CA2255646C - Process for making thermally stable metal coated polymeric monofilament or yarn - Google Patents

Process for making thermally stable metal coated polymeric monofilament or yarn Download PDF

Info

Publication number: CA2255646C
Authority: CA; Canada
Prior art keywords: monofilament; nickel; coating; surfactant; yarn
Prior art date: 1996-05-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA002255646A

Other languages

English (en)

French (fr)

Other versions

CA2255646A1 (en

Inventor

John D. Cawston

Merwin F. Hoover

Thomas F. Burke

Thomas H. Stearns

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Micro Coax Inc

Original Assignee

Micro Coax Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-05-30

Filing date

1997-05-30

Publication date

2008-04-08

1996-05-30 Priority claimed from US08/656,914 external-priority patent/US5935706A/en

1996-05-30 Priority claimed from US08/655,733 external-priority patent/US6045680A/en

1997-05-30 Application filed by Micro Coax Inc filed Critical Micro Coax Inc

1997-12-24 Publication of CA2255646A1 publication Critical patent/CA2255646A1/en

2008-04-08 Application granted granted Critical

2008-04-08 Publication of CA2255646C publication Critical patent/CA2255646C/en

2017-05-30 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

229910052751 metal Inorganic materials 0.000 title claims abstract description 47
239000002184 metal Substances 0.000 title claims abstract description 47
238000000034 method Methods 0.000 title claims description 52
230000008569 process Effects 0.000 title claims description 50
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 160
229910052759 nickel Inorganic materials 0.000 claims abstract description 79
238000000576 coating method Methods 0.000 claims abstract description 39
239000011248 coating agent Substances 0.000 claims abstract description 33
239000004094 surface-active agent Substances 0.000 claims abstract description 27
229910052802 copper Inorganic materials 0.000 claims abstract description 24
239000010949 copper Substances 0.000 claims abstract description 24
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 23
239000002253 acid Substances 0.000 claims abstract description 16
239000000243 solution Substances 0.000 claims description 32
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 27
230000003213 activating effect Effects 0.000 claims description 16
229920003235 aromatic polyamide Polymers 0.000 claims description 9
230000015556 catabolic process Effects 0.000 claims description 9
238000006731 degradation reaction Methods 0.000 claims description 9
239000004760 aramid Substances 0.000 claims description 7
125000000217 alkyl group Chemical group 0.000 claims description 5
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
229910052709 silver Inorganic materials 0.000 claims description 3
239000004332 silver Substances 0.000 claims description 3
239000004952 Polyamide Substances 0.000 claims description 2
150000001412 amines Chemical group 0.000 claims description 2
150000002148 esters Chemical class 0.000 claims description 2
UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 claims description 2
229920002647 polyamide Polymers 0.000 claims description 2
229920000728 polyester Polymers 0.000 claims description 2
150000003839 salts Chemical class 0.000 claims description 2
239000007787 solid Substances 0.000 claims description 2
239000007864 aqueous solution Substances 0.000 claims 1
238000009877 rendering Methods 0.000 claims 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 9
238000007747 plating Methods 0.000 abstract description 5
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 14
238000000151 deposition Methods 0.000 description 14
230000008021 deposition Effects 0.000 description 13
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
239000003054 catalyst Substances 0.000 description 10
239000000203 mixture Substances 0.000 description 10
238000007654 immersion Methods 0.000 description 9
239000003638 chemical reducing agent Substances 0.000 description 7
238000009713 electroplating Methods 0.000 description 7
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 7
229910052763 palladium Inorganic materials 0.000 description 7
229920000642 polymer Polymers 0.000 description 7
-1 sodium alkyl benzoates Chemical class 0.000 description 7
229910045601 alloy Inorganic materials 0.000 description 6
239000000956 alloy Substances 0.000 description 6
239000000835 fiber Substances 0.000 description 6
238000001465 metallisation Methods 0.000 description 6
229910000521 B alloy Inorganic materials 0.000 description 5
239000008367 deionised water Substances 0.000 description 5
229910021641 deionized water Inorganic materials 0.000 description 5
230000003647 oxidation Effects 0.000 description 5
238000007254 oxidation reaction Methods 0.000 description 5
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 4
QDWJUBJKEHXSMT-UHFFFAOYSA-N boranylidynenickel Chemical compound [Ni]#B QDWJUBJKEHXSMT-UHFFFAOYSA-N 0.000 description 4
229910052796 boron Inorganic materials 0.000 description 4
235000004879 dioscorea Nutrition 0.000 description 4
230000035515 penetration Effects 0.000 description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
230000004913 activation Effects 0.000 description 3
229920006231 aramid fiber Polymers 0.000 description 3
229910000085 borane Inorganic materials 0.000 description 3
RJTANRZEWTUVMA-UHFFFAOYSA-N boron;n-methylmethanamine Chemical compound [B].CNC RJTANRZEWTUVMA-UHFFFAOYSA-N 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
239000012141 concentrate Substances 0.000 description 3
238000000454 electroless metal deposition Methods 0.000 description 3
238000003860 storage Methods 0.000 description 3
UORVGPXVDQYIDP-UHFFFAOYSA-N trihydridoboron Substances B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 3
YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
229910021586 Nickel(II) chloride Inorganic materials 0.000 description 2
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
238000005299 abrasion Methods 0.000 description 2
239000012190 activator Substances 0.000 description 2
125000005907 alkyl ester group Chemical group 0.000 description 2
239000002131 composite material Substances 0.000 description 2
238000010276 construction Methods 0.000 description 2
238000010924 continuous production Methods 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
230000007797 corrosion Effects 0.000 description 2
230000000694 effects Effects 0.000 description 2
QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 2
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 2
238000012545 processing Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
238000005382 thermal cycling Methods 0.000 description 2
UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
229910052718 tin Inorganic materials 0.000 description 2
239000002759 woven fabric Substances 0.000 description 2
KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
FPJWBLGHTJEFTL-UHFFFAOYSA-N B.CNC.OC(=O)CC(O)(CC(O)=O)C(O)=O Chemical compound B.CNC.OC(=O)CC(O)(CC(O)=O)C(O)=O FPJWBLGHTJEFTL-UHFFFAOYSA-N 0.000 description 1
239000004471 Glycine Substances 0.000 description 1
229920000271 Kevlar® Polymers 0.000 description 1
229910000990 Ni alloy Inorganic materials 0.000 description 1
VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
229920002292 Nylon 6 Polymers 0.000 description 1
229920002302 Nylon 6,6 Polymers 0.000 description 1
239000004697 Polyetherimide Substances 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000004642 Polyimide Substances 0.000 description 1
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
230000001133 acceleration Effects 0.000 description 1
239000003929 acidic solution Substances 0.000 description 1
229920006397 acrylic thermoplastic Polymers 0.000 description 1
230000001464 adherent effect Effects 0.000 description 1
230000004931 aggregating effect Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
125000005599 alkyl carboxylate group Chemical group 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
238000010923 batch production Methods 0.000 description 1
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
239000004327 boric acid Substances 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
239000003518 caustics Substances 0.000 description 1
230000008859 change Effects 0.000 description 1
XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
239000011231 conductive filler Substances 0.000 description 1
150000001879 copper Chemical class 0.000 description 1
229910000365 copper sulfate Inorganic materials 0.000 description 1
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
239000013078 crystal Substances 0.000 description 1
230000001351 cycling effect Effects 0.000 description 1
238000013461 design Methods 0.000 description 1
238000007865 diluting Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000007772 electroless plating Methods 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
238000009472 formulation Methods 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
239000007789 gas Substances 0.000 description 1
RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
239000004761 kevlar Substances 0.000 description 1
230000007774 longterm Effects 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
229940098779 methanesulfonic acid Drugs 0.000 description 1
230000005012 migration Effects 0.000 description 1
238000013508 migration Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
239000002991 molded plastic Substances 0.000 description 1
229910001453 nickel ion Inorganic materials 0.000 description 1
LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
239000006174 pH buffer Substances 0.000 description 1
MUJIDPITZJWBSW-UHFFFAOYSA-N palladium(2+) Chemical compound [Pd+2] MUJIDPITZJWBSW-UHFFFAOYSA-N 0.000 description 1
229920000889 poly(m-phenylene isophthalamide) Polymers 0.000 description 1
229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
229920003366 poly(p-phenylene terephthalamide) Polymers 0.000 description 1
229920001601 polyetherimide Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920001721 polyimide Polymers 0.000 description 1
229920001343 polytetrafluoroethylene Polymers 0.000 description 1
239000004810 polytetrafluoroethylene Substances 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
150000003242 quaternary ammonium salts Chemical class 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
229910001379 sodium hypophosphite Inorganic materials 0.000 description 1
238000005476 soldering Methods 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
239000000758 substrate Substances 0.000 description 1
ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
238000012360 testing method Methods 0.000 description 1
239000011135 tin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1635—Composition of the substrate
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1635—Composition of the substrate
- C23C18/1639—Substrates other than metallic, e.g. inorganic or organic or non-conductive
- C23C18/1641—Organic substrates, e.g. resin, plastic
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1646—Characteristics of the product obtained
- C23C18/165—Multilayered product
- C23C18/1653—Two or more layers with at least one layer obtained by electroless plating and one layer obtained by electroplating
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
- C23C18/22—Roughening, e.g. by etching
- C23C18/24—Roughening, e.g. by etching using acid aqueous solutions
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1655—Process features
- C23C18/1658—Process features with two steps starting with metal deposition followed by addition of reducing agent
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
- C23C18/28—Sensitising or activating
- C23C18/30—Activating or accelerating or sensitising with palladium or other noble metal

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
General Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Textile Engineering (AREA)
Inorganic Chemistry (AREA)
Chemical Or Physical Treatment Of Fibers (AREA)
Chemically Coating (AREA)

CA002255646A 1996-05-30 1997-05-30 Process for making thermally stable metal coated polymeric monofilament or yarn Expired - Lifetime CA2255646C (en)

Applications Claiming Priority (5)

Application Number	Priority Date	Filing Date	Title
US08/656,914 US5935706A (en)	1996-05-30	1996-05-30	Thermally stable metal coated polymeric monofilament or yarn
US08/655,733 US6045680A (en)	1996-05-30	1996-05-30	Process for making thermally stable metal coated polymeric monofilament or yarn
US08/655,733		1996-05-30
US08/656,914		1996-05-30
PCT/US1997/009116 WO1997048832A2 (en)	1996-05-30	1997-05-30	Process for making thermally stable metal coated polymeric monofilament or yarn

Publications (2)

Publication Number	Publication Date
CA2255646A1 CA2255646A1 (en)	1997-12-24
CA2255646C true CA2255646C (en)	2008-04-08

Family

ID=27097017

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002255646A Expired - Lifetime CA2255646C (en)	1996-05-30	1997-05-30	Process for making thermally stable metal coated polymeric monofilament or yarn

Country Status (6)

Country	Link
EP (1)	EP0902854B1 (de)
JP (1)	JP4060363B2 (de)
CA (1)	CA2255646C (de)
DE (1)	DE69709094T2 (de)
ES (1)	ES2165628T3 (de)
WO (1)	WO1997048832A2 (de)

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EP1435407A1 (de)	2003-01-02	2004-07-07	Teijin Twaron B.V.	Mit einer leitfähigen Ausrüstung versehenes Aramidgarn
WO2006081622A1 (en) *	2005-02-03	2006-08-10	Australian Wool Innovation Limited	Fibre coating composition
GB0505822D0 (en) *	2005-03-22	2005-04-27	Conductive Inkjet Tech Ltd	Treatment of flexible web material
JP5327494B2 (ja) *	2005-11-16	2013-10-30	日立化成株式会社	無電解めっき用触媒濃縮液の製造方法とそれを用いためっき触媒付与方法
GB0614706D0 (en) *	2006-07-25	2006-09-06	Gore W L & Ass Uk	Fabric
EP2596149A2 (de) *	2010-07-23	2013-05-29	Syscom Advanced Materials	Elektrisch leitende metallbeschichtete fasern, kontinuierliches herstellungsverfahren und ihre verwendung
WO2012092505A1 (en)	2010-12-29	2012-07-05	Syscom Advanced Materials	Metal and metallized fiber hybrid wire
JP6220113B2 (ja) *	2011-02-17	2017-10-25	矢崎総業株式会社	シールドスリーブの製造方法
JP6006931B2 (ja) *	2011-11-24	2016-10-12	矢崎総業株式会社	メッキ繊維及びその製造方法
JP2014120327A (ja) *	2012-12-17	2014-06-30	Yazaki Corp	電線用導体
CN114687205A (zh) *	2022-04-19	2022-07-01	中国科学院苏州纳米技术与纳米仿生研究所	高分子纤维材料的多金属复合方法及多金属复合纤维

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GB1243481A (en) *	1969-01-22	1971-08-18	Hoechst Ag	Metallisation of plastics
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1997
- 1997-05-30 CA CA002255646A patent/CA2255646C/en not_active Expired - Lifetime
- 1997-05-30 JP JP50299398A patent/JP4060363B2/ja not_active Expired - Lifetime
- 1997-05-30 WO PCT/US1997/009116 patent/WO1997048832A2/en not_active Ceased
- 1997-05-30 DE DE69709094T patent/DE69709094T2/de not_active Expired - Lifetime
- 1997-05-30 EP EP97944281A patent/EP0902854B1/de not_active Expired - Lifetime
- 1997-05-30 ES ES97944281T patent/ES2165628T3/es not_active Expired - Lifetime

Also Published As

Publication number	Publication date
DE69709094T2 (de)	2002-07-18
JP2000512690A (ja)	2000-09-26
JP4060363B2 (ja)	2008-03-12
CA2255646A1 (en)	1997-12-24
DE69709094D1 (de)	2002-01-24
ES2165628T3 (es)	2002-03-16
WO1997048832A3 (en)	1998-02-26
EP0902854A2 (de)	1999-03-24
EP0902854B1 (de)	2001-12-12
WO1997048832A2 (en)	1997-12-24

Legal Events

Date	Code	Title	Description
2002-03-01	EEER	Examination request
2017-08-01	MKEX	Expiry	Effective date: 20170530

Publication	Publication Date	Title
US6045680A (en)	2000-04-04	Process for making thermally stable metal coated polymeric monofilament or yarn
US5935706A (en)	1999-08-10	Thermally stable metal coated polymeric monofilament or yarn
EP0673451B1 (de)	1996-10-09	Verfahren zur stromlosen metallisierung von aramidfasern
US4900618A (en)	1990-02-13	Oxidation-resistant metal coatings
CA2255646C (en)	2008-04-08	Process for making thermally stable metal coated polymeric monofilament or yarn
US5411795A (en)	1995-05-02	Electroless deposition of metal employing thermally stable carrier polymers
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EP0765413B1 (de)	1998-08-26	Verfahren zur stromlosen metallisierung von aramid-oberflächen
KR101872065B1 (ko)	2018-06-27	비전도성 플라스틱 표면의 금속화 방법
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KR930005928B1 (ko)	1993-06-29	섬유포지의 연속식 무전해 도금방법
WO2007058658A1 (en)	2007-05-24	Conductive composites