CA1286042C - Composition de resine pour le moulage de pare-chocs souples - Google Patents

Composition de resine pour le moulage de pare-chocs souples

Info

Publication number: CA1286042C
Authority: CA; Canada
Prior art keywords: weight; block; iii; molding; ethylene
Prior art date: 1986-03-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA000615668A

Other languages

English (en)

Inventor

Takanobu Kawamura

Tamihiro Oohashi

Shinji Chiku

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

JNC Corp

Original Assignee

Chisso Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-03-18

Filing date

1990-03-05

Publication date

1991-07-09

1986-03-18 Priority claimed from JP6008386A external-priority patent/JPS62240346A/ja

1986-03-18 Priority claimed from JP6008286A external-priority patent/JPS62240342A/ja

1987-03-09 Priority claimed from CA000531521A external-priority patent/CA1285084C/fr

1990-03-05 Application filed by Chisso Corp filed Critical Chisso Corp

1991-07-09 Application granted granted Critical

1991-07-09 Publication of CA1286042C publication Critical patent/CA1286042C/fr

2007-03-09 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

238000000465 moulding Methods 0.000 title claims abstract description 42
239000011342 resin composition Substances 0.000 title abstract description 12
-1 aromatic vinyl compound Chemical class 0.000 claims abstract description 56
239000000203 mixture Substances 0.000 claims abstract description 46
229920005604 random copolymer Polymers 0.000 claims abstract description 35
229920000642 polymer Polymers 0.000 claims abstract description 29
229920001400 block copolymer Polymers 0.000 claims abstract description 28
150000001993 dienes Chemical class 0.000 claims abstract description 17
229920002554 vinyl polymer Polymers 0.000 claims abstract description 8
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 18
239000004793 Polystyrene Substances 0.000 claims description 8
229920002223 polystyrene Polymers 0.000 claims description 8
239000005062 Polybutadiene Substances 0.000 claims description 5
229920002857 polybutadiene Polymers 0.000 claims description 5
229920001195 polyisoprene Polymers 0.000 claims description 3
229920001577 copolymer Polymers 0.000 abstract description 6
229920005989 resin Polymers 0.000 abstract description 5
239000011347 resin Substances 0.000 abstract description 5
239000004416 thermosoftening plastic Substances 0.000 abstract description 4
229920001169 thermoplastic Polymers 0.000 abstract description 3
239000000306 component Substances 0.000 description 51
238000002156 mixing Methods 0.000 description 23
229920001971 elastomer Polymers 0.000 description 16
238000000034 method Methods 0.000 description 13
239000002530 phenolic antioxidant Substances 0.000 description 12
239000005060 rubber Substances 0.000 description 11
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 10
239000005977 Ethylene Substances 0.000 description 10
239000000243 solution Substances 0.000 description 10
238000012360 testing method Methods 0.000 description 9
230000000052 comparative effect Effects 0.000 description 8
229920005674 ethylene-propylene random copolymer Polymers 0.000 description 8
239000003963 antioxidant agent Substances 0.000 description 7
238000001746 injection moulding Methods 0.000 description 7
239000008188 pellet Substances 0.000 description 7
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
230000003078 antioxidant effect Effects 0.000 description 6
125000004432 carbon atom Chemical group C* 0.000 description 6
229920002725 thermoplastic elastomer Polymers 0.000 description 6
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 5
239000000806 elastomer Substances 0.000 description 5
239000003063 flame retardant Substances 0.000 description 5
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 4
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
239000004902 Softening Agent Substances 0.000 description 4
239000000155 melt Substances 0.000 description 4
230000000379 polymerizing effect Effects 0.000 description 4
229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 4
239000000126 substance Substances 0.000 description 4
229920001897 terpolymer Polymers 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
239000000654 additive Substances 0.000 description 3
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
238000002347 injection Methods 0.000 description 3
239000007924 injection Substances 0.000 description 3
239000000463 material Substances 0.000 description 3
ZGEGCLOFRBLKSE-UHFFFAOYSA-N methylene hexane Natural products CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 3
AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 3
239000004332 silver Substances 0.000 description 3
229910052709 silver Inorganic materials 0.000 description 3
229920002633 Kraton (polymer) Polymers 0.000 description 2
239000004594 Masterbatch (MB) Substances 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
229910000019 calcium carbonate Inorganic materials 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
238000000576 coating method Methods 0.000 description 2
239000003086 colorant Substances 0.000 description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
238000005984 hydrogenation reaction Methods 0.000 description 2
239000011256 inorganic filler Substances 0.000 description 2
229910003475 inorganic filler Inorganic materials 0.000 description 2
238000005259 measurement Methods 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
239000004033 plastic Substances 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
239000004014 plasticizer Substances 0.000 description 2
229920001084 poly(chloroprene) Polymers 0.000 description 2
229920006124 polyolefin elastomer Polymers 0.000 description 2
229920001155 polypropylene Polymers 0.000 description 2
229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
229920003051 synthetic elastomer Polymers 0.000 description 2
AQPHBYQUCKHJLT-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-(2,3,4,5,6-pentabromophenyl)benzene Chemical group BrC1=C(Br)C(Br)=C(Br)C(Br)=C1C1=C(Br)C(Br)=C(Br)C(Br)=C1Br AQPHBYQUCKHJLT-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
229920002943 EPDM rubber Polymers 0.000 description 1
239000004606 Fillers/Extenders Substances 0.000 description 1
241001441571 Hiodontidae Species 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
IORUEKDKNHHQAL-UHFFFAOYSA-N [2-tert-butyl-6-[(3-tert-butyl-2-hydroxy-5-methylphenyl)methyl]-4-methylphenyl] prop-2-enoate Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)OC(=O)C=C)=C1O IORUEKDKNHHQAL-UHFFFAOYSA-N 0.000 description 1
VSVVZZQIUJXYQA-UHFFFAOYSA-N [3-(3-dodecylsulfanylpropanoyloxy)-2,2-bis(3-dodecylsulfanylpropanoyloxymethyl)propyl] 3-dodecylsulfanylpropanoate Chemical compound CCCCCCCCCCCCSCCC(=O)OCC(COC(=O)CCSCCCCCCCCCCCC)(COC(=O)CCSCCCCCCCCCCCC)COC(=O)CCSCCCCCCCCCCCC VSVVZZQIUJXYQA-UHFFFAOYSA-N 0.000 description 1
239000006096 absorbing agent Substances 0.000 description 1
239000001361 adipic acid Substances 0.000 description 1
235000011037 adipic acid Nutrition 0.000 description 1
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229910000410 antimony oxide Inorganic materials 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
239000010426 asphalt Substances 0.000 description 1
239000000987 azo dye Substances 0.000 description 1
WXCZUWHSJWOTRV-UHFFFAOYSA-N but-1-ene;ethene Chemical compound C=C.CCC=C WXCZUWHSJWOTRV-UHFFFAOYSA-N 0.000 description 1
FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical class C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical compound [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
238000004040 coloring Methods 0.000 description 1
238000000748 compression moulding Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000006071 cream Substances 0.000 description 1
239000003431 cross linking reagent Substances 0.000 description 1
239000013078 crystal Substances 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000003365 glass fiber Substances 0.000 description 1
239000010440 gypsum Substances 0.000 description 1
229910052602 gypsum Inorganic materials 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
WNLRTRBMVRJNCN-UHFFFAOYSA-N hexanedioic acid Natural products OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
239000002932 luster Substances 0.000 description 1
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
239000000347 magnesium hydroxide Substances 0.000 description 1
229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
238000000691 measurement method Methods 0.000 description 1
101150054634 melk gene Proteins 0.000 description 1
KWKAKUADMBZCLK-UHFFFAOYSA-N methyl heptene Natural products CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
239000010445 mica Substances 0.000 description 1
229910052618 mica group Inorganic materials 0.000 description 1
239000011707 mineral Substances 0.000 description 1
XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
239000003921 oil Substances 0.000 description 1
VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
229960004838 phosphoric acid Drugs 0.000 description 1
235000011007 phosphoric acid Nutrition 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
239000010734 process oil Substances 0.000 description 1
238000012545 processing Methods 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229920001384 propylene homopolymer Polymers 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
229920003048 styrene butadiene rubber Polymers 0.000 description 1
YPMOSINXXHVZIL-UHFFFAOYSA-N sulfanylideneantimony Chemical compound [Sb]=S YPMOSINXXHVZIL-UHFFFAOYSA-N 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
235000010215 titanium dioxide Nutrition 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
239000010456 wollastonite Substances 0.000 description 1
229910052882 wollastonite Inorganic materials 0.000 description 1
229910001928 zirconium oxide Inorganic materials 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

CA000615668A 1986-03-18 1990-03-05 Composition de resine pour le moulage de pare-chocs souples Expired - Lifetime CA1286042C (fr)

Applications Claiming Priority (5)

Application Number	Priority Date	Filing Date	Title
JP(60082/1986)		1986-03-18
JP6008386A JPS62240346A (ja)	1986-03-18	1986-03-18	成形用樹脂組成物
JP6008286A JPS62240342A (ja)	1986-03-18	1986-03-18	成形用エラストマ−状組成物
JP(60083/1986)		1986-03-18
CA000531521A CA1285084C (fr)	1986-03-18	1987-03-09	Composition de resine elastomere a mouler pour pare-chocs mous

Related Parent Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000531521A Division CA1285084C (fr)	1986-03-18	1987-03-09	Composition de resine elastomere a mouler pour pare-chocs mous

Publications (1)

Publication Number	Publication Date
CA1286042C true CA1286042C (fr)	1991-07-09

Family

ID=27167681

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000615668A Expired - Lifetime CA1286042C (fr)	1986-03-18	1990-03-05	Composition de resine pour le moulage de pare-chocs souples

Country Status (1)

Country	Link
CA (1)	CA1286042C (fr)

1990
- 1990-03-05 CA CA000615668A patent/CA1286042C/fr not_active Expired - Lifetime

Legal Events

Date	Code	Title	Description
1999-07-09	MKLA	Lapsed

Publication	Publication Date	Title
KR100632603B1 (ko)	2006-10-09	열가소성 에라스토머 조성물 및 이의 제조방법
US6756446B2 (en)	2004-06-29	Engineered polyolefin materials with enhanced surface durability
KR20020071977A (ko)	2002-09-13	개선된 접착 특성을 가지는 열가소성 탄성중합체
EP0733676B1 (fr)	1999-11-03	Composition d'élastomère thermoplastique
JPH11158346A (ja)	1999-06-15	耐油性に優れた熱可塑性エラストマー
CA1285084C (fr)	1991-06-18	Composition de resine elastomere a mouler pour pare-chocs mous
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