CA1333488C - Procede de preparation de produits d'oxydation du petrole a exces de base - Google Patents

Procede de preparation de produits d'oxydation du petrole a exces de base

Info

Publication number: CA1333488C
Authority: CA; Canada
Prior art keywords: overbased; petroleum; oxidate; mixture; oil
Prior art date: 1986-11-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000616721A

Other languages

English (en)

Inventor

Francis John Slama

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Ethyl Corp

Original Assignee

BP Corp North America Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-11-19

Filing date

1993-07-14

Publication date

1994-12-13

1986-11-19 Priority claimed from US06/932,305 external-priority patent/US5013463A/en

1993-07-14 Application filed by BP Corp North America Inc filed Critical BP Corp North America Inc

1993-07-14 Priority to CA000616721A priority Critical patent/CA1333488C/fr

1994-12-13 Application granted granted Critical

1994-12-13 Publication of CA1333488C publication Critical patent/CA1333488C/fr

2007-11-12 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000003208 petroleum Substances 0.000 title claims abstract description 84
238000000034 method Methods 0.000 title claims abstract description 50
230000008569 process Effects 0.000 title claims description 38
239000002585 base Substances 0.000 claims abstract description 41
-1 phenates Chemical class 0.000 claims abstract description 29
150000001341 alkaline earth metal compounds Chemical class 0.000 claims abstract description 11
239000003607 modifier Substances 0.000 claims abstract description 9
230000001590 oxidative effect Effects 0.000 claims abstract description 9
239000000203 mixture Substances 0.000 claims description 50
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 38
229910052791 calcium Inorganic materials 0.000 claims description 26
239000011575 calcium Substances 0.000 claims description 26
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 25
239000011777 magnesium Substances 0.000 claims description 25
229910052749 magnesium Inorganic materials 0.000 claims description 25
238000007254 oxidation reaction Methods 0.000 claims description 25
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 23
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 23
230000003647 oxidation Effects 0.000 claims description 21
239000011734 sodium Substances 0.000 claims description 17
229910052708 sodium Inorganic materials 0.000 claims description 17
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 16
229910052783 alkali metal Inorganic materials 0.000 claims description 10
150000001340 alkali metals Chemical class 0.000 claims description 10
238000006243 chemical reaction Methods 0.000 claims description 8
150000001875 compounds Chemical class 0.000 claims description 7
YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 claims description 7
229960001860 salicylate Drugs 0.000 claims description 7
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 6
239000003513 alkali Substances 0.000 claims description 6
230000000694 effects Effects 0.000 claims description 6
ZMRQTIAUOLVKOX-UHFFFAOYSA-L calcium;diphenoxide Chemical compound [Ca+2].[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1 ZMRQTIAUOLVKOX-UHFFFAOYSA-L 0.000 claims 1
150000003873 salicylate salts Chemical class 0.000 abstract description 12
239000003599 detergent Substances 0.000 abstract description 11
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 11
239000000758 substrate Substances 0.000 abstract description 11
150000001339 alkali metal compounds Chemical class 0.000 abstract description 8
239000002270 dispersing agent Substances 0.000 abstract description 6
239000003112 inhibitor Substances 0.000 abstract description 6
238000003860 storage Methods 0.000 abstract description 3
150000003871 sulfonates Chemical class 0.000 abstract 2
230000005764 inhibitory process Effects 0.000 abstract 1
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 45
239000000047 product Substances 0.000 description 44
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 29
239000003921 oil Substances 0.000 description 28
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 27
235000001055 magnesium Nutrition 0.000 description 23
229940091250 magnesium supplement Drugs 0.000 description 23
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 21
125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 18
239000003054 catalyst Substances 0.000 description 16
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 14
229910002092 carbon dioxide Inorganic materials 0.000 description 14
239000000654 additive Substances 0.000 description 13
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 11
239000008096 xylene Substances 0.000 description 11
239000001569 carbon dioxide Substances 0.000 description 10
229910052751 metal Inorganic materials 0.000 description 10
239000002184 metal Substances 0.000 description 10
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
238000002360 preparation method Methods 0.000 description 9
239000000344 soap Substances 0.000 description 9
150000001342 alkaline earth metals Chemical class 0.000 description 8
238000001914 filtration Methods 0.000 description 8
239000010687 lubricating oil Substances 0.000 description 8
238000010992 reflux Methods 0.000 description 8
PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 7
239000002480 mineral oil Substances 0.000 description 7
150000003839 salts Chemical class 0.000 description 7
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
229910052788 barium Inorganic materials 0.000 description 6
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 6
239000007789 gas Substances 0.000 description 6
238000010438 heat treatment Methods 0.000 description 6
239000000463 material Substances 0.000 description 6
235000010446 mineral oil Nutrition 0.000 description 6
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
230000002378 acidificating effect Effects 0.000 description 5
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 5
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 5
239000000920 calcium hydroxide Substances 0.000 description 5
235000011116 calcium hydroxide Nutrition 0.000 description 5
229940095643 calcium hydroxide Drugs 0.000 description 5
229910001861 calcium hydroxide Inorganic materials 0.000 description 5
235000011089 carbon dioxide Nutrition 0.000 description 5
239000003795 chemical substances by application Substances 0.000 description 5
239000000395 magnesium oxide Substances 0.000 description 5
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 5
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 5
229910000000 metal hydroxide Inorganic materials 0.000 description 5
150000004692 metal hydroxides Chemical class 0.000 description 5
229910052700 potassium Inorganic materials 0.000 description 5
239000011591 potassium Substances 0.000 description 5
239000002904 solvent Substances 0.000 description 5
229910052712 strontium Inorganic materials 0.000 description 5
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 5
238000012360 testing method Methods 0.000 description 5
235000008733 Citrus aurantifolia Nutrition 0.000 description 4
235000011941 Tilia x europaea Nutrition 0.000 description 4
230000000996 additive effect Effects 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
239000000292 calcium oxide Substances 0.000 description 4
238000002485 combustion reaction Methods 0.000 description 4
239000000706 filtrate Substances 0.000 description 4
229930195733 hydrocarbon Natural products 0.000 description 4
150000002430 hydrocarbons Chemical class 0.000 description 4
239000004571 lime Substances 0.000 description 4
239000001301 oxygen Substances 0.000 description 4
229910052760 oxygen Inorganic materials 0.000 description 4
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
235000011121 sodium hydroxide Nutrition 0.000 description 4
150000003460 sulfonic acids Chemical class 0.000 description 4
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
239000002199 base oil Substances 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
159000000007 calcium salts Chemical class 0.000 description 3
238000007796 conventional method Methods 0.000 description 3
239000010779 crude oil Substances 0.000 description 3
239000003480 eluent Substances 0.000 description 3
238000010828 elution Methods 0.000 description 3
238000005755 formation reaction Methods 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
150000004679 hydroxides Chemical class 0.000 description 3
150000007529 inorganic bases Chemical class 0.000 description 3
239000007788 liquid Substances 0.000 description 3
239000000314 lubricant Substances 0.000 description 3
230000001050 lubricating effect Effects 0.000 description 3
238000002156 mixing Methods 0.000 description 3
230000003472 neutralizing effect Effects 0.000 description 3
239000007800 oxidant agent Substances 0.000 description 3
239000001294 propane Substances 0.000 description 3
239000000741 silica gel Substances 0.000 description 3
229910002027 silica gel Inorganic materials 0.000 description 3
239000000126 substance Substances 0.000 description 3
RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical class [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
150000001447 alkali salts Chemical class 0.000 description 2
229910052728 basic metal Inorganic materials 0.000 description 2
239000001110 calcium chloride Substances 0.000 description 2
229910001628 calcium chloride Inorganic materials 0.000 description 2
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
150000004649 carbonic acid derivatives Chemical class 0.000 description 2
150000007942 carboxylates Chemical class 0.000 description 2
230000015556 catabolic process Effects 0.000 description 2
239000000306 component Substances 0.000 description 2
238000001816 cooling Methods 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
230000007797 corrosion Effects 0.000 description 2
238000009472 formulation Methods 0.000 description 2
238000010348 incorporation Methods 0.000 description 2
229910052744 lithium Inorganic materials 0.000 description 2
230000000051 modifying effect Effects 0.000 description 2
229910017604 nitric acid Inorganic materials 0.000 description 2
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
229940083608 sodium hydroxide Drugs 0.000 description 2
238000000638 solvent extraction Methods 0.000 description 2
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 1
KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
241001061260 Emmelichthys struhsakeri Species 0.000 description 1
NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
KEQFTVQCIQJIQW-UHFFFAOYSA-N N-Phenyl-2-naphthylamine Chemical compound C=1C=C2C=CC=CC2=CC=1NC1=CC=CC=C1 KEQFTVQCIQJIQW-UHFFFAOYSA-N 0.000 description 1
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
210000001217 buttock Anatomy 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
229910001576 calcium mineral Inorganic materials 0.000 description 1
150000001734 carboxylic acid salts Chemical class 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
229910000423 chromium oxide Inorganic materials 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
ZWWCURLKEXEFQT-UHFFFAOYSA-N dinitrogen pentaoxide Chemical compound [O-][N+](=O)O[N+]([O-])=O ZWWCURLKEXEFQT-UHFFFAOYSA-N 0.000 description 1
LZDSILRDTDCIQT-UHFFFAOYSA-N dinitrogen trioxide Chemical compound [O-][N+](=O)N=O LZDSILRDTDCIQT-UHFFFAOYSA-N 0.000 description 1
238000004821 distillation Methods 0.000 description 1
JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000005194 fractionation Methods 0.000 description 1
239000000446 fuel Substances 0.000 description 1
239000004519 grease Substances 0.000 description 1
159000000011 group IA salts Chemical class 0.000 description 1
239000002815 homogeneous catalyst Substances 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
229960002163 hydrogen peroxide Drugs 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000012535 impurity Substances 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000004922 lacquer Substances 0.000 description 1
239000011133 lead Substances 0.000 description 1
239000003879 lubricant additive Substances 0.000 description 1
FYYHWMGAXLPEAU-OUBTZVSYSA-N magnesium-25 atom Chemical compound [25Mg] FYYHWMGAXLPEAU-OUBTZVSYSA-N 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
229940043265 methyl isobutyl ketone Drugs 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
238000003359 percent control normalization Methods 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
239000012286 potassium permanganate Substances 0.000 description 1
229940114930 potassium stearate Drugs 0.000 description 1
ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
239000002994 raw material Substances 0.000 description 1
238000007127 saponification reaction Methods 0.000 description 1
229930195734 saturated hydrocarbon Natural products 0.000 description 1
239000012056 semi-solid material Substances 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
239000010802 sludge Substances 0.000 description 1
PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
239000011343 solid material Substances 0.000 description 1
239000011877 solvent mixture Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
238000010998 test method Methods 0.000 description 1
239000003039 volatile agent Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Landscapes

Lubricants (AREA)

CA000616721A 1986-11-19 1993-07-14 Procede de preparation de produits d'oxydation du petrole a exces de base Expired - Fee Related CA1333488C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000616721A CA1333488C (fr)	1986-11-19	1993-07-14	Procede de preparation de produits d'oxydation du petrole a exces de base

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US07/932,305		1986-11-19
US06/932,305 US5013463A (en)	1986-11-19	1986-11-19	Process for overbased petroleum oxidate
CA000551667A CA1330805C (fr)	1986-11-19	1987-11-12	Procede pour preparer des composes d'oxydation du petrole, a exces de base
CA000616721A CA1333488C (fr)	1986-11-19	1993-07-14	Procede de preparation de produits d'oxydation du petrole a exces de base

Related Parent Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000551667A Division CA1330805C (fr)	1986-11-19	1987-11-12	Procede pour preparer des composes d'oxydation du petrole, a exces de base

Publications (1)

Publication Number	Publication Date
CA1333488C true CA1333488C (fr)	1994-12-13

Family

ID=25671586

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000616721A Expired - Fee Related CA1333488C (fr)	1986-11-19	1993-07-14	Procede de preparation de produits d'oxydation du petrole a exces de base

Country Status (1)

Country	Link
CA (1)	CA1333488C (fr)

1993
- 1993-07-14 CA CA000616721A patent/CA1333488C/fr not_active Expired - Fee Related

Legal Events

Date	Code	Title	Description
1997-12-15	MKLA	Lapsed

Publication	Publication Date	Title
US3493516A (en)	1970-02-03	Carboxylate modified phenates
US4171269A (en)	1979-10-16	Sulfurized lubricant composition
US4057504A (en)	1977-11-08	Method of preparing overbased lubricating oil additives
CA1330805C (fr)	1994-07-19	Procede pour preparer des composes d'oxydation du petrole, a exces de base
US4880550A (en)	1989-11-14	Preparation of high base calcium sulfonates
EP1935970A1 (fr)	2008-06-25	Composition d'huile de lubrifiant pour cylindre diesel
US4302342A (en)	1981-11-24	Process for the preparation of detergent dispersants of high alkalinity for lubricating oils and the product obtained therefrom
US5578235A (en)	1996-11-26	Overbased calcium sulfonate
US4435301A (en)	1984-03-06	Preparation of overbased magnesium phenates
US6642190B2 (en)	2003-11-04	Overbased detergent additives
CA1332602C (fr)	1994-10-18	Detergent lubrifiant a base de phenate surbasique, possedant une tolerance a l'eau amelioree
US4169799A (en)	1979-10-02	Lubricating oil composition
JP2013082948A (ja)	2013-05-09	アルカリ土類金属ホウ酸化スルホネートの製造方法
US5922655A (en)	1999-07-13	Magnesium low rate number sulphonates
US4171270A (en)	1979-10-16	Sulfurized overbased calcium alkylphenolate lubricant composition
US4867891A (en)	1989-09-19	Overbased alkali metal sulfonates
CA1333488C (fr)	1994-12-13	Procede de preparation de produits d'oxydation du petrole a exces de base
CA2273191A1 (fr)	2000-05-05	Alkylarylsulfonate legerement surbase, exempt de chlore et de faible viscosite, ses applications comme additif pour huile de lubrification, et methodes de preparation
US4614602A (en)	1986-09-30	Lubricant overbased detergent-dispersants with improved solubility
JPH02131460A (ja)	1990-05-21	過塩基性スルホン酸塩及びその添加剤としての使用
EP1236792B1 (fr)	2007-01-03	Utilisation d' additifs détergents superbasiques pour mettre des composés d'asphaltene en suspension
CA1234155A (fr)	1988-03-15	Preparation de phenates sulfures surbases
JPH03153794A (ja)	1991-07-01	銅化合物又は銅及びホウ素の化合物を含有する潤滑油用過塩基性添加剤、その製造方法並びに該添加剤を含有する組成物
EP0537840B1 (fr)	1996-07-17	Compositions lubrifiantes contenant des sels de métaux alcalino-terreux surbasiques d'acides hydroxyalkylsulphoniques
CA2545952C (fr)	2013-10-15	Detergent de sulfonate de calcium a indice de base eleve