CA1201242A - Resines de poly(oxyde de phenylene) et compositions de resines stabilisees thermiquement a l'aide de diphosphite de trineopentylene - Google Patents

Resines de poly(oxyde de phenylene) et compositions de resines stabilisees thermiquement a l'aide de diphosphite de trineopentylene

Info

Publication number: CA1201242A
Authority: CA; Canada
Prior art keywords: resin; polyphenylene ether; composition according; trineopentylene; diphosphite
Prior art date: 1981-10-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000413158A

Other languages

English (en)

Inventor

Robert J. Axelrod

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

General Electric Co

Original Assignee

General Electric Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-10-28

Filing date

1982-10-08

Publication date

1986-02-25

1982-10-08 Application filed by General Electric Co filed Critical General Electric Co

1986-02-25 Application granted granted Critical

1986-02-25 Publication of CA1201242A publication Critical patent/CA1201242A/fr

Status Expired legal-status Critical Current

Links

239000011347 resin Substances 0.000 title claims abstract description 35
229920005989 resin Polymers 0.000 title claims abstract description 35
239000000203 mixture Substances 0.000 title claims abstract description 32
229920001955 polyphenylene ether Polymers 0.000 title claims abstract description 16
ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 title claims abstract description 9
230000001590 oxidative effect Effects 0.000 claims abstract description 7
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
-1 poly(2,6-dimethyl-1,4-phenylene ether) Polymers 0.000 claims description 9
229920001971 elastomer Polymers 0.000 claims description 3
239000000945 filler Substances 0.000 claims description 3
239000003063 flame retardant Substances 0.000 claims description 3
239000004014 plasticizer Substances 0.000 claims description 3
239000005060 rubber Substances 0.000 claims description 3
239000003086 colorant Substances 0.000 claims description 2
239000004797 high-impact polystyrene Substances 0.000 claims description 2
230000002787 reinforcement Effects 0.000 claims description 2
239000000654 additive Substances 0.000 claims 1
229920001169 thermoplastic Polymers 0.000 claims 1
239000004416 thermosoftening plastic Substances 0.000 claims 1
239000003381 stabilizer Substances 0.000 abstract description 6
239000004609 Impact Modifier Substances 0.000 abstract 1
239000011342 resin composition Substances 0.000 abstract 1
229920001577 copolymer Polymers 0.000 description 7
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
GLOQRSIADGSLRX-UHFFFAOYSA-N decyl diphenyl phosphite Chemical group C=1C=CC=CC=1OP(OCCCCCCCCCC)OC1=CC=CC=C1 GLOQRSIADGSLRX-UHFFFAOYSA-N 0.000 description 6
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
239000003795 chemical substances by application Substances 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
239000005062 Polybutadiene Substances 0.000 description 3
239000004793 Polystyrene Substances 0.000 description 3
238000000034 method Methods 0.000 description 3
239000003607 modifier Substances 0.000 description 3
238000000465 moulding Methods 0.000 description 3
SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 3
239000008188 pellet Substances 0.000 description 3
230000000704 physical effect Effects 0.000 description 3
229920002857 polybutadiene Polymers 0.000 description 3
229920002223 polystyrene Polymers 0.000 description 3
239000004408 titanium dioxide Substances 0.000 description 3
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
229920001400 block copolymer Polymers 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
125000004122 cyclic group Chemical group 0.000 description 2
150000001993 dienes Chemical class 0.000 description 2
125000005843 halogen group Chemical group 0.000 description 2
229920001519 homopolymer Polymers 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
238000002347 injection Methods 0.000 description 2
239000007924 injection Substances 0.000 description 2
239000000178 monomer Substances 0.000 description 2
229920003052 natural elastomer Polymers 0.000 description 2
229920001194 natural rubber Polymers 0.000 description 2
150000002989 phenols Chemical class 0.000 description 2
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 2
239000000049 pigment Substances 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
230000000576 supplementary effect Effects 0.000 description 2
239000012815 thermoplastic material Substances 0.000 description 2
WAEOXIOXMKNFLQ-UHFFFAOYSA-N 1-methyl-4-prop-2-enylbenzene Chemical group CC1=CC=C(CC=C)C=C1 WAEOXIOXMKNFLQ-UHFFFAOYSA-N 0.000 description 1
IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
229920000178 Acrylic resin Polymers 0.000 description 1
239000004925 Acrylic resin Substances 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
229920002943 EPDM rubber Polymers 0.000 description 1
BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
244000043261 Hevea brasiliensis Species 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
229920000147 Styrene maleic anhydride Polymers 0.000 description 1
239000005083 Zinc sulfide Substances 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
230000002411 adverse Effects 0.000 description 1
230000032683 aging Effects 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
229920005549 butyl rubber Polymers 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
150000001721 carbon Chemical group 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
239000000306 component Substances 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
239000000975 dye Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000000835 fiber Substances 0.000 description 1
239000003365 glass fiber Substances 0.000 description 1
239000010439 graphite Substances 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
229920005669 high impact polystyrene Polymers 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
239000012764 mineral filler Substances 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229920001596 poly (chlorostyrenes) Polymers 0.000 description 1
229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
239000005077 polysulfide Substances 0.000 description 1
229920001021 polysulfide Polymers 0.000 description 1
150000008117 polysulfides Polymers 0.000 description 1
229920003225 polyurethane elastomer Polymers 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
238000005728 strengthening Methods 0.000 description 1
229920003048 styrene butadiene rubber Polymers 0.000 description 1
239000000126 substance Substances 0.000 description 1
229920003051 synthetic elastomer Polymers 0.000 description 1
239000005061 synthetic rubber Substances 0.000 description 1
229920001897 terpolymer Polymers 0.000 description 1
229920002725 thermoplastic elastomer Polymers 0.000 description 1
238000009757 thermoplastic moulding Methods 0.000 description 1
LIPMRGQQBZJCTM-UHFFFAOYSA-N tris(2-propan-2-ylphenyl) phosphate Chemical compound CC(C)C1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C(C)C)OC1=CC=CC=C1C(C)C LIPMRGQQBZJCTM-UHFFFAOYSA-N 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1
229910052984 zinc sulfide Inorganic materials 0.000 description 1
DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)

CA000413158A 1981-10-28 1982-10-08 Resines de poly(oxyde de phenylene) et compositions de resines stabilisees thermiquement a l'aide de diphosphite de trineopentylene Expired CA1201242A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US31589281A	1981-10-28	1981-10-28
US315,892		1994-09-30

Publications (1)

Publication Number	Publication Date
CA1201242A true CA1201242A (fr)	1986-02-25

Family

ID=23226517

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000413158A Expired CA1201242A (fr)	1981-10-28	1982-10-08	Resines de poly(oxyde de phenylene) et compositions de resines stabilisees thermiquement a l'aide de diphosphite de trineopentylene

Country Status (3)

Country	Link
JP (1)	JPS58101151A (fr)
CA (1)	CA1201242A (fr)
DE (1)	DE3238790A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE102004031471A1 (de)	2004-06-30	2006-01-26	Zf Friedrichshafen Ag	Ölversorgungseinrichtung
DE102004031470A1 (de)	2004-06-30	2006-01-26	Zf Friedrichshafen Ag	Ölversorgungseinrichtung

1982
- 1982-10-08 CA CA000413158A patent/CA1201242A/fr not_active Expired
- 1982-10-20 DE DE19823238790 patent/DE3238790A1/de not_active Withdrawn
- 1982-10-27 JP JP18764582A patent/JPS58101151A/ja active Pending

Also Published As

Publication number	Publication date
DE3238790A1 (de)	1983-05-05
JPS58101151A (ja)	1983-06-16

Legal Events

Date	Code	Title	Description
2003-02-25	MKEX	Expiry

Publication	Publication Date	Title
US4154712A (en)	1979-05-15	Low molecular weight polyphenylene ether compositions
US3639506A (en)	1972-02-01	Flame retardant composition of polyphenylene ether styrene resin aromatic phosphate and aromatic halogen compound
US3960808A (en)	1976-06-01	Polyphenylene ether composition
GB2043083A (en)	1980-10-01	Flame retardant polyphenylene ether compositions
US3663654A (en)	1972-05-16	Flame retardant composition of polyphenylene ether,styrene resin and phosphorus
US5081185A (en)	1992-01-14	Polyphenylene ether composition characterized by improved melt flow
US4405739A (en)	1983-09-20	Polyphenylene ether resins and compositions heat stabilized with phosphite compounds
EP0090523B1 (fr)	1987-01-07	Compositions de PPE comprenant un polymère d'éthylène ayant des groupes carbonyles et hydroxyles
US3887646A (en)	1975-06-03	Resinous compositions containing polyphenylene ether, styrene rubber and rubber-modified chlorostyrene polymer
US4835201A (en)	1989-05-30	Compositions of polyphenylene ether resin and high impact polystyrene resin having improved ultraviolet light resistance
JPH068371B2 (ja)	1994-02-02	難燃性樹脂組成物
JPS619450A (ja)	1986-01-17	難燃性樹脂組成物
US4442251A (en)	1984-04-10	Impact resistant polyphenylene ether resin compositions
US4483953A (en)	1984-11-20	Polyphenylene ether resins and compositions heat stabilized with trineopentylene diphosphite
CA1201242A (fr)	1986-02-25	Resines de poly(oxyde de phenylene) et compositions de resines stabilisees thermiquement a l'aide de diphosphite de trineopentylene
EP0146878A2 (fr)	1985-07-03	Compositions de résines de polyéther de phénylène et de résines de polystyrène à haute résistance au choc à stabilité améliorée à la lumière ultraviolette
GB1575457A (en)	1980-09-24	Polyphenylene ether compositions
EP0149454B1 (fr)	1988-12-21	Compositions de résines de poly(éther de phénylène) et de résines de polystyrène à haute résistance au choc ayant une stabilité contre la lumière ultraviolette améliorée
EP0085834B1 (fr)	1987-04-29	Agent d'ignifugation inhibitant la décoloration comprenant un stable composé organique halogéné et un composé de bore
US4584332A (en)	1986-04-22	Flame retardant polyphenylene oxide thermoplastics
CA1269787A (fr)	1990-05-29	Melanges de resine de poly(oxyphenylene) offrant une meilleure stabilite a la lumiere ultra-violette
US4154719A (en)	1979-05-15	Stabilized polyphenylene ether resin compositions containing hindered tris-phenols
US4423176A (en)	1983-12-27	Molding compositions comprising polyphenylene ether, polysulfone and vinyl aromatic-diene block copolymer
US4593058A (en)	1986-06-03	Flame retardant polyphenylene oxide thermoplastics
EP0719832A2 (fr)	1996-07-03	Compositions thermoplastiques contenant des résines polyéther de phénylène et polyoléfines