CA1221797A - Composition a proprietes optiques perfectionnees - Google Patents

Composition a proprietes optiques perfectionnees

Info

Publication number: CA1221797A
Authority: CA; Canada
Prior art keywords: composition; acrylate; weight; highly fluorinated; synergist
Prior art date: 1984-01-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000472370A

Other languages

English (en)

Inventor

Bolesh J. Skutnik

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Ensign Bickford Optics Co

Original Assignee

Ensign Bickford Optics Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-01-20

Filing date

1985-01-18

Publication date

1987-05-12

1984-01-20 Priority claimed from US06/572,397 external-priority patent/US4511209A/en

1985-01-18 Application filed by Ensign Bickford Optics Co filed Critical Ensign Bickford Optics Co

1987-05-12 Application granted granted Critical

1987-05-12 Publication of CA1221797A publication Critical patent/CA1221797A/fr

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 82
230000003287 optical effect Effects 0.000 title claims abstract description 19
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 36
239000003431 cross linking reagent Substances 0.000 claims abstract description 8
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 22
239000013307 optical fiber Substances 0.000 claims description 19
239000000758 substrate Substances 0.000 claims description 15
150000003573 thiols Chemical class 0.000 claims description 9
DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical group C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 4
229940096522 trimethylolpropane triacrylate Drugs 0.000 claims description 4
230000003247 decreasing effect Effects 0.000 claims description 3
QJEJDNMGOWJONG-UHFFFAOYSA-N 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyl prop-2-enoate Chemical group FC(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)COC(=O)C=C QJEJDNMGOWJONG-UHFFFAOYSA-N 0.000 claims 1
ZYMKZMDQUPCXRP-UHFFFAOYSA-N fluoro prop-2-enoate Chemical compound FOC(=O)C=C ZYMKZMDQUPCXRP-UHFFFAOYSA-N 0.000 abstract description 14
239000003999 initiator Substances 0.000 abstract description 9
239000002904 solvent Substances 0.000 abstract description 6
239000007787 solid Substances 0.000 abstract description 4
150000001252 acrylic acid derivatives Chemical class 0.000 abstract description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 abstract 3
PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 abstract 1
125000003396 thiol group Chemical class [H]S* 0.000 abstract 1
239000000835 fiber Substances 0.000 description 36
238000005253 cladding Methods 0.000 description 26
239000011162 core material Substances 0.000 description 23
238000000576 coating method Methods 0.000 description 19
229920001296 polysiloxane Polymers 0.000 description 15
239000011521 glass Chemical group 0.000 description 12
239000000463 material Substances 0.000 description 11
150000001875 compounds Chemical class 0.000 description 8
239000010453 quartz Substances 0.000 description 8
239000011248 coating agent Substances 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
230000008901 benefit Effects 0.000 description 4
239000008199 coating composition Substances 0.000 description 4
239000005350 fused silica glass Substances 0.000 description 4
239000000178 monomer Substances 0.000 description 4
239000000126 substance Substances 0.000 description 4
238000005382 thermal cycling Methods 0.000 description 4
235000018936 Vitellaria paradoxa Nutrition 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
239000004033 plastic Substances 0.000 description 3
229920003023 plastic Polymers 0.000 description 3
229920005989 resin Polymers 0.000 description 3
239000011347 resin Substances 0.000 description 3
238000012360 testing method Methods 0.000 description 3
JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
230000005540 biological transmission Effects 0.000 description 2
239000004744 fabric Substances 0.000 description 2
-1 fluorinated acrylate compound Chemical class 0.000 description 2
238000005259 measurement Methods 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
229920002050 silicone resin Polymers 0.000 description 2
229920001169 thermoplastic Polymers 0.000 description 2
239000004416 thermosoftening plastic Substances 0.000 description 2
CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 1
SZNYYWIUQFZLLT-UHFFFAOYSA-N 2-methyl-1-(2-methylpropoxy)propane Chemical class CC(C)COCC(C)C SZNYYWIUQFZLLT-UHFFFAOYSA-N 0.000 description 1
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Natural products CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 1
208000037062 Polyps Diseases 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000009471 action Effects 0.000 description 1
230000006978 adaptation Effects 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
239000006117 anti-reflective coating Substances 0.000 description 1
230000003667 anti-reflective effect Effects 0.000 description 1
238000003491 array Methods 0.000 description 1
238000010420 art technique Methods 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
238000005452 bending Methods 0.000 description 1
230000008859 change Effects 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000011109 contamination Methods 0.000 description 1
230000008602 contraction Effects 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000000280 densification Methods 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
238000003618 dip coating Methods 0.000 description 1
230000009977 dual effect Effects 0.000 description 1
239000000428 dust Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000012530 fluid Substances 0.000 description 1
229920002313 fluoropolymer Polymers 0.000 description 1
239000003365 glass fiber Substances 0.000 description 1
230000009477 glass transition Effects 0.000 description 1
239000004519 grease Substances 0.000 description 1
125000005842 heteroatom Chemical group 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
KWUZCAVKPCRJPO-UHFFFAOYSA-N n-ethyl-4-(6-methyl-1,3-benzothiazol-2-yl)aniline Chemical compound C1=CC(NCC)=CC=C1C1=NC2=CC=C(C)C=C2S1 KWUZCAVKPCRJPO-UHFFFAOYSA-N 0.000 description 1
239000003921 oil Substances 0.000 description 1
230000035515 penetration Effects 0.000 description 1
230000035699 permeability Effects 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
239000002243 precursor Substances 0.000 description 1
238000012545 processing Methods 0.000 description 1
KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
150000003151 propanoic acid esters Chemical class 0.000 description 1
239000011253 protective coating Substances 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
238000005086 pumping Methods 0.000 description 1
230000005855 radiation Effects 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
239000004753 textile Substances 0.000 description 1
230000000699 topical effect Effects 0.000 description 1
238000011282 treatment Methods 0.000 description 1
150000003673 urethanes Chemical class 0.000 description 1

Landscapes

Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
Surface Treatment Of Glass Fibres Or Filaments (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

CA000472370A 1984-01-20 1985-01-18 Composition a proprietes optiques perfectionnees Expired CA1221797A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US572,397		1984-01-20
US06/572,397 US4511209A (en)	1982-02-24	1984-01-20	Composition having improved optical qualities

Publications (1)

Publication Number	Publication Date
CA1221797A true CA1221797A (fr)	1987-05-12

Family

ID=24287626

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000472370A Expired CA1221797A (fr)	1984-01-20	1985-01-18	Composition a proprietes optiques perfectionnees

Country Status (1)

Country	Link
CA (1)	CA1221797A (fr)

1985
- 1985-01-18 CA CA000472370A patent/CA1221797A/fr not_active Expired

Legal Events

Date	Code	Title	Description
2005-01-18	MKEX	Expiry

Publication	Publication Date	Title
CA1221795A (fr)	1987-05-12	Gainage des fibres optiques
EP0600985B1 (fr)	1997-01-15	Fibres optiques plaquees a forte ouverture numerique et a faibles pertes
CA1133293A (fr)	1982-10-12	Fibres de verre pour communication optique
US4324575A (en)	1982-04-13	Low TG soft UV-curable coatings
US5922787A (en)	1999-07-13	Composition for forming antifouling antifouling film, optical component, and display device
JPH01133011A (ja)	1989-05-25	合成樹脂コーティングを備えた光ファイバ及びその製造方法
EP0425305B1 (fr)	1994-12-28	Composition de revêtement durcissable par radiation
EP0333464A1 (fr)	1989-09-20	Revêtements polymères pour guides d'ondes à fibre optique
CN1047394A (zh)	1990-11-28	有涂层的光传输媒质
JPH10160947A (ja)	1998-06-19	広帯域プラスチッククラッド光ファイバ
CA1317063C (fr)	1993-04-27	Revetement plastique pour fibres optiques a ame de plastique; la fibre optique ainsi obtenue
WO1998039389A1 (fr)	1998-09-11	Composition de revetement a indice de refraction reglable
CA1221797A (fr)	1987-05-12	Composition a proprietes optiques perfectionnees
GB2026716A (en)	1980-02-06	A Glass Optical Fiber Coated with Organopolysiloxane Layers
US5298291A (en)	1994-03-29	Epoxy-functional fluoropolyol polyacrylate coating of optical fibers
JPH07115892B2 (ja)	1995-12-13	光フアイバ−用紫外線硬化性樹脂組成物
CN109021816B (zh)	2021-05-04	一种紫外光固化光纤外涂层涂料及制备方法
JPS6370210A (ja)	1988-03-30	被覆光フアイバ
US5212762A (en)	1993-05-18	Plastic-clad silica (PCS) fibers and methods and apparatuses for producing the same
EP0257863A1 (fr)	1988-03-02	Composition de matière plastique de revêtement pour fibre optique à coeur de verre ou de silice, et fibre optique à coeur de verre ou de silice ainsi préparée
KR0142676B1 (ko)	1998-07-15	광 섬유 도파관용 중합체 피복 조성물
CA2056177C (fr)	1997-03-25	Fibres de silice avec revetement de polymere (pcs); methodes et appareils pour les fabriquer
US20040218864A1 (en)	2004-11-04	Light-pipe arrangement with reduced fresnel-reflection losses
RU2029748C1 (ru)	1995-02-27	Способ получения волоконно-оптических световодов
Lawson et al.	1980	Optical Fiber Buffer Coatings Cured With Ultraviolet Light