CA2145191A1 - Electrostatically painted polymers and a process for making same - Google Patents

Electrostatically painted polymers and a process for making same

Info

Publication number: CA2145191A1
Authority: CA; Canada
Prior art keywords: polymer; electrostatically; metal salt; volatile metal; polymers
Prior art date: 1992-09-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA002145191A

Other languages

English (en)

French (fr)

Inventor

Robert Carswell

Martin C. Cornell

Cynthia K. Groseth

James R. Porter

Ralph D. Priester, Jr.

Ricky L. Tabor

Melissa J. Zawisza

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Dow Global Technologies LLC

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-09-30

Filing date

1993-09-09

Publication date

1994-04-14

1993-09-09 Application filed by Individual filed Critical Individual

1994-04-14 Publication of CA2145191A1 publication Critical patent/CA2145191A1/en

Status Abandoned legal-status Critical Current

Links

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238000000034 method Methods 0.000 title claims abstract description 32
239000000203 mixture Substances 0.000 claims abstract description 97
239000003973 paint Substances 0.000 claims abstract description 89
239000000463 material Substances 0.000 claims abstract description 64
229910052751 metal Inorganic materials 0.000 claims abstract description 56
239000002184 metal Substances 0.000 claims abstract description 56
150000003839 salts Chemical class 0.000 claims abstract description 53
238000009472 formulation Methods 0.000 claims abstract description 46
238000010422 painting Methods 0.000 claims abstract description 45
230000001939 inductive effect Effects 0.000 claims abstract description 31
230000000704 physical effect Effects 0.000 claims abstract description 14
-1 perfluoroalkyl sulfonate Chemical compound 0.000 claims description 43
239000000126 substance Substances 0.000 claims description 31
238000010107 reaction injection moulding Methods 0.000 claims description 22
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 21
JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 19
150000001450 anions Chemical class 0.000 claims description 18
238000000576 coating method Methods 0.000 claims description 18
150000001768 cations Chemical class 0.000 claims description 17
239000011248 coating agent Substances 0.000 claims description 15
229910052700 potassium Inorganic materials 0.000 claims description 12
229910052708 sodium Inorganic materials 0.000 claims description 8
239000004202 carbamide Substances 0.000 claims description 6
229910052744 lithium Inorganic materials 0.000 claims description 6
238000001746 injection moulding Methods 0.000 claims description 5
239000004814 polyurethane Substances 0.000 abstract description 39
229920002396 Polyurea Polymers 0.000 abstract description 31
229920003226 polyurethane urea Polymers 0.000 abstract description 26
238000012546 transfer Methods 0.000 abstract description 6
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150000003077 polyols Chemical class 0.000 description 30
239000005056 polyisocyanate Substances 0.000 description 20
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239000003054 catalyst Substances 0.000 description 17
229920003023 plastic Polymers 0.000 description 16
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UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 15
239000000843 powder Substances 0.000 description 14
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229920000570 polyether Polymers 0.000 description 12
238000010998 test method Methods 0.000 description 11
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XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
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239000000654 additive Substances 0.000 description 6
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239000011737 fluorine Substances 0.000 description 6
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PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 5
125000000217 alkyl group Chemical group 0.000 description 5
150000004985 diamines Chemical class 0.000 description 5
239000007788 liquid Substances 0.000 description 5
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
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NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
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125000004429 atom Chemical group 0.000 description 4
235000013877 carbamide Nutrition 0.000 description 4
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229910052736 halogen Inorganic materials 0.000 description 4
150000002367 halogens Chemical group 0.000 description 4
238000002347 injection Methods 0.000 description 4
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150000002513 isocyanates Chemical class 0.000 description 4
ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 4
238000007591 painting process Methods 0.000 description 4
238000012545 processing Methods 0.000 description 4
239000002904 solvent Substances 0.000 description 4
238000005507 spraying Methods 0.000 description 4
150000003512 tertiary amines Chemical class 0.000 description 4
229920001187 thermosetting polymer Polymers 0.000 description 4
150000004072 triols Chemical class 0.000 description 4
PISLZQACAJMAIO-UHFFFAOYSA-N 2,4-diethyl-6-methylbenzene-1,3-diamine Chemical compound CCC1=CC(C)=C(N)C(CC)=C1N PISLZQACAJMAIO-UHFFFAOYSA-N 0.000 description 3
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
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NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
125000001931 aliphatic group Chemical group 0.000 description 3
125000003277 amino group Chemical group 0.000 description 3
150000004984 aromatic diamines Chemical class 0.000 description 3
239000002585 base Substances 0.000 description 3
230000008901 benefit Effects 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
229910052801 chlorine Inorganic materials 0.000 description 3
239000011231 conductive filler Substances 0.000 description 3
239000004020 conductor Substances 0.000 description 3
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239000008367 deionised water Substances 0.000 description 3
229910021641 deionized water Inorganic materials 0.000 description 3
125000005442 diisocyanate group Chemical group 0.000 description 3
150000002009 diols Chemical class 0.000 description 3
239000012530 fluid Substances 0.000 description 3
125000003709 fluoroalkyl group Chemical group 0.000 description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
239000011810 insulating material Substances 0.000 description 3
150000002500 ions Chemical class 0.000 description 3
238000005259 measurement Methods 0.000 description 3
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239000011574 phosphorus Substances 0.000 description 3
239000000049 pigment Substances 0.000 description 3
239000005060 rubber Substances 0.000 description 3
239000000758 substrate Substances 0.000 description 3
150000005846 sugar alcohols Polymers 0.000 description 3
229910052717 sulfur Inorganic materials 0.000 description 3
239000011593 sulfur Substances 0.000 description 3
229920001169 thermoplastic Polymers 0.000 description 3
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RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 3
ARXKVVRQIIOZGF-UHFFFAOYSA-N 1,2,4-butanetriol Chemical compound OCCC(O)CO ARXKVVRQIIOZGF-UHFFFAOYSA-N 0.000 description 2
JGYUBHGXADMAQU-UHFFFAOYSA-N 2,4,6-triethylbenzene-1,3-diamine Chemical compound CCC1=CC(CC)=C(N)C(CC)=C1N JGYUBHGXADMAQU-UHFFFAOYSA-N 0.000 description 2
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
RQEOBXYYEPMCPJ-UHFFFAOYSA-N 4,6-diethyl-2-methylbenzene-1,3-diamine Chemical compound CCC1=CC(CC)=C(N)C(C)=C1N RQEOBXYYEPMCPJ-UHFFFAOYSA-N 0.000 description 2
DVPHIKHMYFQLKF-UHFFFAOYSA-N 4-tert-butyl-2-methylbenzene-1,3-diamine Chemical compound CC1=C(N)C=CC(C(C)(C)C)=C1N DVPHIKHMYFQLKF-UHFFFAOYSA-N 0.000 description 2
HLDUVPFXLWEZOG-UHFFFAOYSA-N 4-tert-butyl-6-methylbenzene-1,3-diamine Chemical compound CC1=CC(C(C)(C)C)=C(N)C=C1N HLDUVPFXLWEZOG-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
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WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
229920000049 Carbon (fiber) Polymers 0.000 description 2
RYECOJGRJDOGPP-UHFFFAOYSA-N Ethylurea Chemical compound CCNC(N)=O RYECOJGRJDOGPP-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
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238000000889 atomisation Methods 0.000 description 2
HIFVAOIJYDXIJG-UHFFFAOYSA-N benzylbenzene;isocyanic acid Chemical class N=C=O.N=C=O.C=1C=CC=CC=1CC1=CC=CC=C1 HIFVAOIJYDXIJG-UHFFFAOYSA-N 0.000 description 2
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TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
LAZAPLSLBNDLDM-UHFFFAOYSA-N [Li].FC(F)F Chemical compound [Li].FC(F)F LAZAPLSLBNDLDM-UHFFFAOYSA-N 0.000 description 1
UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
XQBCVRSTVUHIGH-UHFFFAOYSA-L [dodecanoyloxy(dioctyl)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCCCCCC)(CCCCCCCC)OC(=O)CCCCCCCCCCC XQBCVRSTVUHIGH-UHFFFAOYSA-L 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
229920001893 acrylonitrile styrene Polymers 0.000 description 1
239000001361 adipic acid Substances 0.000 description 1
235000011037 adipic acid Nutrition 0.000 description 1
230000002411 adverse Effects 0.000 description 1
239000000443 aerosol Substances 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical class N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
235000011130 ammonium sulphate Nutrition 0.000 description 1
229910052787 antimony Inorganic materials 0.000 description 1
229910052785 arsenic Inorganic materials 0.000 description 1
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
229910052789 astatine Inorganic materials 0.000 description 1
RYXHOMYVWAEKHL-UHFFFAOYSA-N astatine atom Chemical compound [At] RYXHOMYVWAEKHL-UHFFFAOYSA-N 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
229910052790 beryllium Inorganic materials 0.000 description 1
CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
150000001718 carbodiimides Chemical class 0.000 description 1
238000005266 casting Methods 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
238000005253 cladding Methods 0.000 description 1
239000008199 coating composition Substances 0.000 description 1
238000000748 compression moulding Methods 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
230000003750 conditioning effect Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
238000005520 cutting process Methods 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
230000007547 defect Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
239000003599 detergent Substances 0.000 description 1
239000012975 dibutyltin dilaurate Substances 0.000 description 1
XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
238000007599 discharging Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000000806 elastomer Substances 0.000 description 1
238000004070 electrodeposition Methods 0.000 description 1
125000006575 electron-withdrawing group Chemical group 0.000 description 1
229920003247 engineering thermoplastic Polymers 0.000 description 1
230000002708 enhancing effect Effects 0.000 description 1
239000003822 epoxy resin Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
238000005530 etching Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
HJUFTIJOISQSKQ-UHFFFAOYSA-N fenoxycarb Chemical compound C1=CC(OCCNC(=O)OCC)=CC=C1OC1=CC=CC=C1 HJUFTIJOISQSKQ-UHFFFAOYSA-N 0.000 description 1
239000011152 fibreglass Substances 0.000 description 1
239000012765 fibrous filler Substances 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000003063 flame retardant Substances 0.000 description 1
229910052730 francium Inorganic materials 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
239000003365 glass fiber Substances 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
229910052735 hafnium Inorganic materials 0.000 description 1
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
150000004000 hexols Chemical class 0.000 description 1
150000002483 hydrogen compounds Chemical class 0.000 description 1
150000002466 imines Chemical class 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
239000011630 iodine Substances 0.000 description 1
229910052741 iridium Inorganic materials 0.000 description 1
GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 description 1
FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 description 1
OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 description 1
229910052747 lanthanoid Inorganic materials 0.000 description 1
150000002602 lanthanoids Chemical class 0.000 description 1
229910052745 lead Inorganic materials 0.000 description 1
239000012705 liquid precursor Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
239000000594 mannitol Substances 0.000 description 1
235000010355 mannitol Nutrition 0.000 description 1
230000000873 masking effect Effects 0.000 description 1
239000000155 melt Substances 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
239000006082 mold release agent Substances 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000000178 monomer Substances 0.000 description 1
XFLSMWXCZBIXLV-UHFFFAOYSA-N n,n-dimethyl-2-(4-methylpiperazin-1-yl)ethanamine Chemical compound CN(C)CCN1CCN(C)CC1 XFLSMWXCZBIXLV-UHFFFAOYSA-N 0.000 description 1
KQSABULTKYLFEV-UHFFFAOYSA-N naphthalene-1,5-diamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1N KQSABULTKYLFEV-UHFFFAOYSA-N 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
229910052758 niobium Inorganic materials 0.000 description 1
RNVCVTLRINQCPJ-UHFFFAOYSA-N o-toluidine Chemical compound CC1=CC=CC=C1N RNVCVTLRINQCPJ-UHFFFAOYSA-N 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
229910052762 osmium Inorganic materials 0.000 description 1
125000006353 oxyethylene group Chemical group 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
RZXMPPFPUUCRFN-UHFFFAOYSA-N p-toluidine Chemical compound CC1=CC=C(N)C=C1 RZXMPPFPUUCRFN-UHFFFAOYSA-N 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
125000005010 perfluoroalkyl group Chemical group 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
125000004437 phosphorous atom Chemical group 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
239000004632 polycaprolactone Substances 0.000 description 1
229920001610 polycaprolactone Polymers 0.000 description 1
239000004417 polycarbonate Substances 0.000 description 1
229920005668 polycarbonate resin Polymers 0.000 description 1
239000004431 polycarbonate resin Substances 0.000 description 1
229920000647 polyepoxide Polymers 0.000 description 1
229920005906 polyester polyol Polymers 0.000 description 1
229920002959 polymer blend Polymers 0.000 description 1
229920006324 polyoxymethylene Polymers 0.000 description 1
150000008442 polyphenolic compounds Chemical class 0.000 description 1
235000013824 polyphenols Nutrition 0.000 description 1
229920001451 polypropylene glycol Polymers 0.000 description 1
238000011417 postcuring Methods 0.000 description 1
ZUFQCVZBBNZMKD-UHFFFAOYSA-M potassium 2-ethylhexanoate Chemical compound [K+].CCCCC(CC)C([O-])=O ZUFQCVZBBNZMKD-UHFFFAOYSA-M 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
230000037452 priming Effects 0.000 description 1
239000000047 product Substances 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
230000005855 radiation Effects 0.000 description 1
229910052705 radium Inorganic materials 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
229910052702 rhenium Inorganic materials 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
229910052701 rubidium Inorganic materials 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
229910052706 scandium Inorganic materials 0.000 description 1
125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
229910052711 selenium Inorganic materials 0.000 description 1
239000011669 selenium Substances 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
241000894007 species Species 0.000 description 1
238000007592 spray painting technique Methods 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
239000005720 sucrose Substances 0.000 description 1
150000008163 sugars Chemical class 0.000 description 1
125000004434 sulfur atom Chemical group 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
229910052715 tantalum Inorganic materials 0.000 description 1
229910052713 technetium Inorganic materials 0.000 description 1
229910052714 tellurium Inorganic materials 0.000 description 1
PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
150000003918 triazines Chemical class 0.000 description 1
QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
QZQIWEZRSIPYCU-UHFFFAOYSA-N trithiole Chemical class S1SC=CS1 QZQIWEZRSIPYCU-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
150000003672 ureas Chemical class 0.000 description 1
150000003673 urethanes Chemical class 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
239000002023 wood Substances 0.000 description 1
239000000811 xylitol Substances 0.000 description 1
HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
235000010447 xylitol Nutrition 0.000 description 1
229960002675 xylitol Drugs 0.000 description 1
229910052727 yttrium Inorganic materials 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1
PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
- B05D1/04—Processes for applying liquids or other fluent materials performed by spraying involving the use of an electrostatic field
- B05D1/045—Processes for applying liquids or other fluent materials performed by spraying involving the use of an electrostatic field on non-conductive substrates
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material

Landscapes

Physics & Mathematics (AREA)
Chemical & Material Sciences (AREA)
Dispersion Chemistry (AREA)
Spectroscopy & Molecular Physics (AREA)
Application Of Or Painting With Fluid Materials (AREA)
Laminated Bodies (AREA)
Injection Moulding Of Plastics Or The Like (AREA)
Paints Or Removers (AREA)

CA002145191A 1992-09-30 1993-09-09 Electrostatically painted polymers and a process for making same Abandoned CA2145191A1 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US95462892A	1992-09-30	1992-09-30
US07/954,628		1992-09-30

Publications (1)

Publication Number	Publication Date
CA2145191A1 true CA2145191A1 (en)	1994-04-14

Family

ID=25495711

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002145191A Abandoned CA2145191A1 (en)	1992-09-30	1993-09-09	Electrostatically painted polymers and a process for making same

Country Status (10)

Country	Link
EP (1)	EP0662867B1 (de)
JP (1)	JPH08501981A (de)
KR (1)	KR100282103B1 (de)
AT (1)	ATE170109T1 (de)
BR (1)	BR9307150A (de)
CA (1)	CA2145191A1 (de)
DE (1)	DE69320644T2 (de)
MX (1)	MX9306078A (de)
RU (1)	RU2119830C1 (de)
WO (1)	WO1994007612A1 (de)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5629050A (en) *	1995-08-30	1997-05-13	The Dow Chemical Company	Process for preparing coated articles
US5817376A (en) *	1996-03-26	1998-10-06	Minnesota Mining And Manufacturing Company	Free-radically polymerizable compositions capable of being coated by electrostatic assistance
ATE210706T1 (de) *	1996-03-26	2001-12-15	Minnesota Mining & Mfg	Kationisch polymerisierbare zusmmensetzungen, die zur beschichtung in einem elektrostatischen verfahren verwendet werden können
US5858545A (en) *	1996-03-26	1999-01-12	Minnesota Mining And Manufacturing Company	Electrosprayable release coating
US5962546A (en) *	1996-03-26	1999-10-05	3M Innovative Properties Company	Cationically polymerizable compositions capable of being coated by electrostatic assistance
US5844037A (en) *	1996-07-24	1998-12-01	The Dow Chemical Company	Thermoplastic polymer compositions with modified electrical conductivity
KR19980046324A (ko) *	1996-12-12	1998-09-15	위르겐 에르트만, 베른트 뮐러	비전도성 합성 수지 부재들의 코팅 방법
IL145077A0 (en) *	1999-03-02	2002-06-30	Skc Acquisition Corp	Conductive or static dissipative coating
DE10032558B4 (de) *	2000-07-05	2014-10-23	Volkswagen Ag	Verfahren zum elektrostatischen Beschichten von Fahrzeuganbauteilen, danach hergestelltes Fahrzeuganbauteil und dessen Verwendung
US6746751B2 (en)	2001-06-22	2004-06-08	Agfa-Gevaert	Material having a conductive pattern and a material and method for making a conductive pattern
DE60228572D1 (de) *	2001-06-22	2008-10-09	Agfa Gevaert	Material mit leitfähigem muster und material sowie methode zur herstellung eines leitfähigen musters
CN101283027A (zh) *	2005-08-08	2008-10-08	卡伯特公司	包含纳米管的聚合物组合物
RU2343010C1 (ru) *	2007-05-30	2009-01-10	Общество с ограниченной ответственностью "Производственная компания "Теплофон"	Способ электростатического окрашивания диэлектрических изделий
US8574414B2 (en) *	2010-07-14	2013-11-05	Ppg Industries Ohio, Inc	Copper prerinse for electrodepositable coating composition comprising yttrium
CN118106204A (zh) *	2024-03-04	2024-05-31	浙江鼎晟休闲用品有限公司	一种塑料花盆的表面处理工艺

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* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3535294A (en) *	1966-12-08	1970-10-20	Lion Fat Oil Co Ltd	Method for electrostatically coating synthetic resin moldings
JPH0618911B2 (ja) *	1987-09-25	1994-03-16	ポリプラスチックス株式会社	静電塗装プラスチックス成形品の製造方法
US5188783A (en) *	1990-02-20	1993-02-23	Hughes Aircraft Company	Method of making articles containing an ion-conductive polymer
JPH04122775A (ja) *	1990-09-14	1992-04-23	Dai Ichi Kogyo Seiyaku Co Ltd	樹脂の導電性改質方法

1993
- 1993-09-09 BR BR9307150A patent/BR9307150A/pt not_active IP Right Cessation
- 1993-09-09 RU RU95112572A patent/RU2119830C1/ru active
- 1993-09-09 EP EP93920503A patent/EP0662867B1/de not_active Expired - Lifetime
- 1993-09-09 WO PCT/US1993/008470 patent/WO1994007612A1/en not_active Ceased
- 1993-09-09 DE DE69320644T patent/DE69320644T2/de not_active Expired - Fee Related
- 1993-09-09 AT AT93920503T patent/ATE170109T1/de not_active IP Right Cessation
- 1993-09-09 JP JP6509074A patent/JPH08501981A/ja not_active Ceased
- 1993-09-09 KR KR1019950701219A patent/KR100282103B1/ko not_active Expired - Fee Related
- 1993-09-09 CA CA002145191A patent/CA2145191A1/en not_active Abandoned
- 1993-09-30 MX MX9306078A patent/MX9306078A/es not_active IP Right Cessation

Also Published As

Publication number	Publication date
EP0662867B1 (de)	1998-08-26
ATE170109T1 (de)	1998-09-15
KR100282103B1 (ko)	2001-02-15
EP0662867A1 (de)	1995-07-19
KR950703414A (ko)	1995-09-20
WO1994007612A1 (en)	1994-04-14
RU95112572A (ru)	1997-01-10
RU2119830C1 (ru)	1998-10-10
BR9307150A (pt)	1999-03-30
JPH08501981A (ja)	1996-03-05
DE69320644D1 (de)	1998-10-01
DE69320644T2 (de)	1999-01-14
MX9306078A (es)	1995-01-31

Legal Events

Date	Code	Title	Description
2000-09-06	EEER	Examination request
2006-08-21	FZDE	Discontinued

Publication	Publication Date	Title
US5830541A (en)	1998-11-03	Process for electrostatically painting polymers containing a non-volatile metal salt conductivity inducing material
EP0662867B1 (de)	1998-08-26	Elektrostatische beschichtung von polymergegenständen und verfahren zur herstellung
EP1461372B1 (de)	2008-07-09	Beschichtungsverfahren und zusammensetzung
US3462328A (en)	1969-08-19	Method of making vehicle tire tread
US4251427A (en)	1981-02-17	Coating compositions from polyurethanes containing a molecular sieve of the sodium aluminum silicate type
US20020114940A1 (en)	2002-08-22	Engineered composite system, system component compositions, and methods of use
US4871579A (en)	1989-10-03	Process and device for spraying a reaction mixture capable of forming a transparent protective layer of high optical quality
KR100314475B1 (ko)	2001-12-28	내산성도료에대한우레탄접착제의결합을개선시키기위한하도제조성물
CA2006725A1 (en)	1990-06-28	Manufacturing process of spray urethane elastomer
AU644840B2 (en)	1993-12-23	Primer composition for improving the bonding of a urethane adhesive
DE10055559A1 (de)	2002-05-29	UV-beständiger Beflockungsklebstoff für Polymere Substrate
CA2905767C (en)	2018-04-03	Soft-feel coatings
EP1382625A1 (de)	2004-01-21	Primer mit langer Offenzeit für polymere Untergründe
US5607998A (en)	1997-03-04	Process for the repair of plastic parts using non-sagging, sandable polyurethane compositions
US6399206B1 (en)	2002-06-04	Electrostatically painted polymers and a process for making same
WO2005019362A1 (en)	2005-03-03	Increased pot-life urethane coatings
US3769069A (en)	1973-10-30	Polyesterurethane coated metal
KR970009325B1 (ko)	1997-06-10	폴리에테르디올, 폴리에테르트리올, 글리세롤 및 폴리이소시아네이트로 구성되는 폴리우레탄조성물 및 그 제조방법
JPH08509998A (ja)	1996-10-22	プラスチック支持体および金属支持体を被覆するための基礎ラッカー中に使用される充填剤ペースト、基礎ラッカー、ならびに金属支持体およびプラスチック支持体を直接塗装するための方法
JPS63270579A (ja)	1988-11-08	線材被覆方法
US20220219380A1 (en)	2022-07-14	Depositing thermosetting material on a three dimensional object
US4891086A (en)	1990-01-02	Strand coating method
US4365000A (en)	1982-12-21	Molded bodies of vulcanized rubber having a vulcanized-on layer of varnish
JPH10158353A (ja)	1998-06-16	一液型熱硬化性ウレタン組成物
CA2106254A1 (en)	1994-03-18	Atomizable and sprayable lacquer, coating and sealing compositions containing synthetic resin powder as fillers