CA1186806A - Varistance metal-oxyde a capacite et tension de claquage controlables - Google Patents

Varistance metal-oxyde a capacite et tension de claquage controlables

Info

Publication number: CA1186806A
Authority: CA; Canada
Prior art keywords: varistor; lithium; heating; varistor material; capacitance
Prior art date: 1981-08-24
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000408962A

Other languages

English (en)

Inventor

Herbert R. Philipp

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

General Electric Co

Original Assignee

General Electric Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-08-24

Filing date

1982-08-06

Publication date

1985-05-07

1982-08-06 Application filed by General Electric Co filed Critical General Electric Co

1985-05-07 Application granted granted Critical

1985-05-07 Publication of CA1186806A publication Critical patent/CA1186806A/fr

Status Expired legal-status Critical Current

Links

230000015556 catabolic process Effects 0.000 title claims abstract description 28
229910044991 metal oxide Inorganic materials 0.000 title abstract description 16
150000004706 metal oxides Chemical class 0.000 title abstract description 16
239000000463 material Substances 0.000 claims abstract description 39
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 37
229910052744 lithium Inorganic materials 0.000 claims abstract description 37
238000009792 diffusion process Methods 0.000 claims abstract description 9
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 21
238000000034 method Methods 0.000 claims description 16
238000010438 heat treatment Methods 0.000 claims description 13
IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 claims description 12
239000000203 mixture Substances 0.000 claims description 11
239000011787 zinc oxide Substances 0.000 claims description 10
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 9
AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims description 8
FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 6
WMWLMWRWZQELOS-UHFFFAOYSA-N bismuth(iii) oxide Chemical compound O=[Bi]O[Bi]=O WMWLMWRWZQELOS-UHFFFAOYSA-N 0.000 claims description 5
UPWOEMHINGJHOB-UHFFFAOYSA-N oxo(oxocobaltiooxy)cobalt Chemical compound O=[Co]O[Co]=O UPWOEMHINGJHOB-UHFFFAOYSA-N 0.000 claims description 5
ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 3
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
150000001875 compounds Chemical class 0.000 claims description 3
239000002904 solvent Substances 0.000 claims description 3
GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 claims description 2
239000000470 constituent Substances 0.000 claims description 2
NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims 4
230000007423 decrease Effects 0.000 claims 2
XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 claims 2
238000001704 evaporation Methods 0.000 claims 2
YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 claims 1
239000000654 additive Substances 0.000 description 5
239000004973 liquid crystal related substance Substances 0.000 description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
239000003990 capacitor Substances 0.000 description 4
239000010410 layer Substances 0.000 description 4
230000003071 parasitic effect Effects 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
230000001747 exhibiting effect Effects 0.000 description 3
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
230000035515 penetration Effects 0.000 description 3
239000000243 solution Substances 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 2
230000000996 additive effect Effects 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
239000002019 doping agent Substances 0.000 description 2
239000000395 magnesium oxide Substances 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
229910000480 nickel oxide Inorganic materials 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
239000011591 potassium Substances 0.000 description 2
235000012239 silicon dioxide Nutrition 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
230000009471 action Effects 0.000 description 1
JLDSOYXADOWAKB-UHFFFAOYSA-N aluminium nitrate Inorganic materials [Al+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O JLDSOYXADOWAKB-UHFFFAOYSA-N 0.000 description 1
229910000416 bismuth oxide Inorganic materials 0.000 description 1
239000004327 boric acid Substances 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
229910000423 chromium oxide Inorganic materials 0.000 description 1
229910000428 cobalt oxide Inorganic materials 0.000 description 1
IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
230000002301 combined effect Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
230000008878 coupling Effects 0.000 description 1
238000010168 coupling process Methods 0.000 description 1
238000005859 coupling reaction Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000005684 electric field Effects 0.000 description 1
229910052808 lithium carbonate Inorganic materials 0.000 description 1
229910001947 lithium oxide Inorganic materials 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
DBJLJFTWODWSOF-UHFFFAOYSA-L nickel(ii) fluoride Chemical compound F[Ni]F DBJLJFTWODWSOF-UHFFFAOYSA-L 0.000 description 1
230000008520 organization Effects 0.000 description 1
GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
230000002028 premature Effects 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000005245 sintering Methods 0.000 description 1
239000002344 surface layer Substances 0.000 description 1
229910001887 tin oxide Inorganic materials 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical compound [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1

Classifications

- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/10—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material voltage responsive, i.e. varistors
- H01C7/105—Varistor cores
- H01C7/108—Metal oxide
- H01C7/112—ZnO type

Landscapes

Engineering & Computer Science (AREA)
Microelectronics & Electronic Packaging (AREA)
Physics & Mathematics (AREA)
Electromagnetism (AREA)
Thermistors And Varistors (AREA)

CA000408962A 1981-08-24 1982-08-06 Varistance metal-oxyde a capacite et tension de claquage controlables Expired CA1186806A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US29590181A	1981-08-24	1981-08-24
US295,901		1981-08-24

Publications (1)

Publication Number	Publication Date
CA1186806A true CA1186806A (fr)	1985-05-07

Family

ID=23139706

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000408962A Expired CA1186806A (fr)	1981-08-24	1982-08-06	Varistance metal-oxyde a capacite et tension de claquage controlables

Country Status (4)

Country	Link
EP (1)	EP0074177A3 (fr)
JP (1)	JPS5866304A (fr)
BR (1)	BR8204971A (fr)
CA (1)	CA1186806A (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
SE466826B (sv) *	1990-06-28	1992-04-06	Asea Brown Boveri	Saett att framstaella en metalloxidvaristor med foerbaettrad energihaallfasthet
KR100564930B1 (ko) *	2002-10-29	2006-03-30	티디케이가부시기가이샤	칩 형상 전자 부품 및 그 제조 방법

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3723175A (en) *	1967-10-09	1973-03-27	Matsushita Electric Industrial Co Ltd	Nonlinear resistors of bulk type
CA970476A (en) *	1971-08-27	1975-07-01	Matsushita Electric Industrial Co., Ltd.	Process for making a voltage dependent resistor
DE2345753C3 (de) *	1972-09-11	1978-03-09	Tokyo Shibaura Electric Co., Ltd., Kawasaki, Kanagawa (Japan)	Metalloxid-Varistor
US4147670A (en) *	1975-12-04	1979-04-03	Nippon Electric Co., Ltd.	Nonohmic ZnO ceramics including Bi2 O3, CoO, MnO, Sb2 O.sub.3
FR2373497A1 (fr) *	1976-12-10	1978-07-07	Europ Composants Electron	Corps ceramique a resistance dependant de la tension appliquee

1982
- 1982-08-04 EP EP82304111A patent/EP0074177A3/fr not_active Withdrawn
- 1982-08-06 CA CA000408962A patent/CA1186806A/fr not_active Expired
- 1982-08-18 JP JP57142243A patent/JPS5866304A/ja active Pending
- 1982-08-23 BR BR8204971A patent/BR8204971A/pt unknown

Also Published As

Publication number	Publication date
EP0074177A3 (fr)	1983-08-31
JPS5866304A (ja)	1983-04-20
BR8204971A (pt)	1983-08-02
EP0074177A2 (fr)	1983-03-16

Legal Events

Date	Code	Title	Description
2002-05-08	MKEC	Expiry (correction)
2002-08-06	MKEX	Expiry

Publication	Publication Date	Title
US4495482A (en)	1985-01-22	Metal oxide varistor with controllable breakdown voltage and capacitance and method of making
CA1153828A (fr)	1983-09-13	Varistor en couche mince
US4276578A (en)	1981-06-30	Arrester with graded capacitance varistors
EP0452511B1 (fr)	1995-08-09	Varistor a l'oxyde de zinc, production de ce composant et verre cristallise pour revetement
US4436650A (en)	1984-03-13	Low voltage ceramic varistor
CA1186806A (fr)	1985-05-07	Varistance metal-oxyde a capacite et tension de claquage controlables
US4460623A (en)	1984-07-17	Method of varistor capacitance reduction by boron diffusion
EP0358323A1 (fr)	1990-03-14	Résistances non linéaires dépendant de la tension
EP0603565B1 (fr)	1999-05-12	Varistance en forme de puce et sa méthode de fabrication
JPH04568B2 (fr)	1992-01-08
JP2830322B2 (ja)	1998-12-02	電圧依存性非直線抵抗体磁器組成物およびバリスタの製造方法
JP2789714B2 (ja)	1998-08-20	電圧依存性非直線抵抗体磁器組成物およびバリスタの製造方法
JP2727693B2 (ja)	1998-03-11	電圧依存性非直線抵抗体磁器組成物およびバリスタの製造方法
JPS5912002B2 (ja)	1984-03-19	電圧非直線抵抗器とその製造方法
JP2822612B2 (ja)	1998-11-11	バリスタの製造方法
JPS6236611B2 (fr)	1987-08-07
Levinson	2004	ZnO varistor technology
JPS6348802A (ja)	1988-03-01	電圧依存性非直線抵抗体磁器組成物
JPH038766A (ja)	1991-01-16	電圧依存性非直線抵抗体磁器組成物およびバリスタの製造方法
JPS634681B2 (fr)	1988-01-30
JPH021835Y2 (fr)	1990-01-17
Levinson	2018	Schenectady, New York, U. SA
JPS6236615B2 (fr)	1987-08-07
JPS5910042B2 (ja)	1984-03-06	電圧非直線抵抗器
JPH0682562B2 (ja)	1994-10-19	電圧依存性非直線抵抗体磁器組成物