CA2112040C - Herbicides pulverulents se dispersant dans l'eau - Google Patents

Herbicides pulverulents se dispersant dans l'eau Download PDF

Info

Publication number: CA2112040C
Authority: CA; Canada
Prior art keywords: weight; sodium; carrier; water dispersible; mixture
Prior art date: 1992-12-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA 2112040

Other languages

English (en)

Other versions

CA2112040A1 (fr

Inventor

Joseph Kimler

Robert Kubisch

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF SE

Original Assignee

BASF SE

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-12-23

Filing date

1993-12-21

Publication date

2004-11-23

1992-12-23 Priority claimed from US07/996,221 external-priority patent/US5294594A/en

1992-12-23 Priority claimed from US07/996,412 external-priority patent/US5296450A/en

1993-12-21 Application filed by BASF SE filed Critical BASF SE

1994-06-24 Publication of CA2112040A1 publication Critical patent/CA2112040A1/fr

2004-11-23 Application granted granted Critical

2004-11-23 Publication of CA2112040C publication Critical patent/CA2112040C/fr

2013-12-21 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 92
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 32
230000002363 herbicidal effect Effects 0.000 title claims abstract description 31
239000004009 herbicide Substances 0.000 claims abstract description 40
239000003795 chemical substances by application Substances 0.000 claims abstract description 25
CAAMSDWKXXPUJR-UHFFFAOYSA-N 3,5-dihydro-4H-imidazol-4-one Chemical compound O=C1CNC=N1 CAAMSDWKXXPUJR-UHFFFAOYSA-N 0.000 claims abstract description 21
239000006185 dispersion Substances 0.000 claims abstract description 18
LZGUHMNOBNWABZ-UHFFFAOYSA-N n-nitro-n-phenylnitramide Chemical compound [O-][N+](=O)N([N+]([O-])=O)C1=CC=CC=C1 LZGUHMNOBNWABZ-UHFFFAOYSA-N 0.000 claims abstract description 17
230000002708 enhancing effect Effects 0.000 claims abstract description 15
238000000034 method Methods 0.000 claims abstract description 12
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical group O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 14
-1 alkyl naphthalene sulfonate Chemical compound 0.000 claims description 13
239000000440 bentonite Substances 0.000 claims description 13
229910000278 bentonite Inorganic materials 0.000 claims description 13
229920000642 polymer Polymers 0.000 claims description 13
239000002585 base Substances 0.000 claims description 9
239000000080 wetting agent Substances 0.000 claims description 9
239000004927 clay Substances 0.000 claims description 8
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 8
239000000463 material Substances 0.000 claims description 8
239000000375 suspending agent Substances 0.000 claims description 8
238000002156 mixing Methods 0.000 claims description 7
229910052901 montmorillonite Inorganic materials 0.000 claims description 7
238000003801 milling Methods 0.000 claims description 6
IZWPGJFSBABFGL-GMFCBQQYSA-M sodium;2-[methyl-[(z)-octadec-9-enoyl]amino]ethanesulfonate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CCS([O-])(=O)=O IZWPGJFSBABFGL-GMFCBQQYSA-M 0.000 claims description 6
235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 claims description 5
YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 claims description 5
COHIUILBPQNABR-UHFFFAOYSA-N dodecyl phenylmethanesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)CC1=CC=CC=C1 COHIUILBPQNABR-UHFFFAOYSA-N 0.000 claims description 5
PVFRIQXOAVHRMF-UHFFFAOYSA-N formaldehyde;naphthalene;sulfuric acid Chemical compound O=C.OS(O)(=O)=O.C1=CC=CC2=CC=CC=C21 PVFRIQXOAVHRMF-UHFFFAOYSA-N 0.000 claims description 5
UYDLBVPAAFVANX-UHFFFAOYSA-N octylphenoxy polyethoxyethanol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCOCCOCCOCCO)C=C1 UYDLBVPAAFVANX-UHFFFAOYSA-N 0.000 claims description 5
229920005552 sodium lignosulfonate Polymers 0.000 claims description 5
159000000000 sodium salts Chemical class 0.000 claims description 5
DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 claims description 5
FBWNMEQMRUMQSO-UHFFFAOYSA-N tergitol NP-9 Chemical compound CCCCCCCCCC1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 FBWNMEQMRUMQSO-UHFFFAOYSA-N 0.000 claims description 5
239000002518 antifoaming agent Substances 0.000 claims description 4
229920001519 homopolymer Polymers 0.000 claims description 4
HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims description 4
239000003507 refrigerant Substances 0.000 claims description 4
150000008044 alkali metal hydroxides Chemical class 0.000 claims description 3
238000001035 drying Methods 0.000 claims description 3
238000004519 manufacturing process Methods 0.000 claims description 2
239000005995 Aluminium silicate Substances 0.000 claims 2
235000012211 aluminium silicate Nutrition 0.000 claims 2
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical group O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims 2
238000002360 preparation method Methods 0.000 abstract description 5
238000003860 storage Methods 0.000 abstract description 2
235000012216 bentonite Nutrition 0.000 description 12
238000009472 formulation Methods 0.000 description 9
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 8
238000012360 testing method Methods 0.000 description 7
239000000969 carrier Substances 0.000 description 6
239000008187 granular material Substances 0.000 description 6
CHIFOSRWCNZCFN-UHFFFAOYSA-N pendimethalin Chemical compound CCC(CC)NC1=C([N+]([O-])=O)C=C(C)C(C)=C1[N+]([O-])=O CHIFOSRWCNZCFN-UHFFFAOYSA-N 0.000 description 6
239000005591 Pendimethalin Substances 0.000 description 5
230000008961 swelling Effects 0.000 description 5
CABMTIJINOIHOD-UHFFFAOYSA-N 2-[4-methyl-5-oxo-4-(propan-2-yl)-4,5-dihydro-1H-imidazol-2-yl]quinoline-3-carboxylic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC2=CC=CC=C2C=C1C(O)=O CABMTIJINOIHOD-UHFFFAOYSA-N 0.000 description 4
239000005981 Imazaquin Substances 0.000 description 4
XVOKUMIPKHGGTN-UHFFFAOYSA-N Imazethapyr Chemical compound OC(=O)C1=CC(CC)=CN=C1C1=NC(C)(C(C)C)C(=O)N1 XVOKUMIPKHGGTN-UHFFFAOYSA-N 0.000 description 4
239000004480 active ingredient Substances 0.000 description 4
238000011156 evaluation Methods 0.000 description 4
238000002844 melting Methods 0.000 description 4
ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 4
PVSGXWMWNRGTKE-UHFFFAOYSA-N 5-methyl-2-[4-methyl-5-oxo-4-(propan-2-yl)-4,5-dihydro-1H-imidazol-2-yl]pyridine-3-carboxylic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC=C(C)C=C1C(O)=O PVSGXWMWNRGTKE-UHFFFAOYSA-N 0.000 description 3
229920002785 Croscarmellose sodium Polymers 0.000 description 3
WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
239000000378 calcium silicate Substances 0.000 description 3
229910052918 calcium silicate Inorganic materials 0.000 description 3
OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 3
230000008018 melting Effects 0.000 description 3
CGNBQYFXGQHUQP-UHFFFAOYSA-N 2,3-dinitroaniline Chemical class NC1=CC=CC([N+]([O-])=O)=C1[N+]([O-])=O CGNBQYFXGQHUQP-UHFFFAOYSA-N 0.000 description 2
CLQMBPJKHLGMQK-UHFFFAOYSA-N 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC=CC=C1C(O)=O CLQMBPJKHLGMQK-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
241000196324 Embryophyta Species 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
239000001767 crosslinked sodium carboxy methyl cellulose Substances 0.000 description 2
235000010947 crosslinked sodium carboxy methyl cellulose Nutrition 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
239000007788 liquid Substances 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
229940045905 sodium tallowate Drugs 0.000 description 2
239000007787 solid Substances 0.000 description 2
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
LQIAZOCLNBBZQK-UHFFFAOYSA-N 1-(1,2-Diphosphanylethyl)pyrrolidin-2-one Chemical compound PCC(P)N1CCCC1=O LQIAZOCLNBBZQK-UHFFFAOYSA-N 0.000 description 1
239000005471 Benfluralin Substances 0.000 description 1
239000004135 Bone phosphate Substances 0.000 description 1
101150106671 COMT gene Proteins 0.000 description 1
244000025254 Cannabis sativa Species 0.000 description 1
PTFJIKYUEPWBMS-UHFFFAOYSA-N Ethalfluralin Chemical compound CC(=C)CN(CC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O PTFJIKYUEPWBMS-UHFFFAOYSA-N 0.000 description 1
NEKOXWSIMFDGMA-UHFFFAOYSA-N Isopropalin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(C)C)C=C1[N+]([O-])=O NEKOXWSIMFDGMA-UHFFFAOYSA-N 0.000 description 1
229920000168 Microcrystalline cellulose Polymers 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
241000209504 Poaceae Species 0.000 description 1
229910021536 Zeolite Inorganic materials 0.000 description 1
VJHCJDRQFCCTHL-UHFFFAOYSA-N acetic acid 2,3,4,5,6-pentahydroxyhexanal Chemical compound CC(O)=O.OCC(O)C(O)C(O)C(O)C=O VJHCJDRQFCCTHL-UHFFFAOYSA-N 0.000 description 1
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
125000003342 alkenyl group Chemical group 0.000 description 1
125000000304 alkynyl group Chemical group 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
SMDHCQAYESWHAE-UHFFFAOYSA-N benfluralin Chemical compound CCCCN(CC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O SMDHCQAYESWHAE-UHFFFAOYSA-N 0.000 description 1
VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
235000010980 cellulose Nutrition 0.000 description 1
150000005829 chemical entities Chemical class 0.000 description 1
230000000295 complement effect Effects 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000012050 conventional carrier Substances 0.000 description 1
229960005168 croscarmellose Drugs 0.000 description 1
229960001681 croscarmellose sodium Drugs 0.000 description 1
239000003599 detergent Substances 0.000 description 1
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
238000010410 dusting Methods 0.000 description 1
239000004495 emulsifiable concentrate Substances 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
230000009969 flowable effect Effects 0.000 description 1
CSRCNKZJIYKJOT-UHFFFAOYSA-N formaldehyde;naphthalene;sodium Chemical compound [Na].O=C.C1=CC=CC2=CC=CC=C21 CSRCNKZJIYKJOT-UHFFFAOYSA-N 0.000 description 1
229910021485 fumed silica Inorganic materials 0.000 description 1
125000000623 heterocyclic group Chemical group 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
235000019813 microcrystalline cellulose Nutrition 0.000 description 1
239000008108 microcrystalline cellulose Substances 0.000 description 1
229940016286 microcrystalline cellulose Drugs 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
229910000273 nontronite Inorganic materials 0.000 description 1
UNAHYJYOSSSJHH-UHFFFAOYSA-N oryzalin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(S(N)(=O)=O)C=C1[N+]([O-])=O UNAHYJYOSSSJHH-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
230000000361 pesticidal effect Effects 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
230000036314 physical performance Effects 0.000 description 1
239000000843 powder Substances 0.000 description 1
229910000275 saponite Inorganic materials 0.000 description 1
239000000344 soap Substances 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Inorganic materials [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000010186 staining Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
239000004557 technical material Substances 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
239000004562 water dispersible granule Substances 0.000 description 1
238000009463 water soluble packaging Methods 0.000 description 1
239000010457 zeolite Substances 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
- A01N25/14—Powders or granules wettable
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
- A01N33/18—Nitro compounds

Landscapes

Life Sciences & Earth Sciences (AREA)
Health & Medical Sciences (AREA)
General Health & Medical Sciences (AREA)
Dentistry (AREA)
Plant Pathology (AREA)
Engineering & Computer Science (AREA)
Pest Control & Pesticides (AREA)
Agronomy & Crop Science (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Toxicology (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)

CA 2112040 1992-12-23 1993-12-21 Herbicides pulverulents se dispersant dans l'eau Expired - Fee Related CA2112040C (fr)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US07/996,221		1992-12-23
US07/996,221 US5294594A (en)	1992-12-23	1992-12-23	Water dispersible granular herbicidal compositions comprising dinitroaniline herbicides, montmorillonite carrier and water-swellable polymer
US07/996,412		1992-12-23
US07/996,412 US5296450A (en)	1992-12-23	1992-12-23	Water dispersible granular herbicidal compositions comprising dinitroaniline herbicides, montmorillonite carrier, and a base

Publications (2)

Publication Number	Publication Date
CA2112040A1 CA2112040A1 (fr)	1994-06-24
CA2112040C true CA2112040C (fr)	2004-11-23

Family

ID=27130672

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2112040 Expired - Fee Related CA2112040C (fr)	1992-12-23	1993-12-21	Herbicides pulverulents se dispersant dans l'eau

Country Status (1)

Country	Link
CA (1)	CA2112040C (fr)

1993
- 1993-12-21 CA CA 2112040 patent/CA2112040C/fr not_active Expired - Fee Related

Also Published As

Publication number	Publication date
CA2112040A1 (fr)	1994-06-24

Legal Events

Date	Code	Title	Description
2000-12-21	EEER	Examination request
2010-12-21	MKLA	Lapsed

Publication	Publication Date	Title
US4511395A (en)	1985-04-16	Method for the preparation of water dispersible granular herbicidal compositions with increased thermal stability
US4871392A (en)	1989-10-03	Aqueous suspension concentrate compositions of pendimethalin
JPH02221204A (ja)	1990-09-04	低揮発性塩類
US6013676A (en)	2000-01-11	Agricultural chemical composition with improved raindrop resistance
EP0604906B1 (fr)	1999-05-26	Compositions herbicides granulaires, dispersibles dans l'eau
AU592643B2 (en)	1990-01-18	Stable aqueous suspension concentrate compositions
US5294594A (en)	1994-03-15	Water dispersible granular herbicidal compositions comprising dinitroaniline herbicides, montmorillonite carrier and water-swellable polymer
US5393731A (en)	1995-02-28	Water dispersible granular herbicidal compositions comprising dinitroaniline and imidazolinone herbicides with montmorillonite carriers
US6156803A (en)	2000-12-05	Aqueous, flowable suspension concentrate of an agriculturally active chemical, and sprayable use formulation thereof
AU666436B2 (en)	1996-02-08	Herbicidal extruded granular compositions
CA2112040C (fr)	2004-11-23	Herbicides pulverulents se dispersant dans l'eau
CA2137412A1 (fr)	1995-06-09	Compositions herbicides granulaires se dispersant dans l'eau
HK1013217B (en)	2000-05-05	Water dispersible granular herbicidal compositions
US4197112A (en)	1980-04-08	Water-dispersible herbicide compositions
CA1202500A (fr)	1986-04-01	Methode de preparation d'un herbicide granule soluble a l'eau, a stabilite accrue a la chaleur
US4776881A (en)	1988-10-11	Herbicide composition and process
JP2023152973A (ja)	2023-10-17	農業用および家庭園芸用薬品組成物