFAOYSA-N 0.000 description 1
- BEWCNXNIQCLWHP-UHFFFAOYSA-N 2-(tert-butylamino)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCNC(C)(C)C BEWCNXNIQCLWHP-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- HFCUBKYHMMPGBY-UHFFFAOYSA-N 2-methoxyethyl prop-2-enoate Chemical compound COCCOC(=O)C=C HFCUBKYHMMPGBY-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241000521257 Hydrops Species 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 206010030113 Oedema Diseases 0.000 description 1
- 229940048053 acrylate Drugs 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 125000002348 vinylic group Chemical group 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26892481A | 1981-06-01 | 1981-06-01 | |
| US268,925 | 1981-06-01 | ||
| US06/268,925 US4410588A (en) | 1981-06-01 | 1981-06-01 | Process for sizing textile yarns |
| US268,924 | 1981-06-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1178003A true CA1178003A (fr) | 1984-11-20 |
Family
ID=26953412
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000401465A Expired CA1178003A (fr) | 1981-06-01 | 1982-04-22 | Methode d'ensimage de produits textiles |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0066078B1 (fr) |
| BR (1) | BR8202900A (fr) |
| CA (1) | CA1178003A (fr) |
| DE (1) | DE3277539D1 (fr) |
| MX (1) | MX159154A (fr) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5626952A (en) * | 1995-12-15 | 1997-05-06 | Callaway Corporation | Process for sizing spun yarns |
| FR2879630B1 (fr) | 2004-12-22 | 2007-02-23 | Emz Trek | Nouvelle composition d'encollage de fils textiles |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB467492A (en) * | 1935-11-11 | 1937-06-11 | Roehm & Haas Ag | Condensation products of methacrylamide and formaldehyde |
| DE1037128B (de) * | 1956-03-17 | 1958-08-21 | Basf Ag | Verfahren zur Herstellung von in Wasser loeslichen, Amid- und Estergruppen enthaltenden Mischpolymerisaten |
| US3114651A (en) * | 1960-07-22 | 1963-12-17 | American Cyanamid Co | Water insolubilization of acrylamido polymers with a salt of trivalent chromium |
| DE1277801B (de) * | 1964-07-04 | 1968-09-19 | Basf Ag | Verwendung von flockungsstabilen Mischungen aus Polyacrylsaeureamidloesungen und waessrigen Dispersionen von Hydrophobiermitteln zum Ausruesten von Textilien |
| GB1126120A (en) * | 1966-05-16 | 1968-09-05 | Dow Chemical Co | Sizing composition for siliceous fibres |
| US3525723A (en) * | 1967-11-03 | 1970-08-25 | Denki Kagaku Kogyo Kk | Sizing agent for textile fibers derived from methanolysis of a vinyl acetate acrylamide copolymer |
| DE2527804A1 (de) * | 1975-06-21 | 1976-12-30 | Hans Prof Dipl Chem Dr Wilhelm | Waessrige zubereitungen von amidgruppen enthaltenden polymerisaten fuer die textilveredlung |
| US4098987A (en) * | 1976-07-14 | 1978-07-04 | American Cyanamid Company | Non-ionic surfactants from water soluble copolymers of acrylamide with hydrophobic monomers |
-
1982
- 1982-04-22 CA CA000401465A patent/CA1178003A/fr not_active Expired
- 1982-04-22 EP EP19820103397 patent/EP0066078B1/fr not_active Expired
- 1982-04-22 DE DE8282103397T patent/DE3277539D1/de not_active Expired
- 1982-05-19 BR BR8202900A patent/BR8202900A/pt not_active IP Right Cessation
- 1982-06-01 MX MX19296082A patent/MX159154A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| MX159154A (es) | 1989-04-26 |
| EP0066078A3 (en) | 1985-03-20 |
| BR8202900A (pt) | 1983-05-03 |
| EP0066078A2 (fr) | 1982-12-08 |
| DE3277539D1 (en) | 1987-12-03 |
| EP0066078B1 (fr) | 1987-10-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3995998A (en) | Method of polymerizing and fixing carboxyl-containing vinyl monomers in high conversion on fibrous substrates | |
| TWI235755B (en) | Process for improving polyamide, acrylic, aramid, cellulosic and polyester properties, and modified polymers produced thereby | |
| JPH11106437A (ja) | ポリマー組成物 | |
| JPS6253633B2 (fr) | ||
| HUT59730A (en) | Method for treating porous substratums | |
| JP2000054260A (ja) | 布を仕上げる方法及び仕上げ浴 | |
| JP2002348780A (ja) | 吸湿発熱性セルロース系繊維 | |
| JP2000506909A (ja) | カルボン酸を含むポリマー/レゾール樹脂耐汚染性剤 | |
| JPH02135207A (ja) | 水溶性または水分散性グラフト重合体、その製造方法ならびにその使用 | |
| JPS63268721A (ja) | フッ素化された単量体によって重合体物質をグラフトして重合体物質の耐水性を確実にする方法およびそれによって得られる物質 | |
| JPH02142810A (ja) | 水溶性または水分散性共重合体、その製造方法ならびにその使用 | |
| CN110382775B (zh) | 纤维素系纤维用湿摩擦坚牢度提高剂,使用其的染色纤维素纤维的制造方法,及其用途 | |
| US3440200A (en) | Treatment of woven fabrics with aqueous dispersion of interpolymer of vinyl acetate,ethylene and glycidyl acrylate | |
| JPH021795A (ja) | 撥水撥油剤 | |
| JPH02261851A (ja) | 酢酸ビニル/エチレン/自己橋かけするモノマーおよびテトラメチロールグリコルリルの不織バインダ | |
| KR970001083B1 (ko) | 폴리아미드 제품의 방오처리방법 | |
| CA1097834A (fr) | Substances de finition a base de resines | |
| US4410588A (en) | Process for sizing textile yarns | |
| US4515855A (en) | Process for sizing textile materials | |
| EP0066078B1 (fr) | Procédé d'encollage de fils textiles | |
| US5230711A (en) | Dyeing of cellulose with soluble sulphur dyes without reducing agent | |
| Nuessle et al. | Acrylic resins in textile processing | |
| CA2284054C (fr) | Pates gonflantes imprimables et leur utilisation | |
| JP4314501B2 (ja) | 吸湿性ポリエステル繊維成形品 | |
| JPS6228826B2 (fr) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEC | Expiry (correction) | ||
| MKEX | Expiry |