CA2153312C - Composition detergente et procede de production - Google Patents

Composition detergente et procede de production Download PDF

Info

Publication number: CA2153312C
Authority: CA; Canada
Prior art keywords: weight; detergent composition; dissolution aid; nonionic; surfactant system
Prior art date: 1993-01-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA002153312A

Other languages

English (en)

Other versions

CA2153312A1 (fr

Inventor

Mark Phillip Houghton

Fransiscus Hermannus Gortemaker

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever PLC

Original Assignee

Unilever PLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1993-01-08

Filing date

1993-12-17

Publication date

2003-09-16

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=10728467&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2153312(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1993-12-17 Application filed by Unilever PLC filed Critical Unilever PLC

1994-07-21 Publication of CA2153312A1 publication Critical patent/CA2153312A1/fr

2003-09-16 Application granted granted Critical

2003-09-16 Publication of CA2153312C publication Critical patent/CA2153312C/fr

2013-12-17 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 74
239000003599 detergent Substances 0.000 title claims abstract description 46
238000000034 method Methods 0.000 title claims description 16
230000008569 process Effects 0.000 title claims description 14
238000004090 dissolution Methods 0.000 claims abstract description 30
239000002736 nonionic surfactant Substances 0.000 claims abstract description 25
239000004094 surface-active agent Substances 0.000 claims abstract description 19
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims abstract description 14
125000002947 alkylene group Chemical group 0.000 claims abstract description 14
125000000129 anionic group Chemical group 0.000 claims abstract description 5
239000003945 anionic surfactant Substances 0.000 claims abstract description 5
239000000463 material Substances 0.000 claims description 18
-1 alkylbenzene sulphonate Chemical class 0.000 claims description 13
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 9
238000007046 ethoxylation reaction Methods 0.000 claims description 5
238000002156 mixing Methods 0.000 claims description 5
229910019142 PO4 Inorganic materials 0.000 claims description 4
229910021653 sulphate ion Inorganic materials 0.000 claims description 4
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
239000007859 condensation product Substances 0.000 claims description 2
238000004519 manufacturing process Methods 0.000 claims description 2
235000021317 phosphate Nutrition 0.000 claims 1
150000003013 phosphoric acid derivatives Chemical class 0.000 claims 1
239000000843 powder Substances 0.000 description 50
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 16
229910021536 Zeolite Inorganic materials 0.000 description 15
239000002585 base Substances 0.000 description 15
239000010457 zeolite Substances 0.000 description 15
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 12
238000005406 washing Methods 0.000 description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
239000004615 ingredient Substances 0.000 description 8
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
150000001298 alcohols Chemical class 0.000 description 6
229910052783 alkali metal Inorganic materials 0.000 description 6
230000000052 comparative effect Effects 0.000 description 6
229910052708 sodium Inorganic materials 0.000 description 6
239000011734 sodium Substances 0.000 description 6
229910000029 sodium carbonate Inorganic materials 0.000 description 6
238000001694 spray drying Methods 0.000 description 6
238000012360 testing method Methods 0.000 description 6
229910000323 aluminium silicate Inorganic materials 0.000 description 5
230000000740 bleeding effect Effects 0.000 description 5
235000014113 dietary fatty acids Nutrition 0.000 description 5
239000000194 fatty acid Substances 0.000 description 5
229930195729 fatty acid Natural products 0.000 description 5
102000004190 Enzymes Human genes 0.000 description 4
108090000790 Enzymes Proteins 0.000 description 4
239000007844 bleaching agent Substances 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
239000004744 fabric Substances 0.000 description 4
229920001983 poloxamer Polymers 0.000 description 4
229920005646 polycarboxylate Polymers 0.000 description 4
150000003839 salts Chemical class 0.000 description 4
239000000344 soap Substances 0.000 description 4
239000003760 tallow Substances 0.000 description 4
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
229910000503 Na-aluminosilicate Inorganic materials 0.000 description 3
229920001030 Polyethylene Glycol 4000 Polymers 0.000 description 3
239000004115 Sodium Silicate Substances 0.000 description 3
235000021355 Stearic acid Nutrition 0.000 description 3
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 3
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 3
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
150000001340 alkali metals Chemical class 0.000 description 3
230000008901 benefit Effects 0.000 description 3
239000001768 carboxy methyl cellulose Substances 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
150000004665 fatty acids Chemical class 0.000 description 3
239000008187 granular material Substances 0.000 description 3
238000005469 granulation Methods 0.000 description 3
230000003179 granulation Effects 0.000 description 3
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
239000002304 perfume Substances 0.000 description 3
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
239000010452 phosphate Substances 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
239000002002 slurry Substances 0.000 description 3
235000012217 sodium aluminium silicate Nutrition 0.000 description 3
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 3
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 3
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
229910052911 sodium silicate Inorganic materials 0.000 description 3
239000008117 stearic acid Substances 0.000 description 3
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
229920006243 acrylic copolymer Polymers 0.000 description 2
239000011149 active material Substances 0.000 description 2
238000005054 agglomeration Methods 0.000 description 2
230000002776 aggregation Effects 0.000 description 2
239000004411 aluminium Substances 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
239000002518 antifoaming agent Substances 0.000 description 2
238000000280 densification Methods 0.000 description 2
238000007580 dry-mixing Methods 0.000 description 2
239000006260 foam Substances 0.000 description 2
238000009472 formulation Methods 0.000 description 2
230000006872 improvement Effects 0.000 description 2
238000005342 ion exchange Methods 0.000 description 2
239000002245 particle Substances 0.000 description 2
229920000058 polyacrylate Polymers 0.000 description 2
229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 2
239000002689 soil Substances 0.000 description 2
238000003860 storage Methods 0.000 description 2
CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical class OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 1
CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical class OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
GIVLOEWMYMRPJA-UHFFFAOYSA-N 2-[carboxymethyl(ethyl)amino]-2-hydroxyacetic acid Chemical class OC(=O)CN(CC)C(O)C(O)=O GIVLOEWMYMRPJA-UHFFFAOYSA-N 0.000 description 1
XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 1
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
102000005701 Calcium-Binding Proteins Human genes 0.000 description 1
108010045403 Calcium-Binding Proteins Proteins 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 description 1
229920000742 Cotton Polymers 0.000 description 1
229940120146 EDTMP Drugs 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
244000020551 Helianthus annuus Species 0.000 description 1
235000003222 Helianthus annuus Nutrition 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
235000019484 Rapeseed oil Nutrition 0.000 description 1
229920002125 Sokalan® Polymers 0.000 description 1
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
239000004809 Teflon Substances 0.000 description 1
229920006362 Teflon® Polymers 0.000 description 1
229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
150000008041 alkali metal carbonates Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
239000002280 amphoteric surfactant Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
STNSYZSNIYTNMI-UHFFFAOYSA-N azane;[2-[bis(phosphonomethyl)amino]ethyl-(phosphonomethyl)amino]methylphosphonic acid Chemical compound N.OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O STNSYZSNIYTNMI-UHFFFAOYSA-N 0.000 description 1
235000015278 beef Nutrition 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
229910001424 calcium ion Inorganic materials 0.000 description 1
159000000007 calcium salts Chemical class 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000001860 citric acid derivatives Chemical class 0.000 description 1
235000019864 coconut oil Nutrition 0.000 description 1
239000003240 coconut oil Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000000881 depressing effect Effects 0.000 description 1
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
239000000975 dye Substances 0.000 description 1
NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 1
239000003925 fat Substances 0.000 description 1
235000019197 fats Nutrition 0.000 description 1
239000012530 fluid Substances 0.000 description 1
125000005456 glyceride group Chemical group 0.000 description 1
230000036571 hydration Effects 0.000 description 1
238000006703 hydration reaction Methods 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
229910052816 inorganic phosphate Inorganic materials 0.000 description 1
230000002366 lipolytic effect Effects 0.000 description 1
238000011068 loading method Methods 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
230000005012 migration Effects 0.000 description 1
238000013508 migration Methods 0.000 description 1
239000003921 oil Substances 0.000 description 1
235000019198 oils Nutrition 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
230000035515 penetration Effects 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
239000011148 porous material Substances 0.000 description 1
239000002243 precursor Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
230000002797 proteolythic effect Effects 0.000 description 1
239000002994 raw material Substances 0.000 description 1
230000009467 reduction Effects 0.000 description 1
239000003352 sequestering agent Substances 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
229910052814 silicon oxide Inorganic materials 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
229940045872 sodium percarbonate Drugs 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
235000019832 sodium triphosphate Nutrition 0.000 description 1
238000005507 spraying Methods 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
150000003890 succinate salts Chemical class 0.000 description 1
239000002352 surface water Substances 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

CA002153312A 1993-01-08 1993-12-17 Composition detergente et procede de production Expired - Fee Related CA2153312C (fr)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
GB9300311.9		1993-01-08
GB939300311A GB9300311D0 (en)	1993-01-08	1993-01-08	Detergent powders and process for preparing them
PCT/EP1993/003624 WO1994016052A1 (fr)	1993-01-08	1993-12-17	Composition detergente et son procede de production

Publications (2)

Publication Number	Publication Date
CA2153312A1 CA2153312A1 (fr)	1994-07-21
CA2153312C true CA2153312C (fr)	2003-09-16

Family

ID=10728467

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002153312A Expired - Fee Related CA2153312C (fr)	1993-01-08	1993-12-17	Composition detergente et procede de production

Country Status (10)

Country	Link
EP (1)	EP0678119B2 (fr)
JP (1)	JPH08505177A (fr)
AU (1)	AU5814294A (fr)
BR (1)	BR9307809A (fr)
CA (1)	CA2153312C (fr)
DE (1)	DE69314056T3 (fr)
ES (1)	ES2107805T5 (fr)
GB (1)	GB9300311D0 (fr)
WO (1)	WO1994016052A1 (fr)
ZA (1)	ZA939731B (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE19526483A1 (de) *	1995-07-20	1997-01-23	Henkel Kgaa	Tensidabmischungen mit verbesserter Löslichkeit von Aniontensiden auf Basis langkettiger Alkylsulfatsalze auch bei niederen Flottentemperaturen
CN1170921C (zh) *	1999-06-14	2004-10-13	花王株式会社	基本颗粒物和颗粒状洗涤剂
US6818606B1 (en)	1999-06-16	2004-11-16	Kao Corporation	Article for use in washing in sheet form
DE60040462D1 (de) *	1999-06-16	2008-11-20	Kao Corp	Teilchenförmiges waschmitteladditiv
GB0030669D0 (en)	2000-12-15	2001-01-31	Unilever Plc	Detergent compositions
GB0030671D0 (en) *	2000-12-15	2001-01-31	Unilever Plc	Detergent compositions
GB0124308D0 (en) *	2001-10-10	2001-11-28	Unilever Plc	Detergent compositions
GB0124307D0 (en) *	2001-10-10	2001-11-28	Unilever Plc	Detergent compositions
AU2003277486B2 (en)	2002-11-04	2007-11-15	Unilever Plc	Laundry detergent composition
EP1690922A1 (fr) *	2005-02-11	2006-08-16	The Procter & Gamble Company	Composition détergente solide
ATE474906T1 (de)	2006-05-31	2010-08-15	Procter & Gamble	Reinigungsmittel mit amphiphilen pfropfpolymeren auf basis von polyalkylenoxiden und vinylestern
EP2823029A1 (fr)	2012-03-09	2015-01-14	The Procter & Gamble Company	Compositions détergentes comprenant des polymères greffés ayant une large distribution de polarité

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
PH14838A (en) †	1974-03-21	1981-12-16	Procter & Gamble	Detergent composition
US4137197A (en) *	1977-11-10	1979-01-30	Lever Brothers Company	Powdered detergent compositions containing a calcium salt of an anionic surfactant
EP0026013B1 (fr) †	1979-09-21	1983-09-07	THE PROCTER & GAMBLE COMPANY	Compositions de lavage et d'assouplissement et procédés pour leur production
GB8323131D0 (en) †	1983-08-27	1983-09-28	Procter & Gamble Ltd	Detergent compositions
GB8712285D0 (en) †	1987-05-23	1987-07-01	Procter & Gamble	Laundry products
DE69104972T2 (de) †	1991-01-16	1995-05-18	Procter & Gamble	Schaumkontrollmittel in granulierter Form.
GB9108639D0 (en) †	1991-04-23	1991-06-12	Procter & Gamble	Particulate detergent compositions
DE4124701A1 (de) *	1991-07-25	1993-01-28	Henkel Kgaa	Verfahren zur herstellung fester wasch- und reinigungsmittel mit hohem schuettgewicht und verbesserter loesegeschwindigkeit
DE69231555T2 (de) *	1992-03-17	2001-06-07	The Procter & Gamble Company, Cincinnati	Verdünnbare Zusammensetzungen und Verfahren zur Reinigung harter Oberflächen
DE69225702T2 (de) *	1992-07-15	1999-01-21	The Procter & Gamble Co., Cincinnati, Ohio	Verfahren zur Herstellung von kompakten Reinigungsmitteln

1993
- 1993-01-08 GB GB939300311A patent/GB9300311D0/en active Pending
- 1993-12-17 EP EP94903842A patent/EP0678119B2/fr not_active Expired - Lifetime
- 1993-12-17 CA CA002153312A patent/CA2153312C/fr not_active Expired - Fee Related
- 1993-12-17 AU AU58142/94A patent/AU5814294A/en not_active Abandoned
- 1993-12-17 ES ES94903842T patent/ES2107805T5/es not_active Expired - Lifetime
- 1993-12-17 JP JP6515635A patent/JPH08505177A/ja active Pending
- 1993-12-17 WO PCT/EP1993/003624 patent/WO1994016052A1/fr not_active Ceased
- 1993-12-17 BR BR9307809A patent/BR9307809A/pt not_active IP Right Cessation
- 1993-12-17 DE DE69314056T patent/DE69314056T3/de not_active Expired - Lifetime
- 1993-12-28 ZA ZA939731A patent/ZA939731B/xx unknown

Also Published As

Publication number	Publication date
DE69314056D1 (de)	1997-10-23
EP0678119A1 (fr)	1995-10-25
JPH08505177A (ja)	1996-06-04
EP0678119B1 (fr)	1997-09-17
DE69314056T3 (de)	2006-02-02
ES2107805T5 (es)	2005-12-01
ZA939731B (en)	1995-06-28
ES2107805T3 (es)	1997-12-01
BR9307809A (pt)	1995-11-14
GB9300311D0 (en)	1993-03-03
AU5814294A (en)	1994-08-15
CA2153312A1 (fr)	1994-07-21
WO1994016052A1 (fr)	1994-07-21
DE69314056T2 (de)	1998-01-22
EP0678119B2 (fr)	2005-05-25

Legal Events

Date	Code	Title	Description
2000-10-05	EEER	Examination request
2008-12-17	MKLA	Lapsed

Publication	Publication Date	Title
US5139693A (en)	1992-08-18	Granular adsorbent having improved flushing properties
AU647681B2 (en)	1994-03-24	Detergent compositions
EP0221776A2 (fr)	1987-05-13	Compositions détergentes, parties constituantes et leurs procédés de préparation
CA2028204A1 (fr)	1991-04-28	Compositions detergentes
AU662586B2 (en)	1995-09-07	Detergent compositions
JPH0798960B2 (ja)	1995-10-25	高嵩密度顆粒状洗剤組成物及びその製造方法
CA2153312C (fr)	2003-09-16	Composition detergente et procede de production
EP0670888B1 (fr)	1998-02-04	Compositions detergentes
US5583098A (en)	1996-12-10	Detergent compositions
US6900170B2 (en)	2005-05-31	Granular composition
EP0745117B1 (fr)	1997-12-10	Composition detergente contenant un copolymere greffe
EP0700427B1 (fr)	1997-09-17	Compositions detergentes
EP0670887B1 (fr)	1998-02-04	Compositions detergentes