CA2145663A1 - Mildly alkaline dishwashing detergents - Google Patents

Mildly alkaline dishwashing detergents

Info

Publication number: CA2145663A1
Authority: CA; Canada
Prior art keywords: weight; detergent; sodium; around; terized
Prior art date: 1992-09-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA002145663A

Other languages

English (en)

French (fr)

Inventor

Birgit Burg

Juergen Haer'er

Peter Jeschke

Willi Buchmeier

Helmut Blum

Christian Nitsch

Heinz-Juergen Voelkel

Horst-Dieter Speckmann

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Henkel AG and Co KGaA

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-09-25

Filing date

1993-09-16

Publication date

1994-04-14

1993-09-16 Application filed by Individual filed Critical Individual

1994-04-14 Publication of CA2145663A1 publication Critical patent/CA2145663A1/en

Status Abandoned legal-status Critical Current

Links

239000003599 detergent Substances 0.000 title claims description 50
238000004851 dishwashing Methods 0.000 title claims description 11
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims abstract description 17
239000007844 bleaching agent Substances 0.000 claims abstract description 16
102000004190 Enzymes Human genes 0.000 claims abstract description 9
108090000790 Enzymes Proteins 0.000 claims abstract description 9
239000001509 sodium citrate Substances 0.000 claims abstract description 9
238000005260 corrosion Methods 0.000 claims abstract description 8
230000007797 corrosion Effects 0.000 claims abstract description 8
239000003112 inhibitor Substances 0.000 claims abstract description 8
239000012190 activator Substances 0.000 claims abstract description 7
239000007864 aqueous solution Substances 0.000 claims abstract description 4
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 26
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 18
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 13
235000017557 sodium bicarbonate Nutrition 0.000 claims description 13
239000002253 acid Substances 0.000 claims description 8
239000002736 nonionic surfactant Substances 0.000 claims description 8
229910052783 alkali metal Inorganic materials 0.000 claims description 7
229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 6
150000008041 alkali metal carbonates Chemical class 0.000 claims description 6
229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
235000017550 sodium carbonate Nutrition 0.000 claims description 6
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 claims description 5
-1 alkali metal hydrogen carbonate Chemical class 0.000 claims description 5
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 5
229920000642 polymer Polymers 0.000 claims description 5
229920000193 polymethacrylate Polymers 0.000 claims description 5
229940045872 sodium percarbonate Drugs 0.000 claims description 5
229920001059 synthetic polymer Polymers 0.000 claims description 5
108010065511 Amylases Proteins 0.000 claims description 4
102000013142 Amylases Human genes 0.000 claims description 4
239000004367 Lipase Substances 0.000 claims description 4
102000004882 Lipase Human genes 0.000 claims description 4
108090001060 Lipase Proteins 0.000 claims description 4
108091005804 Peptidases Proteins 0.000 claims description 4
239000004365 Protease Substances 0.000 claims description 4
235000019418 amylase Nutrition 0.000 claims description 4
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 4
235000019421 lipase Nutrition 0.000 claims description 4
125000004433 nitrogen atom Chemical group N* 0.000 claims description 4
XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical group CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 claims description 3
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 3
239000000470 constituent Substances 0.000 claims description 3
125000000623 heterocyclic group Chemical group 0.000 claims description 3
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 3
239000004382 Amylase Substances 0.000 claims description 2
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 2
239000004115 Sodium Silicate Substances 0.000 claims description 2
150000007513 acids Chemical class 0.000 claims description 2
150000001413 amino acids Chemical class 0.000 claims description 2
239000001913 cellulose Substances 0.000 claims description 2
229920002678 cellulose Polymers 0.000 claims description 2
229920001308 poly(aminoacid) Polymers 0.000 claims description 2
229920000058 polyacrylate Polymers 0.000 claims description 2
150000003839 salts Chemical class 0.000 claims description 2
229960001922 sodium perborate Drugs 0.000 claims description 2
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
229910052911 sodium silicate Inorganic materials 0.000 claims description 2
IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 claims description 2
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 2
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims description 2
HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical group [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 2
150000001340 alkali metals Chemical class 0.000 claims 2
229920000881 Modified starch Polymers 0.000 claims 1
239000000306 component Substances 0.000 claims 1
235000019426 modified starch Nutrition 0.000 claims 1
239000003795 chemical substances by application Substances 0.000 abstract 2
102000005701 Calcium-Binding Proteins Human genes 0.000 description 12
108010045403 Calcium-Binding Proteins Proteins 0.000 description 12
229920002125 Sokalan® Polymers 0.000 description 9
239000000203 mixture Substances 0.000 description 9
239000001226 triphosphate Substances 0.000 description 9
150000001875 compounds Chemical class 0.000 description 7
229940088598 enzyme Drugs 0.000 description 7
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 7
235000019832 sodium triphosphate Nutrition 0.000 description 7
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
125000000217 alkyl group Chemical group 0.000 description 6
238000009472 formulation Methods 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 5
229910000019 calcium carbonate Inorganic materials 0.000 description 5
238000001035 drying Methods 0.000 description 5
239000008187 granular material Substances 0.000 description 5
239000000654 additive Substances 0.000 description 4
230000000996 additive effect Effects 0.000 description 4
239000003513 alkali Substances 0.000 description 4
150000001735 carboxylic acids Chemical class 0.000 description 4
229920001577 copolymer Polymers 0.000 description 4
238000000354 decomposition reaction Methods 0.000 description 4
238000005469 granulation Methods 0.000 description 4
230000003179 granulation Effects 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
239000011575 calcium Substances 0.000 description 3
229910052791 calcium Inorganic materials 0.000 description 3
235000010216 calcium carbonate Nutrition 0.000 description 3
230000000536 complexating effect Effects 0.000 description 3
239000008139 complexing agent Substances 0.000 description 3
230000003247 decreasing effect Effects 0.000 description 3
238000005187 foaming Methods 0.000 description 3
239000011521 glass Substances 0.000 description 3
239000008233 hard water Substances 0.000 description 3
229920001519 homopolymer Polymers 0.000 description 3
229920001223 polyethylene glycol Polymers 0.000 description 3
239000000377 silicon dioxide Substances 0.000 description 3
159000000000 sodium salts Chemical class 0.000 description 3
CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 2
102000005575 Cellulases Human genes 0.000 description 2
108010084185 Cellulases Proteins 0.000 description 2
229910019142 PO4 Inorganic materials 0.000 description 2
102000035195 Peptidases Human genes 0.000 description 2
239000002202 Polyethylene glycol Substances 0.000 description 2
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric Acid Chemical compound [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
241001625808 Trona Species 0.000 description 2
UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 2
150000001253 acrylic acids Chemical class 0.000 description 2
239000013543 active substance Substances 0.000 description 2
229940025131 amylases Drugs 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
238000004061 bleaching Methods 0.000 description 2
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
239000000969 carrier Substances 0.000 description 2
239000000975 dye Substances 0.000 description 2
150000002170 ethers Chemical class 0.000 description 2
229940117927 ethylene oxide Drugs 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
239000006260 foam Substances 0.000 description 2
239000003205 fragrance Substances 0.000 description 2
VYFOAVADNIHPTR-UHFFFAOYSA-N isatoic anhydride Chemical compound NC1=CC=CC=C1CO VYFOAVADNIHPTR-UHFFFAOYSA-N 0.000 description 2
ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
239000010452 phosphate Substances 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
239000000843 powder Substances 0.000 description 2
229920002545 silicone oil Polymers 0.000 description 2
239000000243 solution Substances 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
235000011178 triphosphate Nutrition 0.000 description 2
238000005406 washing Methods 0.000 description 2
LRZSAGKIMYFLHY-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarboxylic acid;dihydrate Chemical compound O.O.OC(=O)CC(O)(C(O)=O)CC(O)=O LRZSAGKIMYFLHY-UHFFFAOYSA-N 0.000 description 1
UOQHWNPVNXSDDO-UHFFFAOYSA-N 3-bromoimidazo[1,2-a]pyridine-6-carbonitrile Chemical compound C1=CC(C#N)=CN2C(Br)=CN=C21 UOQHWNPVNXSDDO-UHFFFAOYSA-N 0.000 description 1
GWYFIIHULJCWMO-UHFFFAOYSA-N 4-methyl-1,4-dihydropyrazol-5-one Chemical compound CC1C=NNC1=O GWYFIIHULJCWMO-UHFFFAOYSA-N 0.000 description 1
GONFBOIJNUKKST-UHFFFAOYSA-N 5-ethylsulfanyl-2h-tetrazole Chemical compound CCSC=1N=NNN=1 GONFBOIJNUKKST-UHFFFAOYSA-N 0.000 description 1
WGVHNCAJPFIFCR-UHFFFAOYSA-N 5-methyl-1,2-dihydropyrazol-3-one Chemical compound CC1=CC(O)=NN1 WGVHNCAJPFIFCR-UHFFFAOYSA-N 0.000 description 1
101000740449 Bacillus subtilis (strain 168) Biotin/lipoyl attachment protein Proteins 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 description 1
HNDVDQJCIGZPNO-YFKPBYRVSA-N L-histidine Chemical compound OC(=O)[C@@H](N)CC1=CN=CN1 HNDVDQJCIGZPNO-YFKPBYRVSA-N 0.000 description 1
229920000877 Melamine resin Polymers 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
239000005662 Paraffin oil Substances 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
229920000805 Polyaspartic acid Polymers 0.000 description 1
108010020346 Polyglutamic Acid Proteins 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical group [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
229920002472 Starch Polymers 0.000 description 1
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
230000004913 activation Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
229910052910 alkali metal silicate Inorganic materials 0.000 description 1
239000004411 aluminium Substances 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
235000001014 amino acid Nutrition 0.000 description 1
229940024606 amino acid Drugs 0.000 description 1
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
239000012964 benzotriazole Substances 0.000 description 1
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
150000001639 boron compounds Chemical class 0.000 description 1
150000001642 boronic acid derivatives Chemical class 0.000 description 1
239000000872 buffer Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000011362 coarse particle Substances 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
239000013256 coordination polymer Substances 0.000 description 1
229910052906 cristobalite Inorganic materials 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
235000018417 cysteine Nutrition 0.000 description 1
XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 1
238000005034 decoration Methods 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
ZCTRSOMMTLXYCN-SDFKWCIISA-L dipotassium;(2s,3s,4s,5r)-2,3,4,5-tetrahydroxyhexanedioate Chemical compound [K+].[K+].[O-]C(=O)[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O ZCTRSOMMTLXYCN-SDFKWCIISA-L 0.000 description 1
FGJLAJMGHXGFDE-UHFFFAOYSA-L disodium;2,3-dihydroxybutanedioate;dihydrate Chemical group O.O.[Na+].[Na+].[O-]C(=O)C(O)C(O)C([O-])=O FGJLAJMGHXGFDE-UHFFFAOYSA-L 0.000 description 1
238000009826 distribution Methods 0.000 description 1
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
235000013305 food Nutrition 0.000 description 1
239000010794 food waste Substances 0.000 description 1
239000008103 glucose Substances 0.000 description 1
PMYUVOOOQDGQNW-UHFFFAOYSA-N hexasodium;trioxido(trioxidosilyloxy)silane Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] PMYUVOOOQDGQNW-UHFFFAOYSA-N 0.000 description 1
229960002885 histidine Drugs 0.000 description 1
235000014304 histidine Nutrition 0.000 description 1
HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
238000010952 in-situ formation Methods 0.000 description 1
230000002401 inhibitory effect Effects 0.000 description 1
238000002372 labelling Methods 0.000 description 1
229940099563 lactobionic acid Drugs 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
108010020132 microbial serine proteinases Proteins 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
231100000344 non-irritating Toxicity 0.000 description 1
239000001254 oxidized starch Substances 0.000 description 1
235000013808 oxidized starch Nutrition 0.000 description 1
239000002245 particle Substances 0.000 description 1
125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
239000004584 polyacrylic acid Substances 0.000 description 1
229920001515 polyalkylene glycol Polymers 0.000 description 1
108010064470 polyaspartate Proteins 0.000 description 1
229920001748 polybutylene Polymers 0.000 description 1
229920002643 polyglutamic acid Polymers 0.000 description 1
229920001451 polypropylene glycol Polymers 0.000 description 1
XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
UPMFZISCCZSDND-JJKGCWMISA-M sodium gluconate Chemical compound [Na+].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O UPMFZISCCZSDND-JJKGCWMISA-M 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical group [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000008107 starch Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
239000007858 starting material Substances 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
238000003860 storage Methods 0.000 description 1
238000005494 tarnishing Methods 0.000 description 1
239000011975 tartaric acid Substances 0.000 description 1
235000002906 tartaric acid Nutrition 0.000 description 1
108010075550 termamyl Proteins 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
229940048102 triphosphoric acid Drugs 0.000 description 1
WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
239000000080 wetting agent Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38609—Protease or amylase in solid compositions only
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Health & Medical Sciences (AREA)
Emergency Medicine (AREA)
Detergent Compositions (AREA)

CA002145663A 1992-09-25 1993-09-16 Mildly alkaline dishwashing detergents Abandoned CA2145663A1 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE4232170A DE4232170C2 (de)	1992-09-25	1992-09-25	Schwachalkalische Geschirreinigungsmittel
DEP4232170.0		1992-09-25

Publications (1)

Publication Number	Publication Date
CA2145663A1 true CA2145663A1 (en)	1994-04-14

Family

ID=6468844

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002145663A Abandoned CA2145663A1 (en)	1992-09-25	1993-09-16	Mildly alkaline dishwashing detergents

Country Status (10)

Country	Link
EP (1)	EP0662117B1 (de)
JP (1)	JPH08501598A (de)
AT (1)	ATE194012T1 (de)
CA (1)	CA2145663A1 (de)
DE (2)	DE4232170C2 (de)
DK (1)	DK0662117T3 (de)
ES (1)	ES2148239T3 (de)
GR (1)	GR3033851T3 (de)
PT (1)	PT662117E (de)
WO (1)	WO1994007981A1 (de)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US7879154B2 (en)	2007-02-06	2011-02-01	Henkel Ag & Co. Kgaa	Phosphate-free dishwashing detergents comprising builder, bleaching agent, nonionic surfactant, copolymer and a phosphonate
US8303721B2 (en)	2007-02-06	2012-11-06	Henkel Ag & Co. Kgaa	Detergent comprising a builder, a bleaching agent, and a copolymer
US9752100B2 (en)	2007-02-06	2017-09-05	Henkel Ag & Co. Kgaa	Detergents

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CA2162459A1 (en) *	1993-05-08	1994-11-24	Juergen Haerer	Corrosion inhibitors for silver (ii)
US5389303A (en) *	1993-09-10	1995-02-14	Srchem Incorporated	Mixtures of polyamino acids and citrate
DE69413055T2 (de) *	1993-11-03	1999-05-06	The Procter & Gamble Co., Cincinnati, Ohio	Kalziumkarbonatabsetzungskontrolle in geschirrspuelmaschinen
WO1997008281A1 (de) *	1995-08-25	1997-03-06	Henkel Kommanditgesellschaft Auf Aktien	Verwendung von lipasen in niederalkalischen mitteln zum maschinellen geschirrspülen
DE19532304A1 (de) *	1995-09-01	1997-03-06	Henkel Kgaa	Verfahren zur Herstellung granularer Vorprodukte niederalkalischer Reinigungsmittel
DE19540086A1 (de) *	1995-10-27	1997-04-30	Henkel Kgaa	Verwendung von polymeren Aminodicarbonsäuren in Waschmitteln
DE19603760A1 (de) *	1996-02-02	1997-08-07	Henkel Kgaa	Feste Reinigungsmittelzubereitungen
DE19606765A1 (de) *	1996-02-23	1997-08-28	Henkel Kgaa	Verfahren zur Herstellung von Geschirrspülmitteltabletten
DE19649375A1 (de)	1996-11-29	1998-06-04	Henkel Kgaa	Acetonitril-Derivate als Bleichaktivatoren in Reinigungsmitteln
DE19752601C1 (de) *	1997-11-28	1998-12-10	Henkel Kgaa	Verfahren zur Herstellung von Geschirrspülmitteltabletten
DE19908051A1 (de)	1999-02-25	2000-08-31	Henkel Kgaa	Verfahren zur Herstellung compoundierter Acetonitril-Derivate
US6447717B1 (en) *	1999-06-04	2002-09-10	Donlar Corporation	Composition and method for inhibition of metal corrosion
GB2353800A (en) *	1999-09-02	2001-03-07	Procter & Gamble	Antibacterial detergent compositions
JP2004269843A (ja) *	2003-02-19	2004-09-30	Kumano Yushi Kk	自動食器洗い機用洗浄剤
US7271138B2 (en) *	2003-10-16	2007-09-18	The Procter & Gamble Company	Compositions for protecting glassware from surface corrosion in automatic dishwashing appliances
DE102007006627A1 (de)	2007-02-06	2008-08-07	Henkel Ag & Co. Kgaa	Reinigungsmittel
DE102007044418A1 (de)	2007-09-17	2009-03-19	Henkel Ag & Co. Kgaa	Reinigungsmittel
DE102007044417A1 (de)	2007-09-17	2009-03-19	Henkel Ag & Co. Kgaa	Reinigungsmittel
DE102007059677A1 (de)	2007-12-10	2009-06-25	Henkel Ag & Co. Kgaa	Reinigungsmittel
DE102008060470A1 (de)	2008-12-05	2010-06-10	Henkel Ag & Co. Kgaa	Reinigungsmittel
DE102008063801A1 (de)	2008-12-19	2010-06-24	Henkel Ag & Co. Kgaa	Maschinelles Geschirrspülmittel
DE102009029636A1 (de)	2009-09-21	2011-03-24	Henkel Ag & Co. Kgaa	Maschine Geschirrspülmittel
DE102009029635A1 (de)	2009-09-21	2011-03-24	Henkel Ag & Co. Kgaa	Maschinelles Geschirrspülmittel
DE102009029637A1 (de)	2009-09-21	2011-03-24	Henkel Ag & Co. Kgaa	Maschinelles Geschirrspülmittel
DE102009046216A1 (de)	2009-10-30	2011-05-12	Henkel Ag & Co. Kgaa	Maschinelles Geschirrspülmittel
DE102011007695A1 (de)	2011-04-19	2012-10-25	Henkel Ag & Co. Kgaa	Phosphatfreies Geschirrspülmittel
WO2014200656A1 (en)	2013-06-13	2014-12-18	Danisco Us Inc.	Alpha-amylase from streptomyces umbrinus
WO2014200657A1 (en)	2013-06-13	2014-12-18	Danisco Us Inc.	Alpha-amylase from streptomyces xiamenensis
WO2014200658A1 (en)	2013-06-13	2014-12-18	Danisco Us Inc.	Alpha-amylase from promicromonospora vindobonensis
EP3011020A1 (de)	2013-06-17	2016-04-27	Danisco US Inc.	Alpha-amylase aus einem mitglied der bacillaceae-familie
US20160160199A1 (en)	2013-10-03	2016-06-09	Danisco Us Inc.	Alpha-amylases from exiguobacterium, and methods of use, thereof
WO2015050724A1 (en)	2013-10-03	2015-04-09	Danisco Us Inc.	Alpha-amylases from a subset of exiguobacterium, and methods of use, thereof
MX2016006489A (es)	2013-11-20	2016-08-03	Danisco Us Inc	Alfa-amilasas variantes que tienen susceptibilidad reducida a la escision por proteasas y metodos de uso.
WO2017173190A2 (en)	2016-04-01	2017-10-05	Danisco Us Inc.	Alpha-amylases, compositions & methods
WO2017173324A2 (en)	2016-04-01	2017-10-05	Danisco Us Inc.	Alpha-amylases, compositions & methods
EP3257929B1 (de)	2016-06-17	2022-03-09	The Procter & Gamble Company	Spülmittelzusammensetzung für automatisches geschirrspülen
DE102016212248A1 (de)	2016-07-05	2018-01-11	Henkel Ag & Co. Kgaa	Geschirrspülmittel enthaltend Zuckersäure und Aminocarbonsäure
DE102017212561A1 (de) *	2017-07-21	2019-01-24	Henkel Ag & Co. Kgaa	Geschirrspülmittel enthaltend Citratdihydrat und -anhydrat
CN120322535A (zh) *	2022-12-14	2025-07-15	高露洁-棕榄公司	家庭护理组合物

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FR1544393A (fr)	1966-11-14	1968-10-31	Unilever Nv	Compositions détergentes
US4162289A (en)	1977-02-25	1979-07-24	Internacional de Ciencia y Tecnologia, S.A.	Filter unit for avoiding environmental pollution in cemeteries
DE3321082C2 (de)	1982-06-10	1996-08-22	Kao Corp	Bleich-Reinigungsmittel
GB8321923D0 (en)	1983-08-15	1983-09-14	Unilever Plc	Machine-dishwashing compositions
GB8321924D0 (en)	1983-08-15	1983-09-14	Unilever Plc	Enzymatic machine-dishwashing compositions
JPH01146998A (ja)	1987-12-04	1989-06-08	Matsushita Electric Ind Co Ltd	食器洗い機用洗剤
CA2023529A1 (en)	1989-08-22	1991-02-23	Guido Waschenbach	Dish-washer detergent composition
WO1992009680A1 (en) *	1990-11-14	1992-06-11	The Procter & Gamble Company	Nonphosphated dishwashing compositions with oxygen bleach systems
DE4110510A1 (de) *	1991-03-30	1992-10-01	Henkel Kgaa	Niederalkalische, chlor- und phosphatfreie maschinengeschirrspuelmittel in form von schwerpulvern und -granulaten
DE4112075A1 (de) *	1991-04-12	1992-10-15	Henkel Kgaa	Verfahren zur herstellung stabiler, bifunktioneller, phospat- und metasilikatfreier niederalkalischer reinigungsmitteltabletten fuer das maschinelle geschirrspuelen
DE4121307A1 (de) *	1991-06-27	1993-01-07	Henkel Kgaa	Verfahren zur herstellung stabiler, bifunktioneller, phosphat- und metasilikatfreier niederalkalischer reinigungsmitteltabletten fuer das maschinelle geschirrspuelen
ATE153056T1 (de) *	1991-08-29	1997-05-15	Benckiser Gmbh Joh A	Neutrales maschinelles geschirrspülmittel
EP0626996A1 (de) *	1992-02-20	1994-12-07	Henkel Kommanditgesellschaft auf Aktien	Verfahren zur herstellung niederalkalischer, aktivchlor-, silikat-, und phosphatfreier maschinengeschirrspülmittel in form von schwergranulaten
DE4205071A1 (de) *	1992-02-20	1993-08-26	Henkel Kgaa	Verfahren zur herstellung niederalkalischer, aktivchlor-, silikat- und phosphatfreier maschinengeschirrspuelmittel in form von schwergranulaten
EP0630400A1 (de)	1992-03-12	1994-12-28	The Procter & Gamble Company	Niedrig zu dosierendes spülmittel für die geschirrspülmaschine aus monopersulfalt und enzymen
DE4228786A1 (de) *	1992-08-29	1994-03-03	Henkel Kgaa	Geschirrspülmittel mit ausgewähltem Builder-System

1992
- 1992-09-25 DE DE4232170A patent/DE4232170C2/de not_active Expired - Fee Related
1993
- 1993-09-16 AT AT93920745T patent/ATE194012T1/de active
- 1993-09-16 PT PT93920745T patent/PT662117E/pt unknown
- 1993-09-16 DE DE59310064T patent/DE59310064D1/de not_active Expired - Lifetime
- 1993-09-16 WO PCT/EP1993/002510 patent/WO1994007981A1/de not_active Ceased
- 1993-09-16 EP EP93920745A patent/EP0662117B1/de not_active Expired - Lifetime
- 1993-09-16 DK DK93920745T patent/DK0662117T3/da active
- 1993-09-16 ES ES93920745T patent/ES2148239T3/es not_active Expired - Lifetime
- 1993-09-16 CA CA002145663A patent/CA2145663A1/en not_active Abandoned
- 1993-09-16 JP JP6508635A patent/JPH08501598A/ja active Pending
2000
- 2000-06-30 GR GR20000401553T patent/GR3033851T3/el not_active IP Right Cessation

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US7879154B2 (en)	2007-02-06	2011-02-01	Henkel Ag & Co. Kgaa	Phosphate-free dishwashing detergents comprising builder, bleaching agent, nonionic surfactant, copolymer and a phosphonate
US8303721B2 (en)	2007-02-06	2012-11-06	Henkel Ag & Co. Kgaa	Detergent comprising a builder, a bleaching agent, and a copolymer
US9752100B2 (en)	2007-02-06	2017-09-05	Henkel Ag & Co. Kgaa	Detergents

Also Published As

Publication number	Publication date
EP0662117B1 (de)	2000-06-21
PT662117E (pt)	2000-12-29
ATE194012T1 (de)	2000-07-15
DE4232170C2 (de)	1999-09-16
JPH08501598A (ja)	1996-02-20
DK0662117T3 (da)	2000-10-23
DE59310064D1 (de)	2000-07-27
DE4232170A1 (de)	1994-03-31
GR3033851T3 (en)	2000-10-31
ES2148239T3 (es)	2000-10-16
EP0662117A1 (de)	1995-07-12
WO1994007981A1 (de)	1994-04-14

Legal Events

Date	Code	Title	Description
2000-09-15	EEER	Examination request
2002-09-16	FZDE	Discontinued

Publication	Publication Date	Title
US5898025A (en)	1999-04-27	Mildly alkaline dishwashing detergents
CA2145663A1 (en)	1994-04-14	Mildly alkaline dishwashing detergents
CA1227716A (en)	1987-10-06	Detergent bleach compositions
US5246612A (en)	1993-09-21	Machine dishwashing composition containing peroxygen bleach, manganese complex and enzymes
EP0504091B1 (de)	1999-06-09	Phosphatfreies Maschinengeschirrspülmittel
US5525121A (en)	1996-06-11	Dioxirane compounds useful for bleaching fabrics
US5240633A (en)	1993-08-31	Liquid automatic dishwashing composition containing enzymes
EP0518720B1 (de)	1995-09-06	Enzyme enthaltenes nichtwässriges flüssiges Maschinengeschirrspülmittel
US4568477A (en)	1986-02-04	Detergent bleach compositions
US5527483A (en)	1996-06-18	Nonaqueous gelled automatic dishwashing composition containing enzymes
EP2392639A1 (de)	2011-12-07	Mischung aus einem Tensid mit einer Festverbindung zur Verbesserung der Spülleistung von automatischen Geschirrspülmitteln
AU667600B2 (en)	1996-03-28	Nonaqueous gelled automatic dishwashing composition containing enzymes
CA2023529A1 (en)	1991-02-23	Dish-washer detergent composition
US7456143B2 (en)	2008-11-25	Bleach-containing washing or cleaning agents containing a sulfate/silicate coated percarbonate
JP2012500871A (ja)	2012-01-12	マンガン塩及びシュウ酸もしくはそれの塩からなる漂白触媒混合物
US5545344A (en)	1996-08-13	Nonaqueous liquid, improved automatic dishwashing composition containing enzymes
US5527484A (en)	1996-06-18	Phosphate containing powdered automatic dishwashing composition with enzymes
NZ242839A (en)	1995-04-27	Powdered dishwashing detergent containing phosphate, a bacillus strain of a protease enzyme and an amylase enzyme
US5318715A (en)	1994-06-07	Liquid automatic dishwashing composition containing two enzymes
CA2166277A1 (en)	1995-01-05	Dishwashing detergents containing a biologically degradable builder component
EP0516555A2 (de)	1992-12-02	Pulverförmige phosphatenthaltende Zusammensetzung mit Enzymen für Geschirrspülmaschinen
CZ286098B6 (cs)	2000-01-12	Prostředek pro mytí nádobí
CA2166186A1 (en)	1995-01-05	Dishwashing detergents containing a biologically degradable builder component
US20060281655A1 (en)	2006-12-14	Bleaching detergent or cleaning agent
EP0463801A2 (de)	1992-01-02	Zusammensetzung und Methode zur Verhinderung von Gewebeverkrustung

CA2145663A1 - Mildly alkaline dishwashing detergents - Google Patents

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Applications Claiming Priority (2)

Publications (1)

Family

ID=6468844

Family Applications (1)

Country Status (10)

Cited By (3)

Families Citing this family (39)

Family Cites Families (16)

Cited By (3)

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