CA1300852C - Four a procede claus - Google Patents

Four a procede claus

Info

Publication number: CA1300852C
Authority: CA; Canada
Prior art keywords: mol; reaction furnace; claus reaction; gas; catalyst structure
Prior art date: 1988-02-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000559513A

Other languages

English (en)

Inventor

Edward Adrian Luinstra

Charles Terrel Adams

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Shell Canada Ltd

Original Assignee

Shell Canada Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-02-23

Filing date

1988-02-23

Publication date

1992-05-19

1988-02-23 Application filed by Shell Canada Ltd filed Critical Shell Canada Ltd

1988-02-23 Priority to CA000559513A priority Critical patent/CA1300852C/fr

1989-02-21 Priority to GB8903916A priority patent/GB2221853A/en

1992-05-19 Application granted granted Critical

1992-05-19 Publication of CA1300852C publication Critical patent/CA1300852C/fr

2009-05-19 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

238000006243 chemical reaction Methods 0.000 title claims abstract description 51
239000003054 catalyst Substances 0.000 claims abstract description 35
239000013543 active substance Substances 0.000 claims abstract description 11
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 8
239000011148 porous material Substances 0.000 claims abstract description 5
239000002245 particle Substances 0.000 claims description 4
239000011449 brick Substances 0.000 claims description 2
229910052878 cordierite Inorganic materials 0.000 claims description 2
JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims description 2
KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 2
239000012530 fluid Substances 0.000 claims description 2
229910052863 mullite Inorganic materials 0.000 claims description 2
239000011819 refractory material Substances 0.000 claims description 2
239000007789 gas Substances 0.000 description 56
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 32
239000005864 Sulphur Substances 0.000 description 25
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 25
QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 24
239000000203 mixture Substances 0.000 description 21
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 20
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 16
230000003197 catalytic effect Effects 0.000 description 13
229910002092 carbon dioxide Inorganic materials 0.000 description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
239000004291 sulphur dioxide Substances 0.000 description 8
235000010269 sulphur dioxide Nutrition 0.000 description 8
JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 7
238000002474 experimental method Methods 0.000 description 7
238000011084 recovery Methods 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
230000002378 acidificating effect Effects 0.000 description 4
229910052799 carbon Inorganic materials 0.000 description 4
239000001569 carbon dioxide Substances 0.000 description 4
229930195733 hydrocarbon Natural products 0.000 description 4
150000002430 hydrocarbons Chemical class 0.000 description 4
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
239000004215 Carbon black (E152) Substances 0.000 description 3
239000000446 fuel Substances 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
239000000306 component Substances 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
235000012239 silicon dioxide Nutrition 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
101100425082 Emericella nidulans (strain FGSC A4 / ATCC 38163 / CBS 112.46 / NRRL 194 / M139) thiA gene Proteins 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
229910000272 alkali metal oxide Inorganic materials 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
229910052906 cristobalite Inorganic materials 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
239000012535 impurity Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
229920000136 polysorbate Polymers 0.000 description 1
239000010453 quartz Substances 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
101150080237 thiF gene Proteins 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
239000002918 waste heat Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/0426—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process characterised by the catalytic conversion
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/0426—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process characterised by the catalytic conversion
- C01B17/0434—Catalyst compositions

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Inorganic Chemistry (AREA)
Catalysts (AREA)
Exhaust Gas Treatment By Means Of Catalyst (AREA)

CA000559513A 1988-02-23 1988-02-23 Four a procede claus Expired - Fee Related CA1300852C (fr)

Priority Applications (2)

Application Number	Priority Date	Filing Date	Title
CA000559513A CA1300852C (fr)	1988-02-23	1988-02-23	Four a procede claus
GB8903916A GB2221853A (en)	1988-02-23	1989-02-21	Claus reaction furnace

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA000559513A CA1300852C (fr)	1988-02-23	1988-02-23	Four a procede claus

Publications (1)

Publication Number	Publication Date
CA1300852C true CA1300852C (fr)	1992-05-19

Family

ID=4137499

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000559513A Expired - Fee Related CA1300852C (fr)	1988-02-23	1988-02-23	Four a procede claus

Country Status (2)

Country	Link
CA (1)	CA1300852C (fr)
GB (1)	GB2221853A (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE10233820A1 (de) *	2002-07-25	2004-02-12	Thyssenkrupp Encoke Gmbh	Spaltreaktor für eine Claus-Anlage
DE10233819A1 (de) *	2002-07-25	2004-02-12	Thyssenkrupp Encoke Gmbh	Verfahren zur Abtrennung von Schwefelwasserstoff aus Koksofengas mit nachfolgender Gewinnung von elementarem Schwefel in einer Claus-Anlage

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1317168A (en) *	1970-07-13	1973-05-16	Shell Int Research	Porous media burner
GB1473943A (en) *	1974-04-17	1977-05-18	Uop Inc	Recuperative form of thermal-catalytic incinerator
GB1536866A (en) *	1976-10-15	1978-12-20	Horstmann Gear Co Ltd	Thread and worm grinding and milling machines
FR2481145A1 (fr) *	1980-04-23	1981-10-30	Rhone Poulenc Ind	Procede de fabrication de catalyseurs ou de supports de catalyseurs faconnes a base d'oxyde de titane et leurs applications a la catalyse claus
DE3535815A1 (de) *	1985-10-08	1987-04-09	Metallgesellschaft Ag	Verfahren zum reinigen von schwefelwasserstoff und schwefeldioxid enthaltendem abgas

1988
- 1988-02-23 CA CA000559513A patent/CA1300852C/fr not_active Expired - Fee Related
1989
- 1989-02-21 GB GB8903916A patent/GB2221853A/en not_active Withdrawn

Also Published As

Publication number	Publication date
GB2221853A (en)	1990-02-21
GB8903916D0 (en)	1989-04-05

Legal Events

Date	Code	Title	Description
2002-05-21	MKLA	Lapsed

Publication	Publication Date	Title
US4382912A (en)	1983-05-10	Selective combusting of hydrogen sulfide in carbon dioxide injection gas
US7357908B2 (en)	2008-04-15	Apparatus and catalytic partial oxidation process for recovering sulfur from an H2S-containing gas stream
US7108842B2 (en)	2006-09-19	Process for the catalytic partial oxidation of H2S using staged addition of oxygen
CA1212817A (fr)	1986-10-21	Attenuation de la temperature dans une unite claus de production de soufre avec enrichissement en oxygene
SU1709900A3 (ru)	1992-01-30	Способ извлечени серы из сероводородсодержащих газов
US7138101B2 (en)	2006-11-21	Two-stage catalytic process for recovering sulfur from an H2S-containing gas stream
WO2002032810A1 (fr)	2002-04-25	Procede et appareil destines a eliminer un compose sulfure a partir d'un gaz contenant de l'hydrogene sulfure, du mercaptan, du dioxyde de carbone et un hydrocarbure aromatique
US6800269B2 (en)	2004-10-05	Short contact time catalytic sulfur recovery system for removing H2S from a waste gas stream
JPS59182205A (ja)	1984-10-17	Ｈ↓２ｓ含有ガスより硫黄を製造するための接触的方法
AU728951B2 (en)	2001-01-18	Process for the desulphurization of gaseous substrate
JP2594805B2 (ja)	1997-03-26	二重燃焼酸素―エンリッチドクラウスサルファープラント
IT8222893A1 (it)	1984-02-19	Procedimento catalitico per la produzione di zolfo a partire da un gas contenente h2s
US6780392B2 (en)	2004-08-24	Method and device for converting hydrogen sulfide into elemental sulfur
RU1837957C (ru)	1993-08-30	Катализатор дл обработки газов, содержащих серные соединени
CA1300852C (fr)	1992-05-19	Four a procede claus
GB2513962A (en)	2014-11-12	Catalytic treatment
US6083466A (en)	2000-07-04	Process for partial oxidation of a gas stream containing hydrogen sulphide
EP1866061A1 (fr)	2007-12-19	Procede de production d'un flux gazeux appauvri en sulfure d'hydrogene
EP1355719B1 (fr)	2009-06-24	Systeme catalytique de recuperation de soufre pour enlever h2s a temps de contact court
CA1047224A (fr)	1979-01-30	Elimination de l'acide cyanhydrique.
AU2002245145A1 (en)	2003-02-06	Short contact time catalytic sulfur recovery system for removing H2S from a waste gas stream
CA2177299A1 (fr)	1996-11-27	Recuperation de soufre, amelioree par un gaz enrichi en oxygene, provenant de membranes separatrices de gaz
CA2090594A1 (fr)	1993-09-19	Traitement de dechets ou autres matieres