CA2265068C - Methode d'elimination d'ions du plomb - Google Patents

Methode d'elimination d'ions du plomb Download PDF

Info

Publication number: CA2265068C
Authority: CA; Canada
Prior art keywords: lead; lead ion; solution; chloride solution; nickel chloride
Prior art date: 1998-03-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA002265068A

Other languages

English (en)

Other versions

CA2265068A1 (fr

Inventor

Masaki Imamura

Takashi Sugiura

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Sumitomo Metal Mining Co Ltd

Original Assignee

Sumitomo Metal Mining Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-03-23

Filing date

1999-03-09

Publication date

2008-10-21

1998-03-23 Priority claimed from JP9411798A external-priority patent/JPH11267634A/ja

1999-03-09 Application filed by Sumitomo Metal Mining Co Ltd filed Critical Sumitomo Metal Mining Co Ltd

1999-09-23 Publication of CA2265068A1 publication Critical patent/CA2265068A1/fr

2008-10-21 Application granted granted Critical

2008-10-21 Publication of CA2265068C publication Critical patent/CA2265068C/fr

2019-03-09 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

RVPVRDXYQKGNMQ-UHFFFAOYSA-N lead(2+) Chemical compound [Pb+2] RVPVRDXYQKGNMQ-UHFFFAOYSA-N 0.000 title claims abstract description 78
238000000034 method Methods 0.000 title claims abstract description 37
239000000243 solution Substances 0.000 claims abstract description 104
239000003960 organic solvent Substances 0.000 claims abstract description 54
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 48
QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims abstract description 48
229910021586 Nickel(II) chloride Inorganic materials 0.000 claims abstract description 47
238000000605 extraction Methods 0.000 claims abstract description 35
PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 claims abstract description 23
239000002253 acid Substances 0.000 claims abstract description 18
239000002184 metal Substances 0.000 claims abstract description 12
229910052751 metal Inorganic materials 0.000 claims abstract description 12
239000003929 acidic solution Substances 0.000 claims abstract description 10
239000007864 aqueous solution Substances 0.000 abstract description 14
239000011133 lead Substances 0.000 description 49
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 36
229910052759 nickel Inorganic materials 0.000 description 17
238000005406 washing Methods 0.000 description 17
229910017052 cobalt Inorganic materials 0.000 description 16
239000010941 cobalt Substances 0.000 description 16
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 16
239000008346 aqueous phase Substances 0.000 description 15
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 13
239000012535 impurity Substances 0.000 description 13
239000002994 raw material Substances 0.000 description 13
239000011701 zinc Substances 0.000 description 9
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 7
-1 iron metals Chemical class 0.000 description 7
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 6
239000007788 liquid Substances 0.000 description 6
150000002739 metals Chemical class 0.000 description 6
229910052725 zinc Inorganic materials 0.000 description 6
125000000217 alkyl group Chemical group 0.000 description 5
HWSZZLVAJGOAAY-UHFFFAOYSA-L lead(II) chloride Chemical compound Cl[Pb]Cl HWSZZLVAJGOAAY-UHFFFAOYSA-L 0.000 description 5
239000012074 organic phase Substances 0.000 description 5
NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 4
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 4
238000007865 diluting Methods 0.000 description 4
229910000037 hydrogen sulfide Inorganic materials 0.000 description 4
150000002500 ions Chemical class 0.000 description 4
229910052742 iron Inorganic materials 0.000 description 4
150000001455 metallic ions Chemical class 0.000 description 4
238000006386 neutralization reaction Methods 0.000 description 4
230000003472 neutralizing effect Effects 0.000 description 4
238000001179 sorption measurement Methods 0.000 description 4
239000003795 chemical substances by application Substances 0.000 description 3
239000013078 crystal Substances 0.000 description 3
238000010790 dilution Methods 0.000 description 3
239000012895 dilution Substances 0.000 description 3
238000005868 electrolysis reaction Methods 0.000 description 3
238000001914 filtration Methods 0.000 description 3
239000007789 gas Substances 0.000 description 3
239000003456 ion exchange resin Substances 0.000 description 3
229920003303 ion-exchange polymer Polymers 0.000 description 3
238000000926 separation method Methods 0.000 description 3
238000000638 solvent extraction Methods 0.000 description 3
KEQXNNJHMWSZHK-UHFFFAOYSA-L 1,3,2,4$l^{2}-dioxathiaplumbetane 2,2-dioxide Chemical compound [Pb+2].[O-]S([O-])(=O)=O KEQXNNJHMWSZHK-UHFFFAOYSA-L 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
229910052924 anglesite Inorganic materials 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
229910052802 copper Inorganic materials 0.000 description 2
239000010949 copper Substances 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
230000008021 deposition Effects 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
230000001747 exhibiting effect Effects 0.000 description 2
239000007800 oxidant agent Substances 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
239000012071 phase Substances 0.000 description 2
238000012360 testing method Methods 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
229910018661 Ni(OH) Inorganic materials 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
239000003513 alkali Substances 0.000 description 1
229910001854 alkali hydroxide Inorganic materials 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000003957 anion exchange resin Substances 0.000 description 1
239000002635 aromatic organic solvent Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000003729 cation exchange resin Substances 0.000 description 1
238000000658 coextraction Methods 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000003795 desorption Methods 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
230000018109 developmental process Effects 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
238000011835 investigation Methods 0.000 description 1
150000002611 lead compounds Chemical class 0.000 description 1
239000011707 mineral Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000000203 mixture Substances 0.000 description 1
229910000008 nickel(II) carbonate Inorganic materials 0.000 description 1
ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
230000002265 prevention Effects 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
229910052979 sodium sulfide Inorganic materials 0.000 description 1
GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
150000004763 sulfides Chemical class 0.000 description 1
150000003464 sulfur compounds Chemical class 0.000 description 1
238000005987 sulfurization reaction Methods 0.000 description 1
239000002341 toxic gas Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling

Landscapes

Manufacture And Refinement Of Metals (AREA)
Extraction Or Liquid Replacement (AREA)

CA002265068A 1998-03-23 1999-03-09 Methode d'elimination d'ions du plomb Expired - Fee Related CA2265068C (fr)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
JP10-94117		1998-03-23
JP9411798A JPH11267634A (ja)	1998-03-23	1998-03-23	鉛イオンの除去方法
JP19968798		1998-06-30
JP10-199687		1998-06-30

Publications (2)

Publication Number	Publication Date
CA2265068A1 CA2265068A1 (fr)	1999-09-23
CA2265068C true CA2265068C (fr)	2008-10-21

Family

ID=26435428

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002265068A Expired - Fee Related CA2265068C (fr)	1998-03-23	1999-03-09	Methode d'elimination d'ions du plomb

Country Status (3)

Country	Link
AU (1)	AU738180B2 (fr)
CA (1)	CA2265068C (fr)
RU (1)	RU2169601C2 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
RU2501868C2 (ru) *	2012-03-30	2013-12-20	Лидия Алексеевна Воропанова	Экстракция ионов свинца из водных растворов растительными маслами
RU2600041C1 (ru) *	2015-06-25	2016-10-20	Федеральное государственное бюджетное учреждение науки Институт химии и технологии редких элементов и минерального сырья им. И.В. Тананаева Кольского научного центра Российской академии наук (ИХТРЭМС КНЦ РАН)	Способ извлечения свинца из никельсодержащего хлоридного раствора

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2462481A1 (fr) *	1979-07-30	1981-02-13	British Petroleum Co	Procede d'extraction liquide-liquide de metaux en solution aqueuse au moyen de derives organophosphores
AT387987B (de) *	1984-09-26	1989-04-10	Austria Metall	Hydrometallurgisches verfahren zur aufarbeitung von anodenschlamm aus der kupferelektrolyse und aehnlicher rohstoffe
US5084180A (en) *	1990-10-25	1992-01-28	Cominco Ltd.	Method for treating zinc-containing sulfate solution
US5135652A (en) *	1990-10-25	1992-08-04	Cominco Ltd.	Method for the solvent extraction of zinc
RU2042720C1 (ru) *	1993-03-29	1995-08-27	Всероссийский научно-исследовательский институт химической технологии	Способ извлечения труднореэкстрагируемых металлов из предварительно насыщенных ими анионитов

1999
- 1999-03-09 CA CA002265068A patent/CA2265068C/fr not_active Expired - Fee Related
- 1999-03-22 RU RU99105844/12A patent/RU2169601C2/ru not_active IP Right Cessation
- 1999-03-23 AU AU21345/99A patent/AU738180B2/en not_active Ceased

Also Published As

Publication number	Publication date
RU2169601C2 (ru)	2001-06-27
AU738180B2 (en)	2001-09-13
AU2134599A (en)	1999-10-07
CA2265068A1 (fr)	1999-09-23

Legal Events

Date	Code	Title	Description
2003-10-31	EEER	Examination request
2014-04-22	MKLA	Lapsed	Effective date: 20140311

Publication	Publication Date	Title
AU687981B2 (en)	1998-03-05	A process for the extraction and separation of nickel and/or cobalt
CA1090143A (fr)	1980-11-25	Methode pour recuperer du zinc a partir de materiaux contenant du zinc et du fer
US4288304A (en)	1981-09-08	Hydrometallurgical process for treatment of sulphur ores
US4162294A (en)	1979-07-24	Process for working up nonferrous metal hydroxide sludge waste
JP6176491B2 (ja)	2017-08-09	塩化ニッケル水溶液の脱銅方法
US3399055A (en)	1968-08-27	Separation of cobalt by liquid extraction from acid solutions
US3441372A (en)	1969-04-29	Solvent extraction process for separation of zinc from cadmium
JP6149795B2 (ja)	2017-06-21	３級アミン抽出剤による溶媒抽出方法
US4600435A (en)	1986-07-15	Solvent extraction of cobalt (II) from sulfate solutions with cobalt extractants
KR20230028221A (ko)	2023-02-28	황산코발트의 제조 방법
KR101461733B1 (ko)	2014-11-19	니켈-철 화합물로부터 효과적으로 유가금속을 회수하는 방법
BRPI0116892B1 (pt)	2015-07-14	Processo hidrometalúrgico de produção de zinco ultra-puro e seus compostos a partir de materias-primas primárias ou secundárias contendo zinco
CA2265068C (fr)	2008-10-21	Methode d'elimination d'ions du plomb
US5284633A (en)	1994-02-08	Solvent extraction of precious metals with hydroxyquinoline and stripping with acidified thiourea
US4261959A (en)	1981-04-14	Process for extracting ferric iron from an aqueous solution
JP3823307B2 (ja)	2006-09-20	高純度コバルト溶液の製造方法
JP2011208272A (ja)	2011-10-20	銅含有水溶液に含まれるコバルトの回収方法
US4314976A (en)	1982-02-09	Purification of nickel sulfate
US7959881B2 (en)	2011-06-14	Method for scrubbing an amine type extractant after stripping
JP7673528B2 (ja)	2025-05-09	硫酸コバルトの製造方法
JP7707876B2 (ja)	2025-07-15	硫酸コバルトの製造方法
JP2008196039A (ja)	2008-08-28	湿式亜鉛製錬用工程液からフッ素を除去する方法
RU2125477C1 (ru)	1999-01-27	Способ извлечения металла из его органического комплекса
JP3090142B2 (ja)	2000-09-18	塩化ニッケル溶液からの鉛イオンの除去方法
RU2293129C1 (ru)	2007-02-10	Способ извлечения кобальта из хлоридных растворов, содержащих никель и примесные металлы