CA2186222A1 - Diaphragm reactor for converting gaseous base materials - Google Patents
Diaphragm reactor for converting gaseous base materialsInfo
- Publication number
- CA2186222A1 CA2186222A1 CA002186222A CA2186222A CA2186222A1 CA 2186222 A1 CA2186222 A1 CA 2186222A1 CA 002186222 A CA002186222 A CA 002186222A CA 2186222 A CA2186222 A CA 2186222A CA 2186222 A1 CA2186222 A1 CA 2186222A1
- Authority
- CA
- Canada
- Prior art keywords
- membrane
- methanol
- reaction
- fact
- synthesis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000463 material Substances 0.000 title description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 189
- 239000012528 membrane Substances 0.000 claims abstract description 70
- 238000006243 chemical reaction Methods 0.000 claims abstract description 51
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 47
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 44
- 229910001868 water Inorganic materials 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000011541 reaction mixture Substances 0.000 claims abstract description 13
- 239000012808 vapor phase Substances 0.000 claims abstract description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000007789 gas Substances 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 28
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 20
- 239000000047 product Substances 0.000 claims description 20
- 239000003054 catalyst Substances 0.000 claims description 17
- 239000002253 acid Substances 0.000 claims description 11
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 11
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 239000001569 carbon dioxide Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 238000000926 separation method Methods 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 229920003936 perfluorinated ionomer Polymers 0.000 claims description 6
- 239000012466 permeate Substances 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 239000011701 zinc Substances 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 230000035699 permeability Effects 0.000 claims description 4
- 229920005597 polymer membrane Polymers 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 3
- 150000001768 cations Chemical group 0.000 claims description 3
- 229910001416 lithium ion Inorganic materials 0.000 claims description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical group [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims 1
- 125000002091 cationic group Chemical group 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 6
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 238000011010 flushing procedure Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000012510 hollow fiber Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000557 Nafion® Polymers 0.000 description 1
- 230000018199 S phase Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
- B01J12/007—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2475—Membrane reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
- B01J8/009—Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/152—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the reactor used
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/04—Methanol
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH01050/94A CH687004A5 (de) | 1994-04-08 | 1994-04-08 | Membranreaktor fuer die Umsetzung von gasfoermigen Ausgangsstoffen. |
| CH1050/94-0 | 1994-04-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2186222A1 true CA2186222A1 (en) | 1995-10-19 |
Family
ID=4201286
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002186222A Abandoned CA2186222A1 (en) | 1994-04-08 | 1995-04-04 | Diaphragm reactor for converting gaseous base materials |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0754172A1 (de) |
| JP (1) | JPH09511509A (de) |
| CN (1) | CN1147241A (de) |
| AU (1) | AU2065595A (de) |
| CA (1) | CA2186222A1 (de) |
| CH (1) | CH687004A5 (de) |
| WO (1) | WO1995027690A1 (de) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2974785A1 (de) * | 2014-07-14 | 2016-01-20 | Akzo Nobel Chemicals International B.V. | Verfahren zur Trennung von Methanol und Wasser aus nichtkondensierbaren Substanzen |
| EP3743202A1 (de) * | 2018-01-26 | 2020-12-02 | Nederlandse Organisatie voor toegepast- natuurwetenschappelijk Onderzoek TNO | Reaktor und verfahren zur hydrierung von kohlendioxid |
| US12139450B2 (en) | 2021-05-13 | 2024-11-12 | ESEP Inc. | CO2 conversion device |
| US12257557B2 (en) | 2018-08-02 | 2025-03-25 | Mitsubishi Chemical Corporation | Bonded body, separation membrane module equipped with same, and method for producing alcohol |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1117612C (zh) * | 2000-01-31 | 2003-08-13 | 暨南大学 | 烃类选择氧化的管状催化膜反应器 |
| US7019039B1 (en) * | 2005-07-14 | 2006-03-28 | Starchem Technologies, Inc. | High efficiency process for producing methanol from a synthesis gas |
| JP2007055970A (ja) * | 2005-08-26 | 2007-03-08 | Mitsui Eng & Shipbuild Co Ltd | メタノール製造用反応器及びメタノール製造方法 |
| GB0718398D0 (en) * | 2007-09-21 | 2007-10-31 | Robert Gordon The University | Process for the production of alcohols |
| CN102584526B (zh) * | 2011-12-28 | 2014-09-10 | 上海碧科清洁能源技术有限公司 | 一种由合成气制备甲醇的膜接触器方法以及用于该方法的膜反应器 |
| JP7049075B2 (ja) * | 2016-07-04 | 2022-04-06 | 公益財団法人地球環境産業技術研究機構 | メタノール製造方法およびメタノール製造装置 |
| EP3556451B1 (de) * | 2018-04-20 | 2020-06-03 | Siemens Aktiengesellschaft | Verfahren zum betreiben einer reaktoranlage |
| JP6741830B2 (ja) * | 2018-08-01 | 2020-08-19 | 日本碍子株式会社 | 発電システム |
| JP6746763B2 (ja) * | 2018-08-01 | 2020-08-26 | 日本碍子株式会社 | 発電システム |
| JP7430498B2 (ja) * | 2018-08-02 | 2024-02-13 | 三菱ケミカル株式会社 | メタノールの製造方法 |
| DE202018106371U1 (de) * | 2018-11-09 | 2018-11-15 | Muw Screentec Filter- Und Präzisionstechnik Aus Metall Gmbh | Katalytischer Membranreaktor zur Durchführung chemischer Gleichgewichtsreaktionen |
| US10570071B1 (en) * | 2018-12-12 | 2020-02-25 | Saudi Arabian Oil Company | Membrane-based process for butanols production from mixed butenes |
| JP7291350B2 (ja) * | 2020-02-12 | 2023-06-15 | 国立大学法人島根大学 | 内部凝縮型反応器 |
| CN112657435B (zh) * | 2020-12-24 | 2022-05-31 | 中国人民解放军海军工程大学 | Co2加氢合成甲醇膜反应器及总熵生产率最小优化方法 |
| JP7190774B2 (ja) * | 2021-05-13 | 2022-12-16 | イーセップ株式会社 | Co2転換装置 |
| EP4194078A4 (de) * | 2021-06-08 | 2024-09-18 | NGK Insulators, Ltd. | Membranreaktor |
| WO2023112800A1 (ja) * | 2021-12-17 | 2023-06-22 | 日本碍子株式会社 | 液体燃料合成システム及び液体燃料合成方法 |
| AU2022418749B2 (en) * | 2021-12-22 | 2025-06-26 | Ngk Insulators, Ltd. | Reactor and liquid fuel synthesis method |
| CN117043129A (zh) * | 2021-12-22 | 2023-11-10 | 日本碍子株式会社 | 反应器以及液体燃料合成方法 |
| CN117242048A (zh) * | 2022-02-08 | 2023-12-15 | 日本碍子株式会社 | 反应器模块、液体燃料合成方法、分离膜模块及分离方法 |
| CN117015589B (zh) * | 2022-02-08 | 2025-08-22 | 日本碍子株式会社 | 反应器 |
| JP7637310B2 (ja) * | 2022-02-18 | 2025-02-27 | 日本碍子株式会社 | リアクタモジュール |
| CN114588844B (zh) * | 2022-03-18 | 2023-07-21 | 杭州师范大学 | 两面神中空纤维膜反应器在Suzuki-Miyaura反应中的应用及其膜反应器 |
| WO2024048673A1 (ja) * | 2022-09-01 | 2024-03-07 | 日本碍子株式会社 | 液体燃料の製造方法および液体燃料合成システム |
| CN119790122A (zh) * | 2022-09-01 | 2025-04-08 | 日本碍子株式会社 | 液体燃料的制造方法以及液体燃料合成系统 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8518575D0 (en) * | 1985-07-23 | 1985-08-29 | Bp Chem Int Ltd | Esterification process |
-
1994
- 1994-04-08 CH CH01050/94A patent/CH687004A5/de not_active IP Right Cessation
-
1995
- 1995-04-04 AU AU20655/95A patent/AU2065595A/en not_active Abandoned
- 1995-04-04 JP JP7526007A patent/JPH09511509A/ja active Pending
- 1995-04-04 EP EP95913002A patent/EP0754172A1/de not_active Withdrawn
- 1995-04-04 CN CN95192475A patent/CN1147241A/zh active Pending
- 1995-04-04 WO PCT/CH1995/000076 patent/WO1995027690A1/de not_active Ceased
- 1995-04-04 CA CA002186222A patent/CA2186222A1/en not_active Abandoned
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2974785A1 (de) * | 2014-07-14 | 2016-01-20 | Akzo Nobel Chemicals International B.V. | Verfahren zur Trennung von Methanol und Wasser aus nichtkondensierbaren Substanzen |
| EP3743202A1 (de) * | 2018-01-26 | 2020-12-02 | Nederlandse Organisatie voor toegepast- natuurwetenschappelijk Onderzoek TNO | Reaktor und verfahren zur hydrierung von kohlendioxid |
| US12257557B2 (en) | 2018-08-02 | 2025-03-25 | Mitsubishi Chemical Corporation | Bonded body, separation membrane module equipped with same, and method for producing alcohol |
| US12139450B2 (en) | 2021-05-13 | 2024-11-12 | ESEP Inc. | CO2 conversion device |
Also Published As
| Publication number | Publication date |
|---|---|
| MX9604577A (es) | 1997-11-29 |
| CN1147241A (zh) | 1997-04-09 |
| CH687004A5 (de) | 1996-08-30 |
| WO1995027690A1 (de) | 1995-10-19 |
| AU2065595A (en) | 1995-10-30 |
| JPH09511509A (ja) | 1997-11-18 |
| EP0754172A1 (de) | 1997-01-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |