CA1196876A - Hydrogenation de la houille par hydrolise acide et precipitation des asphaltenes - Google Patents

Hydrogenation de la houille par hydrolise acide et precipitation des asphaltenes

Info

Publication number: CA1196876A
Authority: CA; Canada
Prior art keywords: coal; liquid; acid; solids; withdrawing
Prior art date: 1981-12-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000418607A

Other languages

English (en)

Inventor

Paul H. Kydd

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

HRI Inc

Original Assignee

HRI Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-12-28

Filing date

1982-12-24

Publication date

1985-11-19

1982-12-24 Application filed by HRI Inc filed Critical HRI Inc

1985-11-19 Application granted granted Critical

1985-11-19 Publication of CA1196876A publication Critical patent/CA1196876A/fr

Status Expired legal-status Critical Current

Links

239000003245 coal Substances 0.000 title claims abstract description 68
238000005984 hydrogenation reaction Methods 0.000 title claims abstract description 18
238000003916 acid precipitation Methods 0.000 title claims abstract description 14
238000005903 acid hydrolysis reaction Methods 0.000 title 1
239000007788 liquid Substances 0.000 claims abstract description 62
238000000034 method Methods 0.000 claims abstract description 29
229930195733 hydrocarbon Natural products 0.000 claims abstract description 22
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 22
239000000463 material Substances 0.000 claims abstract description 22
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 21
239000003921 oil Substances 0.000 claims abstract description 21
238000001556 precipitation Methods 0.000 claims abstract description 16
239000007787 solid Substances 0.000 claims description 36
239000002253 acid Substances 0.000 claims description 31
229910052739 hydrogen Inorganic materials 0.000 claims description 15
239000001257 hydrogen Substances 0.000 claims description 15
239000000047 product Substances 0.000 claims description 15
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 14
239000002002 slurry Substances 0.000 claims description 12
239000007789 gas Substances 0.000 claims description 9
239000012263 liquid product Substances 0.000 claims description 9
238000006243 chemical reaction Methods 0.000 claims description 8
239000010742 number 1 fuel oil Substances 0.000 claims description 6
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 5
WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 claims description 5
229910052717 sulfur Inorganic materials 0.000 claims description 5
239000011593 sulfur Substances 0.000 claims description 5
230000001376 precipitating effect Effects 0.000 claims description 3
238000009903 catalytic hydrogenation reaction Methods 0.000 claims 2
238000004064 recycling Methods 0.000 claims 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 1
238000005191 phase separation Methods 0.000 claims 1
235000011007 phosphoric acid Nutrition 0.000 claims 1
235000011149 sulphuric acid Nutrition 0.000 claims 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 6
150000007522 mineralic acids Chemical class 0.000 abstract description 5
238000006555 catalytic reaction Methods 0.000 abstract description 2
239000000295 fuel oil Substances 0.000 abstract 1
239000003054 catalyst Substances 0.000 description 13
239000002245 particle Substances 0.000 description 10
238000000926 separation method Methods 0.000 description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical class N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
239000002904 solvent Substances 0.000 description 8
239000000446 fuel Substances 0.000 description 5
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
241000196324 Embryophyta Species 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
239000002585 base Substances 0.000 description 3
238000009835 boiling Methods 0.000 description 3
238000002156 mixing Methods 0.000 description 3
239000002244 precipitate Substances 0.000 description 3
239000012716 precipitator Substances 0.000 description 3
229910015900 BF3 Inorganic materials 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
239000012296 anti-solvent Substances 0.000 description 2
239000011280 coal tar Substances 0.000 description 2
238000002309 gasification Methods 0.000 description 2
-1 hydrochloric acid Chemical class 0.000 description 2
239000000203 mixture Substances 0.000 description 2
238000007670 refining Methods 0.000 description 2
230000000717 retained effect Effects 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
239000006228 supernatant Substances 0.000 description 2
238000009834 vaporization Methods 0.000 description 2
230000008016 vaporization Effects 0.000 description 2
239000007848 Bronsted acid Substances 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
239000002841 Lewis acid Substances 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
240000004064 Poterium sanguisorba Species 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
238000013019 agitation Methods 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
239000002802 bituminous coal Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
238000005345 coagulation Methods 0.000 description 1
230000015271 coagulation Effects 0.000 description 1
150000001868 cobalt Chemical class 0.000 description 1
238000004939 coking Methods 0.000 description 1
239000000470 constituent Substances 0.000 description 1
230000006378 damage Effects 0.000 description 1
239000002283 diesel fuel Substances 0.000 description 1
238000004821 distillation Methods 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000005194 fractionation Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
150000007517 lewis acids Chemical class 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
239000003209 petroleum derivative Substances 0.000 description 1
238000005504 petroleum refining Methods 0.000 description 1
150000007965 phenolic acids Chemical class 0.000 description 1
235000009048 phenolic acids Nutrition 0.000 description 1
230000002028 premature Effects 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000005086 pumping Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
238000011084 recovery Methods 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
239000013049 sediment Substances 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000010802 sludge Substances 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
239000011135 tin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/04—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
- C10G1/045—Separation of insoluble materials

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Life Sciences & Earth Sciences (AREA)
Wood Science & Technology (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

CA000418607A 1981-12-28 1982-12-24 Hydrogenation de la houille par hydrolise acide et precipitation des asphaltenes Expired CA1196876A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US33513981A	1981-12-28	1981-12-28
US335,139		1981-12-28

Publications (1)

Publication Number	Publication Date
CA1196876A true CA1196876A (fr)	1985-11-19

Family

ID=23310438

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000418607A Expired CA1196876A (fr)	1981-12-28	1982-12-24	Hydrogenation de la houille par hydrolise acide et precipitation des asphaltenes

Country Status (6)

Country	Link
JP (1)	JPS58118890A (fr)
AU (1)	AU9183482A (fr)
CA (1)	CA1196876A (fr)
DE (1)	DE3247924A1 (fr)
GB (1)	GB2112806A (fr)
ZA (1)	ZA829488B (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0676585B2 (ja) *	1982-12-28	1994-09-28	三菱化成株式会社	溶剤精製炭の水素化方法
ZA841630B (en) *	1983-03-07	1984-10-31	Hri Inc	Hydrogenation of undissolved coal and subsequent liquefaction of hydrogenated coal
JPH0730340B2 (ja) *	1983-05-16	1995-04-05	三菱化学株式会社	石炭の油留分への転化方法
JPS6051784A (ja) *	1983-08-30	1985-03-23	Kobe Steel Ltd	褐炭の液化方法
JPH0299595A (ja) *	1988-10-06	1990-04-11	Nippon Katsutan Ekika Kk	石炭の液化方法

1982
- 1982-12-23 AU AU91834/82A patent/AU9183482A/en not_active Abandoned
- 1982-12-23 GB GB08236588A patent/GB2112806A/en not_active Withdrawn
- 1982-12-24 CA CA000418607A patent/CA1196876A/fr not_active Expired
- 1982-12-24 DE DE19823247924 patent/DE3247924A1/de not_active Withdrawn
- 1982-12-27 ZA ZA829488A patent/ZA829488B/xx unknown
- 1982-12-28 JP JP57235153A patent/JPS58118890A/ja active Pending

Also Published As

Publication number	Publication date
DE3247924A1 (de)	1983-07-07
AU9183482A (en)	1983-07-07
JPS58118890A (ja)	1983-07-15
GB2112806A (en)	1983-07-27
ZA829488B (en)	1984-03-28

Legal Events

Date	Code	Title	Description
2002-11-20	MKEC	Expiry (correction)
2002-12-24	MKEX	Expiry

Publication	Publication Date	Title
AU2005266712B2 (en)	2009-08-13	A process for direct liquefaction of coal
US4081359A (en)	1978-03-28	Process for the liquefaction of coal and separation of solids from the liquid product
EP0048098B1 (fr)	1985-03-27	Amélioration d'huile résiduelle
US4354922A (en)	1982-10-19	Processing of heavy hydrocarbon oils
US4338183A (en)	1982-07-06	Method of solvent extraction of coal by a heavy oil
EP0051345B1 (fr)	1985-12-18	Liquéfaction au solvant donneur de charbons avec recyclage des produits de queue sous pression élevée
US4473461A (en)	1984-09-25	Centrifugal drying and dedusting process
US4317711A (en)	1982-03-02	Coprocessing of residual oil and coal
US4081360A (en)	1978-03-28	Method for suppressing asphaltene formation during coal liquefaction and separation of solids from the liquid product
US4994175A (en)	1991-02-19	Syncrude dedusting extraction
US4094766A (en)	1978-06-13	Coal liquefaction product deashing process
EP0268612A1 (fr)	1988-06-01	Procede ionique integre de liquefaction
CA1196876A (fr)	1985-11-19	Hydrogenation de la houille par hydrolise acide et precipitation des asphaltenes
US4264429A (en)	1981-04-28	Two-stage coal liquefaction process with process-derived solvent
CA1238288A (fr)	1988-06-21	Traitement des sables bitumineux
CA1227151A (fr)	1987-09-22	Hydrogenation de matiere houillere a teneur de solides dans une zone de reaction thermique avec debit a contre-courant
US4032428A (en)	1977-06-28	Liquefaction of coal
CA1108544A (fr)	1981-09-08	Liquefaction de la houille
US4472263A (en)	1984-09-18	Process for solvent refining of coal using a denitrogenated and dephenolated solvent
US4457830A (en)	1984-07-03	Petroleum hydroconversion using acid precipitation of preasphaltenes in resid recycle
US4764270A (en)	1988-08-16	Simultaneous upgrading of tar sand bitumen and coal by corefining
GB2123025A (en)	1984-01-25	Solvent extraction of coal by a heavy oil
EP0121343B1 (fr)	1988-05-18	Procédé de liquéfaction ionique intégré
US4244805A (en)	1981-01-13	Liquid yield from pyrolysis of coal liquefaction products
JPH047399B2 (fr)	1992-02-10