CA2125977C - Device and process for the production of fibrous starch materials - Google Patents

Device and process for the production of fibrous starch materials Download PDF

Info

Publication number: CA2125977C
Authority: CA; Canada
Prior art keywords: starch; section; chamber; extrusion; starch material
Prior art date: 1992-10-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA002125977A

Other languages

English (en)

French (fr)

Other versions

CA2125977A1 (en

Inventor

Catia Bastioli

Bruno Casale

Gino Zanardi

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Cerestar Holding BV

Original Assignee

Cerestar Holding BV

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-10-16

Filing date

1993-10-11

Publication date

2003-09-30

1993-10-11 Application filed by Cerestar Holding BV filed Critical Cerestar Holding BV

1994-04-28 Publication of CA2125977A1 publication Critical patent/CA2125977A1/en

2003-09-30 Application granted granted Critical

2003-09-30 Publication of CA2125977C publication Critical patent/CA2125977C/en

2013-10-11 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

229920002472 Starch Polymers 0.000 title claims abstract description 94
235000019698 starch Nutrition 0.000 title claims abstract description 94
239000008107 starch Substances 0.000 title claims abstract description 93
239000000463 material Substances 0.000 title claims abstract description 44
238000000034 method Methods 0.000 title claims abstract description 32
230000008569 process Effects 0.000 title claims abstract description 28
238000004519 manufacturing process Methods 0.000 title claims abstract description 14
239000000701 coagulant Substances 0.000 claims abstract description 20
238000001125 extrusion Methods 0.000 claims abstract description 18
239000006185 dispersion Substances 0.000 claims abstract description 17
238000005345 coagulation Methods 0.000 claims abstract description 16
230000015271 coagulation Effects 0.000 claims abstract description 16
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 13
239000003795 chemical substances by application Substances 0.000 claims abstract description 8
239000011780 sodium chloride Substances 0.000 claims abstract description 7
239000007864 aqueous solution Substances 0.000 claims abstract description 5
230000004907 flux Effects 0.000 claims abstract description 4
239000000835 fiber Substances 0.000 claims description 39
230000035611 feeding Effects 0.000 claims description 17
238000009826 distribution Methods 0.000 claims description 12
239000000243 solution Substances 0.000 claims description 9
239000011148 porous material Substances 0.000 claims description 5
238000002360 preparation method Methods 0.000 claims description 5
229910052751 metal Inorganic materials 0.000 claims description 3
239000002184 metal Substances 0.000 claims description 3
229920003043 Cellulose fiber Polymers 0.000 abstract description 3
238000006467 substitution reaction Methods 0.000 abstract 1
239000000047 product Substances 0.000 description 20
239000000123 paper Substances 0.000 description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 7
229910052921 ammonium sulfate Inorganic materials 0.000 description 7
239000001166 ammonium sulphate Substances 0.000 description 7
235000011130 ammonium sulphate Nutrition 0.000 description 7
238000010411 cooking Methods 0.000 description 7
239000000725 suspension Substances 0.000 description 5
229920000945 Amylopectin Polymers 0.000 description 4
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
238000001914 filtration Methods 0.000 description 4
230000014759 maintenance of location Effects 0.000 description 4
239000002245 particle Substances 0.000 description 4
238000003756 stirring Methods 0.000 description 4
239000000126 substance Substances 0.000 description 4
229910021653 sulphate ion Inorganic materials 0.000 description 4
241000196324 Embryophyta Species 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
239000011111 cardboard Substances 0.000 description 3
230000001112 coagulating effect Effects 0.000 description 3
238000005755 formation reaction Methods 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
238000005406 washing Methods 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
229920000856 Amylose Polymers 0.000 description 2
229920002261 Corn starch Polymers 0.000 description 2
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
235000019759 Maize starch Nutrition 0.000 description 2
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
240000008042 Zea mays Species 0.000 description 2
235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 2
235000002017 Zea mays subsp mays Nutrition 0.000 description 2
239000012670 alkaline solution Substances 0.000 description 2
230000004323 axial length Effects 0.000 description 2
239000001913 cellulose Substances 0.000 description 2
229920002678 cellulose Polymers 0.000 description 2
235000014113 dietary fatty acids Nutrition 0.000 description 2
239000004744 fabric Substances 0.000 description 2
239000000194 fatty acid Substances 0.000 description 2
229930195729 fatty acid Natural products 0.000 description 2
150000004665 fatty acids Chemical class 0.000 description 2
239000011521 glass Substances 0.000 description 2
230000002209 hydrophobic effect Effects 0.000 description 2
239000007788 liquid Substances 0.000 description 2
235000009973 maize Nutrition 0.000 description 2
239000007769 metal material Substances 0.000 description 2
239000011087 paperboard Substances 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
230000000717 retained effect Effects 0.000 description 2
238000010008 shearing Methods 0.000 description 2
239000002002 slurry Substances 0.000 description 2
-1 sodium hydroxide Chemical class 0.000 description 2
229910052938 sodium sulfate Inorganic materials 0.000 description 2
235000011152 sodium sulphate Nutrition 0.000 description 2
239000007787 solid Substances 0.000 description 2
239000002904 solvent Substances 0.000 description 2
IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
239000004254 Ammonium phosphate Substances 0.000 description 1
229920001685 Amylomaize Polymers 0.000 description 1
241001056488 Anatis Species 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
YUBJPYNSGLJZPQ-UHFFFAOYSA-N Dithiopyr Chemical compound CSC(=O)C1=C(C(F)F)N=C(C(F)(F)F)C(C(=O)SC)=C1CC(C)C YUBJPYNSGLJZPQ-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
240000003183 Manihot esculenta Species 0.000 description 1
235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
229920000881 Modified starch Polymers 0.000 description 1
239000004368 Modified starch Substances 0.000 description 1
240000007594 Oryza sativa Species 0.000 description 1
235000007164 Oryza sativa Nutrition 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
239000004372 Polyvinyl alcohol Substances 0.000 description 1
229920001131 Pulp (paper) Polymers 0.000 description 1
UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
235000002595 Solanum tuberosum Nutrition 0.000 description 1
244000061456 Solanum tuberosum Species 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000001164 aluminium sulphate Substances 0.000 description 1
235000011128 aluminium sulphate Nutrition 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
229940010556 ammonium phosphate Drugs 0.000 description 1
229910000148 ammonium phosphate Inorganic materials 0.000 description 1
235000019289 ammonium phosphates Nutrition 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
239000007900 aqueous suspension Substances 0.000 description 1
238000000889 atomisation Methods 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
238000001246 colloidal dispersion Methods 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
239000013256 coordination polymer Substances 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
239000003431 cross linking reagent Substances 0.000 description 1
230000007547 defect Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 1
MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
238000007599 discharging Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000005187 foaming Methods 0.000 description 1
238000013467 fragmentation Methods 0.000 description 1
238000006062 fragmentation reaction Methods 0.000 description 1
238000001879 gelation Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000000787 lecithin Substances 0.000 description 1
229940067606 lecithin Drugs 0.000 description 1
235000010445 lecithin Nutrition 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
229910052943 magnesium sulfate Inorganic materials 0.000 description 1
235000019341 magnesium sulphate Nutrition 0.000 description 1
238000010907 mechanical stirring Methods 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
239000011707 mineral Substances 0.000 description 1
235000019426 modified starch Nutrition 0.000 description 1
KRTSDMXIXPKRQR-AATRIKPKSA-N monocrotophos Chemical compound CNC(=O)\C=C(/C)OP(=O)(OC)OC KRTSDMXIXPKRQR-AATRIKPKSA-N 0.000 description 1
230000000877 morphologic effect Effects 0.000 description 1
238000000465 moulding Methods 0.000 description 1
239000012766 organic filler Substances 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
239000001103 potassium chloride Substances 0.000 description 1
235000011164 potassium chloride Nutrition 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
235000009566 rice Nutrition 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000012047 saturated solution Substances 0.000 description 1
238000013341 scale-up Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
235000017550 sodium carbonate Nutrition 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
229940001593 sodium carbonate Drugs 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000002351 wastewater Substances 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/40—Formation of filaments, threads, or the like by applying a shearing force to a dispersion or solution of filament formable polymers, e.g. by stirring

Landscapes

Engineering & Computer Science (AREA)
Chemical & Material Sciences (AREA)
Textile Engineering (AREA)
Mechanical Engineering (AREA)
General Chemical & Material Sciences (AREA)
Dispersion Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Artificial Filaments (AREA)
Polysaccharides And Polysaccharide Derivatives (AREA)
Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Paper (AREA)
Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

CA002125977A 1992-10-16 1993-10-11 Device and process for the production of fibrous starch materials Expired - Fee Related CA2125977C (en)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
ITTO92A000837		1992-10-16
ITTO920837A IT1256971B (it)	1992-10-16	1992-10-16	Dispositivo e procedimento per la produzione di fibre di materiale amidaceo.
PCT/EP1993/002782 WO1994009190A1 (en)	1992-10-16	1993-10-11	Device and process for the production of fibrous starch materials

Publications (2)

Publication Number	Publication Date
CA2125977A1 CA2125977A1 (en)	1994-04-28
CA2125977C true CA2125977C (en)	2003-09-30

Family

ID=11410787

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002125977A Expired - Fee Related CA2125977C (en)	1992-10-16	1993-10-11	Device and process for the production of fibrous starch materials

Country Status (14)

Country	Link
EP (1)	EP0617742B1 (it)
JP (1)	JP3345013B2 (it)
AT (1)	ATE162561T1 (it)
AU (1)	AU669225B2 (it)
BR (1)	BR9305678A (it)
CA (1)	CA2125977C (it)
DE (1)	DE69316585T2 (it)
DK (1)	DK0617742T3 (it)
ES (1)	ES2111186T3 (it)
FI (1)	FI102772B1 (it)
IT (1)	IT1256971B (it)
NO (1)	NO942255D0 (it)
RU (1)	RU2113559C1 (it)
WO (1)	WO1994009190A1 (it)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE4409465A1 (de) *	1994-03-19	1995-09-21	Kinkel Werner Helmut	Biologisch abbaubare Vliese und Vliesverbundmaterialien
EP2246472A1 (en)	2009-03-24	2010-11-03	Mondi Limited South Africa	Process for preparing polysaccharide gel particles and pulp furnish for use in paper making
BR112015008315B1 (pt)	2012-10-22	2021-11-16	Innventia Ab	Método de fibras de fiação ou extrusão
GB2518199A (en) *	2013-09-13	2015-03-18	Xiros Ltd	Method of producing a swellable polymer fibre
HK1249557A1 (zh)	2015-04-28	2018-11-02	Spinnova Oy	用於制造纤维纱线的化学方法和系统

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2988782A (en) *	1958-12-09	1961-06-20	Du Pont	Process for producing fibrids by precipitation and violent agitation
US4205025A (en) *	1975-12-22	1980-05-27	Champion International Corporation	Synthetic polymeric fibrids, fibrid products and process for their production
CA1079016A (en) *	1976-03-25	1980-06-10	Donald S. Greif	Water insensitive starch fibers and a process for the production thereof
US4243480A (en) *	1977-10-17	1981-01-06	National Starch And Chemical Corporation	Process for the production of paper containing starch fibers and the paper produced thereby
IT1249972B (it) *	1991-07-31	1995-03-30	Ferruzzi Ricerca & Tec	Polpa d'amido, procedimento per la sua preparazione e suo impiego nella fabbricazione di carta e cartone.

1992
- 1992-10-16 IT ITTO920837A patent/IT1256971B/it active IP Right Grant
1993
- 1993-10-11 DE DE69316585T patent/DE69316585T2/de not_active Expired - Fee Related
- 1993-10-11 EP EP93922545A patent/EP0617742B1/en not_active Expired - Lifetime
- 1993-10-11 AT AT93922545T patent/ATE162561T1/de not_active IP Right Cessation
- 1993-10-11 ES ES93922545T patent/ES2111186T3/es not_active Expired - Lifetime
- 1993-10-11 DK DK93922545.4T patent/DK0617742T3/da active
- 1993-10-11 BR BR9305678A patent/BR9305678A/pt not_active IP Right Cessation
- 1993-10-11 AU AU51506/93A patent/AU669225B2/en not_active Ceased
- 1993-10-11 JP JP50960394A patent/JP3345013B2/ja not_active Expired - Fee Related
- 1993-10-11 RU RU94032151A patent/RU2113559C1/ru not_active IP Right Cessation
- 1993-10-11 WO PCT/EP1993/002782 patent/WO1994009190A1/en not_active Ceased
- 1993-10-11 CA CA002125977A patent/CA2125977C/en not_active Expired - Fee Related
1994
- 1994-06-15 FI FI942851A patent/FI102772B1/fi active
- 1994-06-15 NO NO942255A patent/NO942255D0/no unknown

Also Published As

Publication number	Publication date
DE69316585D1 (de)	1998-02-26
BR9305678A (pt)	1994-11-22
NO942255L (no)	1994-06-15
EP0617742A1 (en)	1994-10-05
JP3345013B2 (ja)	2002-11-18
IT1256971B (it)	1995-12-27
FI102772B (fi)	1999-02-15
ITTO920837A1 (it)	1994-04-16
AU669225B2 (en)	1996-05-30
FI942851A0 (fi)	1994-06-15
JPH07502312A (ja)	1995-03-09
EP0617742B1 (en)	1998-01-21
NO942255D0 (no)	1994-06-15
RU2113559C1 (ru)	1998-06-20
DK0617742T3 (da)	1998-03-30
FI102772B1 (fi)	1999-02-15
DE69316585T2 (de)	1998-04-23
FI942851L (fi)	1994-06-15
WO1994009190A1 (en)	1994-04-28
ITTO920837A0 (it)	1992-10-16
CA2125977A1 (en)	1994-04-28
ATE162561T1 (de)	1998-02-15
AU5150693A (en)	1994-05-09
ES2111186T3 (es)	1998-03-01

Legal Events

Date	Code	Title	Description
2000-10-11	EEER	Examination request
2007-10-11	MKLA	Lapsed

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