CA2110904A1 - Procede pour la production d'olefines - Google Patents

Procede pour la production d'olefines

Info

Publication number: CA2110904A1
Authority: CA; Canada
Prior art keywords: zeolite; process according; member channel; intersected; alkyl
Prior art date: 1992-04-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA 2110904

Other languages

English (en)

Inventor

Martin P. Atkins

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BP Chemicals Ltd

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-04-22

Filing date

1993-04-20

Publication date

1993-10-28

1992-04-22 Priority claimed from GB929208739A external-priority patent/GB9208739D0/en

1992-05-18 Priority claimed from GB929210548A external-priority patent/GB9210548D0/en

1992-05-18 Priority claimed from GB929210560A external-priority patent/GB9210560D0/en

1992-05-22 Priority claimed from GB929210918A external-priority patent/GB9210918D0/en

1993-04-20 Application filed by Individual filed Critical Individual

1993-10-28 Publication of CA2110904A1 publication Critical patent/CA2110904A1/fr

Status Abandoned legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 33
150000001336 alkenes Chemical class 0.000 title claims abstract description 12
238000004519 manufacturing process Methods 0.000 title claims abstract description 7
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 38
239000010457 zeolite Substances 0.000 claims abstract description 36
229910021536 Zeolite Inorganic materials 0.000 claims abstract description 34
239000003054 catalyst Substances 0.000 claims abstract description 18
125000000217 alkyl group Chemical group 0.000 claims abstract description 13
125000001033 ether group Chemical group 0.000 claims abstract description 5
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 4
DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 14
BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 claims description 11
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 26
239000000047 product Substances 0.000 description 16
238000006243 chemical reaction Methods 0.000 description 15
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
238000011282 treatment Methods 0.000 description 5
238000004458 analytical method Methods 0.000 description 4
238000001354 calcination Methods 0.000 description 4
239000003085 diluting agent Substances 0.000 description 4
239000000377 silicon dioxide Substances 0.000 description 4
235000012239 silicon dioxide Nutrition 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
239000011230 binding agent Substances 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
238000005336 cracking Methods 0.000 description 3
239000007789 gas Substances 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
239000010453 quartz Substances 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
229920002367 Polyisobutene Polymers 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 2
229910021529 ammonia Inorganic materials 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
229910052906 cristobalite Inorganic materials 0.000 description 2
239000008187 granular material Substances 0.000 description 2
239000000017 hydrogel Substances 0.000 description 2
238000005342 ion exchange Methods 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
239000007788 liquid Substances 0.000 description 2
238000002156 mixing Methods 0.000 description 2
229910052680 mordenite Inorganic materials 0.000 description 2
125000001477 organic nitrogen group Chemical group 0.000 description 2
239000000843 powder Substances 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
229910001388 sodium aluminate Inorganic materials 0.000 description 2
229910001415 sodium ion Inorganic materials 0.000 description 2
238000003756 stirring Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
238000003786 synthesis reaction Methods 0.000 description 2
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
FVNIMHIOIXPIQT-UHFFFAOYSA-N 2-methoxybutane Chemical compound CCC(C)OC FVNIMHIOIXPIQT-UHFFFAOYSA-N 0.000 description 1
YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
239000002879 Lewis base Substances 0.000 description 1
208000032005 Spinocerebellar ataxia with axonal neuropathy type 2 Diseases 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
239000004411 aluminium Substances 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
235000011114 ammonium hydroxide Nutrition 0.000 description 1
208000033361 autosomal recessive with axonal neuropathy 2 spinocerebellar ataxia Diseases 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
239000004927 clay Substances 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000009089 cytolysis Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
239000003599 detergent Substances 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000000446 fuel Substances 0.000 description 1
239000002816 fuel additive Substances 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
238000007429 general method Methods 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
238000013101 initial test Methods 0.000 description 1
150000007527 lewis bases Chemical class 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000000203 mixture Substances 0.000 description 1
239000002808 molecular sieve Substances 0.000 description 1
229910000069 nitrogen hydride Inorganic materials 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
210000000056 organ Anatomy 0.000 description 1
125000004817 pentamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
-1 phosphorus compound Chemical class 0.000 description 1
239000011148 porous material Substances 0.000 description 1
238000000066 reactive distillation Methods 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
239000002002 slurry Substances 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
239000010959 steel Substances 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
238000001308 synthesis method Methods 0.000 description 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

CA 2110904 1992-04-22 1993-04-20 Procede pour la production d'olefines Abandoned CA2110904A1 (fr)

Applications Claiming Priority (8)

Application Number	Priority Date	Filing Date	Title
GB9208739.4		1992-04-22
GB929208739A GB9208739D0 (en)	1992-04-22	1992-04-22	Process for the production of isobutene
GB9210548.5		1992-05-18
GB929210548A GB9210548D0 (en)	1992-05-18	1992-05-18	Process for the production of isobutene
GB9210560.0		1992-05-18
GB929210560A GB9210560D0 (en)	1992-05-18	1992-05-18	Process for the production of isobutene
GB9210918.0		1992-05-22
GB929210918A GB9210918D0 (en)	1992-05-22	1992-05-22	Process for the production of isobutene

Publications (1)

Publication Number	Publication Date
CA2110904A1 true CA2110904A1 (fr)	1993-10-28

Family

ID=27450861

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2110904 Abandoned CA2110904A1 (fr)	1992-04-22	1993-04-20	Procede pour la production d'olefines

Country Status (4)

Country	Link
EP (1)	EP0591504A1 (fr)
JP (1)	JPH06508640A (fr)
CA (1)	CA2110904A1 (fr)
WO (1)	WO1993021139A1 (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE10327215A1 (de)	2003-06-17	2005-01-13	Oxeno Olefinchemie Gmbh	Verfahren zur Herstellung von Isobuten aus tert.-Butanol
EP1790627A1 (fr) *	2005-11-29	2007-05-30	BP Chemicals Limited	Procédé de production d'oléfines
AU2012245156A1 (en)	2011-04-21	2013-10-31	Shell Internationale Research Maatschappij B.V.	Process for converting a solid biomass material
CN103597056A (zh)	2011-04-21	2014-02-19	国际壳牌研究有限公司	转化固体生物质材料的方法
US9169444B2 (en)	2011-04-21	2015-10-27	Shell Oil Company	Liquid fuel composition
US8927794B2 (en)	2011-04-21	2015-01-06	Shell Oil Company	Process for regenerating a coked catalytic cracking catalyst
CN103889932A (zh) *	2011-09-07	2014-06-25	国际壳牌研究有限公司	由包含叔烷基醚的给料制备乙烯和丙烯的方法
EP2748130A1 (fr) *	2011-09-07	2014-07-02	Shell Internationale Research Maatschappij B.V.	Procédé pour la préparation d'éthylène et de propylène
CN103889933A (zh) *	2011-09-07	2014-06-25	国际壳牌研究有限公司	由包含叔烷基醚的给料制备乙烯和丙烯的方法
AU2012361005A1 (en) *	2011-12-27	2014-07-10	Shell Internationale Research Maatschappij B.V.	Molecular sieve catalyste and processes for formulating and using the same
WO2013160253A1 (fr)	2012-04-23	2013-10-31	Shell Internationale Research Maatschappij B.V.	Procédé de conversion d'un matériau de biomasse solide
SG11202003319WA (en) *	2017-10-26	2020-05-28	Lyondell Chemical Technology L P	Methods of producing propylene and ethylene
CN111116282B (zh) *	2018-10-30	2022-07-08	中国石油化工股份有限公司	叔丁醇制烯烃的方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4359595A (en) *	1980-04-28	1982-11-16	Mobil Oil Corporation	Selective production of olefins
DE3170195D1 (en) *	1980-12-19	1985-05-30	Ici Plc	Zeolites
DE3048084A1 (de) *	1980-12-19	1982-07-15	EC Erdölchemie GmbH, 5000 Köln	Verfahren zur herstellung von tertiaeren olefinen
DE3269577D1 (en) *	1981-05-20	1986-04-10	Ici Plc	Zeolites
NZ207523A (en) *	1983-04-22	1986-03-14	Mobil Oil Corp	Catalytic production of olefin mixtures from alcohols and/or ethers
US4476338A (en) *	1983-06-02	1984-10-09	Mobil Oil Corporation	Olefins from methanol and/or dimethyl ether
US5157192A (en) *	1991-11-12	1992-10-20	Mobil Oil Corporation	Conversion of tertiary alcohols to C8+ olefins

1993
- 1993-04-20 CA CA 2110904 patent/CA2110904A1/fr not_active Abandoned
- 1993-04-20 JP JP5518149A patent/JPH06508640A/ja active Pending
- 1993-04-20 EP EP93909070A patent/EP0591504A1/fr not_active Withdrawn
- 1993-04-20 WO PCT/GB1993/000823 patent/WO1993021139A1/fr not_active Ceased

Also Published As

Publication number	Publication date
JPH06508640A (ja)	1994-09-29
EP0591504A1 (fr)	1994-04-13
WO1993021139A1 (fr)	1993-10-28

Legal Events

Date	Code	Title	Description
1995-10-22	FZDE	Dead

Publication	Publication Date	Title
AU2007253396B2 (en)	2011-06-23	Process for the preparation of an olefin
US5210364A (en)	1993-05-11	Process for the preparation of branched olefins
US7268268B2 (en)	2007-09-11	Dimerization of olefins
CA2705013A1 (fr)	2009-05-28	Procede de preparation d'un produit olefinique
AU2007253393A1 (en)	2007-11-29	Process for the preparation of an olefin
US5503818A (en)	1996-04-02	Aluminosilicate catalyst, a process for the manufacture thereof and a process for the skeletal isomerization of linear olefins
CN102858718A (zh)	2013-01-02	制造用于醇脱水工艺的包含磷改性沸石的催化剂的方法
US20240359168A1 (en)	2024-10-31	Mesoporous Catalyst Compounds and Uses Thereof
WO2007135053A1 (fr)	2007-11-29	Procédé de préparation d'oléfines c5 et/ou c6
JPH07506831A (ja)	1995-07-27	Ｎ−オレフィンの骨格異性化方法
WO1993021139A1 (fr)	1993-10-28	Procede de production d'olefines
AU2329692A (en)	1993-03-02	Process for the conversion of hydrocarbons
US4548913A (en)	1985-10-22	Catalyst, a process for its preparation and an isomerization process in the presence of this catalyst
WO1994012452A1 (fr)	1994-06-09	Procede de production d'olefines ramifiees
US4918249A (en)	1990-04-17	Silicometallate molecular sieves and their use as catalysts in oxidation of alkanes
CA2055107A1 (fr)	1992-05-09	Procede d'obtention d'olefines ramifiees
US4665250A (en)	1987-05-12	Process for converting light olefins to gasoline, distillate and lube range hydrocarbons
US9120078B2 (en)	2015-09-01	Process for the preparation of an olefinic product, oxygenate conversion catalyst particles, and process for the manufacutre thereof
US5146029A (en)	1992-09-08	Olefin interconversion by shape selective catalysis
US4929791A (en)	1990-05-29	Catalytic conversion of propane to ethylene over ZSM-50
AU2007253402B2 (en)	2011-06-16	Process for the preparation of propylene from a hydrocarbon feed
US5243112A (en)	1993-09-07	Lubricant range hydrocarbons from light olefins
JPH0673383A (ja)	1994-03-15	線状オレフィンからなる供給原料の変換方法
EP0128721B1 (fr)	1989-07-26	Catalyseur modifié avec du silica et son application pour la production sélective de para-dialcoyl benzènes
WO1994015897A1 (fr)	1994-07-21	Conversion d'hydrocarbures