CA1299460C - Granular non-phosphorus-containing bleach activator compositions and use thereof in granular detergent bleach compositions - Google Patents

Granular non-phosphorus-containing bleach activator compositions and use thereof in granular detergent bleach compositions

Info

Publication number: CA1299460C
Authority: CA; Canada
Prior art keywords: phosphorus; bleach activator; granular; weight; bleach
Prior art date: 1986-03-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000532482A

Other languages

English (en)

French (fr)

Inventor

James Gavin De Bernat

Ian Donald Robb

Raymond John Wilde

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever PLC

Original Assignee

Unilever PLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-03-25

Filing date

1987-03-19

Publication date

1992-04-28

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=10595210&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA1299460(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1987-03-19 Application filed by Unilever PLC filed Critical Unilever PLC

1992-04-28 Application granted granted Critical

1992-04-28 Publication of CA1299460C publication Critical patent/CA1299460C/en

2009-04-28 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 73
239000007844 bleaching agent Substances 0.000 title claims abstract description 70
239000012190 activator Substances 0.000 title claims abstract description 61
239000003599 detergent Substances 0.000 title claims abstract description 38
239000011574 phosphorus Substances 0.000 title claims abstract description 29
229910052698 phosphorus Inorganic materials 0.000 title claims abstract description 29
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims abstract description 28
239000000463 material Substances 0.000 claims abstract description 29
239000004927 clay Substances 0.000 claims abstract description 18
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 15
150000003839 salts Chemical class 0.000 claims abstract description 10
229910021647 smectite Inorganic materials 0.000 claims abstract description 10
229910000323 aluminium silicate Inorganic materials 0.000 claims abstract description 9
229910019142 PO4 Inorganic materials 0.000 claims abstract description 8
239000010452 phosphate Substances 0.000 claims abstract description 6
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 6
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical group [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 12
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 9
229920000642 polymer Polymers 0.000 claims description 9
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 7
229910052938 sodium sulfate Inorganic materials 0.000 claims description 6
235000011152 sodium sulphate Nutrition 0.000 claims description 6
239000000440 bentonite Substances 0.000 claims description 5
229910000278 bentonite Inorganic materials 0.000 claims description 5
239000011149 active material Substances 0.000 claims description 4
238000005341 cation exchange Methods 0.000 claims description 3
229920005646 polycarboxylate Polymers 0.000 claims description 2
239000008187 granular material Substances 0.000 description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 11
150000001875 compounds Chemical class 0.000 description 10
229910052757 nitrogen Inorganic materials 0.000 description 10
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 9
239000010457 zeolite Substances 0.000 description 8
239000005995 Aluminium silicate Substances 0.000 description 7
229910021536 Zeolite Inorganic materials 0.000 description 7
-1 alpha-acetoxy-(N Chemical class 0.000 description 7
235000012211 aluminium silicate Nutrition 0.000 description 7
229920001577 copolymer Polymers 0.000 description 7
239000004615 ingredient Substances 0.000 description 7
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 7
235000021317 phosphate Nutrition 0.000 description 6
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 5
239000002253 acid Substances 0.000 description 5
235000012216 bentonite Nutrition 0.000 description 5
239000011230 binding agent Substances 0.000 description 5
239000004744 fabric Substances 0.000 description 5
229910052500 inorganic mineral Inorganic materials 0.000 description 5
239000011707 mineral Substances 0.000 description 5
239000002245 particle Substances 0.000 description 5
239000000843 powder Substances 0.000 description 5
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
229920002125 Sokalan® Polymers 0.000 description 4
229920002472 Starch Polymers 0.000 description 4
235000014113 dietary fatty acids Nutrition 0.000 description 4
239000000194 fatty acid Substances 0.000 description 4
229930195729 fatty acid Natural products 0.000 description 4
239000008202 granule composition Substances 0.000 description 4
229910000271 hectorite Inorganic materials 0.000 description 4
KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 4
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
238000000034 method Methods 0.000 description 4
229910052901 montmorillonite Inorganic materials 0.000 description 4
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 4
150000004965 peroxy acids Chemical class 0.000 description 4
239000000047 product Substances 0.000 description 4
229910000275 saponite Inorganic materials 0.000 description 4
239000011734 sodium Substances 0.000 description 4
235000019832 sodium triphosphate Nutrition 0.000 description 4
239000008107 starch Substances 0.000 description 4
235000019698 starch Nutrition 0.000 description 4
238000005406 washing Methods 0.000 description 4
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
239000004115 Sodium Silicate Substances 0.000 description 3
238000004061 bleaching Methods 0.000 description 3
239000001768 carboxy methyl cellulose Substances 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
239000002734 clay mineral Substances 0.000 description 3
238000000354 decomposition reaction Methods 0.000 description 3
150000004665 fatty acids Chemical class 0.000 description 3
UPBDXRPQPOWRKR-UHFFFAOYSA-N furan-2,5-dione;methoxyethene Chemical compound COC=C.O=C1OC(=O)C=C1 UPBDXRPQPOWRKR-UHFFFAOYSA-N 0.000 description 3
ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
238000002844 melting Methods 0.000 description 3
239000000344 soap Substances 0.000 description 3
229910052708 sodium Inorganic materials 0.000 description 3
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
229910052911 sodium silicate Inorganic materials 0.000 description 3
239000001993 wax Substances 0.000 description 3
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
229910052910 alkali metal silicate Inorganic materials 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
150000008064 anhydrides Chemical class 0.000 description 2
230000009286 beneficial effect Effects 0.000 description 2
239000011575 calcium Substances 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
235000014633 carbohydrates Nutrition 0.000 description 2
235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
239000008112 carboxymethyl-cellulose Substances 0.000 description 2
229940105329 carboxymethylcellulose Drugs 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
150000002191 fatty alcohols Chemical class 0.000 description 2
238000009472 formulation Methods 0.000 description 2
VPVSTMAPERLKKM-UHFFFAOYSA-N glycoluril Chemical compound N1C(=O)NC2NC(=O)NC21 VPVSTMAPERLKKM-UHFFFAOYSA-N 0.000 description 2
239000003979 granulating agent Substances 0.000 description 2
238000005342 ion exchange Methods 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
239000011976 maleic acid Substances 0.000 description 2
229910021645 metal ion Inorganic materials 0.000 description 2
XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 2
239000002736 nonionic surfactant Substances 0.000 description 2
150000002894 organic compounds Chemical class 0.000 description 2
ATGAWOHQWWULNK-UHFFFAOYSA-I pentapotassium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [K+].[K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ATGAWOHQWWULNK-UHFFFAOYSA-I 0.000 description 2
150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
229920002689 polyvinyl acetate Polymers 0.000 description 2
239000011118 polyvinyl acetate Substances 0.000 description 2
229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
239000001267 polyvinylpyrrolidone Substances 0.000 description 2
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
XTHRMVQDBJOEPD-UHFFFAOYSA-N prop-1-ene;urea Chemical compound CC=C.NC(N)=O.NC(N)=O XTHRMVQDBJOEPD-UHFFFAOYSA-N 0.000 description 2
229960001922 sodium perborate Drugs 0.000 description 2
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 2
239000000243 solution Substances 0.000 description 2
238000003860 storage Methods 0.000 description 2
229910021653 sulphate ion Inorganic materials 0.000 description 2
230000008961 swelling Effects 0.000 description 2
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
RKHMZKDESOMZLE-UHFFFAOYSA-N (1,3-diacetyl-5-acetyloxyimidazolidin-4-yl) acetate Chemical compound CC(=O)OC1C(OC(C)=O)N(C(C)=O)CN1C(C)=O RKHMZKDESOMZLE-UHFFFAOYSA-N 0.000 description 1
MSELUFTVMYHJGR-UHFFFAOYSA-N (1,3-diacetyl-5-propanoyloxyimidazolidin-4-yl) propanoate Chemical compound CCC(=O)OC1C(OC(=O)CC)N(C(C)=O)CN1C(C)=O MSELUFTVMYHJGR-UHFFFAOYSA-N 0.000 description 1
NIHKFGMYMWGERR-UHFFFAOYSA-N (3-chlorobenzoyl) 3-chlorobenzoate Chemical compound ClC1=CC=CC(C(=O)OC(=O)C=2C=C(Cl)C=CC=2)=C1 NIHKFGMYMWGERR-UHFFFAOYSA-N 0.000 description 1
VAVZXZURPCYUHS-RQOWECAXSA-N (z)-3-(hydrazinecarbonyl)-4-oxopent-2-enoic acid Chemical compound OC(=O)/C=C(C(=O)C)\C(=O)NN VAVZXZURPCYUHS-RQOWECAXSA-N 0.000 description 1
CBBKKVPJPRZOCM-UHFFFAOYSA-N 1,4-diacetylpiperazine-2,5-dione Chemical compound CC(=O)N1CC(=O)N(C(C)=O)CC1=O CBBKKVPJPRZOCM-UHFFFAOYSA-N 0.000 description 1
NOGFHTGYPKWWRX-UHFFFAOYSA-N 2,2,6,6-tetramethyloxan-4-one Chemical compound CC1(C)CC(=O)CC(C)(C)O1 NOGFHTGYPKWWRX-UHFFFAOYSA-N 0.000 description 1
125000004825 2,2-dimethylpropylene group Chemical group [H]C([H])([H])C(C([H])([H])[H])(C([H])([H])[*:1])C([H])([H])[*:2] 0.000 description 1
CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical class OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
WFXJWACFHGTNEH-UHFFFAOYSA-N 3,6-dimethyl-1,4-di(propanoyl)piperazine-2,5-dione Chemical compound CCC(=O)N1C(C)C(=O)N(C(=O)CC)C(C)C1=O WFXJWACFHGTNEH-UHFFFAOYSA-N 0.000 description 1
JBNHKYQZNSPSOR-UHFFFAOYSA-N 4-(carboxymethylperoxy)-4-oxobutanoic acid Chemical class OC(=O)CCC(=O)OOCC(O)=O JBNHKYQZNSPSOR-UHFFFAOYSA-N 0.000 description 1
YNSJJJCTNXHMEW-UHFFFAOYSA-N 4-methoxy-n-methyl-n-methylsulfonylbenzamide Chemical compound COC1=CC=C(C(=O)N(C)S(C)(=O)=O)C=C1 YNSJJJCTNXHMEW-UHFFFAOYSA-N 0.000 description 1
BUJPYXOTTZPZGS-UHFFFAOYSA-N 4-propoxycarbonyloxybenzenesulfonic acid Chemical compound CCCOC(=O)OC1=CC=C(S(O)(=O)=O)C=C1 BUJPYXOTTZPZGS-UHFFFAOYSA-N 0.000 description 1
XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 1
229920002126 Acrylic acid copolymer Polymers 0.000 description 1
102000013142 Amylases Human genes 0.000 description 1
108010065511 Amylases Proteins 0.000 description 1
ZYUIGKFFTYKJHB-UHFFFAOYSA-L C(CCC(=O)[O-])(=O)OC(=O)O.C(CCC(=O)[O-])(=O)OOC.[Na+].[Na+] Chemical class C(CCC(=O)[O-])(=O)OC(=O)O.C(CCC(=O)[O-])(=O)OOC.[Na+].[Na+] ZYUIGKFFTYKJHB-UHFFFAOYSA-L 0.000 description 1
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
235000013162 Cocos nucifera Nutrition 0.000 description 1
244000060011 Cocos nucifera Species 0.000 description 1
229920001353 Dextrin Polymers 0.000 description 1
QEVGZEDELICMKH-UHFFFAOYSA-N Diglycolic acid Chemical compound OC(=O)COCC(O)=O QEVGZEDELICMKH-UHFFFAOYSA-N 0.000 description 1
101100536354 Drosophila melanogaster tant gene Proteins 0.000 description 1
241000448280 Elates Species 0.000 description 1
102000004190 Enzymes Human genes 0.000 description 1
108090000790 Enzymes Proteins 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
PAYRUJLWNCNPSJ-UHFFFAOYSA-N N-phenyl amine Natural products NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 1
102000035195 Peptidases Human genes 0.000 description 1
108091005804 Peptidases Proteins 0.000 description 1
239000004372 Polyvinyl alcohol Substances 0.000 description 1
239000004365 Protease Substances 0.000 description 1
229920001131 Pulp (paper) Polymers 0.000 description 1
101100208039 Rattus norvegicus Trpv5 gene Proteins 0.000 description 1
239000004902 Softening Agent Substances 0.000 description 1
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
239000001083 [(2R,3R,4S,5R)-1,2,4,5-tetraacetyloxy-6-oxohexan-3-yl] acetate Substances 0.000 description 1
UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 1
OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical group [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
230000009471 action Effects 0.000 description 1
230000010933 acylation Effects 0.000 description 1
238000005917 acylation reaction Methods 0.000 description 1
239000003513 alkali Substances 0.000 description 1
229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
150000008041 alkali metal carbonates Chemical class 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
235000019418 amylase Nutrition 0.000 description 1
229940025131 amylases Drugs 0.000 description 1
239000002518 antifoaming agent Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
238000004380 ashing Methods 0.000 description 1
229960000892 attapulgite Drugs 0.000 description 1
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
KXDAEFPNCMNJSK-UHFFFAOYSA-N benzene carboxamide Natural products NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 1
229910000281 calcium bentonite Inorganic materials 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
239000001110 calcium chloride Substances 0.000 description 1
229910001628 calcium chloride Inorganic materials 0.000 description 1
239000001175 calcium sulphate Substances 0.000 description 1
235000011132 calcium sulphate Nutrition 0.000 description 1
150000001720 carbohydrates Chemical class 0.000 description 1
125000005521 carbonamide group Chemical group 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
150000004651 carbonic acid esters Chemical class 0.000 description 1
MMCOUVMKNAHQOY-UHFFFAOYSA-N carbonoperoxoic acid Chemical compound OOC(O)=O MMCOUVMKNAHQOY-UHFFFAOYSA-N 0.000 description 1
150000007942 carboxylates Chemical class 0.000 description 1
150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
210000004534 cecum Anatomy 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920003086 cellulose ether Polymers 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
239000002178 crystalline material Substances 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000002939 deleterious effect Effects 0.000 description 1
230000008021 deposition Effects 0.000 description 1
ZFTFAPZRGNKQPU-UHFFFAOYSA-N dicarbonic acid Chemical compound OC(=O)OC(O)=O ZFTFAPZRGNKQPU-UHFFFAOYSA-N 0.000 description 1
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
229940088598 enzyme Drugs 0.000 description 1
239000007850 fluorescent dye Substances 0.000 description 1
230000002070 germicidal effect Effects 0.000 description 1
150000004676 glycans Chemical class 0.000 description 1
238000005469 granulation Methods 0.000 description 1
230000003179 granulation Effects 0.000 description 1
238000001033 granulometry Methods 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
229940091173 hydantoin Drugs 0.000 description 1
150000001469 hydantoins Chemical class 0.000 description 1
230000036571 hydration Effects 0.000 description 1
238000006703 hydration reaction Methods 0.000 description 1
239000000413 hydrolysate Substances 0.000 description 1
150000002443 hydroxylamines Chemical class 0.000 description 1
229910052900 illite Inorganic materials 0.000 description 1
MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
230000006872 improvement Effects 0.000 description 1
229910017053 inorganic salt Inorganic materials 0.000 description 1
230000003993 interaction Effects 0.000 description 1
229940094522 laponite Drugs 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 1
239000000391 magnesium silicate Substances 0.000 description 1
235000012243 magnesium silicates Nutrition 0.000 description 1
WRIRWRKPLXCTFD-UHFFFAOYSA-N malonamide Chemical class NC(=O)CC(N)=O WRIRWRKPLXCTFD-UHFFFAOYSA-N 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
RTWNYYOXLSILQN-UHFFFAOYSA-N methanediamine Chemical compound NCN RTWNYYOXLSILQN-UHFFFAOYSA-N 0.000 description 1
230000005012 migration Effects 0.000 description 1
238000013508 migration Methods 0.000 description 1
150000004682 monohydrates Chemical class 0.000 description 1
239000000178 monomer Substances 0.000 description 1
QGILZBNKDUVXNM-UHFFFAOYSA-N n-methyl-n-methylsulfonyl-4-nitrobenzamide Chemical compound CS(=O)(=O)N(C)C(=O)C1=CC=C([N+]([O-])=O)C=C1 QGILZBNKDUVXNM-UHFFFAOYSA-N 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 description 1
229910000273 nontronite Inorganic materials 0.000 description 1
150000004967 organic peroxy acids Chemical class 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
125000004430 oxygen atom Chemical group O* 0.000 description 1
229910052625 palygorskite Inorganic materials 0.000 description 1
239000002304 perfume Substances 0.000 description 1
125000005342 perphosphate group Chemical group 0.000 description 1
LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical compound C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
BXRNXXXXHLBUKK-UHFFFAOYSA-N piperazine-2,5-dione Chemical compound O=C1CNC(=O)CN1 BXRNXXXXHLBUKK-UHFFFAOYSA-N 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920001282 polysaccharide Polymers 0.000 description 1
239000005017 polysaccharide Substances 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
229920003124 powdered cellulose Polymers 0.000 description 1
235000019814 powdered cellulose Nutrition 0.000 description 1
239000002243 precursor Substances 0.000 description 1
230000008569 process Effects 0.000 description 1
DJFSSKAXFAGDFE-UHFFFAOYSA-N prop-2-ene-1,2-diamine Chemical compound NCC(N)=C DJFSSKAXFAGDFE-UHFFFAOYSA-N 0.000 description 1
229910052903 pyrophyllite Inorganic materials 0.000 description 1
239000011435 rock Substances 0.000 description 1
229910000276 sauconite Inorganic materials 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
229940074404 sodium succinate Drugs 0.000 description 1
ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
239000007787 solid Substances 0.000 description 1
241000894007 species Species 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
235000000346 sugar Nutrition 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
150000004685 tetrahydrates Chemical class 0.000 description 1
150000003852 triazoles Chemical class 0.000 description 1
AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
229910052902 vermiculite Inorganic materials 0.000 description 1
239000010455 vermiculite Substances 0.000 description 1
235000019354 vermiculite Nutrition 0.000 description 1
229940117958 vinyl acetate Drugs 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3935—Bleach activators or bleach catalysts granulated, coated or protected
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds

Landscapes

Chemical & Material Sciences (AREA)
Inorganic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

CA000532482A 1986-03-25 1987-03-19 Granular non-phosphorus-containing bleach activator compositions and use thereof in granular detergent bleach compositions Expired - Fee Related CA1299460C (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GB8607388		1986-03-25
GB868607388A GB8607388D0 (en)	1986-03-25	1986-03-25	Activator compositions

Publications (1)

Publication Number	Publication Date
CA1299460C true CA1299460C (en)	1992-04-28

Family

ID=10595210

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000532482A Expired - Fee Related CA1299460C (en)	1986-03-25	1987-03-19	Granular non-phosphorus-containing bleach activator compositions and use thereof in granular detergent bleach compositions

Country Status (9)

Country	Link
EP (1)	EP0240057B2 (ja)
JP (1)	JPH0645800B2 (ja)
AU (1)	AU587315B2 (ja)
CA (1)	CA1299460C (ja)
DE (1)	DE3760055D1 (ja)
ES (1)	ES2008046T5 (ja)
GB (1)	GB8607388D0 (ja)
TR (1)	TR24553A (ja)
ZA (1)	ZA872199B (ja)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB8607387D0 (en) *	1986-03-25	1986-04-30	Unilever Plc	Activator compositions
US5002691A (en) *	1986-11-06	1991-03-26	The Clorox Company	Oxidant detergent containing stable bleach activator granules
DE3639115A1 (de) *	1986-11-15	1988-05-19	Henkel Kgaa	Lagerbestaendiges bleichmittelgemisch mit verbessertem loesungsvermoegen
EP0299575B1 (en) *	1987-07-14	1994-01-12	The Procter & Gamble Company	Detergent compositions
GB8810630D0 (en) *	1988-05-05	1988-06-08	Unilever Plc	Process for preparing bodies containing peroxyacid & compositions comprising said bodies
US5269962A (en) *	1988-10-14	1993-12-14	The Clorox Company	Oxidant composition containing stable bleach activator granules
GB8919006D0 (en) *	1989-08-21	1989-10-04	Unilever Plc	Granulated bleach activator particles
DE3938526A1 (de) *	1989-11-21	1991-05-23	Basf Ag	Verwendung von heterocyclischen verbindungen als bleichaktivatoren oder optische aufheller in wasch- und reinigungsmitteln
GB9022999D0 (en) *	1990-10-23	1990-12-05	Bp Chem Int Ltd	Bleach activators
AU4324693A (en) *	1992-06-18	1994-01-04	Unilever Plc	Machine dishwashing composition
DE4439039A1 (de) *	1994-11-02	1996-05-09	Hoechst Ag	Granulierte Bleichaktivatoren und ihre Herstellung
GB2294707A (en) *	1994-11-05	1996-05-08	Procter & Gamble	Bleaching composition
GB9422369D0 (en) *	1994-11-05	1995-01-04	Procter & Gamble	Detergent compositions
GB9424009D0 (en) *	1994-11-29	1995-01-18	Procter And Gamble The Company	Peroxyacid bleach precursor compositions
DE19605526A1 (de)	1996-02-15	1997-08-21	Hoechst Ag	Ammoniumnitrile und deren Verwendung als Bleichaktivatoren
DE19719397A1 (de) *	1997-05-07	1998-11-12	Clariant Gmbh	Bleichaktive Metall-Komplexe
DE19728021A1 (de) *	1997-07-01	1999-01-07	Clariant Gmbh	Metall-Komplexe als Bleichaktivatoren
DE19740671A1 (de) *	1997-09-16	1999-03-18	Clariant Gmbh	Bleichaktivator-Granulate
DE19740668A1 (de)	1997-09-16	1999-03-18	Clariant Gmbh	Lagerstabiles Bleichaktivator-Granulat
DE19841184A1 (de)	1998-09-09	2000-03-16	Clariant Gmbh	Bleichaktivatorgranulate
DE19943254A1 (de)	1999-09-10	2001-03-15	Clariant Gmbh	Bleichaktive Metallkomplexe
DE10019877A1 (de)	2000-04-20	2001-10-25	Clariant Gmbh	Wasch- und Reinigungsmittel enthaltend bleichaktive Dendrimer-Liganden und deren Metall-Komplexe
EP1894993A1 (de) *	2006-08-28	2008-03-05	Süd-Chemie Ag	Waschmitteladditiv auf der Basis von Tonmineralien und PVP-haltigen Copolymeren

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IE51848B1 (en) *	1980-11-06	1987-04-15	Procter & Gamble	Bleach activator compositions,preparation thereof and use in granular detergent compositions
AU549000B2 (en) *	1981-02-26	1986-01-09	Colgate-Palmolive Pty. Ltd.	Base beads for detergent compositions
DE3268039D1 (en) *	1981-09-28	1986-01-30	Basf Ag	Granular bleach activator
US4539131B1 (en) *	1982-06-25	1990-09-04	Lever Brothers Ltd	Solid detergent composition containing sodium perborate monohydrate having specified surface area
GB8328017D0 (en) *	1983-10-19	1983-11-23	Unilever Plc	Detergent powders
CA1275019A (en) *	1985-10-09	1990-10-09	The Procter & Gamble Company	Granular detergent compositions having improved solubility

1986
- 1986-03-25 GB GB868607388A patent/GB8607388D0/en active Pending
1987
- 1987-03-12 DE DE8787200466T patent/DE3760055D1/de not_active Expired
- 1987-03-12 ES ES87200466T patent/ES2008046T5/es not_active Expired
- 1987-03-12 EP EP87200466A patent/EP0240057B2/en not_active Expired - Lifetime
- 1987-03-19 CA CA000532482A patent/CA1299460C/en not_active Expired - Fee Related
- 1987-03-20 AU AU70507/87A patent/AU587315B2/en not_active Ceased
- 1987-03-25 JP JP62071315A patent/JPH0645800B2/ja not_active Expired - Lifetime
- 1987-03-25 ZA ZA872199A patent/ZA872199B/xx unknown
- 1987-03-25 TR TR87/0202A patent/TR24553A/xx unknown

Also Published As

Publication number	Publication date
AU7050787A (en)	1987-10-01
EP0240057A1 (en)	1987-10-07
ES2008046B3 (es)	1989-07-01
EP0240057B1 (en)	1989-03-01
ES2008046T5 (es)	1995-08-01
GB8607388D0 (en)	1986-04-30
DE3760055D1 (en)	1989-04-06
TR24553A (tr)	1991-11-21
EP0240057B2 (en)	1993-09-22
JPH0645800B2 (ja)	1994-06-15
ZA872199B (en)	1988-11-30
JPS62240395A (ja)	1987-10-21
AU587315B2 (en)	1989-08-10

Legal Events

Date	Code	Title	Description
1998-04-28	MKLA	Lapsed

Publication	Publication Date	Title
EP0240057B2 (en)	1993-09-22	Granular non-phosphorus-containing bleach activator compositions and use thereof in granular detergent bleach compositions
US4259200A (en)	1981-03-31	Bleaching and cleaning compositions
US6133216A (en)	2000-10-17	Coated ammonium nitrile bleach activator granules
CA1152845A (en)	1983-08-30	Granular laundry compositions
US4444674A (en)	1984-04-24	Granular bleach activator compositions and detergent compositions containing them
US4422950A (en)	1983-12-27	Bleach activator granules and preparation thereof
CA2304033A1 (en)	1999-03-25	Coated ammonium nitrile bleach activator granules
CA1214705A (en)	1986-12-02	Detergent composition
KR910006073B1 (ko)	1991-08-12	저장-안정성 표백 시스템-함유 세탁제
EP0213953A2 (en)	1987-03-11	Antifoam ingredient for detergent compositions
CA1191067A (en)	1985-07-30	Cleaning composition
EP0242138A2 (en)	1987-10-21	Process for the preparation of detergent powders
JPH04321513A (ja)	1992-11-11	ケイ酸塩組成物
US4333844A (en)	1982-06-08	Detergent compositions
EP0241962B1 (en)	1990-05-16	Granular non-phosphorus detergent bleach compositions
JPH04292411A (ja)	1992-10-16	ケイ酸塩
CA1316790C (en)	1993-04-27	Non-phosphorus detergent bleach compositions
CA2216813C (en)	2002-02-19	Process for producing granular detergent components or compositions
EP0870008B1 (en)	2006-10-18	Process for producing granular detergent components or compositions
IE57965B1 (en)	1993-06-02	Peroxygen bleach activators and bleaching compositions
EP0056723B1 (en)	1984-12-05	Detergent compositions
EP0070191B1 (en)	1985-12-04	Detergent additives and detergent compositions containing them
CA1182026A (en)	1985-02-05	Detergent compositions
US6140301A (en)	2000-10-31	Process for producing granular detergent components or compositions
US5925614A (en)	1999-07-20	Process for producing granular detergent components or compositions