CA1276335C - Rubber-modified epoxy resins - Google Patents

Rubber-modified epoxy resins

Info

Publication number
CA1276335C
CA1276335C CA000512354A CA512354A CA1276335C CA 1276335 C CA1276335 C CA 1276335C CA 000512354 A CA000512354 A CA 000512354A CA 512354 A CA512354 A CA 512354A CA 1276335 C CA1276335 C CA 1276335C
Authority
CA
Canada
Prior art keywords
composition
elastomeric
phase
continuous phase
functionality
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA000512354A
Other languages
English (en)
French (fr)
Inventor
David E. Henton
Dale M. Pickelman
Charles B. Arends
Victor E. Meyer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of CA1276335C publication Critical patent/CA1276335C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C08F291/02—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to elastomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/902—Core-shell

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Resins (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Epoxy Compounds (AREA)
CA000512354A 1985-06-26 1986-06-25 Rubber-modified epoxy resins Expired - Fee Related CA1276335C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US74907885A 1985-06-26 1985-06-26
US749,078 1985-06-26

Publications (1)

Publication Number Publication Date
CA1276335C true CA1276335C (en) 1990-11-13

Family

ID=25012154

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000512354A Expired - Fee Related CA1276335C (en) 1985-06-26 1986-06-25 Rubber-modified epoxy resins

Country Status (10)

Country Link
US (1) US4778851B1 (2)
EP (1) EP0228450B1 (2)
JP (2) JPS62501299A (2)
KR (1) KR900007766B1 (2)
AU (1) AU574932B2 (2)
BR (1) BR8606779A (2)
CA (1) CA1276335C (2)
DE (1) DE3674902D1 (2)
NZ (1) NZ216650A (2)
WO (1) WO1987000188A1 (2)

Families Citing this family (115)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63235351A (ja) * 1987-03-25 1988-09-30 Kureha Chem Ind Co Ltd 熱可塑性樹脂組成物
DE3712017A1 (de) * 1987-04-09 1988-10-27 Basf Ag Epoxidharzmassen mit verbesserter lagerstabilitaet
DE3811014A1 (de) * 1988-03-31 1989-10-19 Basf Ag Schlagfeste thermoplastische formmasse und deren verwendung
JPH02117948A (ja) * 1988-08-30 1990-05-02 Japan Synthetic Rubber Co Ltd 変性エポキシ組成物
JPH02110127A (ja) * 1988-10-19 1990-04-23 Toshiba Chem Corp 封止用樹脂組成物
JP2692208B2 (ja) * 1988-12-14 1997-12-17 日本合成ゴム株式会社 変性エポキシ組成物
EP0391183B1 (de) * 1989-04-07 1994-06-29 Asea Brown Boveri Ag Elektrischer Isolator
JPH0639562B2 (ja) * 1989-06-08 1994-05-25 信越化学工業株式会社 半導体封止用エポキシ樹脂組成物の製造方法
US5002982A (en) * 1990-02-26 1991-03-26 Gencorp Inc. Paper felts or mats
US5115019A (en) * 1990-03-30 1992-05-19 Shell Oil Company Carboxy-functional hydrogenated block copolymer dispersed in epoxy resin
US5789482A (en) * 1990-03-30 1998-08-04 Ciba Specialty Chemicals Corporation Epoxy resin with anhydride, toughener and active hydrogen-containing compound
JPH0762063B2 (ja) * 1990-05-11 1995-07-05 信越化学工業株式会社 エポキシ樹脂組成物
US5284912A (en) * 1990-08-16 1994-02-08 Japan Synthetic Rubber Co., Ltd. Thermoset resin with polyunsaturated monomer-grafted seed particles
DE69123341T2 (de) * 1990-12-28 1997-06-26 Polyplastics Co Kern-Schale-Polymer
US5290857A (en) * 1991-09-04 1994-03-01 Nippon Zeon Co., Ltd. Epoxy resin adhesive composition
USH1405H (en) * 1992-04-09 1995-01-03 Shell Oil Company Epoxy resin composition
DE59308794D1 (de) * 1992-06-25 1998-08-27 Ciba Geigy Ag Lagerstabile Suspension von Härtern und Zähigkeitsvermittlern für Epoxidharze
DE59310074D1 (de) * 1992-07-09 2000-08-17 Ciba Sc Holding Ag Härtbare Suspensionen auf Basis von Epoxidharzen
US5268452A (en) * 1992-07-22 1993-12-07 The B.F. Goodrich Company RLP modified unsaturated polyester resins blended with reactive liquid polymers
US5691416A (en) * 1992-11-05 1997-11-25 Nippon Shokubai Co., Ltd. (Meth)acrylate polymer particles dispersed in epoxy resin
JP3655646B2 (ja) * 1993-05-24 2005-06-02 日産自動車株式会社 エポキシ樹脂用接着補強剤及び該補強剤を含有する自動車用エポキシ樹脂系構造接着性組成物
JPH07109337A (ja) * 1993-08-20 1995-04-25 Toshiba Corp エポキシ樹脂注型材料
JPH08100162A (ja) * 1994-09-29 1996-04-16 Nippon Zeon Co Ltd エポキシ樹脂系接着性組成物を用いる接着方法
ES2175061T3 (es) 1995-11-29 2002-11-16 Vantico Ag Particulas nucleo-cascara (core-shell) y composiciones que contienen estas resinas epoxireticulables.
US6248204B1 (en) 1999-05-14 2001-06-19 Loctite Corporation Two part, reinforced, room temperature curable thermosetting epoxy resin compositions with improved adhesive strength and fracture toughness
US6664318B1 (en) 1999-12-20 2003-12-16 3M Innovative Properties Company Encapsulant compositions with thermal shock resistance
US6344853B1 (en) * 2000-01-06 2002-02-05 Alcone Marketing Group Method and apparatus for selecting, modifying and superimposing one image on another
US6916874B2 (en) * 2001-09-06 2005-07-12 Valspar Sourcing, Inc. Coating compositions having epoxy functional stabilizer
MXPA04002112A (es) * 2001-09-06 2004-07-08 Valspar Sourcing Inc Composiciones de revestimiento estabilizadas.
US6924328B2 (en) * 2001-09-06 2005-08-02 Valspar Sourcing, Inc. Stabilized coating compositions
US20030144415A1 (en) * 2002-01-29 2003-07-31 Dsm N.V. Process for the preparation of a thermoplastic elastomer comprising a partially vulcanized rubber concentrate
US20030198824A1 (en) * 2002-04-19 2003-10-23 Fong John W. Photocurable compositions containing reactive polysiloxane particles
AU2003264513A1 (en) * 2002-09-19 2004-04-08 Mitsui Chemicals, Inc. Sealing composition for liquid crystal displays and process for production of liquid crystal display panels
US8222324B2 (en) * 2003-06-09 2012-07-17 Kaneka Corporation Process for producing modified epoxy resin
US7485680B2 (en) * 2003-09-18 2009-02-03 Kaneka Corporation Process for producing rubbery polymer particle and process for producing resin composition containing the same
KR100548626B1 (ko) * 2003-10-29 2006-01-31 주식회사 엘지화학 고무라텍스 및 이의 제조방법
WO2006019041A1 (ja) * 2004-08-18 2006-02-23 Kaneka Corporation 半導体封止剤用エポキシ樹脂組成物およびエポキシ樹脂成形材料
US8029889B1 (en) 2004-12-03 2011-10-04 Henkel Corporation Prepregs, towpregs and preforms
US7649060B2 (en) * 2005-12-02 2010-01-19 Henkel Corporation Curable compositions
US20060182949A1 (en) * 2005-02-17 2006-08-17 3M Innovative Properties Company Surfacing and/or joining method
KR100646939B1 (ko) * 2005-08-29 2006-11-23 삼성에스디아이 주식회사 박막트랜지스터 및 그 제조방법
JP5031824B2 (ja) * 2006-05-03 2012-09-26 デルファイ・テクノロジーズ・ホールディング・エス．アー．エール．エル． アクチュエーターを被覆するための方法
ES2691528T3 (es) * 2006-07-31 2018-11-27 Henkel Ag & Co. Kgaa Composiciones adhesivas basadas en resina epoxi curable
WO2008045270A1 (en) 2006-10-06 2008-04-17 Henkel Ag & Co. Kgaa Pumpable epoxy paste adhesives resistant to wash-off
JP5409373B2 (ja) 2006-11-13 2014-02-05 ヘンケル コーポレイション コア−シェルゴムを有するベンゾキサジン組成物
US7537827B1 (en) 2006-12-13 2009-05-26 Henkel Corporation Prepreg laminates
EP2092017B1 (en) * 2006-12-19 2013-10-09 Henkel Corporation Cyanoacrylate compositions containing dispersions of core shell rubbers in (meth)acrylates
WO2008085286A1 (en) * 2006-12-19 2008-07-17 Henkel Corporation (meth)acrylate compositions containing dispersions of core shell rubbers in (meth)acrylates
GB0700960D0 (en) * 2007-01-18 2007-02-28 3M Innovative Properties Co High strength epoxy adhesive and uses thereof
EP2123711B1 (en) * 2007-02-28 2016-12-14 Kaneka Corporation Thermosetting resin composition having rubbery polymer particle dispersed therein, and process for production thereof
ATE538608T1 (de) * 2007-07-27 2012-01-15 Research In Motion Ltd Verwaltung von richtlinien für drahtlose vorrichtungen in einem drahtlosen kommunikationssystem
US20110003946A1 (en) * 2008-01-18 2011-01-06 Klaus-Volker Schuett Curable reaction resin system
US7847034B2 (en) * 2008-03-20 2010-12-07 Loctite (R&D) Limited Adducts and curable compositions using same
WO2009126862A1 (en) * 2008-04-11 2009-10-15 3M Innovative Properties Company One-part epoxy-based structural adhesive
DE102008023076A1 (de) * 2008-05-09 2009-11-12 Henkel Ag & Co. Kgaa Polymerisierbare Zusammensetzung
ES2662646T3 (es) 2008-06-12 2018-04-09 Henkel IP & Holding GmbH Composiciones adhesivas epóxicas estructurales de dos partes, altamente reforzadas, de nueva generación
US8309633B2 (en) * 2008-07-17 2012-11-13 Henkel Ireland Ltd. Low temperature, cationically curable compositions with improved cure speed and toughness
CN102159615B (zh) 2008-07-23 2014-10-01 3M创新有限公司 两部分的环氧基结构粘合剂
WO2010011714A2 (en) 2008-07-23 2010-01-28 3M Innovative Properties Company Reactive liquid modifiers
EP2321370B1 (en) 2008-07-23 2017-03-15 3M Innovative Properties Company Two-part epoxy-based structural adhesives
CN102124054B (zh) 2008-08-12 2013-01-30 株式会社钟化 不饱和酯系树脂组合物、不饱和酯系固化物以及它们的制造方法
GB0817795D0 (en) 2008-09-30 2008-11-05 3M Innovative Properties Co Fast curing oil-uptaking epozxy-based structural adhesives
DE102009001855A1 (de) * 2009-03-25 2010-09-30 Henkel Ag & Co. Kgaa Verfahren zur Herstellung eines faserhaltigen Verbundwerkstoffs
JP2012532942A (ja) * 2009-07-08 2012-12-20 ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン 導電性接着剤
CA2772333C (en) * 2009-08-31 2017-01-17 Cytec Technology Corp. High performance adhesive compositions
US9528035B2 (en) 2009-09-11 2016-12-27 3M Innovative Properties Company Curable and cured adhesive compositions
WO2011031399A1 (en) 2009-09-11 2011-03-17 3M Innovative Properties Company Curable and cured adhesive compositions
GB0922599D0 (en) * 2009-12-23 2010-02-10 Cytec Tech Corp Modified resin systems for liquid resin infusion applications, prepreg autoclave applications and hybrids thereof
CN103068946B (zh) 2010-08-10 2015-05-06 3M创新有限公司 环氧树脂结构粘合剂
JP5629009B2 (ja) 2010-09-15 2014-11-19 ヘンケル アイルランド リミテッド 二成分系シアノアクリレート／カチオン硬化性接着剤システム
EP2638093B1 (en) 2010-11-12 2018-08-01 3M Innovative Properties Company Curable compositions
CN103189411B (zh) 2010-11-12 2015-11-25 3M创新有限公司 可固化组合物和已固化组合物
EP2468792A1 (en) 2010-12-23 2012-06-27 3M Innovative Properties Company Curable adhesive composition
EP2662414B1 (en) 2011-01-05 2018-04-11 Kaneka Corporation Polymer microparticle-dispersed resin composition and method for producing same
GB201100568D0 (en) * 2011-01-13 2011-03-02 Cytec Engineered Materials Ltd Particle reinforced polymer composition
WO2013070478A1 (en) * 2011-11-08 2013-05-16 Dow Global Technologies Llc Bimodal toughening agents for thermosettable epoxy resin compositions
JP6063477B2 (ja) 2011-12-16 2017-01-18 スリーエム イノベイティブ プロパティズ カンパニー オキシラン含有ビスアンヒドロヘキシトール誘導体及びその使用
CN104159903B (zh) 2011-12-16 2016-06-29 3M创新有限公司 包含巯基的双失水己糖醇衍生物及其用途
EP2909259A1 (en) 2012-10-19 2015-08-26 Dow Global Technologies LLC Polymer particle dispersions with polyols
US8981027B2 (en) 2013-03-15 2015-03-17 Henkel IP & Holding GmbH Two-part, cyanoacrylate/cationically curable adhesive systems
CN105722933A (zh) 2013-07-26 2016-06-29 泽费罗斯股份有限公司 热固性粘合膜的改进或涉及它的改进
ES2811753T3 (es) * 2013-12-24 2021-03-15 Hexcel Composites Ltd Mejoras para aditivos de matrices
ES2625552T3 (es) 2014-06-17 2017-07-19 3M Innovative Properties Company Composición de adhesivo epoxídico de curado rápido
CN107001898B (zh) * 2014-11-28 2020-10-27 大日本印刷株式会社 粘合剂组合物和使用该粘合剂组合物的粘合片材
DE102014226826A1 (de) 2014-12-22 2016-06-23 Henkel Ag & Co. Kgaa Epoxidharz-Zusammensetzung
FR3031108B1 (fr) 2014-12-24 2018-08-17 Arkema France Composition comprenant un polymere a phases multiples, son procede de preparation et son utlisation
FR3031109B1 (fr) * 2014-12-24 2018-08-17 Arkema France Composition de polymeres, son procede de preparation, son utilisation et composition la comprenant
FR3031106B1 (fr) 2014-12-24 2017-02-03 Arkema France Composition de polymeres a phases multiples, son procede de preparation, son utilisation et composition la comprenant
WO2017004495A1 (en) 2015-07-01 2017-01-05 3M Innovative Properties Company Composite membranes with improved performance and/or durability and methods of use
US10737220B2 (en) 2015-07-01 2020-08-11 3M Innovative Properties Company PVP- and/or PVL-containing composite membranes and methods of use
WO2017004496A1 (en) 2015-07-01 2017-01-05 3M Innovative Properties Company Polymeric ionomer separation membranes and methods of use
DE102017126328A1 (de) 2016-11-11 2018-05-17 GM Global Technology Operations LLC Dual-Cure Konstruktionsklebstoff
EP3596182B1 (en) 2017-03-17 2021-06-30 Dow Global Technologies LLC Epoxy-acrylic hybrid adhesive
EP3660093A4 (en) 2017-07-28 2021-01-20 Kaneka Corporation EPOXY RESIN COMPOSITION
WO2020022798A1 (ko) 2018-07-25 2020-01-30 주식회사 엘지화학 접착제 조성물
KR102183704B1 (ko) 2018-07-25 2020-11-27 주식회사 엘지화학 접착제 조성물
JP7167301B2 (ja) * 2018-07-25 2022-11-08 エルジー・ケム・リミテッド 接着剤組成物
JP7179151B2 (ja) 2018-07-25 2022-11-28 エルジー・ケム・リミテッド 接着剤組成物
US12146079B2 (en) 2018-07-25 2024-11-19 Lg Chem, Ltd. Adhesive composition
US12157839B2 (en) 2018-07-25 2024-12-03 Lg Chem, Ltd. Adhesive composition
CN112449650B (zh) 2018-07-25 2023-03-28 株式会社Lg化学 粘合剂组合物
GB2576791B (en) 2018-08-13 2022-09-14 Henkel Ag & Co Kgaa A two-part cyanoacrylate curable adhesive system
GB2576792B (en) 2018-08-13 2022-09-14 Henkel Ag & Co Kgaa A two-part cyanoacrylate curable adhesive system
CN113227249B (zh) 2018-12-27 2024-03-15 株式会社钟化 树脂组合物及其应用
GB2582537B (en) 2019-03-04 2022-02-23 Henkel IP & Holding GmbH Two-part, cyanoacrylate/cationically curable adhesive systems
WO2020196920A1 (ja) * 2019-03-28 2020-10-01 株式会社カネカ 樹脂組成物の製造方法および樹脂組成物
US20220177695A1 (en) 2019-04-23 2022-06-09 Dic Corporation Curable composition, cured product, fiber reinforced composite material, and molded article and method for producing same
EP3825355A1 (de) 2019-11-22 2021-05-26 Henkel AG & Co. KGaA Formulierungen mit hohen glasübergangstemperaturen für laminate
BR112022012649A2 (pt) * 2019-12-27 2022-09-06 Cytec Ind Inc Material de acabamento de superfície, estrutura compósita, e, método para formar uma estrutura compósita
US11958938B2 (en) 2020-04-28 2024-04-16 3M Innovative Properties Company Curable composition
JP7090824B1 (ja) * 2020-07-22 2022-06-24 株式会社有沢製作所 熱硬化性樹脂組成物、カバーレイフィルム、接着シート、及びフレキシブルプリント配線板
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KR20250026849A (ko) 2022-06-28 2025-02-25 헨켈 아게 운트 코. 카게아아 수중 결합 방법
TW202521610A (zh) 2023-11-15 2025-06-01 美商羅姆暨翰斯公司 用於生產熱固性樹脂分散體之方法
GB2640960A (en) 2024-05-10 2025-11-12 Henkel Ag & Co Kgaa Debonding of a cured composition

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL173809B (nl) * 1951-11-17 Rca Corp Beeldopneeminrichting met kleurcodeerstrookfilterstelsel.
BE598164A (2) * 1959-12-18
US3322852A (en) * 1964-06-19 1967-05-30 Monsanto Co Polyblends containing a graft copolymer of hydroxylated diene rubber, a copolymer containing a monoethylenically unsaturated carboxylic acid with acrylonitrile, and a polyepoxide
US3322853A (en) * 1964-06-19 1967-05-30 Monsanto Co Polyblends containing a graft copolymer of hydroxylated diene rubber, a copolymer containing a polybasic ethylenically unsaturated carboxylic acid with another vinylidene monomer, and a polyepoxide
US3496250A (en) * 1967-02-21 1970-02-17 Borg Warner Blends of epoxy resins and acrylonitrile butadiene-styrene graft copolymers
JPS5034592B1 (2) * 1970-12-18 1975-11-10
JPS5137125B2 (2) * 1971-08-30 1976-10-14
US3856883A (en) * 1973-05-29 1974-12-24 Ford Motor Co Graded rubber particles having hydroxy functionality and a polymeric crosslinking agent
JPS5471127A (en) * 1977-11-17 1979-06-07 Hitachi Chem Co Ltd Resin composition for coating outer surface of for can
US4315085A (en) * 1980-07-25 1982-02-09 Gaf Corporation Core-shell composite polymers having high amounts of carboxylic acid units in the shell
JPS57149370A (en) * 1981-03-11 1982-09-14 Asahi Chem Ind Co Ltd Epoxy resin-base adhesive
JPS5891755A (ja) * 1981-11-26 1983-05-31 Sunstar Giken Kk エポキシ樹脂組成物の製法
US4419496A (en) * 1982-02-22 1983-12-06 The Dow Chemical Company Particle agglomeration in rubber latices
JPS6028418A (ja) * 1983-07-28 1985-02-13 Nippon Oil Co Ltd 電気絶縁用樹脂組成物

Also Published As

Publication number Publication date
EP0228450B1 (en) 1990-10-10
AU6129386A (en) 1987-01-30
EP0228450A1 (en) 1987-07-15
JPH0465092B2 (2) 1992-10-19
US4778851A (en) 1988-10-18
DE3674902D1 (de) 1990-11-15
NZ216650A (en) 1989-08-29
JPS6485216A (en) 1989-03-30
KR900007766B1 (ko) 1990-10-19
WO1987000188A1 (en) 1987-01-15
US4778851B1 (en) 1999-02-09
BR8606779A (pt) 1987-10-13
KR880700021A (ko) 1988-02-15
JPS62501299A (ja) 1987-05-21
AU574932B2 (en) 1988-07-14

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