CA1240231A - Pellicules de poly(alcool vinylique) solubles dans une solution de borate - Google Patents

Pellicules de poly(alcool vinylique) solubles dans une solution de borate

Info

Publication number: CA1240231A
Authority: CA; Canada
Prior art keywords: acid; polyvinyl alcohol; film; molecular weight; laundry
Prior art date: 1981-11-10
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000536542A

Other languages

English (en)

Inventor

Edward J. Kaufmann

Barry A. Sudbury

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Clorox Co

Original Assignee

Clorox Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-11-10

Filing date

1987-05-06

Publication date

1988-08-09

1982-10-28 Priority claimed from CA000414399A external-priority patent/CA1230795A/fr

1987-05-06 Application filed by Clorox Co filed Critical Clorox Co

1987-05-06 Priority to CA000536542A priority Critical patent/CA1240231A/fr

1988-08-09 Application granted granted Critical

1988-08-09 Publication of CA1240231A publication Critical patent/CA1240231A/fr

Status Expired legal-status Critical Current

Links

239000004372 Polyvinyl alcohol Substances 0.000 title claims abstract description 68
229920002451 polyvinyl alcohol Polymers 0.000 title claims abstract description 68
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 title claims abstract description 30
239000002253 acid Substances 0.000 claims abstract description 30
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
239000000203 mixture Substances 0.000 claims abstract description 14
238000010494 dissociation reaction Methods 0.000 claims abstract description 4
230000005593 dissociations Effects 0.000 claims abstract description 4
150000001875 compounds Chemical class 0.000 claims description 23
239000000654 additive Substances 0.000 claims description 22
238000000034 method Methods 0.000 claims description 20
230000000996 additive effect Effects 0.000 claims description 17
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 9
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
239000004014 plasticizer Substances 0.000 claims description 9
229920000642 polymer Polymers 0.000 claims description 9
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 6
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 6
229920002125 Sokalan® Polymers 0.000 claims description 5
239000004584 polyacrylic acid Substances 0.000 claims description 4
239000002904 solvent Substances 0.000 claims description 4
239000005711 Benzoic acid Substances 0.000 claims description 3
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 3
WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 3
KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 3
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
239000001361 adipic acid Substances 0.000 claims description 3
235000011037 adipic acid Nutrition 0.000 claims description 3
235000010233 benzoic acid Nutrition 0.000 claims description 3
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 3
235000013922 glutamic acid Nutrition 0.000 claims description 3
239000004220 glutamic acid Substances 0.000 claims description 3
229910000403 monosodium phosphate Inorganic materials 0.000 claims description 3
235000019799 monosodium phosphate Nutrition 0.000 claims description 3
235000006408 oxalic acid Nutrition 0.000 claims description 3
IWZKICVEHNUQTL-UHFFFAOYSA-M potassium hydrogen phthalate Chemical compound [K+].OC(=O)C1=CC=CC=C1C([O-])=O IWZKICVEHNUQTL-UHFFFAOYSA-M 0.000 claims description 3
AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 3
239000011975 tartaric acid Substances 0.000 claims description 3
235000002906 tartaric acid Nutrition 0.000 claims description 3
XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 claims 2
235000018417 cysteine Nutrition 0.000 claims 2
XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 claims 2
239000000243 solution Substances 0.000 description 23
238000012360 testing method Methods 0.000 description 11
239000011347 resin Substances 0.000 description 10
229920005989 resin Polymers 0.000 description 10
239000002202 Polyethylene glycol Substances 0.000 description 7
229920001223 polyethylene glycol Polymers 0.000 description 7
239000011521 glass Substances 0.000 description 6
150000007513 acids Chemical class 0.000 description 5
238000002156 mixing Methods 0.000 description 5
239000000470 constituent Substances 0.000 description 4
238000011156 evaluation Methods 0.000 description 4
238000005406 washing Methods 0.000 description 4
229930091371 Fructose Natural products 0.000 description 3
239000005715 Fructose Substances 0.000 description 3
RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 3
229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
-1 borate ions Chemical class 0.000 description 3
239000003599 detergent Substances 0.000 description 3
239000006185 dispersion Substances 0.000 description 3
239000012153 distilled water Substances 0.000 description 3
230000007062 hydrolysis Effects 0.000 description 3
238000006460 hydrolysis reaction Methods 0.000 description 3
239000000463 material Substances 0.000 description 3
229920000609 methyl cellulose Polymers 0.000 description 3
239000001923 methylcellulose Substances 0.000 description 3
235000010981 methylcellulose Nutrition 0.000 description 3
IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
208000037062 Polyps Diseases 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
238000013019 agitation Methods 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
229910021538 borax Inorganic materials 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
239000004328 sodium tetraborate Substances 0.000 description 2
235000010339 sodium tetraborate Nutrition 0.000 description 2
230000000007 visual effect Effects 0.000 description 2
241001507939 Cormus domestica Species 0.000 description 1
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
UNXHWFMMPAWVPI-QWWZWVQMSA-N D-Threitol Natural products OC[C@@H](O)[C@H](O)CO UNXHWFMMPAWVPI-QWWZWVQMSA-N 0.000 description 1
UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
238000004061 bleaching Methods 0.000 description 1
239000002981 blocking agent Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
239000004744 fabric Substances 0.000 description 1
239000002979 fabric softener Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
238000004900 laundering Methods 0.000 description 1
238000002386 leaching Methods 0.000 description 1
238000003760 magnetic stirring Methods 0.000 description 1
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
239000011118 polyvinyl acetate Substances 0.000 description 1
238000009877 rendering Methods 0.000 description 1
239000002002 slurry Substances 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1

Landscapes

Detergent Compositions (AREA)
Manufacture Of Macromolecular Shaped Articles (AREA)

CA000536542A 1981-11-10 1987-05-06 Pellicules de poly(alcool vinylique) solubles dans une solution de borate Expired CA1240231A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000536542A CA1240231A (fr)	1981-11-10	1987-05-06	Pellicules de poly(alcool vinylique) solubles dans une solution de borate

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US31996681A	1981-11-10	1981-11-10
US319,966		1981-11-10
CA000414399A CA1230795A (fr)	1981-11-10	1982-10-28	Films d'alcool polyvinylique solubles dans une solution de borate
CA000536542A CA1240231A (fr)	1981-11-10	1987-05-06	Pellicules de poly(alcool vinylique) solubles dans une solution de borate

Related Parent Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000414399A Division CA1230795A (fr)	1981-11-10	1982-10-28	Films d'alcool polyvinylique solubles dans une solution de borate

Publications (1)

Publication Number	Publication Date
CA1240231A true CA1240231A (fr)	1988-08-09

Family

ID=25669847

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000536542A Expired CA1240231A (fr)	1981-11-10	1987-05-06	Pellicules de poly(alcool vinylique) solubles dans une solution de borate

Country Status (1)

Country	Link
CA (1)	CA1240231A (fr)

1987
- 1987-05-06 CA CA000536542A patent/CA1240231A/fr not_active Expired

Legal Events

Date	Code	Title	Description
2005-08-09	MKEX	Expiry

Publication	Publication Date	Title
CA1230795A (fr)	1987-12-29	Films d'alcool polyvinylique solubles dans une solution de borate
US4626372A (en)	1986-12-02	Borate solution soluble polyvinyl alcohol films
US4828744A (en)	1989-05-09	Borate solution soluble polyvinyl alcohol films
US4608187A (en)	1986-08-26	Rubber toughened polyvinyl alcohol film compositions
US4972017A (en)	1990-11-20	Rinse soluble polymer film composition for wash additives
US5102950A (en)	1992-04-07	Water soluble film
JP6246891B2 (ja)	2017-12-13	遅延放出用の水溶性フィルム
US4801636A (en)	1989-01-31	Rinse soluble polymer film composition for wash additives
JPS5854921A (ja)	1983-04-01	拭材
EP3587547B1 (fr)	2023-06-07	Conditionnements de dose unique de détergents à lessive contenant du ricinoléate de zinc et de l'iminodisuccinate de sodium
JPS60262899A (ja)	1985-12-26	織物柔軟仕上げ用ビルダー入り洗浄剤組成物
US4273661A (en)	1981-06-16	Article for dispensing liquid bleach softener composition
CA1240231A (fr)	1988-08-09	Pellicules de poly(alcool vinylique) solubles dans une solution de borate
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