CA1335134C - Composition a base de polyamide resistante a la penetration des fluorocarbures et des hydrocarbures - Google Patents

Composition a base de polyamide resistante a la penetration des fluorocarbures et des hydrocarbures

Info

Publication number: CA1335134C
Authority: CA; Canada
Prior art keywords: weight; percent; acid; ethylene; composition according
Prior art date: 1987-11-05
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000581961A

Other languages

English (en)

Inventor

Charles Driscoll Mason

Wesley Forrest Smith

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Honeywell International Inc

Original Assignee

AlliedSignal Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-11-05

Filing date

1988-11-02

Publication date

1995-04-04

1988-11-02 Application filed by AlliedSignal Inc filed Critical AlliedSignal Inc

1995-04-04 Application granted granted Critical

1995-04-04 Publication of CA1335134C publication Critical patent/CA1335134C/fr

2012-04-04 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 81
239000004952 Polyamide Substances 0.000 title claims abstract description 44
229920002647 polyamide Polymers 0.000 title claims abstract description 44
NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 title claims abstract description 27
229930195733 hydrocarbon Natural products 0.000 title abstract description 16
150000002430 hydrocarbons Chemical class 0.000 title abstract description 16
239000004215 Carbon black (E152) Substances 0.000 title abstract description 15
229920001971 elastomer Polymers 0.000 claims abstract description 42
239000005060 rubber Substances 0.000 claims abstract description 42
239000004014 plasticizer Substances 0.000 claims abstract description 32
-1 polyethylene Polymers 0.000 claims abstract description 31
229920000573 polyethylene Polymers 0.000 claims abstract description 23
239000004698 Polyethylene Substances 0.000 claims abstract description 22
239000004970 Chain extender Substances 0.000 claims abstract description 8
230000015556 catabolic process Effects 0.000 claims abstract description 7
238000006731 degradation reaction Methods 0.000 claims abstract description 7
229920001577 copolymer Polymers 0.000 claims description 29
JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims description 26
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 21
239000005977 Ethylene Substances 0.000 claims description 21
229920000642 polymer Polymers 0.000 claims description 12
150000003839 salts Chemical class 0.000 claims description 12
VXGAPBLISGTEKE-UHFFFAOYSA-N 2-methylbenzenesulfonamide;4-methylbenzenesulfonamide Chemical group CC1=CC=C(S(N)(=O)=O)C=C1.CC1=CC=CC=C1S(N)(=O)=O VXGAPBLISGTEKE-UHFFFAOYSA-N 0.000 claims description 10
239000002253 acid Substances 0.000 claims description 10
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 10
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 8
239000000178 monomer Substances 0.000 claims description 8
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 8
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 6
150000008064 anhydrides Chemical class 0.000 claims description 6
XLYMOEINVGRTEX-UHFFFAOYSA-N fumaric acid monoethyl ester Natural products CCOC(=O)C=CC(O)=O XLYMOEINVGRTEX-UHFFFAOYSA-N 0.000 claims description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 5
150000002148 esters Chemical class 0.000 claims description 5
229910052751 metal Inorganic materials 0.000 claims description 5
239000002184 metal Substances 0.000 claims description 5
XLYMOEINVGRTEX-ONEGZZNKSA-N (e)-4-ethoxy-4-oxobut-2-enoic acid Chemical compound CCOC(=O)\C=C\C(O)=O XLYMOEINVGRTEX-ONEGZZNKSA-N 0.000 claims description 4
IPRJXAGUEGOFGG-UHFFFAOYSA-N N-butylbenzenesulfonamide Chemical compound CCCCNS(=O)(=O)C1=CC=CC=C1 IPRJXAGUEGOFGG-UHFFFAOYSA-N 0.000 claims description 4
150000001299 aldehydes Chemical class 0.000 claims description 4
239000001530 fumaric acid Substances 0.000 claims description 4
150000002576 ketones Chemical class 0.000 claims description 4
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 4
239000011976 maleic acid Substances 0.000 claims description 4
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 4
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 3
WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 claims description 3
CGPRUXZTHGTMKW-UHFFFAOYSA-N ethene;ethyl prop-2-enoate Chemical class C=C.CCOC(=O)C=C CGPRUXZTHGTMKW-UHFFFAOYSA-N 0.000 claims description 3
150000002170 ethers Chemical class 0.000 claims description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
230000009477 glass transition Effects 0.000 claims description 3
150000004820 halides Chemical class 0.000 claims description 3
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 3
XUDBVJCTLZTSDC-UHFFFAOYSA-N 2-ethenylbenzoic acid Chemical compound OC(=O)C1=CC=CC=C1C=C XUDBVJCTLZTSDC-UHFFFAOYSA-N 0.000 claims description 2
XLYMOEINVGRTEX-ARJAWSKDSA-N Ethyl hydrogen fumarate Chemical compound CCOC(=O)\C=C/C(O)=O XLYMOEINVGRTEX-ARJAWSKDSA-N 0.000 claims description 2
AEMRFAOFKBGASW-UHFFFAOYSA-M Glycolate Chemical compound OCC([O-])=O AEMRFAOFKBGASW-UHFFFAOYSA-M 0.000 claims description 2
229910019142 PO4 Inorganic materials 0.000 claims description 2
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 2
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical class C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 claims description 2
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 2
229920006244 ethylene-ethyl acrylate Polymers 0.000 claims description 2
125000005843 halogen group Chemical group 0.000 claims description 2
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 2
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
239000010452 phosphate Substances 0.000 claims description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims description 2
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
125000005591 trimellitate group Chemical group 0.000 claims description 2
KBIWOJBFYNSQKW-UHFFFAOYSA-N 3-ethenylphthalic acid Chemical compound OC(=O)C1=CC=CC(C=C)=C1C(O)=O KBIWOJBFYNSQKW-UHFFFAOYSA-N 0.000 claims 1
239000007795 chemical reaction product Substances 0.000 claims 1
125000005448 ethoxyethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])C([H])([H])* 0.000 claims 1
239000004677 Nylon Substances 0.000 description 12
229920001778 nylon Polymers 0.000 description 12
229920002292 Nylon 6 Polymers 0.000 description 10
230000000704 physical effect Effects 0.000 description 10
239000000463 material Substances 0.000 description 9
238000012360 testing method Methods 0.000 description 8
150000001875 compounds Chemical class 0.000 description 7
229920000554 ionomer Polymers 0.000 description 7
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 6
238000000034 method Methods 0.000 description 6
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
239000004711 α-olefin Substances 0.000 description 6
239000004716 Ethylene/acrylic acid copolymer Substances 0.000 description 5
229920000459 Nitrile rubber Polymers 0.000 description 5
239000006229 carbon black Substances 0.000 description 5
238000009833 condensation Methods 0.000 description 5
229920006226 ethylene-acrylic acid Polymers 0.000 description 5
239000000155 melt Substances 0.000 description 5
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
239000011701 zinc Substances 0.000 description 5
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical class [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
238000002156 mixing Methods 0.000 description 4
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
229910052725 zinc Inorganic materials 0.000 description 4
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 3
229920002302 Nylon 6,6 Polymers 0.000 description 3
229920000577 Nylon 6/66 Polymers 0.000 description 3
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
125000003277 amino group Chemical group 0.000 description 3
TZYHIGCKINZLPD-UHFFFAOYSA-N azepan-2-one;hexane-1,6-diamine;hexanedioic acid Chemical compound NCCCCCCN.O=C1CCCCCN1.OC(=O)CCCCC(O)=O TZYHIGCKINZLPD-UHFFFAOYSA-N 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
230000005494 condensation Effects 0.000 description 3
UFRKOOWSQGXVKV-UHFFFAOYSA-N ethene;ethenol Chemical compound C=C.OC=C UFRKOOWSQGXVKV-UHFFFAOYSA-N 0.000 description 3
229920001038 ethylene copolymer Polymers 0.000 description 3
239000004715 ethylene vinyl alcohol Substances 0.000 description 3
239000000835 fiber Substances 0.000 description 3
235000019253 formic acid Nutrition 0.000 description 3
238000012545 processing Methods 0.000 description 3
229940124530 sulfonamide Drugs 0.000 description 3
229920001897 terpolymer Polymers 0.000 description 3
239000008096 xylene Substances 0.000 description 3
GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 2
229920000181 Ethylene propylene rubber Polymers 0.000 description 2
ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical class C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical class [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
229920003182 Surlyn® Polymers 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
125000003368 amide group Chemical group 0.000 description 2
230000008901 benefit Effects 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
238000000576 coating method Methods 0.000 description 2
238000001816 cooling Methods 0.000 description 2
150000001991 dicarboxylic acids Chemical class 0.000 description 2
239000000975 dye Substances 0.000 description 2
229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 2
239000003063 flame retardant Substances 0.000 description 2
LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
239000000314 lubricant Substances 0.000 description 2
239000006082 mold release agent Substances 0.000 description 2
150000002825 nitriles Chemical class 0.000 description 2
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
239000000049 pigment Substances 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
229920002689 polyvinyl acetate Polymers 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
239000011591 potassium Chemical class 0.000 description 2
239000002994 raw material Substances 0.000 description 2
229920005989 resin Polymers 0.000 description 2
239000011347 resin Substances 0.000 description 2
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Chemical class 0.000 description 2
150000003456 sulfonamides Chemical class 0.000 description 2
DJZKNOVUNYPPEE-UHFFFAOYSA-N tetradecane-1,4,11,14-tetracarboxamide Chemical compound NC(=O)CCCC(C(N)=O)CCCCCCC(C(N)=O)CCCC(N)=O DJZKNOVUNYPPEE-UHFFFAOYSA-N 0.000 description 2
LMYRWZFENFIFIT-UHFFFAOYSA-N toluene-4-sulfonamide Chemical compound CC1=CC=C(S(N)(=O)=O)C=C1 LMYRWZFENFIFIT-UHFFFAOYSA-N 0.000 description 2
150000005207 1,3-dihydroxybenzenes Chemical class 0.000 description 1
150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
YCMLQMDWSXFTIF-UHFFFAOYSA-N 2-methylbenzenesulfonimidic acid Chemical compound CC1=CC=CC=C1S(N)(=O)=O YCMLQMDWSXFTIF-UHFFFAOYSA-N 0.000 description 1
WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 1
UFFRSDWQMJYQNE-UHFFFAOYSA-N 6-azaniumylhexylazanium;hexanedioate Chemical compound [NH3+]CCCCCC[NH3+].[O-]C(=O)CCCCC([O-])=O UFFRSDWQMJYQNE-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical class [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical class [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
JYGLAHSAISAEAL-UHFFFAOYSA-N Diphenadione Chemical compound O=C1C2=CC=CC=C2C(=O)C1C(=O)C(C=1C=CC=CC=1)C1=CC=CC=C1 JYGLAHSAISAEAL-UHFFFAOYSA-N 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
239000004594 Masterbatch (MB) Substances 0.000 description 1
229920000299 Nylon 12 Polymers 0.000 description 1
229920003189 Nylon 4,6 Polymers 0.000 description 1
229920000305 Nylon 6,10 Polymers 0.000 description 1
239000004714 Polar ethylene copolymer Substances 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
239000004372 Polyvinyl alcohol Substances 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
239000001361 adipic acid Substances 0.000 description 1
235000011037 adipic acid Nutrition 0.000 description 1
238000004378 air conditioning Methods 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
150000001413 amino acids Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
239000012965 benzophenone Substances 0.000 description 1
150000008366 benzophenones Chemical class 0.000 description 1
150000001565 benzotriazoles Chemical class 0.000 description 1
NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
229910052980 cadmium sulfide Inorganic materials 0.000 description 1
UHYPYGJEEGLRJD-UHFFFAOYSA-N cadmium(2+);selenium(2-) Chemical compound [Se-2].[Cd+2] UHYPYGJEEGLRJD-UHFFFAOYSA-N 0.000 description 1
239000011575 calcium Chemical class 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
150000007942 carboxylates Chemical group 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
239000003086 colorant Substances 0.000 description 1
238000013329 compounding Methods 0.000 description 1
230000003750 conditioning effect Effects 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Chemical class 0.000 description 1
WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
150000004985 diamines Chemical class 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
125000004185 ester group Chemical group 0.000 description 1
AIMMSZVCMQILDY-UHFFFAOYSA-N ethene;furan-2,5-dione;prop-1-ene Chemical compound C=C.CC=C.O=C1OC(=O)C=C1 AIMMSZVCMQILDY-UHFFFAOYSA-N 0.000 description 1
QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 1
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
239000005038 ethylene vinyl acetate Substances 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000000945 filler Substances 0.000 description 1
229920005570 flexible polymer Polymers 0.000 description 1
239000012530 fluid Substances 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
239000007789 gas Substances 0.000 description 1
229920000578 graft copolymer Polymers 0.000 description 1
125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
125000004356 hydroxy functional group Chemical group O* 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
229920000831 ionic polymer Polymers 0.000 description 1
150000003951 lactams Chemical class 0.000 description 1
239000011133 lead Chemical class 0.000 description 1
239000004611 light stabiliser Substances 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000005259 measurement Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
229910001507 metal halide Inorganic materials 0.000 description 1
150000005309 metal halides Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
229920003145 methacrylic acid copolymer Polymers 0.000 description 1
229940117841 methacrylic acid copolymer Drugs 0.000 description 1
239000003607 modifier Substances 0.000 description 1
238000000465 moulding Methods 0.000 description 1
GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
229920006113 non-polar polymer Polymers 0.000 description 1
LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical class CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
239000008188 pellet Substances 0.000 description 1
238000005453 pelletization Methods 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
230000035699 permeability Effects 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920006112 polar polymer Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
239000011118 polyvinyl acetate Substances 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
239000003507 refrigerant Substances 0.000 description 1
238000012552 review Methods 0.000 description 1
150000003873 salicylate salts Chemical class 0.000 description 1
238000007789 sealing Methods 0.000 description 1
239000002195 soluble material Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
238000010998 test method Methods 0.000 description 1
239000003017 thermal stabilizer Substances 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
239000004416 thermosoftening plastic Substances 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
238000004448 titration Methods 0.000 description 1
235000013799 ultramarine blue Nutrition 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
230000004580 weight loss Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)

CA000581961A 1987-11-05 1988-11-02 Composition a base de polyamide resistante a la penetration des fluorocarbures et des hydrocarbures Expired - Fee Related CA1335134C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US11692187A	1987-11-05	1987-11-05
US116,921		1987-11-05

Publications (1)

Publication Number	Publication Date
CA1335134C true CA1335134C (fr)	1995-04-04

Family

ID=22370047

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000581961A Expired - Fee Related CA1335134C (fr)	1987-11-05	1988-11-02	Composition a base de polyamide resistante a la penetration des fluorocarbures et des hydrocarbures

Country Status (6)

Country	Link
EP (1)	EP0386113A1 (fr)
JP (1)	JPH03500900A (fr)
KR (1)	KR890701694A (fr)
CA (1)	CA1335134C (fr)
MX (1)	MX169446B (fr)
WO (1)	WO1989004348A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5219665A (en) *	1991-01-30	1993-06-15	E. I. Du Pont De Nemours And Company	Fabricated articles with improved resistance to hydrohalocarbons
ATE211062T1 (de) *	1993-09-09	2002-01-15	Ausimont Spa	Mehrschichtstrukturen aus fluorierten und nicht- fluorierten thermoplastischen polymeren
BE1010820A3 (nl) *	1996-12-23	1999-02-02	Dsm Nv	Flexibele polyamidesamenstelling.
KR20010054434A (ko) *	1999-12-06	2001-07-02	이계안	폴리아미드 수지 조성물
KR100384014B1 (ko) *	2000-11-30	2003-05-14	현대자동차주식회사	내 가솔린성과 내한 충격성이 우수한 폴리아미드 수지조성물
KR100387850B1 (ko) *	2000-12-29	2003-06-18	현대자동차주식회사	폴리아미드 수지 조성물 및 이를 이용한 합성수지제품
WO2006121141A1 (fr) *	2005-05-10	2006-11-16	The Yokohama Rubber Co., Ltd.	Composition elastomere themoplastique

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4338413A (en) *	1980-10-16	1982-07-06	Monsanto Company	Polymer blends
US4404325A (en) *	1981-05-11	1983-09-13	Allied Corporation	High impact nylon composition containing copolymer esters and ionic copolymers
JPS5823850A (ja) *	1981-08-04	1983-02-12	Asahi Chem Ind Co Ltd	耐衝撃性ポリアミド組成物
JPS5829854A (ja) *	1981-08-17	1983-02-22	Toray Ind Inc	ポリアミド樹脂組成物
JPS6069159A (ja) *	1983-09-27	1985-04-19	Ube Ind Ltd	ポリアミド組成物の製法
CA1276341C (fr) *	1985-01-15	1990-11-13	James Francis Dunphy	Polyamide offrant une forte resistance aux impacts
DE3785472T2 (de) *	1986-01-07	1993-07-29	Tonen Sekiyukagaku Kk	Thermoplastische zusammensetzung.
JPS62241941A (ja) *	1986-04-14	1987-10-22	Tonen Sekiyukagaku Kk	熱可塑性樹脂組成物
KR960013123B1 (ko) *	1986-09-25	1996-09-30	셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이	내충격성 중합체 조성물 및 그 제조 방법
EP0327551B1 (fr) *	1986-10-20	1991-04-10	AlliedSignal Inc.	Melanges de polyamides, de polyolefines et de copolymeres ethylene-alcool vinylique

1988
- 1988-10-20 WO PCT/US1988/003688 patent/WO1989004348A1/fr not_active Ceased
- 1988-10-20 EP EP88910270A patent/EP0386113A1/fr not_active Withdrawn
- 1988-10-20 JP JP63509362A patent/JPH03500900A/ja active Pending
- 1988-10-20 KR KR1019890701223A patent/KR890701694A/ko not_active Withdrawn
- 1988-11-01 MX MX013636A patent/MX169446B/es unknown
- 1988-11-02 CA CA000581961A patent/CA1335134C/fr not_active Expired - Fee Related

Also Published As

Publication number	Publication date
JPH03500900A (ja)	1991-02-28
MX169446B (es)	1993-07-05
WO1989004348A1 (fr)	1989-05-18
EP0386113A1 (fr)	1990-09-12
KR890701694A (ko)	1989-12-21

Legal Events

Date	Code	Title	Description
1999-04-06	MKLA	Lapsed

Publication	Publication Date	Title
CA1177996A (fr)	1984-11-13	Composition a base de nylon resistant bien aux chocs et renfermant des copolymeres d'esters et des copolymeres ioniques
US4485214A (en)	1984-11-27	High impact polyamide composition
EP2670805B1 (fr)	2017-11-08	Composition thermoplastique obtenue par mélange à chaud
EP0234819B1 (fr)	1992-05-06	Compositions de résine thermoplastiques
CA1326092C (fr)	1994-01-11	Compositions de polyamide comportant du caoutchouc nitrile et un copolymere d'ethylene et d'alpha-olefine
JPS6215258A (ja)	1987-01-23	耐塩性ポリアミド組成物ならびにこれからなる物品およびその使用法
KR20180071430A (ko)	2018-06-27	내충격성 열가소성 조성물
EP0574532B1 (fr)	1996-08-21	Compositions thermoplastiques souples comprenant du nylon
AU2422592A (en)	1993-03-16	Blow moldable thermoplastic polyamide composition
EP2748260A2 (fr)	2014-07-02	Thermoplastique recyclé comprenant un durcisseur
JP2023552871A (ja)	2023-12-19	ポリアミド、ガラス繊維、および中空ガラス強化材をベースとする成形用組成物ならびにその使用
US5061757A (en)	1991-10-29	High impact strength polyamide blends and method for preparation thereof
AU743799B2 (en)	2002-02-07	Copolyamides and polyamide compositions, process of manufacture and applications
WO1989004348A1 (fr)	1989-05-18	Composition de polyamide resistant a la penetration de fluorocarbones et d'hydrocarbures
US6462129B1 (en)	2002-10-08	Thermoplastic resin compositions comprising a rigid dispersed phase
US4801633A (en)	1989-01-31	Salt resistant polyamide composition
US20110207885A1 (en)	2011-08-25	Toughened polyamide compositions
TWI846279B (zh)	2024-06-21	具有二聚酸和二聚胺的脂族和半芳族聚醯胺
US5453463A (en)	1995-09-26	Molding materials based on polyaryl ethers and toughened partly aromatic copolyamides
EP0389479B1 (fr)	1993-12-01	Compositions de polyamide a haute resistance aux chocs a basses temperatures
NO309485B1 (no)	2001-02-05	Fleksibel gjennomskinnelig blanding, samt anvendelse derav
US20130289148A1 (en)	2013-10-31	Toughened polyamide compositions
JPH0228256A (ja)	1990-01-30	安定化された樹脂組成物