CA1269472A - Melange de poly(terephtalate d'alcoylene) et de polyester totalement aromatique et de masse moleculaire elevee; methode de preparation - Google Patents

Melange de poly(terephtalate d'alcoylene) et de polyester totalement aromatique et de masse moleculaire elevee; methode de preparation

Info

Publication number: CA1269472A
Authority: CA; Canada
Prior art keywords: approximately; wholly aromatic; aromatic polyester; percent; blend
Prior art date: 1984-03-05
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000448882A

Other languages

English (en)

Inventor

Frank M. Berardinelli

David E. Cincotta

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Celanese Corp

Original Assignee

Celanese Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-03-05

Filing date

1984-03-05

Publication date

1990-05-22

1984-03-05 Application filed by Celanese Corp filed Critical Celanese Corp

1984-03-05 Priority to CA000448882A priority Critical patent/CA1269472A/fr

1990-05-22 Application granted granted Critical

1990-05-22 Publication of CA1269472A publication Critical patent/CA1269472A/fr

2007-05-22 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

125000003118 aryl group Chemical group 0.000 title claims abstract description 175
229920000728 polyester Polymers 0.000 title claims abstract description 175
239000000203 mixture Substances 0.000 title claims abstract description 174
238000000034 method Methods 0.000 title claims abstract description 82
230000008569 process Effects 0.000 title claims abstract description 64
229920001283 Polyalkylene terephthalate Polymers 0.000 title claims abstract description 39
229920002959 polymer blend Polymers 0.000 claims abstract description 45
238000006116 polymerization reaction Methods 0.000 claims abstract description 45
-1 polyethylene terephthalate Polymers 0.000 claims abstract description 39
239000000155 melt Substances 0.000 claims abstract description 27
239000005020 polyethylene terephthalate Substances 0.000 claims abstract description 18
238000002156 mixing Methods 0.000 claims abstract description 17
229920000139 polyethylene terephthalate Polymers 0.000 claims abstract description 15
230000001747 exhibiting effect Effects 0.000 claims abstract description 9
239000012071 phase Substances 0.000 claims description 50
125000004432 carbon atom Chemical group C* 0.000 claims description 30
238000006467 substitution reaction Methods 0.000 claims description 26
239000007787 solid Substances 0.000 claims description 16
XBNGYFFABRKICK-UHFFFAOYSA-N 2,3,4,5,6-pentafluorophenol Chemical compound OC1=C(F)C(F)=C(F)C(F)=C1F XBNGYFFABRKICK-UHFFFAOYSA-N 0.000 claims description 15
IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachloro-phenol Natural products OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 claims description 15
239000000835 fiber Substances 0.000 claims description 14
150000001875 compounds Chemical class 0.000 claims description 12
229910052736 halogen Inorganic materials 0.000 claims description 12
150000002367 halogens Chemical class 0.000 claims description 12
238000000465 moulding Methods 0.000 claims description 12
125000003545 alkoxy group Chemical group 0.000 claims description 11
125000000217 alkyl group Chemical group 0.000 claims description 11
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 11
125000002947 alkylene group Chemical group 0.000 claims description 7
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 7
239000012298 atmosphere Substances 0.000 claims description 6
239000000945 filler Substances 0.000 claims description 6
238000001125 extrusion Methods 0.000 claims description 5
230000001590 oxidative effect Effects 0.000 claims description 3
239000012744 reinforcing agent Substances 0.000 claims description 3
239000007790 solid phase Substances 0.000 claims 2
239000004698 Polyethylene Substances 0.000 claims 1
229920000573 polyethylene Polymers 0.000 claims 1
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 abstract description 14
229920001281 polyalkylene Polymers 0.000 abstract description 7
229920000642 polymer Polymers 0.000 description 31
239000000306 component Substances 0.000 description 27
239000000463 material Substances 0.000 description 12
230000000052 comparative effect Effects 0.000 description 11
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 7
238000010128 melt processing Methods 0.000 description 7
239000000178 monomer Substances 0.000 description 7
229920001707 polybutylene terephthalate Polymers 0.000 description 7
238000002360 preparation method Methods 0.000 description 7
238000001746 injection moulding Methods 0.000 description 6
238000002844 melting Methods 0.000 description 6
230000008018 melting Effects 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 5
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
238000010438 heat treatment Methods 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
239000008188 pellet Substances 0.000 description 3
239000006069 physical mixture Substances 0.000 description 3
239000000376 reactant Substances 0.000 description 3
239000002002 slurry Substances 0.000 description 3
125000001424 substituent group Chemical group 0.000 description 3
FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
229920000049 Carbon (fiber) Polymers 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
229920013683 Celanese Polymers 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
229920001400 block copolymer Polymers 0.000 description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
229910052794 bromium Inorganic materials 0.000 description 2
239000004917 carbon fiber Substances 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
238000009833 condensation Methods 0.000 description 2
230000005494 condensation Effects 0.000 description 2
238000000354 decomposition reaction Methods 0.000 description 2
230000000994 depressogenic effect Effects 0.000 description 2
238000009826 distribution Methods 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
229910052734 helium Inorganic materials 0.000 description 2
239000001307 helium Substances 0.000 description 2
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
238000002347 injection Methods 0.000 description 2
239000007924 injection Substances 0.000 description 2
230000003287 optical effect Effects 0.000 description 2
238000000399 optical microscopy Methods 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000002245 particle Substances 0.000 description 2
239000000843 powder Substances 0.000 description 2
230000003014 reinforcing effect Effects 0.000 description 2
229920005989 resin Polymers 0.000 description 2
239000011347 resin Substances 0.000 description 2
239000000243 solution Substances 0.000 description 2
229910001887 tin oxide Inorganic materials 0.000 description 2
239000010936 titanium Substances 0.000 description 2
229910052719 titanium Inorganic materials 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
101150034533 ATIC gene Proteins 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
229920003043 Cellulose fiber Polymers 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
229920000742 Cotton Polymers 0.000 description 1
241000448280 Elates Species 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
238000004566 IR spectroscopy Methods 0.000 description 1
235000003332 Ilex aquifolium Nutrition 0.000 description 1
235000002296 Ilex sandwicensis Nutrition 0.000 description 1
235000002294 Ilex volkensiana Nutrition 0.000 description 1
239000002841 Lewis acid Substances 0.000 description 1
229920000106 Liquid crystal polymer Polymers 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
239000005062 Polybutadiene Substances 0.000 description 1
229920002367 Polyisobutene Polymers 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
239000003377 acid catalyst Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
125000002252 acyl group Chemical group 0.000 description 1
125000004423 acyloxy group Chemical group 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
239000003513 alkali Substances 0.000 description 1
239000000956 alloy Substances 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
VCNTUJWBXWAWEJ-UHFFFAOYSA-J aluminum;sodium;dicarbonate Chemical compound [Na+].[Al+3].[O-]C([O-])=O.[O-]C([O-])=O VCNTUJWBXWAWEJ-UHFFFAOYSA-J 0.000 description 1
229910003481 amorphous carbon Inorganic materials 0.000 description 1
238000000149 argon plasma sintering Methods 0.000 description 1
239000010425 asbestos Substances 0.000 description 1
125000001246 bromo group Chemical group Br* 0.000 description 1
239000000378 calcium silicate Substances 0.000 description 1
229910052918 calcium silicate Inorganic materials 0.000 description 1
OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
125000002843 carboxylic acid group Chemical group 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000002131 composite material Substances 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007906 compression Methods 0.000 description 1
238000000748 compression moulding Methods 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
230000007547 defect Effects 0.000 description 1
JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 1
238000001035 drying Methods 0.000 description 1
125000004185 ester group Chemical group 0.000 description 1
239000012530 fluid Substances 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
239000003365 glass fiber Substances 0.000 description 1
150000002334 glycols Chemical class 0.000 description 1
239000010439 graphite Substances 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
150000007517 lewis acids Chemical class 0.000 description 1
239000004973 liquid crystal related substance Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
238000002074 melt spinning Methods 0.000 description 1
239000010445 mica Substances 0.000 description 1
229910052618 mica group Inorganic materials 0.000 description 1
239000011490 mineral wool Substances 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
AJCDFVKYMIUXCR-UHFFFAOYSA-N oxobarium;oxo(oxoferriooxy)iron Chemical compound [Ba]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O AJCDFVKYMIUXCR-UHFFFAOYSA-N 0.000 description 1
229920002857 polybutadiene Polymers 0.000 description 1
229920001748 polybutylene Polymers 0.000 description 1
229920001225 polyester resin Polymers 0.000 description 1
239000004645 polyester resin Substances 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229920001343 polytetrafluoroethylene Polymers 0.000 description 1
239000004810 polytetrafluoroethylene Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
229910052895 riebeckite Inorganic materials 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
238000005245 sintering Methods 0.000 description 1
239000012265 solid product Substances 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
238000010129 solution processing Methods 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000010959 steel Substances 0.000 description 1
229920001059 synthetic polymer Polymers 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
150000004684 trihydrates Chemical class 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000003039 volatile agent Substances 0.000 description 1
239000002023 wood Substances 0.000 description 1
210000002268 wool Anatomy 0.000 description 1
239000004246 zinc acetate Substances 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)
Polyesters Or Polycarbonates (AREA)

CA000448882A 1984-03-05 1984-03-05 Melange de poly(terephtalate d'alcoylene) et de polyester totalement aromatique et de masse moleculaire elevee; methode de preparation Expired - Fee Related CA1269472A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000448882A CA1269472A (fr)	1984-03-05	1984-03-05	Melange de poly(terephtalate d'alcoylene) et de polyester totalement aromatique et de masse moleculaire elevee; methode de preparation

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000448882A CA1269472A (fr)	1984-03-05	1984-03-05	Melange de poly(terephtalate d'alcoylene) et de polyester totalement aromatique et de masse moleculaire elevee; methode de preparation

Publications (1)

Publication Number	Publication Date
CA1269472A true CA1269472A (fr)	1990-05-22

Family

ID=4127339

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000448882A Expired - Fee Related CA1269472A (fr)	1984-03-05	1984-03-05	Melange de poly(terephtalate d'alcoylene) et de polyester totalement aromatique et de masse moleculaire elevee; methode de preparation

Country Status (1)

Country	Link
CA (1)	CA1269472A (fr)

1984
- 1984-03-05 CA CA000448882A patent/CA1269472A/fr not_active Expired - Fee Related

Legal Events

Date	Code	Title	Description
1995-11-22	MKLA	Lapsed

Publication	Publication Date	Title
US4408022A (en)	1983-10-04	Blend of polyalkylene terephthalate and wholly aromatic polyester and process for producing the same
EP0154065B1 (fr)	1989-04-26	Mélange de polyalkylène téréphtalate et de polyester totalement aromatique, à haut poids moléculaire et procédé pour sa fabrication
CA1163740A (fr)	1984-03-13	Polycarbonate et polyester tout aromatique en melange
US4489190A (en)	1984-12-18	Blend of polyalkylene terephthalate and wholly aromatic polyester
US4267289A (en)	1981-05-12	Blend of wholly aromatic polyesters
US4460736A (en)	1984-07-17	Blend of sulfone polymer and wholly aromatic polyester
CA1197979A (fr)	1985-12-17	Transformation par fusion de polymeres de cristaux liquides thermotropiques
US4473682A (en)	1984-09-25	Melt processable polyester capable of forming an anisotropic melt comprising a relatively low concentration of 6-oxy-2-naphthoyl moiety, 4-oxybenzoyl moiety, 4,4'-dioxybiphenyl moiety, and terephthaloyl moiety
US4256624A (en)	1981-03-17	Polyester of 6-hydroxy-2-naphthoic acid, aromatic diol, and aromatic diacid capable of undergoing melt processing
EP0356226B1 (fr)	2000-11-02	Polyesters aromatiques; polyester-amides aromatiques et procédé pour leur préparation
JP3105281B2 (ja)	2000-10-30	溶融加工可能なポリエステル
EP0183433B1 (fr)	1989-06-21	Composition de polyester entièrement aromatique et de poly(ester-amide) capables de former une phase fondue anisotrope
CA1301392C (fr)	1992-05-19	Composition de resine presentant des proprietes anisotropiques a lafusion
CA2086931C (fr)	1999-06-15	Materiau composite auto-renforce forme de polymeres cristallins liquides thermotropiques
JPH01294767A (ja)	1989-11-28	全芳香族ポリエステル成形組成物
EP0298692A2 (fr)	1989-01-11	Polyester transformable par fusion, capable de former une fusion anisotrope, contenant une concentration relativement faible de motif de 6-oxy-2-naphtoyle, un motif 4-oxy-benzoyle, un motif 2,6-dioxynaphthalène, et un motif téréphtoyle
EP0169947B1 (fr)	1989-04-19	Mélange à l'état fondu de polyesters entièrement aromatiques non thermotropiques et thermotropiques
JPH0379612A (ja)	1991-04-04	分岐状共ポリエステルの製法
EP0273423A2 (fr)	1988-07-06	Polyesters aromatiques et leur utilisation
US5393848A (en)	1995-02-28	Process for forming improved liquid crystalline polymer blends
JPH0665705B2 (ja)	1994-08-24	ポリアルキレンテレフタレ−トと高分子量完全芳香族ポリエステルとのブレンドおよびその製法
US5306800A (en)	1994-04-26	Pseudo network condensation polymers
US5091464A (en)	1992-02-25	Polymer compositions having improved molding characteristics
EP0237358A2 (fr)	1987-09-16	Polyester entièrement aromatique moulable par fusion
JPH0655883B2 (ja)	1994-07-27	非サ−モトロピツクおよびサ−モトロピツク全芳香族ポリエステルの溶融ブレンド